wm ¢ PRACTICE QUESTION PAPER, 2022-23 i CHEMISTRY ‘ ‘ (CODE 043) na CLASS XII : | Time Allowed : 3 Hours & 15 Minutes Maximum Marks :70 General Instructions : Read the following instructions very carefully and strictly follow them {) The question paper comprises three sections—A, B and C. Attempt all the sections. (i) All questions are compulsory. (Gi) Internal choice is given in each section. (Gv) This question paper consists ofa total of 36 questions. (*) Use of calculator is not permitted SECTION -A : 1. Read the following case study below and is = 40 mm, Molecular mass of water = 18, answer the questions that follows [— gavmole, molecular mass of ethanol is = 46 ‘When a solute is added to a pure solvent and sgnvmole, If solvent is non-volatile and non. a homogeneous solution is prepared, then electrolyte and solution is dilute and ideal properties like boiling point, freezing point The following questions are multiple choice 0 and vapour pressure etc. of pure solvent | questions. Choose the most appropriate changes. All these properties are colligative | answer properties. Colligative properites are very | (i) The colligative properties of a solution useful in daily life, like a mixture of ethylent depend on (i glycol and water is used as antifreezing | _(a) Nature of solute particles present init reagent in the radiator of vehicles. Given (0) Nature of solvent used ethanol is mixed in water and solution Mis _(c) Number of solute particles present init prepared : (@) Number of moles of solvent only In this mixture mole fraction of ethanol is | @j Coligative properties are used forthe deter- 09 molal depresion constant of wate i Ky Senae water = mol, molal depressio aaa Crs cfetanaic cial Zokag MIMS mol", molal elevation constant of water (Ky water) = 052 K kg mot! molal elevation | (©) Arrangement of molecules constant of ethanol (K, ethanol) = 1.2 K kg { (@) Melting point and boing point 5 mot, standard freezing point of water is = _ (ii) What will be the freezing point of solution 2 273K standard freezing point of ethanol is M? 1557 K, standard boiling, point of water is (2) 268.7 K i 373 K and standard boiling point of ethanol (©) 2685K is = 351.5 K, vapour pressure of pure water (€)2342K = 32.8 mm, vapour pressure of pure ethanol (@) 1509K * For Detailed Answers, Scan [Bywl a i) ) On adding water to solution M, and mole Fraction of water is 0.9. Calculate boiling point of water (a) 380.4 K (b)376.2K ()3755K (a) 354.7 K ) What will be the vapour pressure of M ? (a) 39.3 mm (©) 36.0 mm (29.5 mm (a) 288 mm Redox reaction play a vital role in chemistry ‘and biology. The values of standard potential (E) of two half-cell reactions decide w' \vay the reaction is expected to proceed. A Simple example is a Daniel cell in which zine + goes into solution and copper gets deposited jn these questions a statement of assertion followed by a statement of reason is given. | Choose the correct answer out of the } following choices (a) Assertion and reason are correct statements, and reason is the correct explanation of the assertion. (Assertion and reason are correct statements, and reason is not the correct explanation of the assertion. (c) Assertion is correct, but reason is wrong statement. (d) Assertion is wrong, but reason is correct statement Assertion : Copper liberates hydrogen from a solution of dil. HCL Reason : Hydrogen is above copper in the | reactivity series. ; Assertion: For the Daniel cell Zn |Zn?*| } [Cu?*|Cu with En application of opposite potential greater than 1.1 V results into } flow of electron from cathode to ! anode. LIV, the | ay (iw) Practice Question Paper 321 Reason: Zn is deposited at anode and Cu is deposited at cathode. Assertion : In an electrochemical cell anode and cathode are respectively negative and positive electrocds Reason: At anode oxidation takes place and at cathode reduction takes place. Assertion : Zinc displaces copper from copper sulphate solution Reason: The E” of zinc is ~0.76 V and that of copper is + 0.34 V The half-life of a reaction is the time in which the concentration of a reactant is reduced to one half of its initial concentration. It is represented as typ. For a zero order reaction, tia is directly proportional to the initial concentration of the reactants and inversely proportional to the rate constant. for a first order reaction, half-life period is constant, ie,, it is independent of initial concentration of the reacting species. The half-life of a first order equation is readily calculated from the rate constant and vice versa For zero order reaction fy. = (Rly. For first order reaction tz is independent of (Rly (Whats the unit of first order reaction? (i) From the following data for the decomposition of NO; in CCl, solution at 48°C, show that the reaction is of the first order t (mts) wo 1 2 % Vol of O, evolved 6.30 895 1140 3475 (ii) Why hydrolysis of ester follows first order Kinetics ? SECTION - B Given below is diagrammatic representation } of chemical properties of lanthanoids. Answer the following questions based on this Tm0; H, LaN LIC) —_Ln(OH)s+ Hy : (i) What happens when lanthanoids burns in carbon? i) What is the nature of oxides formed by reaction of lanthanoids ? Reverse Osmosis (RO) is a process that uses semipermeable spiral wound membranes to separate and remove dissolved solids, ‘organic, pyrogens, submicron colloidal matter, colour, nitrate and bacteria from water. Feed water is delivered under pressure through the semipermeable membrane, where water permeates the minute pores of the membrane and is delivered as purified water called permeate water Impurities in the water are concentrated in the reject stream and flushed to the drain is called reject Foie ete al322 CLASS 12 CHEMISTRY (Reference: Universal Journal Research and Technology Department of Environmental { water, These membranes are semipermeable and reject the salt ions while letting the water molecules pass. The materials used | for RO membranes are made of cellulose | acetate, polyamides and other polymers, The membrane consists of hollow-fiber, spiral- wound used for treatment; depend on the feed water composition and the operation parameters of the plant. Reverse Osmosis (RO}isa membrane based process technology used for desalination. Membrane-based seawater desalination and wastewater reuse are widely considered as promising solutions to augment water supply and alleviate water scarcity (S. Lee etal., 2010). The most common membrane processes used are the Reverse Osmosis (RO) and the Electro dialysis (ED) used for brackish water desalination, but only RO competes with distillation processes in seawater desalisation (Kalogirou, 2005). of Environmental Science and Technology, Shivaji University, Kolhapur i (Maharashtra); By: Gard R. M., Kore S.V, Kore VS., Kulkarni G.S.) Note of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices : (a) ) © (d) @ @ + In the following questions a statement Both assertion and reason are true and the reason is the correct explanation of assertion. Both assertion and reason are true and the teason is not the correct explanation of assertion Assertion is true but the reason is false, Assertion is false but reason is true. Assertion : Reverse Osmosis (RO) is a membrane based process technology used for desalination. : The membranes used are semi- permeable and reject the salt ions while letting the water molecules pass. + If a cell is placed in water, it shrinks. When isotonic solutions are } separated by semipermeable | membrane water flows of higher concentration to lower concentration, Given below is the figure of a cell. Reason Assertion Reason: Gasket 7. RIX maxXmarks Anode Anode cap Cell can Separator Cathode This cell is used is suitable for low current devices like hearing aids, watches. Following reaction occurs in this cell Zn(Hg) + 20H —+ ZnO(s) + H,0 + 2¢ HgO + H,0 + 2e—> Hg(l) + 20H" Identify the cell and name of element used as anode. (@) Mercury cell, Zn (Hg) (©) Mercury cell, HgO (© Dry cell, Zn(Hg) (@) Dry cell, HgO The number of reacting species (atoms, ions or molecules) taking part in an elementary reaction, which must collide simultaneously in order to bring about a chemical reaction is called molecularity of a reaction. What can be the maximum molecularity of a reaction? @l &)2 ©@3 (4 Aldehydes which do not have an a-hydrogen atom, undergo self oxidation and reduction (disproportionation) reaction on treatment with concentrated alkali. In this reaction, one molecule of the aldehyde is reduced to alco- hol while another is oxidised to carboxylic acid salt. C)-«x0 + Cone, NaOH — Benzaldehyde ‘What will be the product of the following ? (a) Ethyl alcohol (b) Benzyl alcohol (©) Benzene (@) Methyl alcohol Primary and secondary amines are engaged in intermolecular association due to hydrogen bonding between nitrogen of one and hydrogen of another molecule. This intermolecular association is more in primary amines than in secondary amines as there are two hydrogen atoms available for hydrogen10. 2 18. 4 15. n bond formation in it. Tertiary amines do not have intermolecular association due to the absence of hydrogen atom available for hydrogen bond formation. The correct order of boiling points of isomeric amines is @r>ras i @r<2se er >rx>r ax arer ‘The best single use of the lanthanoids is for the production of alloy steels for plates and pipes. A well known alloy is mischmetall which consists of a lanthanoid metal (~ 95%) and iron (~ 5%) and traces of S, C, Caand Al. A good deal of mischmetall is used | 1. Practice Question Paper 323 in Mg-based alloy to produce bull and ighter fin” Prom tlle, she The composition of mise. met (a) Lanthanide metals (99)% + fron ( Traces of S, C, 81, Ca and Al(5)% ) Lanthanide metals (94.95)% + fron (4)% + Traces of $, C, Si, Ca and Al (1)% (©) Lanthanide metals (95.96)% + fron (9)% + Traces of S, C, Si, Ca and Al (1)% (4) Lanthanide metals (94.95)% + fron (5)% + Traces of 8, C, Si, Ca and Al Acid anhydrides on reaction with primary amines give .. (a) Amide () Secondary amine (©) imide (d) Imine SECTION - C ‘The correct order of increasing acidic strength 18 meee (@) Phenol < Ethanol < Chloroacetic acid < Acetic acid (b) Ethanol < Phenol < Chloroacetic acid < Acetic acid (© Ethanol < Phenol < Acetic acid < Chloroacetic acid (d) Phenol < Chloroacetic acid < Acetic acid < Ethanol TUPAC name of the complex K,[Al(C,0,)s] is (@) potassiumtrioxalatoaluminium (I) (®) potassiumtrioxalatoaluminate(II) (©) potassiumtrisoxalatoaluminate(II) (d) potassiumtrioxalatoaluminate(III) Assertion : Aromatic 1° amines can be prepared by Gabriel phthalimide synthesis. Reason : Aryl halides undergo nucleo- philic substitution with anion formed by | phthalimide. Assertion : The a-hydrogen atom in carbonyl compounds is less acidic. Reason : The anion formed after the loss of ‘-hydrogen atom is resonance stabilised. Which of the following complexes are homoleptic ? (@) (Co(NH,) JC, (b) [Co(NH,),Ch]* (©) (Co(NH,),(H,0),]Cl, (4) (NiQNH;),Ch) Assertion : Ce** is used as oxidising agent in volumetric analysis. Reason : Ce‘ has the tendency to acquire +3 | Oxidation state. i beeen 18. 19. 20. 2. ‘The rate constant of a reaction is 58 x 107% s-. The order of the reaction is (a) First order (©) zero order (c) Second order (d) Third order. Which of the following option will be the limiting molar conductivity of CH,COOH if the limiting molar conductivity of CHCOONais 91S cm? mot? Limiting molar conductivity for individual ions are’ given in the following table. S.No. | Tons 1 | Ht | 2. | Nat | 3. | Kt 4 | OF 1981 | (@)350Scm*mot! —_(b) 375$ cm? mol" (©) 3905S cm*mol (4) 3404S em? mot" Assertion : Conductivity of all electrolytes decreases on dilution, Reason : On dilution number of ions per unit volume decreases. Chlorobenzene is formed by reaction of chlorine with benzene in the presence of AICI,. Which of the following species attacks the benzene ring in the reaction ? (acr mar (AIC, (a) (AIC Which one of the following binary liquid mixtures exhibits positive deviation trom Raoult’ law ? (i) Acetone + chloroform (ii) Water + nitric acid (iii) HCL + water (iv) ethanol + water324 CLASS 12 23, 24, 25, (b) 21. @) ® CHEMISTRY Low concentration of oxygen in the blood and tissues of people living at high attitude is due to, (low temperature. Gi) low atmospheric pressure Gi) high atmospheric pressure. Gv) both” low. temperature atmospheric pressure. The best reagent for converting 2-phenyl- propanamide into 2-phenylpro-panamine is, and high (a) excess Hy (b) Br; in aqueous NaOH (c) Iodine in the presence of red phosphorus (@) LiAIH, in ether (@) Ribose in RNA and deoxyribose in DNA differ in the structure around which carbon atom ? i How many peptide linkage are present in | tripeptide ? Write the reagents required in the following reactions (@) CH,—COOH —*+ CH,—cONH, (b) Arrange the following compounds in ! increasing order of acidic character Cl — CH,COOH, F—CH,—COOH, CH;— COOH (acidic character) (i) Write the electronic configuration of iron ion in the following complex ion and predict | its magnetic behaviour : {Fe(H,0).)* Write the TUPAC name of the coordination complex : [CoCl,(en),INOs oR Predict the geometry of [NiCl,]* Calculate the spin only magnetic moment of [Cu(NH,),}** ion. Analyse the given graph, drawn between concentration of reactant vs time : Concentration of reactant Predict the order of reacton. Theoretically, can the concentration of the reactant reduce to zero after infinite time ? Explain, i 29. 30. 33, fa) (b) 34, 35. (i i) i) mops(marks Caleulate the degree of dissociation a of acetic acid if its molar conductivity (1) is 39.05 S cm? mot! Given qe, = 3496 S cm? mot! and Mercooy = 40.98 em? mol An alkene ‘A’ (Mol, formula CHiq) on ozonolysis gives a mixture of two compounds ‘Band 'C. Compound B’ gives positive Fehling's test and also forms indoform on treatment with I, and NaOH. Compound 'C’ does not give Fehling’s test but forms iodoform. Identify the compounds A, B and C. Write the reaction for ozonolysis and formation of iodoform from B and C. Account for the following : pkb of aniline is methylamine. more than that of Ethylamine is soluble in water whereas aniline is not. Give the three reactions of glucose which cannot be explained by its chain structure ? OR How will you distinguish between 1° and 2° hydroxyl groups present in glucose ? Explain with reactions. Using Crystal field theory, draw energy level diagram, write electronic cofiguration of the central metal atom or ion and determine the magnetic moment value of the following : [CoP], [Co(H,0),P*, [Co(CN) I> [FeF J, [Fe(H,0),P*, [Fe(CN),I* (a) Give reasons for the following : (® Compounds of transition elements are generally coloured. (ii) MnO is basic while MnO, acidic. (©) Calculate the magnetic moment of 2 divalent ion in aqueous medium if its atomic number is 26. (a) Write the product(s) in each of the following reaction ; CjHs—O—CH, + HI—> (CHs I CHs—C—cH; —CuS23K _ | ou@ ® 0 @ @ @ ai) o) @ @ CH; —OH _Zndust_ Hs — Write the chemical equations involved in the following reactions Reimer-Tiemann reaction Friedel-Crafts alkylation of anisole oR What happens when © Phenol reacts with conc, HNO. Salicylic acid reacts with (CH,CO),0/H*. Ethyl chloride reacts with NaOCHy Write the chemical equations involved in the above reactions. Distinguish between Ethanol and Phenol Propan-2-ol and 2-methyl propan-2-ol Draw the structures of major monohalo products in each of the following reactions: | (a) (by iS (a) (e) Practice Question Paper 325 oH CH;CHy cr () Bry heat of aaa ON CV Tight CHOH HO’ .CHs CY on Ol» wise