a rented wi va wees sie 4. pete uni ct cm oe cee named Oe Oe ae me eer depres ° rane tnomer of MNES, Cle O97 eww aoc oi eT eens ed aon omic etn of FP E ati sively sant ti) Elcrn gin ena ©% 7 (210. tent prot in won <3 a> —— om “Qos + m0 10 ‘qi Beplain cassication of aldehydes, (©% 12) 0.12. tdenf A and Bin the following reaction. fO% 29) qct.se Regt 8 ratte © 9.23. calcuate emf ofthe following cll at 25°. Wot net ell reaction antes cara Coa Oos nc OTN aoa 9.4. ro ie ofideal gn expanded nother and eerily om 20118 LG K. Calculate work done (R=8.314 JK? mol"), (Ch 4) ene > Attempt any EIGHT: Lad 0.15, Define pyrometaiungy. (8) What isthe ation of and metal on elements of eroup 172(0% 7) Write clasication of polymers on the bass f intermolecular forces (Ch 25) 0.37, Define Green Chemistry. Write two advantages of nanotechnology, (Ch: 16) 0.18. Define and explain peptide bond. Writ the structure or name of monomer of natural rubber. (© 14) 16. \Write chemical reaction when hot copper is treated with = 19. (6) Vapours of 1° (primary alcohol (i) Vapours of 2 eecondary) alcohol : (i) Vapours of 3 (tertiary) leohol, (Oh 13) 0.20. Deine coordination complex. Write wo applications of coordination 2.21, Explain classification of alloys, Write two uses of KMnO,, (Ch. 8)022, Wateaotecn pnd. a9) 108) 0.29, Find Ain the lwingeacion: (on 12) W CH,COONe» WOK —+ A+ Bw 1 encvo ai» Rocco 080-9 tun B>on0 + MOR SH anati nce tT a a qa w of ae renee et zg eee aes jan = ces om shire | non (K,) of water. (Ch. 3) Pai or spanner a es sevens eu. rive standard electrode potential = ii js —0.76 V. Calculate its: electrode 2a 2 oe to ower te freezing Pol cron oins et oma ba sure TS TT "yond kg ml! aed oar ase = 256 6011) oo 4 (9.18. Define entropy. a eo equim constant forthe flaming reaction 298K. INHlgg * COng —> NH,WCOONH aug * #290) = 13.6 kJ mol", (Ch. 4) (cn. 2) (Given Ky ‘Attempt any EIGHT: Cobbs standard energy change at 298K 0.26. What are mer, one and two dimensional nanoscale structures? (X18) _ civ two uses of alloys: What are ferromagnetic substances? (Ch. 7) 0.17, Define inner transition element 0.18. Define organometallic compound. Write the product in the fllowing reaction ‘and sodium metal in presence of dry ether. UW) Bromobenzene reacts with methyl bromide iy) Chlorobenzene reacts with sodium metal in presence of dry ether, (Ch. 10) 0.19. Explain: Phetiols are acid while alcohol is neutral. Write two uses of ether. (Ch. 11) (0.20. Define reverse osmosis. Name the four cllgative properties that are oftently used for determination | of molecular mass. (Ch. 2) 221. Explain the typeof biles with example. Give two applications of buffer solutions. (Ch. 3) 2.22, What are pseudo frat ondéeaction? (Ch. 6) Give the imitations of VB. (Ch. 9)eines Popes 3 a aN Wiieecuenaven ey peat sau it) Total volds in 0.7 mot “e ate fou anny colourtess white 1 hat are post netinoid elements? (Ch. #) =, Distinguish between ethyta ie ms mine, diethylamine and teth Bereta oonaeca ethyl amine using Minaberas reagent. (Oh. 13) ie example. (Ch. 12) | atcempt any THREE: j section} vy. What are crystal defects and point detec pifferentiate between order and a smolecularity a (on) (cro) 9.28 Define isobar process and enthalpy RR Caaat wori doe wn 0.8 molto CO ampremedIntermaly ad feveray 398 m1 0920, Draw neat abled diagram often accutaor:Wete 4 ous aptone emt ssi (8 op, Whats onde? Wee names oft oxen (Oh 7 Dena carbohydrates. (Ch. 14) Papeete vestateer peers i) got: Define metallure. (Ch. 8) metntion the type of hybridization in[CaNH),* complex. (&% 9) Convert: thy iodide o met socyanide (Ch. 10) (Nee ald (Ethane aio ey alcool. (Oh 12) aChemistry Papers So = a coe une rane de as oe Dunop 18 clements are wnreactive, Cive reason. (A. oe maw i structure of complex PUNH,),Chy (oh 9 0:12. Write 4. Define peptide bond and explain basicity of amines. % 13) @ peptide bond and expla rt eee stionic crystals and covalent network creystals. (Ch 1) of 1TD.37 V, Egg = +0.799 V. (Ch. 8) eas. 2.16. Write cell reaction ad calculate Ey May IME? cag TAB's s01 Bas Fae tion of buffer solution. (OR. 3) (0.17. Define buffer solution. Give classification of| ates it. binerendate berwcen order and molecularty. What isan elementary reaction? (Ch. 6) Q:19. What are oxides? Give classification of oxdes. (© 7) What fs oxidation state of manganese in (i) Ma0, (#) MnO,-? Define lanthanoid contraction. pi State any two uses of actinoids. (Ch. 8} @.21. Define ligand. Wete four postulates of Werner's Theory. (Ch. 9 (9.22. Wate IUPAC names of; (@)CH,-CH, 9) OH —(@)H#,C-O-CH, _(@h 14) du on No, Pah ee Jnegar 2 (Ch. 12) 0.28. Identity A and B in the reaction: CH,C=N + CH,MgClqae-» A T°". B. What is vinegar 0.24, What are colligative properties ? Name two collgative properties. (Ch. 2) How will you convert ethyl bromide to ethylamine? (Ch. 10) (2.25. What do you mean by reversible process? State the features of reversible process. (Ch. 2) 0.26, Define : (a) Vuleanization (b) Enzymes (e} Biodegradable polymers. (Ch. 18 and 14) Ce m > Attempt any THREE: 2.27, A weak monobasic acid is 0.05% dissociated in 0,02 M solution. Calculate dissociation constant of the aci. Explain and show that AH = AU‘ An,RT. (Ch. 3) (2-28. Explain any three principles of Green Chemistry. Define coordination compounds. (Ch. 16 and 9) 2.29. The halflife of first order reaction is 990 s. Ifthe initial concentration of reactant is 0.08 mot dm: what concentration would remain after 35 min? Define metallurgy and roasting. (Ch. 6 and 8) (Ch. 10) 2.80. Define and explain SN? reaction with suitable example. (Ch. 3, 9 and 7) 2.1, Define molar conductivity and homoleptic complexes, Draw structure of H,SO, and CIP.ELcarrg On ge mark e0ch sins gg tee mart sh o4 —— one : anol ae A ° none Smee tis aga with its alphabet al face pet : ene 4 (7 rorecn mane ie Bike MAX ibe considered Spine pra ten tis eo ry in wal amr? in a) 13:5 * 10 Oy tan th et rn 2 io" wiges io nares on eee tape h Maeno (odin rare Se a aor an ciiecece og 1008) (a -70%8 rotons e mm snmtinctn cementin goo tomes (OR rau Tear iy secon : aaleay (y tanthanoa are characte ty era ing $= ser (Peed tase ma cm tr) Resril on tilt with zn st Ges —_——— Pe (erovcsherane )tene (e) bene (a) benzene (i) Vnegarconiana (en : (aera (fri (o) cei acid (2) propionie acid (ei) ntti amine, (33) i wr wr ar as 6) Moon ae bres (R13) (a semisyntiee 0) polyamide (0 ptveter (a) callaose 69 NICAD storage cells made wp of. tectodes. (0% 5) (a eke 1b) Mercury (o) Cadmium (a) Wickel-Cadmiumn « 2:2. Answer the following: (0) The solubility oN, gas in water at 25°C and 1 bar is 6.85 « 10-* mol L-. ine yaw eat fet pecs tt a (iy Caleate ehe mound the standard enthalpy formation of methanol ~ 238.9 kJ mol"!. (ch. 4) a 4 a ba fa (Wat outa? fon 9 1) What icin carn na? 10) (9) What are aromatie ketone? (19 1) Date tcp. fo 4i) What is nanochemistry? (ch, 16) ‘ga. Wate the SIUCHIFE f grom, Ga AcomPoundl made ofelernegs te cube: ACOMA OF D are we ne cant? SO pefine coMlantive os Properties Nay 96. Balin the Per oF ectochems tian pe Spec g.12. Name the dlstingwishing tes for ditencg nn 2! ee (933. Calculate ByaH Of the H,0 from given a a4 Explain hydrlysia of sucrose, fen i) INE 1° amine from 2° and 3° > Attempt any EIGHT: (0.15. What is erystal defect? Explain vacancy defect and fect and interstitial defect, (CM 1 {q.16. Define osmotic pressure (x). Prove m, = M2ET ey, a defect. (2%. 1) (9.17. What is common ion effect? Explain it. (eh 3 18. Define open system, CCaleulate heat evolved 4,H° for combustion of 13 gm of acetylene (C3H,) giver 3 Given: CzHlag + FOnyy—F 2COny +H, 0p 581° =~ 1900 13. (Om 4) 0.19. Calculate the voltage of cell: $A4jq1827° (9.02 m9 AB“ o.01 wy AB at 25°C Given: Bs, = 0.136 V, B%4,7 0.8 V. (Ch 8) 0.20. Define first order reaction ‘Show that for first order reaction half-life of reaction is (0.21. Name tw elotropes of sulphur, Writ ote on anomalous behaviour f @FBEn = MP 16. (0.22. Define: (a) Minerals (b) Metallurgy. Compounds formed by transition metals ar colored, Give reson: C™ 9) 0.28. What is EAN? How is EAN calculated? Find [EAN of Co in Co[NH,}_°. (Ch 91 Q.24, Explain reaction of 1° and alcohol with oxidising agent chromie ankyiide (Cr03) Give two uses of phenol. (Ch. 11) Q.25. Write a note on Cannizzaro reaction. (ch. 12) jysaccharides and polypeptides: (0.26. Differentiate between Pols independent of initial concentration. (% 6) (canurram’s xu-chemistry Paper: noe Saareeie ion of alkyt halide using thionyl chloride (SOCL): 1 ofthe sotution. (Ch. 3) What isthe advantage ofthis method ? [OH"] concentration is 2.87 « 10 in the sotution of NaOH. Caleulate PE Write a note on refining of iron. (ch. 8) sant volume, '50,Cl, at the cons Following data were obtained during the frst ordcr decomposition of SO.Clz es Calculate the rate constant ofthe reaction. (Ch 6) Define system and surroundings. (C”. 4) Differentiate between cast iron and wrought iron. (Ch 8) Define racemic mixture and write uses of chlorine. (Ch. 10) Leserereeeryo PP aa ees ces Oe ears HH, + Cr gon 9 pee: iow san CHCI OIC are presen 7 Serb tn PS a ny four conventions to write ween owe ao of (cal gas is expanded fs 2b oe ne expanded nthermaly are reversiy 90K Carte work dove fen TEN tom 204 qua Ment Band write srctre of th inthe ain gg B fen ta) eopropy alcohol —g-— A — (9st Wate the lasiication of ethers. (en 14) Wate note on commercial manufacturing of & Fe Ig of benzaldehyde, Explain side chain chlorination of toluene 913, Wie the name of any two instruments used in analyse of nanomaterials, What information they provide for characterization of nanomaterials? eh. 16) {Q14 What are polyamide polymers? Name two important polyamide polymers Eh. 14) Se aa > Attempt any EIGHT: (018. Define van't Hof factor. Calculate it for(i) NaCl and (i) Na,S0y. (ER. (946 Define: (a) Degree of dissociation (a (b) Lewis acids (e) Lewis bases. (Ch. 3) (017, Explain Bravais lattices of cubic system. (Ch. 1) (18. State and explain Hess's law. Give application of Hess's law. (Ch. 4) (949, Write cell representation and calculate the value of equilibrium constant (K) for given reaction. Nig +248" —» NP*+ 20a, (Given: At 25°C, E%, ~-0.25 Vand E°,, 0.799). (ch 8) (020, Explain collision theory of bimolecular reaction, (Ch. 6) (221. What are proteins? Writ the classification of proteins (Ch. 14) cl 022, Give IUPAC name of CH,-C-CHO. Explain why carboxylic acids have higher boiling point than those of aldehydes, ketones, ethers of comparable molar masses. (Ch. 12) 923. How anisole is obtained from phenol? Give the reaction for preparation of diethyl ether from alcohol, (Eh. 23)sa with example 4 wi rancda form coloured compound 26. Wry do lant +18 10° fr CH,C00 } + action of acetic acid. (Given ys dt againat constant Pressure of 3.0 ty > ascenp ny TREE oi. os funn gn npn thermal fom 12 Shmtwoul be the hae a rdnaon omplx en Maia orang Ong > 280g Rte = HOMO ane MO a nan igetiemncttecemiats? a What is overall order of reaction and order with respect 19 central metal fon 18 4. (6m » coordination number of central : Give the characteristic features of nanopaticles. (CX 16) 0.30. Distinguish between SN! and SN* reaction, (Gh 10) Define double salt. (om. 9) Q.31. Define homopolymer. (oh. 25) What do you mean by denaturation of protein? (Ch 14) Predict the product ‘Ain the following reaction cH,-c-NH, + 4m) HAH, car fen 13) a MM Ther Write the structure of zone. (Ch. 7) <ry eater ar ae b ee eee monary 10 we the © orrect answer along are of stn core tn abphabet of th =0.34Vis____— (a) 134V 0.1 Setect and write the correct ante (@ The "on concentration of () 301 fa) 3010" 10" (9 Tre eto cll PY Hg IH ig OOP ml he Pt 134 (%) 0.34. aoa (un Maxima colony ef mutpairie —_—_—= MT Ae (a) four (©) cight eS (in whichscrics given below ll elements are radionctve? (9) cin {aj tanthenoide———() Actinods (c) Chalcorent (a) d block elements {tn pherole, carbon atom attached to-OH group (hydro group) undersers. oma (9) =p () sp? (6) 9p? (a) dep* tr The carboxylic acid present in lemon is = (08 22) (a) acetic acid (0) formic aid (6) lactic aia {e) citric acid (vin Fora reaction at 300 K enthalpy is 138 kl and entropy change is 115.5 K-1. The free enersy change in reaction is en 4) (a) 130563, (1035 {6110.35 kd (4) 1308 es i) The hybridisation of trogen in primary amine i + (Oh 13) (sp () sp? (6) sp (4) spd (a) Starch is a polymer of. eh 14) (@) a-amino acids (b) a-D glucose (c) B-D glucose (4) a-D galactose |) Viscose rayon is a type of_____ polymer. (Ch. 18) naka {(b) semisynthetic {€) synthetic (4) animal 0.2. Answer the following: (9 What are ferromagnetic substances? (Ch 21) (i) What is degre of dissociation of monobasic acd ifit is 0.008 percent dissociated. (Ch. 3) (ii) Define chemical kinetics, (Ch. 6) (iv) Write the name of most electronegative element of group 17. (Ch. 7) (9) What is co-ordination complex? (Ch. 9) (vi) What is Green Chemistry? (Ch. 16) pe (96) (ce(cot) WS ase tan ne a an ee TI Pm vse) eye PLL 6c NPI! OP Se ene oe oy, se ana ae WHEE 120-1 uo) men wre mane sop iad heer seeO° en nae ee tee... ete cnet a en ie ba fe she 27. What i ero order reaction’? Give one example f 270 ore 8 the he area 25 Casa ok or ink 7a 110%. RD 29. Writes note on Kate eaten. mH gees ox (20. Te toa nmr oa elements 9. Determine whether Peramagnct ea ne rom benzophenone, O12) 2.28 rte he complete reaction fr the preparation fens le ofeach. (Oh 25) £22: What are homopaymers and copaymers: Give one examph vial 212. Derive the relationship berween salty and solublity predict oo (0-74 What i the ation of fuming H,80, and methyl chloride in presence ‘on chlorobensene? (eh 10) > Attempt any BioHT: 2:15. Write the reactions for: 1) Acety chloride on thanamine i} Ethanoy chloride on dcthylamine Ul) Accty chloride on teethylamine. (Cm 413) 2.16. Write a note on characteris features of nanoparticles. (Ch 16) San Qiaciss the mechani of alkaline hydrolysis ofmety! bromide ER 10) 2:18, Convert the folowing ) Ethanal to ethanol il) Chiorobensene to phenol (44) lodomethane to phenol. (Ch 11) San, ie not on lathanods.Deice metallurgy, (8