Ejercicio propuesto 𝐴+𝐵⇒𝑅 ⌊𝐴⌋0=⌊𝐵⌋0 = 1,5mol/L

t(s) 1000 167 167

XA 0.75 0.5 0.75
TºC 7 7 20
QºC cm3/s 0.5 3 3

1000/0,5= (1,5∗0,75)/(−𝑟𝑎) => -ra =

𝑉/𝑄0=(𝐶𝐴0∗𝑋𝐴)/(−𝑟𝑎) 1,125/2000 => 5,6X10-4
1000/3= (1,5∗0,5)/(−𝑟𝑎) => -ra =
0,75/333,333 => 2,25X10-3
1000/3= (1,5∗0,75)/(−𝑟𝑎) => -ra =
1,125/333,333 => 3,375X10-3

𝐶𝐴=1,5(1−0,75) ⇒0,375
𝐶𝐴=𝐶𝐴0(1−𝑋𝐴) 𝐶𝐴=1,5(1−0,5) ⇒0,75
𝐶𝐴=1,5(1−0,75) ⇒0,375

VXA0 VXA1
T CA ra A 1 0
1000 0.375 0.00056 B 1 0
167 0.75 0.00225 R 0 1
167 0.375 0.003375 Ʃ 2 1
εA -0.5

LogCA Log(-ra)
-0.42596873 -3.25181197
-0.12493874 -2.64781748
-0.42596873 -2.47172622

Log(-ra)
0
-0.45 -0.4 -0.35 -0.3 -0.25 -0.2 -0.15 -0.1
-0.5
-1
-1.5
log -ra

-2
-2.5
f(x) = 0.710731884219138 x − 2.55901953820706
-3
R² = 0.0911539539554953 -3.5
log CA
 -1.5

log -r
-2
-2.5
f(x) = 0.710731884219138 x − 2.55901953820706
-3
R² = 0.0911539539554953 -3.5
log CA

l𝑜𝑔(−𝑟𝑎)=𝑙𝑜𝑔𝐾+nlogCA
 k r
0.6347