wees | App: Chen-Z- Come 26-05-16 Q.P. Code : 28592 (2. Hours) | Total Marks, NB. : (1) Question No. 1 is compulsory. (2) Answer any three questions from remaining five question: (3) Figure to the right indicates full marks. (4) Atomic weights : Ca = 40, Mg = 24, Cl = 35.5, $= 32,4 1. Attempt any five from the following : “ 15 C (a) Write two balanced equations to describe Cepres that occur when hard water is boiled. x (b) Give reasons to explain why natural eds vultanization. (c) Give the preparation and uses of si 8 (a) Give the number of phases in the follow?ng system (any three) (i) Saturated solution of jbrium fhe conditions in which greases are used? canqét be reshaped and reused, Give (iv) Ice == Watene reasons. water cai following salts per litre. Cal 2mg; Mg(HCO,), = 75mg; (ji) Mixture of rhombic clinic: sulphur (©) What is grease 2 WI (g) Calculate ty@ CODMof an.#ffluent sample if 25c.c. of the effluent Cas mg: MgSO, = 24.0mg, (iii) Mixture of O, an () — Thermosetting sample ¢ .3 ¢.ccf 0.001M K,C:,0, for oxidation. 2. (a) Calculate @: oftlime and soda required for softening 50,000L of 6 O.Omg. fain the following terms : _fondensed Phase rule (ii). Triple point a (c) "What are carbon nanotubes ? Describe the laser method of preparation of 4 CNT. FW-Con.11225-16. TURN OVERy - (a) (b) (c) f@ (b) (c) - (a) ft) (c) (b) QP. Code : 28592 2 (3) Discuss the mechanism of Extreme pressure lubrication. (ii) Name any four additives in blended oil and give two examples of each. Describe a moulding method suitable for thermoplastic resins, Discuss the limitations of phase rule. ( Give the preparation, properties and uses of (any two) (i) PMMA (fi) Silicone rubber (iii) B 2 Write brief notes on any two methods “—O) pigipal water with reactions. 1.5g of an oil was saponified with 50m! a solution. After refluxing the mixture required 7.5ml of 0, for neutfalisation. Find the saponification value of oil. Draw a neat diagram of rotary 08 and mention the reactions in eac! Or. of portland cement at ate the factors affecting glass What is glass transition temp transition temperature ? Whabis ifS\sighificaice 2 The hardness of 10, pei water sample was completely removed by passing it through a z€olite Softener The softener then required 400litres of sodium chloride i ‘ontaitiing 100g/L of NaCl for regeneration. Calculate the har 'e wate? sample. (i) Discu; leap ern and regeneration reactions in the lon-exchange proc Reverse Osmosis method of purification of water. i) 2 at of the following constituents in the compounding of plastis (wo) two} Flash and Fire point (ii), "Acid value (ili) Viscosity and viscosity Index ( sticiser (ii) Lubricants (iii) Stabiliser. . ind explain the significance of the following properties of lubricants FW-Con.11225-16.