. . Chemistry Model Question Papers 12" Standard Revision Test Note: i) Draw diagrams and write equations whenever necessary PARTI Note: i) Answer all the questions 10 x1=10 ii) Choose the most appropriate answer from given four alternatives and write the option code and corresponding answer 1. Inthe reaction sequence, Ethene ““S A 4 Bthane-1,2—diol. A and X respectively are a) Chloroethane and NaOH b) ethanol and HSO, PYF chloroethan -L-ol and NaHCO; d) ethanol and H: O 2. Inthe reaction Ethanol “3 x MA} yy SOWIE 7 oe grig a) Ethane AS Bthoxyethane c) Ethylsulphide 4) Ethanol 3. Isopropyl benzene on air oxidation in the presence of dilute acid gives a) CoHsCOOH ——_b) CsHsCOCHy ©) CsHsCOCcHs, 2) CoHsOH 4, HO-CH:-CH:-OH on heating with periodic acid gives a) COs b) Glyoxal PMethanal a) Methanoie acid 5. Williamsdn synthesis of preparing dimethyl ether is a/an/ a) Sy1 reactions AF Sk2 reaction ¢) Electrophilic addition 4) electrophilic substitution 6. One mole of an organi compound (A) with the formula CsH4O reacts completely with two moles of HI to form X and Y. When Y is boiled with aqueous alkali it forms Z. 2 ‘answers the iodoform test. The compound (A) is ) Propan—2-ol —b) propan -1-ol, Milos ethane garthoxy chane1. Glycerol has: a) 3 primary alcoholic group ‘b) 3 secondary alcoholic group ©) 1 primary alcohol and 2 secondary alcoholic groups _8Fpkimary alcoholic groups and 1 secondary alcoholic group 8. The oxidizing agent which completes the oxidation of alcohols with the formation of aldehyde and ketone is bcc b) NazCr207 ©) KxCr07 d) KMnOx 9. Which of the following on reaction with phenyl magnesium bromide to give secondary alcohol? AKPropionicacid bY Acetaldehyde _9 Benzaldehyde 4) Acetone 10. Among the following, the more acidic is A Pnitro Phono! b) Ethanol ©) Cresols 4) phenol PART-II Answer any 5 of the following questions. Sx2 Li. 12. 13. 14. 15. 16. Answer any 5 of the following questions. 17. 18. 19. Write a note on Hydroboration reaction. Explain Swern oxidation. Give the preparation of glycerol. Write three tests to differentiate phenols and alcohols. Mention the uses of diethyl ether. Is it possible to oxidize t-butyl alcohol using acidified potassium dichromate to form carbonyl compound? PART-II 5x3=15 Explain Saytzeff's rule with an example. Convert glycol into a) acetaldehyde b) dinitroglycol Complete the following reactions An dust, CH3C/ AlCl Acid KMnO 4 i) HOH SS A BS oc ip Aniote SMO TA 4 SC yg Sas Ww21, 22. Give any three preparing methods of ethers. Describe briefly the Victor-Mayer's test to differentiate primary, secondary and tertiary alcohols. Predict the product A, B, X and Y in the following sequence of reaction Butan-2-ol 3 Ma ther Cu/ 573K PART- IV Answer the following questions. 23, 24, 25. 26. 3x5=15 a) Illustrate the electrophillic substitution reaction of anisole, 'b) How will you convert benzyl alcohol to benzoic acid How will you prepare a) 1,4 benzoquinone form phenol __) Acrolein from glycerol ©) Ethanol from diethyl ether d) Acetone from isopropyl alcohol e) Phenol from anisole a) Explain the oxidation reactions of giycerol b) Write short notes on Dow's process. a) Compound (A) of molecular formula CcH;0 gives violet colour with neutral ferric chloride. Compound (A) reacts with CO; under 400K /4-7 bar followed by hydrolysis gives compound (B). Also compound (A) reacts with phthalic anhydride in the presence of Con HzO, to gives compound (C). Identify (A),(B) and (C).Explain the reactions