(SEC – A) Answer the multiple choice questions (18 ×1=18)

1. The specific conductance of 0.1 M HNO3 is 6.3×10-2 Ω-1cm-1. The molar conductance of the
solution is _____

a) 100 Ω-1cm2 b) 511 Ω-1cm2 c) 630 Ω-1cm2 d) 6300 Ω-1cm2

Choose the correct option of assertion and reason

a) Both A and R are correct R is the correct explanation of A

b) Both A and R correct but, R is not the correct explanation of A

c) A is correct R is incorrect

d) R is correct A is incorrect

2. Assertion (A): Conductivity always increases with decrease in concentration for strong and
weak electrolytes.

Reason (R): Number of ions per unit volume decrease on dilution

3. Assertion (A): Kolrausch law helps to find the molar conductivity of waek electrolyte at
infinite dilution.

Reason (R): Molar conductivity of weak electrolyte at infinite can’t be determined

experimentally.

4. Which of the metals will reduce zinc oxide to zinc?

a) Pb b) Fe c) Mg d) Cu

5. E°cell of the reaction is Zn(S) + Cu 2+(aq) Zn 2+(aq) + Cu(S). If E°Zn2+/Zn = -0.76;

E°Cu2+/Cu = 0.34.

a) 0.34 V b) -0.76 V c) 1.10 V d) -1.10 V

(SEC-B) Answer any SEVEN questions. Each part contain 2 marks (7 ×2=14)

19. Draw the structure of product when propanal is treated with zinc amalgam and Concentrated
hydrochloric acid?

20. (i)Define conductivity of electrolytic solution? Write the S.I unit?

(ii) Why does the conductivity of a solution decreases with dilution?

21. Given the standard electrode potential ? K+/K = -2.93 V; Ag+/Ag = 0.80 V; Hg+/Hg = 0.79 V;
Mg2+/Mg = -2.37; Cr3+/Cr= 0.74 V. Arrange these metal in their increases order of reducing power?

22. Arrange the compounds in their increasing order of reactivity towards nucleophilic addition reaction

Benzaldehyde, P-tolualdehyde, P-Nitrobenzaldehyde, acetophenone.

(OR)

22. Draw structure of semicarbazone of cyclopentane?

23. Arrange the following complex ion in the increase order of crystal field splitting energy.

Δ° [CrCl6]3- [Cr(CN)6]
3-
[Cr(NH3)6]
3-

24. (i)Why do transition elements show variable oxidation state ?

(ii) Name the element that show +3 oxidation state.

25. How is the vapour pressure of solvent affected when a non-volatile solute is dissolved in it?

SEC-C) This section contain 5 question with internal choice two questions. The following
question are short answer type and carry 3 marks each. (5×3=15)

26. Define an ideal solution and write one of its characterstics?

27. 24. Give the IUPAC name of following compound (i) K4[Fe(CN) 6] (ii)[Co(NH3)5(NO2)]Cl2