ISON A e/oae ROO NCO SIT Ne STRUCTURAL ISOMERISM @ LINKAGE IsomerIsM This type of isomerism is shown by the coordination compounds having ambidentate ligands. [Co(NHs}s(NO2)]CI and [Co(NHs)s(ONO)]CI or pentammine nitrito - N Cobalt (III) chloride and pentaammine nitrito - O'Cobalt (III) chloride. @ coorDINnaTION ISOMERISM RSS eg ane RGU ue cn nee Las complexes of different metal ions present in a complex. [cr(NHs)c] [CO(CN)c] and [CO(NHs}e] [Cr{(CN)é] © IONISATION ISOMERISM BCU RUC uC U Ce UR Ua Coe [Co(NHs)s) SOsJBr and (Co(NH3)sBr]SOs @ sovvate IsoMERISM BSS COUR USM US une oe Re LC SRC CULT Ra ae UC ae eo ae [Co(H20)s]Cls, [Co(H20)«Cl2]CI.2H20, [Co(H20)sCls].3H20 @ POLYMERIZATION ISOMERISM Pee mR a Rtg (eee Cao kcLy PO Cu UU ee [Co(NHs)s(NOz)s] TUL Ey euler | [Co(NH3)s(NO2)][Co(NHs)2(NO2)«]2 Leo n=2 hrSTEREOISOMERISM @ SEOMETRICAL ISOMERISM eee Ce COs SOREL RUSS econ ee LE CLC ce COMPLEXES WITH COORDINATION NUMBER 4 OR eee eu cet Use Cue Seca Lee ecu ea ue Om ua isomerism. The two X ligands may be arranged adjacent to each other in a cis isomer or Ce RR ue ne Or ore ees) OC CL ee Me CuO CUn Sul Ronee UC CRI us [Pt(NH3)(Br)(CI)(Py)] rye Re ee See enon UTR UR RUC Ra che a ere Pr uli Ci 1@ opticat IsoMERISM Ree eo a OC UU BR PCR CLC Mn Coe COLUSA eet nec n ius Tetrahedral complexes with formula [M(A8)2] show optical isomers and Pree eee td Cen esa ne asColours shown by Metals in various Generally white light is a oxidation states mix of two opposite colors on colour wheel. These two TITANIUM (Ti) colour are called component colours. MANGANESE (Mn) h s* Tore! —_, 2 ‘i= light IRON (Fe Why we are seeing Blue, Why Not Red or Green ? Let's see what happens inside the solution containing co-ordination @ e compound when we cast a white light on it In presence of Tee el = aa Pr (cr White light of This electron nee energy E a absorbs the wavelength nearial a 3 Is pessed wavelength & oe eo e@ through the and gets excited solution to d.? orbital. ‘ { COBALT NICKEL COPPER If the wavelength, that got absorbed by solution represents e the colour in colour wheel, then its complinentary colour, blue will be seen by vieweroO J ----~> dy dy dx dey dt D-orbitals of metal ions when there are no-surrounding ligands Orbital Energy ! 1 1 1 ' 1 1 1 1 ! dey? de @ - Ligand axis. So the repulsion between dry dye dix has more energy than d,® = Sat tea at tec He a eres >Cl >SCN >S° >Br >I >a, In Octahedral complex, Ligands approach along x,y,2 axis. 'n crystal field theory. bonding between metal and ligands is purely electrostatic. Ligands are considered as negative point charges. CO=CN >PPh3 >NO2 >NHs >pyridine > CH3CN >NCS > H20 © C20. Ac- Energy gap between ta, & ey . . . + e° OO. = 6 © - Ligand approaching metal When Ligand approaches the metal ions, there will be a change in energy of electrons in d-orbitals of Metal ions Energy Ao: Energy gap between te, & e, *? and da? orbitals align along the and Ligands leads to increase in energy. In tetrahedral complexes, Ligands approach between the x,y and z axis therefore dey, dye and