Total number of pages—16 25T CHEM 2015 CHEMISTRY (Theory) Full Marks : 70 Pass Marks : 21 Time : Three hours General Instructions : w@ a) (i ay o wi) All questions are compulsory. Marks for each question are indicated against it. Question number 1 consists of eight very short answer type questions and carry 1 mark each. Question numbers 2 to 11 are short answer type questions and carry 2 marks each, Question numbers 12 to 20 are also short answer type questions and carry 3 marks each Question numbers 21 to 23 are long answer type questions and carry 5 marks each Contd.1 Answer the following : 1x8=8 was fratcarea Gea fray 2 {) Which point defect lowers the density of a crystal ? cant fay athe mee oe wy a AP (ii) Liguid-liquid sols are known as (Fill in the blank) CaaS ETA oA sa AH (i697 HB At a) (iti) Which metal foils are used for wrapping chocolates ? HRC Age ATS DECAD GARETT ace qeelt Fal VI? fiv) In the first transition series of elements, which element shows highest oxidation state ? aay AER CHa Glerae Sete coach] Gee aeRis Sd GTR CHYART? (vy) Write the formula for the co-ordination compound : tetracarbonylnickel (0). GRR Ra Few (0), GA SEATS weIpEslA egfoa| [VR PTE EPA 28} | 251 CHEM [5] Contd.8. Explain why : (Any Tivo) +12 (i) Phenols are acidic in nature. (ii) Ethers have lower boiling points than alcohols. (iii) Propan-2-ol is more basic than propan-I-ol. apenas (Ric@rea Abr) (iy Fomor expe wife (ii) SERA Ba Cee SH) (iii) Steer ef eR-] wets lee wT | 9. Complete the following reactions 141-2 wae frat faerie af sal ¢ (o) CH,~CH,-O-CH,+H[—> 7 + 2 int “* (not in excess) 10. Answer the following : fa) Arrange in increasinig order of basic strength : CH,NH,, (CH,), NH, (CH), (in aqueous solution) 251 CHEM. [6](b) Ky value of aniline is Jess than that of methyl amine, Why ? @. () HEE Cig Sears Ace § CH,NH,, (CH,), NH, (CH,),N (wat 8) feide aBenete afm A, ae ei ae ll Give the formulae of 4, B, C and D in the following reactions — ficare Rferuraiae 4, B.C Bre Da aes fr — wo (ip) (6) (a) (b) thanolie Yew fini CH,CH, ~ cl —temiesece, gi, g efBICL NaNO, {HO} CyHyNO, SS, ¢ A> D 141-2 For one mole close packed spheres’ how many octahedral and tetrahedral voids are present ? 1 Atoms of element ¥ form hep lattice and those of element ¥ form occupy 3rd of the tetrahedral voids. Determine te formula of the compound formed by the elements ¥ and ¥? a ee ws Fag age ches Rom wtih oie vytad zg afore Tar Xe cieatgeace hep Gite wie Gta Ya ogra DENT aH Fed Rete wea) aX ee Ye ara afew Toca aww Fe ee Rela sa 251 CHEM [7] Contd.@) fa) @) What is an ideal solution 2 1 Urea [(WHz)2CO] forms an idcal solution in water. Calculate the vapour pressure of an aqueous solution containing 5% by mass of urea at 298K. At 298K, vapour pressure of water is 23-75mm Ig. 2 wind wat fee BAEZ [(VH)CO] ate wl wa sida Tes | Sa Borer 5% BSI viet wee za GF BOAR Bi} WKS seAT FeAl) VK A ? on ) CH, = CH, + Br, +»? ( 2X€O>—cl+2Na Sess? 251 CHEM [9] Contd.18. What are carbohydrates ? Give the general formula of carbohydrates. Why are polysaccharides called non-sugars ? [4141-3 arPerereitan Fee arteeowbeares aera Gre fral| aroeRRoLaAE Gala CTA ea a? Or /2A1, What are proteins ? Give one example each of fibrous and globular proteins. ea Be wes afta ore aa aia sewers ecarbite Carear fret: 19. (a) What are polymers ? 1 ae st fee (b) Name the monomers of polythene, Teflon and Nylon-6, 6 Yxd=2, ieee, Cea cre APER-6, 64 wT EBS AT FTA | Or / Beet, (a) What is vuleanisation of rubber ? 2 wees weenie fe (b) What is the role of sulphur on vulcanisation of rubber ? 1 ee STAB oas Yorwiag Efisy ir 25ST CHEM 10]20. Give one example each of the following : (a) A non-narcotic analgesic (b) An artificial sweeter. (c) A food preservative chemical was fier acoaca acoibice Saree firm & (a) i FoRea Feame (b) a1 fas rarer: fo) 6] Amy HSE ARS Te Or / BAI, (@ Mention one advantage of the use of synthetic detergent dver soap. CLAMS ATA Gentes gages Boratto: bp Gard Fal (ii) What is tincture of iodine ? Mention one use of tincture of iodine. focors cra crates fey Bane aby eee Vere a1 21. Answer either (a) or (b) : (a) eter (by Riccercan aiora Sex Frat: (a) (i) Define order of a reaction. fafsex abr arae Ae Fre (ii) For the reaction & — P, write the differential rate law. RP fafearbes ae weavers 24 Ae Fra 251 CHEM Cy 1x3=3, L+142 Coritd.fii) (iv) eo) @ i) 251 CHEM Yor the reaction R—>P, the rate becomes 4 times faster when the concentration of the reactant is doubled at a given temperature. What is the order of the reaction ? 2 ot BS STIS Rp Reade cafe Re yao eal ar, Rae ara 4 oe Ge ote efaearey cee wre Pek ar Define activation energy of a reaction. 1 Rien a0 afer sfx He Fat Or / 8°, Show that the integrated rate Jaw for the fisst order reaction R— P is ~ {Rho fal, 2-303 jeg) aan wae fea R> Pa Ae CARRIE Fee ee — 2:308 jog Lele i trl A first order reaction takes 40 minutes for 20% decomposition. Calculate its half life period 2 atin aaa feral cb 20% Reckre 2421 40 BRD aratert at (tre OSTA AY FA | (12)22. Answer either (a) and (bj, or (c) and (d). (a) th) o Give reasons for the following : (i) Nitrogen exhibits +5 oxidation state. But it does not form pentahalide. fii) Sulphur vapour is paramagnetic. (iti) Moist chlorine is powerful bleaching agent. wate flratcarat reel woifal ¢ (TRY CAA +5 Gre SERA crys, fee E cote de CA | Gi) Sere ae BARAT | (iii) fre we Ga Fees Complete the following reactions — ware fra Riga ayR Fey STs @ P,+3NaOH +3H,0 —>? (ii) 2F,(g)+24,0() —>? Or / Bl, Describe the manufacture of ammonia by Haber's process with favourable conditions. 3 wap ASS cers refers aaa ey Geol ayes AN 251 CHEM (13) Contd.23, 25T CHEM (a) (@ (b) v Draw the structures of the following molecules : sare fan aerated meafes foe wie W XeFy (ii) HsPO3 How will you bring about the follow ‘ing conversions ? (Give chemical equations only) 2 (Toluene to benzaldehyde, (ii) Ethanenitrile to ethanoic acid, eas Gian aRerenRS conte Rate (rent amit ABs FAR) « OQ Re cnenfeeitury (i) Rewaieaas Boa he alewta | Identify 4, B, C and D in the following reactions : 2 ep ae ot Scr ties FER? wv O +CH,Coci tach , p ai) 2 €-cHo Le. ox (14]() Name one biodegradable polymer 68 Tareas RH FECA AP FST 251 CHEM {15}