AIEEE 2007 Organic Minor Test #2

Ques 1 -12 [1.5 marks] / Ques 13-25 [3 marks] / Ques 26-50 x 4.5 marks -ve marks are one third Test duration 1 hour

1.The pKa of acetylaslicyclic acid (aspirin) is 3.5.The pH of gastric juice in human stomach is about 2-3 and pH in the small intestine is about 8.Aspirin will be [1] Unionized in the small intestine and in the stomach. [2] completely ionized in the stomach and almost unionized in the small intestine. [3] Ionized in the stomach and almost unionized in the small intestine. [4] Ionized in the small intestine and almost unionized in the stomach. 2.What is the product of the following reaction :

[1] PhCOCH2-CH2COOEt [2] PhCOCH2CH2COOH [3]

[4]

3.What is A in the following reaction ?

[1]

[2]

[3]

[4]

4.What is product of the following reaction

[1] C6H5CH=CHCOOH

[2] [3] [4] C6H5CH=CHCOOCH2 5.The most suitable conformation for E2 reaction is :

[1]

[2]

[3]

[4]

6.Aromatic compound among the following is

[1]

[2]

[3] [4] All of these

7.In the reaction [1] [2]

is

[3]

[4]

8.The major product in the reaction

[1]

[2]

[3]

[4]

9.The correct order of solvolysis in the following alkyl halide is [1] CH2Cl > CH2 = CH - CH2Cl > CH3CH2CH2Cl [2] CH2 = CH-CH2 Cl > CH2Cl CH3CH2CH2Cl [3] CH3CH2CH2Cl > CH2 = CH - CH2Cl > CH2Cl [4] CH2 = CH - CH2Cl > CH3CH2CH2Cl > CH2Cl 10.The compound having maximum enol content [1] CH3CH2CHO [2] CH3COCH3 [3] CH3CHO [4] CH3COCH2COCH3 11.The stability of carbenes is [1]Singlet carbene > Triplet carbene [2]Singlet carbene = Triplet carbene [3]Singlet carbene < Triplet carbene [4]Cannot be predicted 12.The end product [C] in the reaction

[1]

[2]

[3]

[4]

13.The reaction of [1] [3] [2] [4] All of these

gives,

14.m-Chlorobenzaldehyde acid on reaction with conc.KOH gives [1] Potassium m-chlorobenzoate and m-hydroxybenzaaldehyde [2] m-hydroxybenzaldehyde and m-chlorobenzyl alcohol [3] m-chlorobenzyl alcohol and m-hydroxy benzyl alcohol [4] Potassium m-chlorobenzoate and m-chlorobenzyl alcohol 15.The products of the reaction HCHO and PhCHO in the presence of concentrated base are : [1] CH3OH + PhCOO- [2] HCOO- + PhCH2OH [3] PhCOOCH3 [4] HOOCCH2Ph 16.In Cannizzaro's reaction,the intermediate that will be the best hydride donor is [1] [2]

[3]

[4]

17.Which one is resistance toward decarboxylation [1] CH3-CH=CH-COOH [2] RCOCH2COOH

[3]

[4] None of these

18. B in the above sequence of reaction is [1] [3] [2] [4]

19.Predict the product 'P'

[1] [2] [3] [4] 20.Of the following orders of reactivity of Cl with AgNO3 which one is correct ? [1] CH2 = CHCH2Cl > CH3CH2CH2Cl > CH3CH = CHCl

[2] CH2 = CHCH2Cl > CH3CH2CH2Cl < CH3CH = CHCl [3] CH2 = CHCH2Cl < CH3CH2CH2Cl > CH3CH = CHCl [4] CH2 = CHCH2Cl < CH3CH2CH2Cl < CH3CH = CHCl 21.Of the following statement regarding the addition of HBr to butadiene,which one is not correct ? [1] 1,2 -Adduct is the rate-controlled product [2] 1,4 -Adduct is the thermodynamically controlled product [3] 1,2 -Adduct can be changed to 1,4 -Adduct on increasing temperature [4] 1,4 -Adduct can be changed to 1,2 -Adduct on decreasing temperature 22.Enolisation is maximum in case of : [1] [2]

[3]

[4]

23.

X is :

[1] [2] [3] [4]

24. structure :

X and Y (Y is alcohol ,D is deuterium)X and Y will have

[1]

[2]

[3]

[4] None is correct

25.

. Product ?A formed can :

[1] give iodoform test [2] further react with CH3MgBr/H3O+ to give t-butyl alcohol [3] be obtained by the ozonolysis of 2,3-dimethyl-2-butene [4] All correct

26. [1] [2]

, A is:

[3]

[4]

27. [1] A forms oximes [2] A shows tautomerism [3] A shows iodoform test [4] All true

A is formed by Claisen condensation,which is/are true about A ?

28. Select the correct statement : [1] alkyl C-O bond breaks and O18 is contained in acid [2] alkyl C-O bond breaks and O18 is contained in alcohol [3] acyl C-O bond breaks and O18 is contained in acid [4] acyl C-O bond breaks and O18 is contained in alcohol 29.An optically active compound 'X' has molecular formula C4H8O3.It evolves CO2 with aq.NaHCO3.'X' reacts with LiAlH4 to give an achiral compound.'X' is : s

[1] [3]

[2] [4]

30.Consider following compounds :

Which of the above compounds reacts with NaHCO3 giving CO3 : [1] I,II and III [2] I and III [3] II and III [4] I and II 31. concentration in one litre water is 10-7 mole then degree of ionisation of water will be [1] 1.8 x 10-7 % [2] 0.8 x 10-9 % [3] 3.6 x 10-9 % [4] 3.6 x 10-7 % 32.The Ionisation constant of Acetic acid is 1.8 x 10-5 then at which concentration the dissociation will be 2% [1] 1 M [2] 0.045 M [3] 0.018 M [4] .45 M 33.In aqueous solution the will behave as [1] Base [2] Acid [3] neutral [4] Acid & Base both 34.The pH of which of the following solution will be maximum [1] 0.01 M NaOH [2] 0.02 M CH3COONa [3] 0.01 M NaHCO3 [4] .10 M H2SO4 35.At the time of excitement and fear the speed of breathing increases so conc. of CO2 in the blood decreases then pH of the blood will [1] Decrease [2] Increase [3] No change [4] seven 36.if the pH of pure water is 6.63 then the temperatureof water will be [1] 298 K [2] < 298 K [3] > 298 K [4] Cannot Predict 37.when 0.5 M HNO3 and 0.2 N NaOH solution are mixed then,the heat liberated will be

[1] 13.7 K. Cal [3] 13.7 x 0.2 K. Cal

[2] 0.5 x 13.7 K. Cal [4] 27.2 K. Cal

38.The mol ten NaCl is good conductor of electricity due to [1] Free electrons [2] Free atoms [3] Free Ions [4] Hydrated Ions 39.The conductance of which of the following solution will be maximum if the conc.of all solutions is same [1] K4[Fe(CN)6] [2] K3[Fe(CN)6] [3] FeSO4.Cr2(SO4)3.24 H2O [4] Na[Ag(CN)2] 40.What will be the pH of 0.1 M potassium formate solution if the degree of hydrolysis=10% [1] 2 [2] 12 [3] 11 [4] 1 41.When conc. is same then the increasing order of compounds will be : [1] H2S < H2SO4 < NaCl < NaNO2 [2] NaNO2 < NaCl < H2S < H2SO4 [3] NaCl < NaNO2 < H2S < H2SO4 [4] H2S < NaNO2 < NaCl < H2SO4 42.The number of [1] 10-7 [2] 55.4 x 1023 x 6 in one litre water will be [2] 10-7 x 55.4 [4] 6 x 1023 x 10-7 Ion conc. for the solution of following

43.The Hydrolysis of anion of which of the following acid does not occurs [1] Acetic acid [2] Nitric Acid [3] Ethane diolic acid [4] methane nitrile 44.Select the law that corrosponds to data for the reaction A + B [A] [B] Initial rate 0.012 0.035 0.1 0.024 0.070 0.8 0.024 0.035 0.1 0.012 0.070 0.8 products.

[1] Rate = K [B]3

[2] Rate= K[A] [B]2

[3] Rate= K [A]2>[B]1 [4] Rate= [A]2[B]2

45.How much faster would a reaction proceed at 25oC then at 0oC if the activation energy is 62.3 kJ [1] 5 times [2] 2 times [3] 16 times [4] 10 times 46.A reaction x2 + y2 x2 x + y2 x +y [1] 0 [3] 1.5 [2] 1 [4] 2 2xy follows the following mechanism x + x (fast) xy + y (slow) xy (fast).The order of overall reaction is-

47.The enzyme catalysed reactions are faster than metal catalysed reaction because its activation energy is[1] lower than that of metal catalysed reaction [2] higher than that of metal catalysed reaction [3] same as that of metal catalysed reaction. [4] N.O.T. 48.99% of a first order reaction is completed in 32 min.when will 99.9% of the reaction complete[1] 46 min. [2] 48 min. [3] 50 min. [4] 32 min. 49.conc. of A is 1.0 M.After 1 min. it becomes 0.9982 M.What is the rate of reaction-(unit = mole 1-1 min-1)[1] 3.6 x 10-4 [2] 6.6 x 10-5 [3] 4.2 x 10-6 [4] 1.8 x 10-3 50.It takes 160 min. for the completion of 80% of the reaction,which is of zero order.What is the rate constant[ [ 16 1 2 1/160 0 ] ] 1/100 [ 1/ [ 3 20 4 Answers ]0 ] Que 0 0 0 0 0 0 0 0 0 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 7

stio n Ans wer Que stio n Ans wer

1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 4 4 3 2 2 4 3 1 1 4 3 1 4 4 2 4 4 4 2 1 3 2 1 1 4 2 2 2 2 3 3 3 3 3 3 3 3 3 3 4 4 4 4 4 4 4 4 4 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 2 4 4 3 1 1 2 2 1 2 3 3 3 3 2 2 4 2 1 4 3 1 2 4 3