43.

The reducible representation, r, in the table is

equal to the following superposition of the irreducible
representations of C2v, point group.
C2v E C2 (JV
(J. I
V

A1 1 1 1 1

A2 1 1 -1 - 1

B1 1 - 1 1 -1

B2 1 -1 -1 1

r 8 -2 -6 4
(1) A1 EB 2A 2 EB SB1
(1) A.1 EB 2A.2...EB 582
(3) SA1 EB A 2 EB 281
( 4) A1 EB SA 2 EB 2B2
lrl\~.. :: Yu.. C'tl I~ 1 + l:-2.' I~
"t II I) + (:-e, )~ I ll I + lf Y! t "1 ]

~ "!u..Cf-f-t+~J
~ 'l~~u.. ~\~
\ [ bl 't I 'I \ .\- l: 2.-l le' l '1H .\ H ) Y (: 1) ;x-1 + y ~ l}x 1J
)!y Cf} -)- +t -;{
'!'-\ '{ t) = \ 2--1'1'2...
---~

y'-1 (
-----
8 W/! \ t ~ 2-)~ rJ )~ I + t- ~ )11(~1 ) l<' I -1- l./ x, 1 x 1
1/ll[e+2.+ttL1 J
yLI~ 'l,o :: t i,--gL

~ -t 0(4 2-- ..\- .l,

 ,f silver ni,t rat,e u ·as electrolysed between silver electrodes. Betoa
ained 0·01788 grani of sH,•er nitrate. After the experiment. 20-0,
u I] •06227 gran1 of silver .nitrate. At the same time, 0·00947911'8DJ ·
...
 ?~ l 11 ~

r o, Of, 11
' Io

B< \ ~~(._ et., c-ho ~d~~..1 ,

/a d'"Y) cef"' CO~£i ~ 0 · 0\1 '&'v ~~ °t) AQt-Xl~
lu."' \.-i ~ t:,J o tt . . ,·... ,\'ir· 1
• 1Q - l • l' 1ri 't? ~
- ~. () &0 i~n,

e c. t , t-1 • £1 &? i ) ~ 11\>(l u-.. IAo. ~ Cl o 11 ti~ ',n 't}t,..))~

~, O l'1 & o> ~ . %f\7' }JO'>
Ii o \J
~ 0- · l} 2.. I 9 -."') w-c~ t t V'O- ~ ;:.
n , O \... , D' l~ ~~
---170 ;,. <l , I fl ? \".l-
r; <.,, 1 1,'(r'"l l Q,.,_ ~ ~ t , (ll', (? ~ 'X '}D • 0 ) 113
l,.Io X ~ • Cf &? I '2-

r o. c,n(' l \ e . ll,t\J~
(\\, ,.... '<b ti, l,..... , (1.
0 , Q_ ( h ~J 1-tl IJ ,..
l · Ct l ~t 2> - • \C I 1
~- o ~ n n o I {1....~ '? \

,~ ,.i o- ~ C, ._ ~ (Xt ;~u/ ~'r)

~) • t1b C.u r ~\
t!O-¼C- ' ~ ~\- ru,,o~ ~
~c_~ \~~ .... ~""' ~
Q· CJ 00 ri.,_q 6\ - t) · Ot.JO \ ~~ _?., -1
~_J
:J
_...,

--- 0 · oo O \'-\I")~
•
0 · ooo 1>\\) \
 < April NET & GAT... >

Q-37 U nattempted @oo:33

Q, Tllo .,..., 11,u ~.CWN'II c•rh o 11 <ll11tlfltl~ n n ,I 0110110

CS,(e) + ID;{e) ➔ CO:(c) + ?S0,(,0
11 nH!11!lk4 mh111." lm 1r rxcrss *r Clii , T110 p.rrs.•11rr of l!i9111" ~• 11 f1Jllnl~11 oflhnt
iJ !!)wu ho clie followlug u olll~. \\liu1 b cl1• or'1•r or ~ •1<11••?

Thnr S Ozour P1 1"S)IU"f' totr

0 I.•,
30 1.0.i
60 o.-,
120 o.~z
iso o.r
?-10 O.ll>

n) 0 ~) l t) ? • ) tnu•c b• ,lot•nnluod

C
 0
-;::::;-
V •
lr(t _,. tt.o
~ \. O'-( -"7' °'{-
to tJ,19
j 1,,0 tJ ·.C2

J~q ~.
\;I A~ ~ Y.-1,n +-~
'

\/ ;\.~-~ '! \,1b + ¥-X '?ro

b. q i ~ o. r1 4 ~ \~

t1D ~ :; tJ ,q t- 0 ,!1
k ~ tJ,'1/f;~
~D._fLA I
-
u Y"-t: == Yim .\- ,Lt--
,110-1q .-. \; -\- 1 1.11,
~ )(-<>o

\,2...1 =- o.~, + kok

l,OK. = l·'ll- O · C-1
b o \L -= tJ. 'l
lt:... ::: b· 1_ ::::: O, t, 12..
bO
V'~LM.. i ~ \I -~ t} ~o\Act 0-V-. ~ I

--tk,(L a"¼:,'--" cl~ \..1 irr ;;)~~ ~Lt .

 < April NET & GAT... >

Q-36 Incorrect -1 (5)os:ss •••

Q. .I. , ••«Ion 11••• t lu ough 01 0 r,Dowlu; • lflnouuv , · .-,,,or.

k, ► 1 C (fast)
A+ B
"1
k,
A+C (sl.ow)
AfQUnlug 1h111 •lf'luly :111p1-..:dmMl011 rr111 lo~ 1l1'11lltd 10 C. 011 olon~lltoJ l h •
.,,1.,
l"onr, ncr, u lon orA. 111• ,...,., or prodnctiGn or D ,till ;.,,.. bJ' (n.<J- lnit ~: (.\I <<
1.4 (CJ

r) 8 d) 2 / ?

C
h .i ! J I! "// I JV
- f,, l

''

-
 < April NET & GAT.. ,

Q-43 U nattempted (9 00:11

Q. 1J11e i'fPndr,t ~, Nati 111 ~~ ~ ?. lf1] • 1DJ kl m-J. \!f'llf-11 X~7Sl IPm Ml,jllUndln•
1

lmpl 1'1',ing ~ wm~ IPn~ 101 !,S.I pm mr• 111edw •11•

!GO n:'fJNtion DI Nn,t"ll orOIJ'!II ac
tw ~ • uf 5.Jit•. Cnkukil~ dff' 1mml•1 af.Nn... mul ~ Jom1:in Illar iEd.l c:el..

bI -,

C
 . -
<)_,. O .\0'2.Jb

~I
~JA'O :
-- q
~ Y'\'L -\ \L '\. +~ L

'"1--B 'L :: q 9-
f '2.. 1- -\-D -\--U - '2-

°';· N0-
~
\\I\
 < April NET & GAT... >

Q~41 Unatte,m pted ©00:2,0

Q. ;\_ '""~OlL:!ii C'Ulff.l1'0DIJ.d A r('IDfU 11, · rc luff mdl'iiN:t.dNd lia11 ( cu dc-J 11111r,r ~e\\' ((L1 -;hi,nn
ID O;;m11,) \dl.h nue, 1CDmlntd ! )II 10-J~J, :.l !0-1 1ml1 l..!JJ !Ur'"' ffl"'"1 [111,1 p1odncu B.. C
1 1
....

0c1ml D tii,pPrti,~lY-
rUubfnD)-- Pllll'"f' ,,\ -w;I J l'nia-H ID n d1q,d c,outrua•rw.if-1 J' iai s: ..., JbiJIDI 1lhP pm~
IP~.l.l'llr@ orB (in1otllil lllfier IIID IH hm 5UD."l of 1!Sp·Mmll.f,l lf:
1

8 1'.g.t

llfsl

{d) Naur 11rtl1111t.

B
- ~--x ~
--
{) 0. ~
----- \-- -
e-
-------
- -
< April NET & GAT... >

r■
U na1ttempted (900~12 i
•

Q. .A. Cit~1-GJJ di.-1" Ii PHffid.D. I.I 2.11.0 li'o co~phit• hJJ 19... mmut l!'~~ Ro,11 l11u11. wW the
1

u~11m1u trtk, lo 11w S-~,!iiV ,11 ,,:m11IP1tt? Ca'lnJln1, du• htlfl ('OIJIUJJU fol ~ li0111ttlon.
1

bi J,50 min

B
 f\ - ) p
J....o 0

~~ O?:, ')( o,, 2-

\ '\ ·l
~~ -- "..:_a-I'/ ~ -f
-t "-Rf \MA~ ~~ ~ ~
~ {'. ~-,. ~ AA c:)jJrv) '
A. - l f
D.,o 0
t ~~ ~o-B~·~"~o
/R
{J_oo - &ci.9~
C ltt'O ►

e;-
U'O
~

'2, '$0..1:_ ~6" ~)' \l

-0 ,Q\'-\ {J \" ,( ~
O, R
--=- '2.,~oe ~ L. -
-o,~~
--- \1, ,t ~
If 0, denotes the characteristic temperature of rotation then the magnitude of,
f{0,(HD)0, (D2))/0, (H2)]2 (assume the bond lengtbs to be the same for all the molecules) is:
(a) 2/3 (b) 3/2 (c) 9/16 (d) 9/8
Given the operator a+= ( 1 / ✓2)(x + ip:J and a_= (l / ✓2)(x-ipx ) where x and Px are the position
and linear momentum operator, respectively the value of commutator [a+> aj is equal to
(a)ih / 2rr (b) - ih / 2rr (c) h / 2rr (d)-b / 2rr
 < April NET & GAT... >

Q-42 Unattempted (900:06 ••

•

Q. For nu wzyu,~ -ab.n rnc. 5)1lun obtyh1J th• ,la&JI• Jl.lklm•lb-l\Itm•u 19,rhnub111.
tilt' rn1t of pt ••luct r01·w11t1i111 " h,n tbfl 1uh.\11lollt cour,llfn.tlon k ,... ,, •Imp. Im-" tltP
lhni1ina ,•itlHt O.t 2 mffl• tn'°"'. ,\ I u 11al,~u ·u 1t renr,1,1n1tltt• •r L~ ag ,hn...J. tht, 1-nft
u hnlf 1hl< ,'llltt•. Colmlnlf l.:1 k.1 llU1llllblJ rl1J>1 I;; « 1:..,.

•> 0.00~ ,Ion' ••it"' b) .008 du,' in:-1 <) 0.16D duaJ mc1 ti) .006 dh11 lftlr1

D
 A "- 11 J~o;
A ~ l U
~ loo - t_. x o . ol'.J r x 2 -dJ
- 0 TT
1)-"1 l O <:: :: s x c, 'I' .2-- -0)
u °t 0

clt~ ,,./clt LJ e.p Q) ~ (iD

-0o /, ·61 -- -= ~"x"_?. oo r-'x x;_
lcJl•II y"tc_Yj !
~ 0 • (y ?-A-} ~ 0 , tHJ !.~
- - -
 r
1
for H "'Br oocma • 500.
~ ---- -- on occurs at:
(a) 50.1 - ~ , \DJ oo.~ cm · (c) 16.7 cm·
27. The 1
~ •·
~;;1.
~~~Is for CO in the g,ound and the first excitod ..,'L ;' 1
_:,- ~Jy!,The % change in the internuclear distance due to vibe•
(~ 'j I• (b) 30 (C) \6
I .inked A answer Type Q. 28 and Q. 29:
The infrared spectrum of a dtatomic tnolecule exhibits transitions a\ 2144
corresponding to excitations from the ground state to the first, second and
respecti vet y:
1
28. The fundan1cntal transition (cm ) of the diatomic 1no\ecule is at
(c)2\83
You are offiine. Some functionality may be unavailable. X
,ic molecule 1s
(j (\10 th\l\fll') ,,., I\ (\(\1,.
 IUJ U
...._.,._.~A i■fflrr T)p~ Q. 28 and Q. 29:
the infrared spectrum of a d1atom1c molecule exhibits transilions at 2144, 4262 and 6354 cm
coatspondmg to exc1tat1ons from the ground slate to the first. second and third v1brat1on st.ate
~CCII\CI)

28 lbe funcbml'ntal tr.tns1uon (cm 1) of the drntom,c molecule ,sat

(D} 2157 (bl 2170 (c) 218] ld)2l96
1
29 The an nnonrcll) con~1an1 (cn1 ) of the drntum,c n1olccuh: 1s

(ll) 018 (b)OOl2 (c) 0 006 Id) 0 003

It 7 /M/112,M BLOCK, KAKADEO KANPUR NAGAR UTTAR PRADESH

CONT ACT NO. 7880546666, 7380546666

y may be unavailable X
 9--/!) -e ~ !tr0•7 1 ~
ro ., !:>--P o . 1 'L
'1-
r=. 9- ro I 2) i en ">r ~
( 0 (?:, .:=: lD~ b(O • ~~
~. 7- ~?,. ~ l, \,f 'l-

(~)f~ - ID" H2-

- ID 4 0~
b X '0 f O l'\l'llt ~

-- 9 ?:, • Lt ~ ~ 3 Vvv\ i
-· ¥1.'Y) cl
 I '-') \n 1n 4 , n1 IJ or ...JJ~ )'<f
I
., )' r
/ ! n P. ,n I ,riv I CH ~1n,

r, f'o x 1ro
yll ..

JI h •
I l 'jl') (
si.ii 1·"
L, [
Bo Sffi 1J•l 0j 2 l,.l <';) 1>? (

!""S) S,
Br
y
•6,'L r
('
ij~
)2
-J (!:;) - ~ ~. P,l

l•q rm l
DCJ
.I - I. L- ( t1\ ,
\ I
Att· +, ,i; QJmW

W~ f I - 2 'l« ) -= 21 4\.t ! ,m -f ( Vt>--> J ,--J?w,(i ,1-,,,,. )

-
?-V'I'~ ( l,. ?/l-~) ~ tl ;> ~2 r m1 rv t,-}] --½~~4 ~)

- - -~ :l1~ '-1 r.wi ~

trf.e. - 2.w.e.:~

2wt - t ~ ?\Jt -:: 4 ? " ~ e_.r,,1

~IT) ~ )(' ri, - ~f' ®

~~ _ ).,VI e ?\.t.. - .Q4 p2 tJY1 J

;).lY i - kw;_ '>\.l .::::. '-1 u, 1 ~f/(tJ

--4'\
~/
= ~,,orJ'Y'1,2__
~
- ) fur~ ~,l'Q~

we. ( 1 - 2 ~ )= '-i"' u,.,,---1

.Q 1

( \ - 2 ?tt)- 2'1\1 \\ c..~'1

-d) ~7 0

=!) _r OU1 ,, D•1>M, j) a nh OJUT'O:,, i c,~

tm .! "-o. .-i1-
32. A quantun:i mecl1anical state Q is a superposition of Two normalized energy elgen states A and
Bio an amplitude ratio 2:1. Jf the two sta'tes are degenerate with a co1nroon eigenvalue E. what
is the energy of the state Q:
(a) 0 (b) E (c) SE (d) 3E
 Cl ? 2 c_L -::,.)

F
J

'--y -:.. -k 2
q> I + -Jc
1 c:vL_

'L
f -: :. [l 2 fl + CL- £1.
p
- - Lf e -t- _l
r-
~

~ '
-- e
 C)_ X' '9~ t,-1>
- q~~~
~ 0,0tJ°l~~~•t.-C"'"

- - \; )t O ' o-tr°l C\
/q OQ....

:.-- {) . 001.--l.-l4 ~
0t 0·00~-~

t~ 0 z,, l\..t ~ I f Ot_C uf-U- v+-t, ~'" '2 2-,

CfC-= 7-- 2\,{ 0 0 ~

~o o, o o ,u '\fV\.,Q -lt_ ~ 0/).__ oc e ~ 1

I

,o , oo'l~" 'X ')_ '2- ~ ro

~ ~~
 ry & f-BLOCK ELEMENTS
K, N2 Is absorbed ona mica surface. A plot of a 1/V vs 1/P (V In mJ
ht line with a slope equal to 2 . 0 x 10-s torr m- 3 and Intercept eq1
)( 10-' m3 • The adsorption coefficient and the number of molecules of N fo1
vely, are : 2

) 1.25 x 1012 torr 1 and 1.075 x 10 18 (8) 2 .5 x 1012 torr 1 and 1.

12 1
{C) 2.5 x 10 torr and 1.75 x 10 18 (D) 1.25 x 1010 torr 1 and 1.
~ermal which has fractional covera_9!:, linearl
- . .-
 . . . (C) 2 .0 (
~ptk,n coefficient of sea water In the visible region Is 6.2 • 10
l\om the sea surface at which Intensity of high becomes one-te t the
?
fTIFR-2015]
(B) 0.9 m (C) 1. 1 m (D) 8.0m
(7
,. • ..._ .,.., n•---"'- .,.
 'l' 'J,o e\:s 1.0
'1..-=-- ,o,\1:o

~- ~ ,~oo
~4 ~~ : _ \~\µ co

~CkA ~ ~~ :; \ B<OJ? ~ \ ~

~ t, ~ ~A= ~
~~u

l
~ '12- 1,0'1 )<' ~ . ~

2-·i~
o 11 A ~-k11ero order ReactJon ha~ K-- 0.025 MS-l toe o, ~ ~tSaPPi!imrncc ,~ A wliat wm be the
m:im;1mUJtlon d A 'ilfhr 1.5 5.l!f.~od~ Ulhe ln1l11:1I mnacm,-1111:m b, D SN,?

a)D. llSM b} O,l.llM e10,.a1sM d) D.ObM

II
 t

VJ
~
D.,.

a
vJ
u
Q;:16. far~ RY:t,on wu h rate r,g .uiil
L -dt
Hoo -;; s ICC'I" Ctr 1nu
...
Ca :'I! the mJ'lmn1 mi ID01i af re aeta 11t :at lime
0-and t r ~ ~ l ' f lJ10r,tl"uliPS W'f'r~ ~frill'Et rnr Qi t o ~ ~ Co/l. tile: Ume ~uJrm for
ca to t>«o,,,~r•.r,i• h?

1) 2.0 mln IJ) 3£1 mfn ,J 4D min. G) 611 min

 •

J --LS0
-

-
-

1) (f) (f) , J , ) ( ) 1) q) ~ ) ,) '

( ( t
 Thi falO,mg NUta hava ta.In oblainld Ming thl khltill: 11.i.dM of !NI macticn

- • • C ._.p

DPEAIMBlf fA VffdPIM I S Jft":10J WD"9 ~ a~~

a~• rli!lfr.'11!'!

I D OI OJJDI!

2 OB 0~ 0£i72

3 0..! O.A 0.29a

0mmw'II the Gfdlr of tllKIDI.

 'Q:\_l,, o<-~ aj~Q, j 'r
t-'q)
\
l ;
'-
r\___O ' \ }L (o . \_)'ti ::. o . 'O o~

,_ - . ~\0 • 'I;, ·:r-- t -1 1-- ::. o . o1 1..

t) • '._J

~ - \_~,1J~ c \)·\\:J':r ~ ().12__ii

L\_ _ _ _ .. \_ti •,\,_, j "'-.a t O ~ \) 't- ':- 0, C) '),.)•·\ 0

I
~ .- \_o ,\ J'll \_b •\/J"r

'-\ ~ ,'{)"- 'C_o/\yr "' ala LJ

,~Gd.t., «- Ct\J' te:f

~"'--o.~l ytlo_, ~ ~
ti
-
11. For the reaction
2Jtl0+2H 2 - ,v +2H 0
1 1

The overall rate expression is third order.

RN2=k[N0] 2[H2]
Show that two mechanism below consistent with rate
equation
1
2NO + H : ' • N ,. + 1H :0. {~low)

A. (jasl )

I\".'
B. 2NO -;;" N 20 2 fast
4
1V 1 O1 +H 2 ' :. N 1 +2H 2O sl ow
J-f 1 0 1 +H 1 '
1 4 2H , O (fast )
 . \

~ -
fvri} ~ ~wv1o nwv- °i\>'5<)~, ~ L½~ k.J
(Iv)

c~2~
-~~oj
~ .Q4o)\.,
~~

~~ ~'. '~> c~,~)(}\~1-J ~

I

,Lv
,
¥-
30. Toe fundamental vibrational wave numbers for l-h and Ii are 440.32 cm- 1 and 214.5 cm- 1
respectively. The relative population of the lirst vibrational excited states of theselwo n1olecular
compounds to their respective ground states al 300 K are respectively:
(a) 6.75 x 10- 1 and 3.57 x 10- 1 (b) 6.75 x 10- 10 and 3.57 x 10 1
(c) 3.57 x 10-6 and 6.75 x 10- 1 (d) 3.57 x 10- 1 and 6.75 x 10- 1

3 L. The rotational Raman spectru1u of 19 F shows a series of stokes lines at 19230.769 cm- •. 19227. 238
cn,- 1 and 19223.707 c 1n- 1. The rotational consttmt for 19 F in GHz is?
(a) 26.484 (b) 52.968 (c) 105.936 (d) 3.531
----
vz) ---

V:..0

V) Y-:::1

Yl v-:::.O

f'fl v ,:J ------- --~---

Q

O
{_. 6x , o,...1'1 :<' ~-x 1 D r v- 2f'f . ~
-- Q i . ;g ~ Hf L ~ "< ~ IT\)

- 0 · ~_( 7
°'
O(YJL U- . ~w
6} L(iv\)}t.~ ~\,u.J
\\Y' 'lA.. M~ - ~ A-l/V~
~ "-\~
.. "' M I \ C\ '1-~1J 7 b1
t

. '0\1-17 · ~
1, i 11

---