Time Allowed: 3 hours] [Maximum Marks: 79 Read the following instructions carefully. _ @ There are 35 questions in this question paper with internal choice. | (6) Section A consists of 18 multiple-choice questions carrying 1 mark each. (©) Section B consists of 7 very short answer questions carrying 2 marks each. | @ Section C consists of 5 short answer questions carrying 3 marks cach, © Section D consists of 2 case-based questions carrying 4 marks cach. () Section E consists of 3 long answer questions carrying 5 marks each. ) Use of Jog tables and calculators is not allowed. ; Section-A ‘The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. 1. The reaction of CH,—CH=CH—CH, with HBr produces CH=CH—CH, (@) C,H,CH,CH,CH,Br @) Br © CHs—CH—CH—CH, @ CHy-CH,—~C—CH, Br Br 2. A primary alkyl halide would prefer to undergo . (@) Syl reaction (6) Sy? reaction () &-Elimination (@) Racemisation 3. Which set of ions exhibit specific colours? (Atomic number of Se = 21, Ti = 22, V = 23, Mn = 25, Fe = 26, Ni = 28 Cu = 29 and Zn =30) (a) Sc**, Ti**, Mn** (6) Sc, Zn?*, Ni* (©) V8, vt, Foot (d) TH, TH, NPY 4. Rate constant ‘k’ for a certain reaction is 2.3 x 10° L mot" s. Order of reaction is @o (6) 1 (c) 2 @35. The molar conductivity of HCOOH at infinite dilution is 400 $ cm*/mol ‘using the graph and given information, A®, HCOONa will be 450 425 400 Bot F 350 < a) @ 250 < 200 = Naci a - omy? @) 100Scm* mol (6) 115 $ em? mor" (©) 150 S cm? mot (@) 125 Sem? mor" 25 x 10% mol L* 6. The decomposition of NH, on platinum surface is zero order reaction. If k st, the rate of production of H, i (@) 25 x 10+ mol (®) 75 x 104 mol Ls (©) 5.0 x 10+ mol L's (@) 10.0 x 10% mol L** 7. Propanamide on rea in aqueous NaOH gives: (@) Propanamine —_(b) Etanamine (©) N-Methylethanamine —_(d) Propanenitrile 8, Ambidentate ligands like NO; and SCN” are: (@) unidentate (©) didentate (©) polydentate (@) has variable denticity 9. Which one of the following compounds has the most acidic nature? OH OH Ou I CH, CH,OH POY” oC 0 wh 10. TUPAC name of product formed by reaction of methylamine with two moles of ethyl chloride is: (@) N.N-Dimethyl ethanamine (©) NN-Diethy! methanamine (©) N-Methyl ethanamine (@) N-Ethyl-N-Methyl ethanamine 11. Which of the following does not give iodoform test? ° ° ° ° _t! —t ] I @ CH-C-H — ) CHy-C—cH, (© GA-C—H @ Cu—E—cH, 12, The slope of the line shown in graph is equal to ' k @k © wath aes @) -k ir © ~ 3305 | — 13, The formula of the coordination compound Tetraamminenquachloridocobalt(III) chloride is (a) [Co(NH,),(H,0)CICl, (6) [Co(NH,),(H,O)CI}C1, (©) [Co(NH,),(4,0)CNCI, (@) [Co(NH,),(H,0)C]CI 14, Toluene to benzaldehyde can be converted with the help of (@) K,Cr,0/H,80, (b) KMn0,/H1,S0, (© Cr0,Cl, (d) KMn0/KOH= ~ 18), a statement of assertion followed by statement of a reason ig tiven, In the following questions (Q. No. 15 Choose the correct answer out of the following choices. (@) Both A and R are true and R is the correct explanation of A. (®) Both A and R are true but R is not the correct explanation of A. (©) Ais true but R is false. @) Ais false but R is true. ethyl ether has dipole moment. }: Diethyl ether is a linear molecule. 16, Assertion (A): Globular proteins are soluble in water. Reason (R): Keratin is fibrous protein. Assertion (A): Cu?* is paramagnetic, Cu* is diamagnetic. Reason (R): Cu’* has one unpaired electron, Cu* does not. Assertion (A): Ethyl amine is more basic than Aniline. Reason (R): pK, of ethyl amine is higher than that of Aniline. 17. 18. Section-B This section contains 7 questions with internal choice in two questions. The following questions are very short answer type and carry 2 marks each. 19. The following results have been obtained during the kinetic studies of the reaction: P+204R +25 Exp. Initial P(moW/L) Initial Q (mol/L) Init. Rate of Formation of R (M mir 1 0.10 0.10 3.0 x 104 2 0.30 0.30 9.0 x 104 3 0.10 030 3.0 x 104 4 0.20 0.40 60 x 104 Determine the rate law expression for the reaction. 20. Define the following: (a) Invert sugar (6) Nucleoside oR (a) What happens when glucose reacts with Br,(ag)? Write chemical reaction involved. (6) Identify the globular and fibrous protein from the following: Albumin and Keratin 21, With the help of resonating structures explain the effect of presence of nitro group at ortho position in chlorobenzene. OR Cary out the following conversions in not more than 2 steps: (a) Aniline to chlorobenzene () 2-bromopropane to 1-bromopropane 22. (a) Write the electronic configuration of iron ion in the following complex ion and predict its magnetic beh¥™ [Fe(H,0),}** (6) Write the IUPAC name of the coordination complex: [CoCl,(en),]NO. ,(en),]NO;23. Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The A,, of ‘B’ increases 1.5 times while that of A increases 2S times. Which of the two isa strong electrolyte? Justify your answer. Graphically show the behavior of“ 24, The C-14 content of an ancient piece of wood was found to have three tenths of that in living trees. How old is that piece of wood? (log 3 = 0.4771, log 7 = 0.8540, Half-life of C-14 = 5730 years ) 25. Arrange the following in the increasing order of their property indicate: (a) Benzoie acid, Phenol, Picric acid, Salicylic acid (pK, values). (©) Acetaldehyde, Acetone, Methyl tert. butyl ketone (reactivity towards NH,OH). Section-C This section contains § questions with internal choice in two questions. The following questions are short answer type and carry 3 marks each, 26. Give the structures of final products expected from the following reactions: (@) Hydroboration of propene followed by oxidation with H,O, in alkaline m () Dehydration of (CH,),C—OH by heating it with 20% H,PO, at 358 K. naa cof Yoon 7. (a) CrCl,.6H,0 gives 2 moles of AgCI when treated with excess of AgNO, solution. Write structural formula of the complex. (b) Write hybridization, shape and magnetic property of [Fe(CN),]>. [Atomic number of Fe = 26]. . A 0.01 m aqueous solution of AICI, freezes at — 0.068 °C. Calculate the percentage of dissociation, "_[Given: K, for Water = 1.86 K kg mot" becomes coloured on long standing. B,C, D, E and F in the following: =D saya CHCH—CH,—Br ithe KOH, HBr, cH, Naldry ether | woe, é F oR The following haloalkanes are hydrolysed in presence of aq. KOH: hlorobutanese otowing questions are case-based ra enera tt pasnage carey and answer he 4 nis VITAMINS are 13 vitamins known till today. it ae able (By. Bee on » Oy Let's know the histor 32. Section-D an internal choice and carries 4 Each question has an int (+142) uestions that follow: or (By Swetha Shiv Kumar August 21, 2922, yp ich are fat soluble (A, D, E, K) and rest of which are at! wry how vitamins were discovered, Water questions. Four of whi soluble (By, B;, By, Bs, By By By By eee By the end of mid-1800 scientists had discovered that pathogens caused ai - Ut was assumed thay i ferme instead of vitamin deficiency. Dutch Bio Scien patchy skin, falling eye-sight etc. is also caused by germs f vitamin deficiency. Dut at Piiiviaan Eijkman reported in 1895, that chickens that ate polished rice developed beri-beri. He was awarded m : vit s. ‘Vita’ (Latin—for important to lif loble Prize in for his contribution in discovery of vitami 7 fe), amine crass ao ‘all vitamins). In the begining vitamin C was called Sen ae = iver and adipose (fat storing) tissues. colligative property. ‘A student determined value of ‘i’ at various concentration of NaCl, KCl, MgSO, and K,SO,. The values are given in the following table. ‘Table: Values of van’t Hoff factor, i, at Various Concentrations for NaCl, KCI, MgSO, and K,SO,. a] Van trom Factor Vitor complete olooiimi a dissociation of solute Nac 1.97 2.00 KCI Hise 300 MgSO, 1.82 2.00 os 2.84 3.00 __* represent values for incomplete dissociation. Answer the following questions based on above table. (@ How is van't Hoff factor related to molality and why? @) What is value of 7 in case of (i) electrolyte (ii) non-electrolyte? (©) Determine the amount of CaCl, (i = 2.47) dissolved in 2.5 L of water si fat its osmotic pressure is 075 atm at 27°C. [B= 0.082 L atm K mot] [Ca 40u, Cl = 35.5 uf nn net tS osmoue Ps oR Determine the osmotic pressure of a solution prepared by dissolviny si assuming it is completely ionised. py vio 22 ae cA seOa IR = 0.082 L atm K mol, K = 39 u,s = 32, 0 = 16 ul A in 2 L solution at 25°CSection-E ‘The following questions are long answer type and carry 5 marks each. Two questions have an internal choice. 33. (a) State Koblrausch law. (6) Calculate the emf of the following cell at 298 K: Al(s)/AP™(0.15M)\'Cu"* (0,025M)/Cu(s) [Given E(AP*/Al) = -1.66 V, E(Cu*"/Cu) = 0.34 V, log 0.15 = -0.8239, log 0.025 = -1.6020] is the strongest oxidising agent. CeO} + 14H* + 6° —5 2Cr* + THO ET = +133 (®) The following figure, represents variation of (A,,) vs ¥@ for an electrolyte. Here A,, is the molar conductivity and c is the concentration of the electrolyte. 1500 oe oa 1490 196 0.005 010 015 020 025 030 035 Ucn)? (2) Define motar conductivity. (6) Identify the nature of electrolyte on the basis of the above plot. Justify your answer. (©) Determine the value of A;, for the electrolyte, (d) Show how to calculate the value of A for the electrolyte using the above graph. 34. An organic compound ‘A’ C,H, on treatment with dilute H,SO, containing mercuric sulphate gives compound “B’. This compound “B’ can also be obtained from a reaction of benzene with acetyl chloride in presence of anky AIC,,.“B' on treatment with I, in ag. KOH gives ‘C’ and a yellow compound ‘D’. Identify A, B, C and D. Give the chemical reactions involved. OR (@) Write the reaction for cross aldol condensation of acetone and ethanal. (6) How will you carry out the following conversions: (@ Benzyl alcohol to phenyl ethanoic acid (i) Propanone to propene (di) Benzene to m-nitroacetophenone 35. (a) Why are fluorides of transition metals more stable in their higher oxidation state as compared to the lower dation state? (6) Which one of the following would feel attraction when placed in magnetic field: Co", Ag’. Tt, Za” (0) Ithas been observed that first ionization energy of Sd series of transition elements are higher than that of 3d and 4d series, explain why” (d) Why Manganese has lower melting point than Chromium? (e) Why do transition metals of 3d series have lower melting points as compared to 4d series?