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Ethylene Production Via Cracking of Ethane-Propane - Chemical Engineering - Page 1
Ethylene Production Via Cracking of Ethane-Propane - Chemical Engineering - Page 1
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ETHYLENE PRODUCTION VIA SEARCH...
CRACKING OF ETHANE-PROPANE
By Chemical Engineering | November 1, 2015
181
Ethylene is a critical building block for the petrochemical industry, and is among the most produced
organic compounds. It is usually produced in steam-cracking units from a range of petroleum-based
feedstocks, such as naphtha, and is used in the manufacture of several major derivatives.
THE PROCESS
The process shown in Figure 1 is a steam-cracking process for ethylene production from an ethane-
propane mixture. The process can be divided into three main parts: cracking and quenching;
compression and drying; and separation. BREAKTHROUGH TECHNOLOGIES
APPLYING CAPACITIVE DEIONIZATION FOR CRITICAL-METALS
RECOVERY
Separation. The dried cracked gas is fed to a cold box for the removal of hydrogen and light
hydrocarbons, while minimizing ethylene losses.
At this point, condensates from the chilling train are fed to a series of separation columns. In the first Chemical Engineering publishes FREE eletters that bring our original content to
column (demethanizer), methane is obtained from the top and further used in the cold box, while the our readers in an easily accessible email format about once a week.
bottom stream is fed to a second column (deethanizer).
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The top of the deethanizer, composed primarily of ethylene and ethane, is fed to an acetylene
converter and then fractionated in the C2-splitter. In this column, lights are removed from the
overheads and recycled to the compression system, while polymer-grade (PG) ethylene is drawn from
the column as a side stream. Ethane, from C2-splitter bottoms, is recycled to the cracking furnaces.
The deethanizer bottom stream is fed to a depropanizer, which distills C3 components in the
overheads. This overhead stream is catalytically hydrotreated for methyl acetylene and propadiene
removal, and then fed to the C3-splitter. In this column, lights are removed from the overheads and
recycled to the compressors, while polymer-grade (PG) propylene is drawn from the column as a side
stream. Propane from C3-splitter bottoms is recycled to the cracking furnaces. A C4+ stream is
obtained from the depropanizer bottoms.
ECONOMIC PERFORMANCE
An economic evaluation of the process was conducted based on data from the first quarter of 2015,
considering a facility with a nominal capacity of 1,700,000 ton/yr of ethylene constructed on the U.S.
Gulf Coast.
Estimated capital expenses (total fixed investment, working capital and initial expenses) to construct
the plant are about $2.37 billion, while the operating expenses are estimated at about $360 per ton of
ethylene produced.
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