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    41 views4 pages

    BSC Part 2 Chemistry Physical Chemistry 10206 2020

    Uploaded by

    gaurav chauhan

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    ronidtaraaysdit, hittps://www.mjpruonline.com ‘Total No.of Questions: 8] Total No, of Prd Pages: 8 Paper Code : 10206 2025 B.Sc. (Part 11) Examination, 2020 (Three-year Degree Course) (New Course) CHEMISTRY Paper-IIl (Physical Chemistry) Time: 3 Hours | [Maximum Marks 36 Note == Aempt all Sections 3 directed fetergn aH oe om ete Section-A cave-30 Long Answer Type Questions dd srt ey Attempt any three questions, fat ata eh om ‘What is heat of neutralization 2 Why heat of neutralization of STO"E 8cid and strong. hase 18 always 13.7 ket? 6 each Note Law S415 ay Tun over bttps://www.mjpruonine.com turos-ouyjuonsdfar aavayseny ronidtaraaysdit, () 2 ) w s-15 hittps://www.mjpruonline.com eerie sum er aol 7 TR FI es waa an st eerie son RT 13.7 kcal Ba? Explain Nemst heat theorem, What 1s residual ‘entropy ? we ger the a agama Cet PO eet t > Desenbe Osiwat’s difuion fa, is uses and applications. Sam é fem, we arin aq sions a a if) Denve Kirchholl's cuaton which establishes the relation between temperature and feat of reaction feats sia a ant site a other Se Explain entropy. Denve an expansion for the ‘entropy change accompanying. the isoherml expansion of an ideal gs. ett a omer fee) ret te at seer AAA a and cers & Bie a opin The melung point of sulphur #8 398 K and its Fate hest OF vapoursation is 9.3 ealfgm. Find the change in meting. pot of sulphur per atmosphere change jn pressure if the er gram sous of sand fom ate 0.752 ce and 0.1070 ve respi (2) bttps://www.mjpruontine.com turos-ouyjuonsdfar aavayseny ronidtaraaysdit, 4 «a ® @ s$-15 hittps://www.mjpruonline.com wer Haas 398K 0G eat ata at ye 307 93 calm $1 om oy argarecta afer RW SERS ais fay a feta aA orn SIR Ee a oh BF Bove ma FMA aM: 0.782cc aM 0.7070 ce €1 What is specific. molar and equivalent conductivities ? Explain the effect of dilution on these conductivities caren ere aif aa TS oa a te Ff 0.5 solution of salt surounding 6 platinum cleciodes 2.1 em ajrhand 42 aqem in area was found to offer 8 fesistance of 25 ohms Calelate the equivalent conductivity of the solution, OG & raeds 21 Sh wh gd ae BOS N fem a ey Ek oH Qaea 42 wi ahh 25 st (Ohm) wm virty Qe @) fe Ft Ewe eee ae fra) ‘What is modified Phase rule’? How is it modified for two component system > fata ween Pr Rene law Se ee Pe a ot? wy Tuner bttps://www.mjpruonine.com turos-ouyjuonsdfar aavayseny ronidtaraaysdit, o 6 @ » S15 hittps://www.mjpruonline.com ApPIY Phase rule top Busmuth-Cadmm (Bh Cd) system, BiCd a fry eee feo ar sifaGs What do you understand by 2 and by transport number Describe Hite? method for determing of anspor sumber of Ag* and NOF in a solution of AgNO, weno " wretd we A om en amet #7 AgNO, S frerm § As" sh NO; a Zaid gen Ha wei 8g es tie iy fae State and explain Kohlrausch’s law af ionie mobilities. Discus ts applications amis stata & shaman fre et Fein Af FER eran om wate are Section-B ceavs-%) Short Answer Type Questions (yaaa oe) 2 each bttps://www.mjpruonine.com turos-ouyjuonsdfar aavayseny jonudtiravanay sd hittps://www.mjpruonline.com Gi) 10 motes of an ides! gas tinal pressure of Tam at O°C WEE CXPanded reversibly under isothermal conditions 10 8 final pressure of 0.1 faim. Calculate Work done by the was. (R 1.987 cat k*! mot) Oc 10 ni ate Ae a aie ae separa wan, uf a | am #0 atm cm fer mms a Ge fg my at wT vera! (R= 1.987 cal mor) Giiy Why “Henry's law’ called “Limiting law" ? Explain i Sent faa! ahaa Fron’ eh wet 7 are aire Gis) White a short nove on ButFer solutions. cast fers 3 y afer fess foe () What is conductometi tration ” Discuss the ature, of typical curve obtained in Pondyetometsic tiraton of strong acid with a Strong: base. hips’. mjpdontine cm creer sare #8? ST oe ya OT B fees TasH ETO For a aH OME wife! (ox) Write 4 shor note 0” eutectic point and uiple point Gare fry a AIT ing we if oor ‘efi s-15 roa) bhutps://www.mjpruontine com Tun over wros-ouyjuonsdfr mays ronidtaraaysdit, hittps://www.mjpruonline.com (i) Derive the following relation (vii) Write short note ‘on activity and xt 6-8 free erasy fh egee wife: G,-G=R svi cxeficient safc ch wien apis at fire fro ‘eer Section-€ (aren) Objective Type Questions aafrs 9) 1 each Chom the correct answer wae we afm: 6) S15 Which oe ofthe following hive AH} value rot equal t0 ret at 25°C temperature and Vat pressure ? a) Fe 6) 0 © cs Ne 28C AL amen wa_T FA A Pram My a am? (3) Fe (ao > Cy Co) (@) Ne (6) heps:¢Avww.mjpruonline.com turos-ouyjuonsdfar aavayseny rondfar aauysdit, s-15 hittps://www.mjpruonline.com Gi The sition of best OF ration with temperstse ss given by eh Kirchholt's equation

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