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    HSG Hóa HN Vòng 2

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    s0 GIAO DYC VA DAO TAO Ki THI CHON DOI TUYEN THANH PHO HANOI DY THI HQC SINH GIOI QUOC GIA NAM HOC 2022 - 20 bE CHINE THUC 1c 2022 - 2023 Mén thi: HOA HOC Neay thi: 22 thang 10 nim 2022 ‘Thi gian lam bai: 180 phut (Bé thi gém 04 trang) Chit §: Ba thi gém 06 edu. Thi sinh Idm mdi cdu vao O1 16 gidy thi. Cho biét: H= 1; Li=7s 4; 0 = 16; F= 19; Ne = 20; Na = 23; Cl = 35,5; K = 39; Cu = 64; Rb = 85,5; Sr = 88; 1 = 127; Cs 33; Po = 211 6485 C.mol; R= 8,314 Jamol.K™ =0,082 litatmamol!.K"} 1 eV = 1,602.10"? J; 1 bar = 10° Pa; 1 atm = 1,01325 bar; Na = 6,022.10; 0.0592 4 a RT 1Ci = 3,7.10"° Bq; 0 298K: —In= ——ke i = H+Htte Cau 1 (5,0 diém) 1. Cho gin dé nang lugng biéu dién méi quan hé gitka He va cdc dang tn tai khde H, H’, Ha! (déu 6 trang thai co bin, thé £,=13,6eV hi) nhu hinh bén. a) Tinh tng nang lygng lién két gidta electron véi hat nhan trong phan tis Ho va trong ion H3 theo don vi eV. 6) Tinh ning long kém theo qu rin: He HY +h ‘Biét: Ai luc electron cia nguyén tir H la -66 ki/mol. ¢) Trong anion H’, hai electron day ln nhau Jam giam luc hit cia hat nhén mOt gia tri dign tich trong. img la o @uge goi la hing s6 chin), khi 46 nang lugng ign két gitra electron vi hat nhan duge bidu din boi céng thire sau: (Z-oF B, =-13,6% 's a Hite ABy= 154 eV Hy véi n la sé hong tir chinh va Z 1a dign tich hat nhan. Xée dinh gid tri hding s6 chin cia ion H. 2, Nhiét d6 s6i cia mot sé chit duge cho trong bang duéi day: Chat Li CHa NH ¥20 HF Ne__| [ Nhigt d9 soi co) | > 900 —164 33 100 19 246 | a) Giai thich sw bin déi nhiét 46 ‘si ctta céc chat trong bang trén. ) Vé cdu tric ba chiéu cia bo hidrua 6 cong thite thye nghiém la BHs (cht X). Nhiét €9 sdi cba X nim. trong khoang nhiét d6 sdi ca hai chit nao trong bang trén? Giai thich. 3. M@t trong nhimg vat ligu dau tign 6 trang thai rin duge sir dung trong ce thidt bi dign tir 1 dng) oxit. Ngay nay, dna) oxit con duge sit dung trong pin mat trbi 2) M@t 8 bao co s8 i tung ota tinh thé déng() oxit duge cho nhur hinh én, BG dai canh té bao 18 427,0 pm. A, B tuong img v6i ki igo ola nguyén t6 héa hoc nao? Trong mot 6 mang co so 66 ‘bao nhiéu nguyén tir dong, oxi? ') Tinh khodng cdc nbd nat gita eée nguyen th O-O, Cv-0, Cu-Cu o6 trong mang tinh thé trén. ¢) Tinh khéi lugng riéng cia tinh thé ddng() oxit (don vi g.cm*). d) Mét nhuge diém pho ‘bién cia mang tinh thé déng(1) oxit 1a su Khuyét mot so nguyén tir déng trong kkhi mang tinh thé cla oxi khong: Gi. Khi nghién ciru thinh phan mot ‘miu tinh thé khiém khuyét nhu vay A ‘Trang V/4 ~ ngudi ta thay 6 0,2% tng s6 nguyén tir dng eé trang thai oxi héa +2. Cong thie ting quat cho mau nay 1a Cuz,0. Tim x. 4, Poloni (!"Po) thude ho phong xa urani c6 chu Ky ban 1a 138,38 ngay. “Po phan ra tao thanh dong. vj bén Pb. a) Viét phuong trinh phan ung phn ra ca hat nhin*};Po. b) Tai thoi diém ban dau (t= 0) c6 mét mau poloni nguyén chat. Tai thei diém ty, ti s6 gitta sé hat nhan Po va ee : ads 210Po va s6 hat nhan Pb trong mau la 7 Tai thoi diém 0+ 415,14 ngay, ti sé gitta sé hat nhan 74¢Po va%Pb trong mau bling bao nhiéu? °) Chat thai phéng xa!°Po duge coi la an ton véi mdi traémg khi 46 phéng xa kh6ng vuot qua 0,25 pCi. Mot mau chat thai ban dau chita 0,25 mg *"PoCh duge coi 1a an toan phOng xa sa thoi gian ngén nbét la bao nhiéu ngay? Cau II (3,0 diém) 1. Mét binh chan khdng c6 thé tich 1,5 L. Thém vio binh 1 gam eacbon vat 3 gam stronti cacbonat, Nung néng binh dén 880°C cé cée phan tmg sau xay ra: StCO3) = S10 + COW wo Ce + CO293 = 2COw) 2) Khi hé dat cn biing, ap suat do duge trong binh 1a 24 kPa, Cho thong 6 nhiét dng chun cita céc chat: Chat SCO S10) CO ‘AH? (ki/mol) -1220,1 -592,0 3935 ‘S° (/K.mol) 97,0 55,5 218,8 | a) Xéc dinh hing s6 can bang Kp cia céc phan img (1), (2) (gia thiét AH®, S°khéng phy thude nbiét 46). b) Xéc dinh phan trim kh6i lugng cia ede chit trong hn hop rén khi hé cén bing. c) Git nguyén nhigt 46, tinh thé tich t6i thigu cia binh dé mét trong hai chét rin ban dau bién mat. 4) Giét nguyén nhiét 46 va lugng cacbon ban tinh khdi hrong SrCOs tdi thiéu can thém vao binh (img voi thé tich t6i thiéu cia binh) 48 khi he dat can biing, SrO 1a chat rn duy nhat c6n Iai 2. Khi dét chy 3,9 gam hoi benzen 6 25°C, 1 atm véi mot long oxi du tod ra 163400 J, san pham gdm COrm) va H201. a) Tinh nhiét tod ra khi dét chay 7,8 gam he phim gém CO2q) va H20., { ») Tinh nhigt d6 ota ngon lira benzen chay 6 4p suat | atm, 25°C trong 2 trang hep sau day: i) Trong khéng khi (chiza 20% oxi va 80% nite ve thé tich). ii) Trong oxi nguyén chat. Biét: C2 (COz khi) = 26,80 + 42,3. 10°T (J/mol.K); C8 (Nz khi) = 27,10 + 6,00.10°T (J/mol.K); AH? bay hoi cia nude long & 373 K li 40,66 (ki/mol); C2 cia muse long 1a 75,3 (I/mol-K); CQ cia nude Khi 1a 30,2 + 1,00.10°T (J/mol-K). i benzen bing oxi dir trong bom nhiét Iuong ké 6 25°C, san Cau THT (2,0 diem) é xée dinh d6 tan ca cde mudi gdm 2 dién cyc duge ndi voi nhau bi khé tan ngubdi ta thurdmg ding Ki thugt dign hoa hoc. Mét pin dign héa Jing clu mudi, Dign cye thir nhdt gdm mét thanh Zn nhiing trong dung Trang 2/4 dich Zn(NOs)2 0,200 M, dign cy thir hai gdm mét thanh Ag nhing trong dung dich AgNOs 0,100 M. Méi dung dich o6 thé tich 1,00 L tai 25°C. 1. Viét so dé pin vA phan tmg xay ra trén timg dign eye, phan tmg xy ra trong pin khi pin hoat dong. 2. Tinh site dign dong cba 3, Tinh dign huang phéng thich trong qué trink pin phéng dign (gi sir pin phéng dia hod todn va luong Zn du). 4, Trong m6t thi nghigm khéc, KCl duge thém vao dung dich AgNOs & dign eve thir hai. Su tgo than két tha AgCl lim thay ddi site dign dng cia pin. Sau Khi thém KCl, ste dign d6ng eta pin 1a 1,04 V va [K*] = 0,300 M. Tinh tich s6 tan cua AgCl. Biét: E. 0,76 V; E°., . = + 0,80 V. Coi hoat 4 cia mot chat tan ciing bing nng dé cita chat d6. "naa NaN Cau IV (3,0 diém) Ton iodua phan tng véi hidro peoxit trong dung dich axit theo phuong trinh sau: 21-(ag) + H20x(aq) + 2H"(aq) —* lag) + 24200) Phan img durge thy hign 6 18,8°C véi si c6 mt cha natrithiosunfa, tinh b6t va hén hop CHsCOOH, NaOH 4é diéu chinh pH. Tét od cde thanh phan ngoai trir hidro peoxit da doe tron tnrdc, cudi cing méi thém dung dich hidro peoxit va khdi dng dng hd bam gid. Sau khi thém hidro peoxit, dung dich van Khéng mau cho dén khi dét nhién chuyén sang mau xanh tim, tai thoi diém nay ding hd bam gid ghi dugc la tgidy. Thyc nghiém thu duge céc dit ligu sau day: py | CHSCOOH1,0M | NaOH 1,0M | K10.20 ™M | 42020,20M | NazS2030,020M | H20 | ¢ (mL) (mL) (mL) (mL) (mL) (mL) |_(s) 1 2,0 1,0 2,0 2,0 1,0 2,0 | 68,2 2, 4.0 1,0 2,0 2,0 1,0 0 | 68.9 3 2,0 1,0 40 2,0 1,0 0 [33,2 4 2,0 1,0 2,0 40 1,0 0 | 329 1. Gidi thich tai sao dung dich d6t ngét chuyén sang mau xenh tim sau mot Khodng thii gian nhat dinh? 2, Tinh néng 46 H* ban dau trong thi nghiém 1, 2 va gidi thich tai sao ndng d6 Ht thay ddi khéng dang ké trong qué trinh cae phan tmg xay ra? Biét: Ks cha CHsCOOH [a 1,8.10° 3, Phuong trinh dng hoe ola phan img e6 dang v= k.'J".[H202)"(H'P, trong 46 m,n va p 18 ede sb nguyén, Tinh gid tri cla m, n, p va k trong c4c didu kign thye nghiém nay. cho phan img gitta ion iodua va hidro peoxit trong dung dich axit duge d8 xuat nhu sau: 4.Cod (1) H2O2(ag) + H'(ag) = H302"(aq) nhanh (2) HsO2"(aq) + F(ag) —> HOl(ag) + F200 chim (3) HOI(ag) + H"(aq) == FROT"(ag) nhanh (4) HOT (aq) + (aq) —> b(ag) + H20 nhanh Co ché dé xudt nay ¢6 phit hop v6i két qua thu duge & ¥ (3) khong? Cau V (4,0 diém) 1. Quinin (CosH24N202) duge sir dung dé didu tri bénh sét rét. a) DG tan eda quinin trong nude 1d 1,6.10° M. Tinh pH cia dung dich quinin bio hoa. ») Do it tan trong made nén ngudi ta phai chuyén quinin thank quinin hidro clorua (CooH2sN2O2.H1Cl). Nong d6 cé kha nang khang sét rét cia quinin hidro clorua la 1,5%. Tinh pH cia dung dich quinin hidro clorua 1,5%, d= 1 g.mL" ‘Biér: Quinin la mot bazo 2 nde c6 pK,,= 5,1 va pK,.=9,7. Trang 3/4 2. Trong méi trudmg nude, ion Pb?" tao két tia PbO 1a mot oxit ludng tinh. Trong moi trudng axit chi c6 dang Pb** t6n tai. Khi ting din pH, PbO va Pb(OH), duge tao thanh v6i lugng dang ké. Can bling cha yéy cia céc dang chi trong méi truémg nude dugt cho dudi day: PDO (r) + #20 (1) == Pb** (aq) + 20H" (aq) Kap =8,0.107 PbO (1) + 320 (1) == PO(OH)s (aq) +Hs0" (aq) Ka=1,0.10"* t a) Néuban dau ndng dé cla Pb** trong dung dich la 1.10 M thi pH 48 PbO bit ddu két tha la bao nhiéu? ') Bit du tr gid tri pH tinh duge trong cfu (a), kh ting pH dé mot git nbdt dinh, két tha lai tan ra. Tai pH bing bao nhiéu thi két tha tan hoan toin? ) Vé mat li thuyét, kha nang hoa tan 16i thigu cha PbO dat duge khi pH 18 9,4. Tinh tng nong 46 cae dang tn tai cla chi trong dung dich & iu kign nay. 4) Tinh khoang gid tri pH dé tng néng d6 eée dang tén tai cia chi trong dung dich khéng vuot qué 103M. Cau VI (3,0 diém) Ba hop chat ion Au, A2, As déu chita hai nguyén t6 trong 46 06 nguyén 16 kim loai X. Ca ba hop chat déu 4 phan hiiy cho sin phim chita it nhét mot don chit. Trong c6ng thite héa hoe cia mot chét, X déu chiém 25% s8 nguyén tt. Khi cho 14,6 gam hidroxit eia X téc dung véi ozon thu duge 17,62 gam Ar. X’ [a kim loai nhe nhét cling nhém véi X. X’ phan img trye tiép véi nito & digu kién thuong cho hop chat Bs’. Bs cfing la hgp chat cua X’ véi nito, tng sé nguyén tir trong cOng thite hoa hoc cia Bs va Bs’ bang nhau. Bs va As 6 ciing anion. Az chita 25,86% X theo kh6i long, Cée hop chat ion D1 va Dz 6 cing anion voi As, én nhiét déng hoc hon Aa, méi phan tir chi chia mot Ioai nguyén tir hidro. D1 chita 39,33% cacbon; 9,9% hidro va 11,47% nito. D2 kh6ng chia cacbon. Phan hay hoan ton 1,65m gam D2 6 digu kign thich hop thu duge sén pham chira m gam mét chat rin. 1. Xée dinh X, cdc hgp chat Au, A2, As, D1, Dz va viét phurong trinh héa hoc cia cde phan img. 2. Viét cong thite héa hgc cia ba hop chat cé thanh phan dinh tinh giéng véi Au. 3, Bigu dién cdu tric cde anion trong Au, Az va As. be ooo Ht Cain b6 coi thi khong gi “ nich gi thém. , 86 béo danh: Ho, tén va chit ki ciia cén b6 coi thi s6 1: Ho, tén va chit ki cita can bé coi thi ‘Trang 4/4 sO GIAO DUC VA DAO TAO Ki THI CHON DOI TUYEN THANH PHO HANOL DY THI HQC SINH GIOI QUOC GIA NAM HQC 2022 — 2023 Mén thi: HOA HOC Nea thi: 23/10/2022 ‘Thdi gian lam bai: 180 phat (Dé thi gdm 04 trang) pr CHINH THUC §: Dé thi gdm 06 cau. Thi sinh lam mdi edu vao 01 (6, gidy thi. Ciie chit va ki higu vid tit: Ac: acetyl; AIBN: 2,2'-az0 bisisobutyronitrile; Bn: benzyl; Boo: tert- butoxycarbonyl; Bu: butyl; Bu: fert-butyl; mCPBA: meta chloroperbenzoic acid; Cy: cyclohexyl; DMAP: N,N-4-dimethylaminopyridine; DMP: Dess - Martin periodinane; DMSO: dimethylsulfoxide; Et: ethyl; HMPA: hexamethylphosphoramide; LDA: lithium diisopropylamide; Me: methyl; Mes: mesityl; Ph: phenyl; Pyr. pyridine; TBAF: tetra-n-butylammonium fluoride; TBDPS: ‘-butyldiphenylsilyl; THF: tetrahydrofuran; TMS: trimethylsilyl; Ts: tosyl. Chit Cho biét: H= 1; C= 12;N= 14; 0 = 16; P= 31; C1= 35,5; Mn = 55; Fe= 56; Ni = 58; Co = 59; Cu= 64. Cau I (4,0 diém) 1. Cho céc chit Ai va A2c6 edu tao nhu hinh bén, Biéu HH di€n cdu tric c&c déng phan lap thé cé thé c6 cia At, Aa. He ‘CHO NO Chi ra méi quan hé gitta céc ding phan lgp thé 46 OH (enantiomer, dia). 2. Ngudi ta xéc dinh duge céc gid tri pKa cia cyclopentadiene, indene, florene trong pha khi va trong ODO dung moi DMSO nu sau (khdng theo thirty): 18,0; 20,1; Qo CO 22,6; 343,9; 344,6; 347,8. Hay ghép céc gid trj pKa voi cyclopentadiene_indene florene cac chat trong méi diéu kién twong img va giai thich. 3. a) Gidi thich sy khac nhau vé nhiét d6 s6i cla cdc chat sau: O (ya yo so 4 8, (81°C) B, (108%) B, (150°C) B. (206°C) b) Sap xép cde chat sau theo chiéu gidm din dé tan trong muse va gidi thich: 5 y S: OOH COOH cy COOH NO» CHyNH, — CH:NHy & o ce cs 4. Nguyén tit nitrogen trong phan tir amine e6 thé dong vai trd nhu m6t trung tam bat déi (vi du phan tir D). Tuy nhién tén thy té, hop chat D khong quang hoat do lun tn tai céin bing chuyén héa gitta hai dang d6i quang cia n6, Sur chuyén héa gitta 2 dang 46i quang c6 hang rao néng lugng Ea > 0. “wo Me, le N twa —owh o et et a) Sir dung hinh anh orbital nguyén tir m6 ta co ché chuyén héa gitka hai dang d6i quang cia D. ) So sanh hang rio nang Iuong (E,) cla sy chuyén héa gitta hai dang (tuong ty nh chat D) cita cdc cap chit sau: 1 Dye Ce mf g D NSte ny ches ey Ey Trang 1/4 chu Ht (2,0 dim) Dé nuit eo ché cho ee chuyén hoa sau +4) NaN, — rh DD Wo Ke) o ) é on oi 6, HN 2 eo ye ie Rohe od Mes an 8h a ie A wk . Presa oN ‘ a 2 Ph MeO0OC. ‘NH Na ome etecene P ope WN ed eT Clu IIL (3,0 adm) i 1. Cho hydrocarbon A (CioHis) tham gia vao ofe chuyén ha sav ee SOs ¢ Lattin onchiC. 78° E:0NA D2E © NaBHs,CHsOH (Crottse) Zn, CHgCOOH EtOH Biét D va E 14 ding phan cia A. Ozone phan D 138i xirly hn hop sén phdm voi dung dich H202/OH chi thu duge m6t sén phdm, cbn néu tién hanh trong tur v6i E sé thu duge 2 sin phim. Xéc dink cdu tao cba cdc chat tir A dén E. 2, Xir ly hop chat spiro[3,3}heptan-1-one yGi TSNHNH? thu duge hop chat F c6 bd khung carbon khong thay d8i. Cho F téc dung voi NaH tao thanh mudi G v6i higu suat 100%. Nbigt phan muéi G sinh ra cfu tir trung gian kém bén [H], du tir nay c6 thé chuyén hoa thinh cic hydrocarbon X1, X2, X3, Xa khie nhaw co ccang dng thite phan tt CrHio; trong 46 Xava Xs dddu chita lién két d6i ¢6 4 nhém thé. Dudi tae dung cua mhigt d6, Xs va Xa déu 6 thé xay ra phan img mé vong (tuong tr nhu cyclobutene), sinh ra cae sin pham Xs va Xe tuong (mg. 2) Vidt cng thite edu tgo eta spiro[3,3]heptan-I-one vaF, G, [H]. b) Viét cong thite du tao va gidi thich sy tao thanh Xa, X2, Xa, Xa, Xs, Xo. Cau TV (4,0 diém) 1. Cho so dé tang hop duge chat anatoxin-a nhu sau: 4) SOC 1)80¢,0, E6N © coon MEOH A “DMAP. a, Sa01CHaMlasr n, CESCOOM ay 1) P10n. Ho N 3) LAMY cyy,0,n 2, TEDPSC! THE S 2) TsCl BN oo imidazole 3) Pa(OH)2, Hz oraops —UOMP_.,, “UTA. 1.08 PPh % {BU0K 4 srHasNOe N Hous 4 itOADAHO.THE a, PME. Avo aor * 72) NaBH, ‘MeOH 2yMestl_ tes ne Ona anatoxin-a tcl Pow a) Cho biét cfu tric ciia cdc chat tir Ar dén Ato. ) Giai thich sy tgo thinh Av tir Ae, Ag tir As, Trang 2/4 2, Khi dun néng chat X xay ra chuyén héa sau: Quy trinh tng hgp terpene zizaene ¢6 bude db tign cting die hwyén hoa cb Xo én: -0 4s’. p, KOH pe, DIDAME Be Nal, By : > HPAES i087 Crt? hele ens Bs Bits —- By SOPBAL By 18u0K Be WaHPO,, NatPOs ‘HOCH:CHLOH HMPA HOS . By HER CyathazO2 Bu 4) Zizaene o6 ba nigu nguyen 8 carbon bit di, o6 bao nhiew dng phan tap mer ve cha mie dng phan lap thé cla zizaene. ip) Xac dinh céu tao cfc chit tir Br dén Biz, c) Giai thich sir tao thanh Ba tir chat ban da ya Bs tir Bs cau V G0 a8 1. Cho so a chuyén hoa sau: e-ti_p-—*—¢ EL Beatin) Glu = Glutamic acid, €6 cfu trie nbu sau: 3 HOC. 00H 4 2 ws \ NM | _»—H- « 2H F (CtinN0d) pide ing C ong 12 mot amino acid cé trong tu ain; DEF, J 06 be 3 ang ngung ti D vad 1a oe ding phan cdu tao. ‘Kac dinh edu tric cde chit tir A dén J trong so 46 tren. 7 pechdt X e6 cong tite phn tt CirHlesNOnn. Thy phan X nh’ enzyme B-slicosidase thu due chat Y (Céltia0s,thude day D) vi nit Z, Cho X phin img véi Mel/Ag20 thu sau dé sin phém doe thy Zhan trong moi ung acid, thw GUE Ge any yrony--metnypliine2-

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