Edexcel

A-Level
CHEMISTRY
Formulae, Equations & Amount of Substance
Moles, Equations and Qualitative

Time allowed
896 minutes

QUESTION PAPER

Score Percentage

/747 %
4.1 | CELL BIOLOGY | QUESTION PAPER 1 1
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A piece of iron, mass about 3 g, was placed in a glass beaker. 50 cm3 of

0.5 mol dm ²3 aqueous copper sulphate solution was measured using a
measuring cylinder and added to the beaker. The temperature of the
mixture was measured immediately before the addition and every minute
afterwards until no further change took place.

Fe + CuSO4 FeSO 4 + Cu

Timing before 1 min 2 mins 3 mins 4 mins 5 mins

addition
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Alcohol = ethanol, C 2H5OH

Molar Mass (C2H5OH) = 46.0 g mol ±1
Volume of water in beaker = 200 cm 3
Ú mass of water in beaker = 200 g
Weighings
Spirit lamp + ethanol before combustion =
198.76 g
Spirit lamp + ethanol after combustion = 197.68
g
Temperatures
Water before heating = 19.5 C
Water after heating = 38.1 C
Specific heat capacity of water = 4.18 J g ±1 C±1

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My calculated value of the enthalpy of combustion was

numerically much less than the data
book value. The
reasons for my low value include:
1 heat losses to the surrounding air;
2 when I re-checked the mass of the spirit lamp and
ethanol after combustion, I noticed that it had lost
mass even when it was not being used;
3 a black solid which formed on the base of the
beaker.

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