iy NY (A Ohersichcasers bergmannulfdetmed Angaben aus dem Tet: Tei 28C , Ad, i= 376 auerdem: Tabellenwerte (im Folgenden rosa hinterlegt), zu finden in: hitp:/imoodl.uni-duisburg-essen defile. php/53/Materalier/M_cp_h0_s0_ausgewaehiter_Verbindungen pat 1. Stellen Sie die Reaktionsgleichung der Verbrennung auf [SP] = Allgemeine Reaktionsgleichung (schematisches Vorgehen flir Kohlenwasserstoffe) 1% Brennstoff + voz * Op + Yy2 % Nz —> Voge * COs + Vyzg * HzO + Yop * Op + Yye * Np Anzahl der Kohlenstoffatome im Brennstoff ist vq:= | Anzahl der Wasserstoffatome im Brennstoff ist y,;:= 4 Menge an Kohlendioxid im Abgas yco2'= YC voo2=! Menge an Wasser im Abgas, vH20 vy20=2 Menge des zugefugten Saverstoffs ("E" fUrEdukt) voy p= vorn=6 Menge des zugefigten Stickstoffs vn Yo2.E V2 = 2256 Menge des nicht ungesetzten Sauerstotis im Abgas =), — (°P" far Produkt) Perec OnE. Damit lautet die Reaktionsgleichung CH, + 6.0, + 22,56N, —> CO, +2H,0 + 4:0; + 22,56N 2. Bestimmen Sie den Taupunkt des Abgases.. [5P] Die Gesamtstoffmenge des Abgases ist. yp. Yeo2 * ¥H20* YorP + ¥N2 YH20 ’p Laut Dampftafel liegt cieser Dampfdnuck zischen 36 und 40°C psu. = S.628KPa—pygog = 7.384 kPa ‘Am Taupunkt ist der Partiaidrack des Wassers im Abgas P bar P= 6.766 kPa ac - 38°C EASE (9 — asec) + 35°C Tig = 3824°C Paore~ P3s°c 3. Berechnen Sie die Masse an Abgas, die pro mol Methan ausgestoBen wird. [SP] 4 8. ‘mol ™p= ¥co2"Mco2 + ¥H20™MH20 * Yo2.p"Mo2* ¥N2MN2_— ™P=ee pontiat tnttey Ger h ay! Usarps OF Stabe veer alte Bat Compost AAW at corte’ 7,7 (Za, Ti [3 ng Sele warn ele, a. a oe i4, Berechnen Sie die Verbrennungsenthalpie. (5P] = Zum Berechnen der Standardreaktionsenthalpie benctigt man die Standardoildungsenthalpien aus der mitgegevenen Tabele. Die Standaraiidungsenthalpien von Sauerstoff und Stickstoff sind null; sie sind deshalb der Ubersichtichkeit haber nicht aufgefub. ks heya = 86409 2 Standardreaktionsenthalpie bei 7 : : = is Umeatz von einem Mal Methan "r= ¥co2'Hco2 + YiH20'SHi20.g- 4M crs Abe 7908 Das Abgas ist tatsachlich warmer als bei Berechnung der Standardreaktionsenthalpie, namlich um Alp Ip-Tg | ATp=67SK — FUrdlese Differenz muss die oben berechnete Standardreaktionsenthalpie korrigiert werden. Weitere Korrekturen sind nicht notwendig, da die Edukte bei T., = 298.15°C voriegen Ah, an, ATp (Se) mit (Sve) = vco2%p.co2 + VH20"p.4t20.g * Yo2.Pp.02 + YN2"pN2 Mit den Warmekapazitaten J 1 J spoor=37— sprog BSE epon= 93S pn = 28125 4, Berechnen Sie die Austritisgeschwindigkeit des Abgases. [5P] ; 1 Hs.aaera 01 FSS montane? 82) TM aan?) "8 none Pn.cH4 * "Luft, Luft Paus nub * mp cay Pans ‘aus aus~ ("CHa cH4 * Mutt n,Luf) a me 2Tpax = 100°C 0c ad Thei = Tmax * A hy 28h? yg ~ ah ‘ane 572-2 ' ‘No2~ AP N204 en s78 eyes pie epg 48%p= Ab, Tee ("N02 ~ S*N204) Aeros - ae, RT ah Kysec= Kpc= OMS Kye = Kascent z= 029 i © s weapon b femp. correc a 5, = 309.308 3 molK‘Angaben aus dem Text ous0S . dye. ISC , pyistbar Tyg 6PC 1, Berechnen Sie die Wasserbeladung des Luftstroms in den Zustinden 1 und 2 (X;, X)_[5P] Zur Berechnung der Wasserbeladungen bendtigt man die Sattigungsdampfdrucke p,(T) far'T, und T,. Diese lassen sich aus den Dampftafein ablesen p(y) =1708kPa und p(T) = 3.169 kPa Nach der Forel in Mwy p(T) der Sammlung ist die x, -= Y.-S __ X1=0100535 analog Xp = 0.02035 Wasserbeladung Mp pun pti) or 2. Berechnen Sie die Enthalpien des Luftstroms in den Zustiinden 1 und 2 (h®, h°,) [SP] Die Enthalpie (unjgesattaterfeuctterLuftist wep (TF Ty) + X[hy + ep.w(T- Te] Da die Temperatur des Tripelpunktes von Wasser nahe am Nullpunkt der Celsius-Skala liegt (1),-0.01°C), ist es. in der Kiausur, wie in den Ubungen besprochen erlaubt, statt der Differenz direkt die Temperatur in °C einzusetzen - a Bee T + Xr(hy tepwT) By #305742 analog Hey" 3617 2 CRs 3. Bestimmen Sie den erforderlichen Massenstrom an trockener Luft im, [SP], Kontroliraum ist die gesamte skizzierte Aniage. Der 1. HS lautet! Hy + ‘Hs +'Q= "Hy ‘omy by + mgs + 'Q-= my hey ‘hp — mp bey — Im (Xp — Xi) hs = 2772 ns The =m = (X= Xap mm, = seal 4. Wie gro8 ist der Kthiwassermassenstrom im Zustand 3 ‘my3? [SP] : : Der Kontrolraum umfaest nun dle Zustande 3 bis 6 (also ohne den KUhiturm). Der 1. HS lautet: “Hg 4 Hs + ‘ms = 'm:(%- Xi) sims aos sh Ow,» PIB Way? = LIA ayy), ay Ay ls mgsrore Fy cua yay ls $ Py = 100. €9 4/6) tig = e Eye te Ser Gar ml Reng ASmixz - Bim 6 nals taka ) — Pin Ong inks) = = Spr ae neqecte®—— ahuny Xe <4 wm ASmik 0 2. Ey 50Ae @ ws S/g N,04 a ZNO \ keh 2? pchos (22HG, F (213418) ~ V6 = eee mal 9 Ln kp, -eacp= SEE (+, -4,) oe eet 2 © “yste 35 0.17983 ral dE aa. ee: [@xrm09- 304,24] Kio bey Ko, - —bs p a= en( pst) - Lap, = ls 926?23 oO. Bew- Tacs? oe 2 ype EN mal only S624 b > Lnyepys -1.426%3 ~ Se ele8) ; AAA - 90-4762 ep, 2 OMSRBE x 0-6211 zl ky (By Unor) 2 ORE ° KNOY eee x i) wet re wf ye 2 2 ee Nxhape 0/264 N\Wo 2 = 0.53684 03106 - 030" ona erat E 22" OOF 2 sae 0.2684 c@ WSIS/TE a ag = ex jae 7 7 : Ber sk dyayy Lee ex. - kx Pie 2 es Zz a Kx = eye S = Eb 5 ORO dt ees 0.26243 Kye Uke Fobl sper Kina: 0 .54F Tds- da + Pav non = On828? oe Ong? oF 316 Tds Zo Cale pressure Anor2 915368 Gis Tést4et : lec dk = t ds = dh vide se ca Btw: du =0 s. Tas = dhe da Aa 3ysiem =. Work dont io due fo désorder af tht moalecutes in tne mix due dae 49 reackin eat copy : ° TT Siz Vasu thay * Va, oy Chy,oul® ae YS 1223 IS 2 304,24) 2. a ra)Se + 77.28 la Sa + 3.04 39F Ss naews 15/16 ® problem 3: 25°C 790°C \, CHy + 6(0,43-%6k)— CD *ZHO + 4 0, F 22:56 Ne Des (oe a, i Arar - Dyer ask 0.0 676 Ree Sect era Biyo = Pu X20 = 0% 0.0676: 676599 KR Interpolation gi P25, c2@engt= 7.324 % sedan + LE WSN-IHY (40-35 = F.3M — 5.628 C ' 3 3Bq.74 °C 3. ™ = Un, Meo, + Vigo Mio + Vo, MO, + VA MNe yo) + (2x 15019) + (yx aait)t (22-S6x 28012) ZU0.00428 ae 0. 24 Ae 4 Beh. (2x -241,827) 4 oF + ( 343,522) = -790 71 SS Ace FO F6R + (700- “a3)uis? (07 WW + (4x24, 389) 4 (22SbK 24125) + (28 33,578) | a . 3 - 147.649 2 os o 5 Se AS ae see =) v /i) WS IS/IG y . "i at x OY rd PO Z min Chint aS )- Zrrout Choy + Cut) =O 2 é=0 Cs0 £2, oa Ae : : i mat i i Couge — Mong Reha F Magy Reutt AP hp - mp Gat = 0 inp Gaath a eaphp + cH heey + Pah heute Zz ts «rT my at. php + Morwheny + m bevy moon 2 1s vey 7 a) Cou h ea apt wr Mpa ~ Np p+ MCHy hcHy * van, huft S aa patel Cammar faieror “4 7 [mal CHy mol I Ys mate mol Fuge” mp Cour’. Vphp + Vary har + Ve hours) | i mpCagt® ae dol fier Uphp- dea eel ra - 695.8 % -3 Cours Vo xX Coats ebch cm)@ ws (S/16 Prabiemns Sige | Ne 1S2C Pus OS stare 2 T, 2287 Qe \ Sra 3 T3: doe carer Flaw) grate 4 avec 14 2s°c grate? 087 1s9c (Pu = too mart meet of Sd rata stat t 72 60°C Qze1 ste S Fall condensed \. _ Ky = 0-622 Poatis Br 204622 40Sx051 Pye Psari ® 199 ~ (1/7054 OSI) = 9.005456 hee eee 020356 10 - SG ~ 2: bbe Cos004x (Ss) + 9.0 054s (2500 + ts 1igpx tS) pe = 29° 253 B he = (004% 25)+ 9.920356 2599 * \ 2¢aules 1S 8 aF 25) yous bys Cwty = SFT EE i age Cw TS = ord ance He whale system now enetyy, wi 45,4 emi fing polat ioe eavering is polar 1m arn, +Hs = Yr) stole z m,Chi-h2) + Myhs =O 150 mw nls a Kha me faulé = vac U%a-Xt) sox t me CAd- np) + MT rh) =° : a 3 _ _cfsoxte? 3 he2736 WAhP Gy Make 209A tea7” 31H, 502 yee chewy Iegetabthy Meo Hs Hy 4FIS93B 2 . Mws > 3 7 a8 ste He tHy Hees eat an er ‘ooo [ eq y= Co (B= 6H mM Wa2 Mb > rnwig rt rae — MUS awy = " — Ao pe © mw3 hg — my h4 a3 = __@ tts Cs ha) na -hy iE (SOx? )+ upas (62-7 - 04's) z veal = (04.4 h0Buey\ Welhod @ ks 3 Edel vy a of patter Sipr = Souk - Sin 2 Va x Sees, 6 Sits m ( Sauk Sin) = a * Late a or he)” eo s : et S- Ev = Tu Sirf ie aid E 8a PT Tee fo daw me 2 eu oe Oo SRS Tok sable iHeenietie oes LD. Method ode’ = Caps Eg -Eg= iavsy (Che shu) - Ta (56 - Su) ~ ((hgg- hu) - Te (53-$4)) } Ter ? &e= ray (cu (ty 7) - TH cw the Gs Th, a mw cae y MWe ayy hy + mus he = M3 “ (uty tng) hy # asks = MWS NG | lage Gees tteisy hy emedchs mw3 c (036634 KE = Cu Tb Tos 24.7age?o |f WS 1516 eye ee 7 ( te 19 (ser DHFR) — CES FAB) X GE 2498340 1q PK?) 449 _ peer Be BAH _ 2611. 451782 ve Ezer €@ ee -) Ty Q € Vota : Qe 6 ( 7 Tsoarce = 14 < 2 ison (1 7) one pot wane lee 4 ete = Ext Mra 2 Nance Ke WEA \ hs -Wu hth \ LOX isSSIS pe \ critica) Porat ; OT has the ‘highest slope af ak te as Hae Volune dif Fererce yet Qin relavively real4 Smalt ass really gall nunrbl~ onl Ying) cove ower curves \iqued ond Solid *S = BWtras warte | en) Ss aby we divide by C clapeyrn equa sian) de We Wane big, slope. Ba! aé Ago Cyr Vihax vy) Y JSount Fe £4 .® 3» ae Speckic entaalp will ENE [CA>e Ace a ns? [ane 188 «Vdp We can velense WA alsa Fram — 79 Wed diagrun Pgh : 7 a DAC IM om isentrapir A PE ess Hat eathalpy inc, — Yes 1 wil depend an We phase as For example in liquids and ae Vispecific) e LES U specific gas sa 1F Yue phase Chuge tne Nae oF Hae en inal pier D5 wilt changt. \ ws ty S50 Vol Jo CO So val% Ho T2300 k — Pelbar rac lg S Suny 2? PN nat Puc WRT Z 3 \yixn Vc 149 x 9-287 x 300% vr agel ~ k Rage WHS ane FOP 7.0089! oS x O61 Kooy 58 ~i} Bown =—min (Xeo taxco + Xho a -Q.e7Kr? x ( 2C05 ino5) ) XB3I4S “BH S18 Z OMENS 1989332 gg = ote EZ we@ ssiS pCobiem 2 ent DAY. Shake | Ty= 39°C @=9-4 aO stake 2 X22 X3 aty Syak 3 44.25% Oz=0.4 Voie = S08 air 3 x AN aagix ott = Eee Xe Xa O. 622 « i 109 -C3:161X0-® =X hee (004 x 2s)+ Gags nis2Sa0b & (BA 26) | a ig Clee Jw 2 AL = pi) Yar ko 4 gst? 0.622 Pa Bo 3 \o00 - % ay as Yo=\ Poe \. rete bw Ly gaan vob 1. (abe bP0) (1510) Ve 71 itosi 12276 70.41 88°C) Ad 7 ‘3 Xie O-622% $618 x Od = 0.93327 100 = (5.622499FS\ Foard zt ® SSIS Qin wd Aout =? Pidhay * Qoute mp Cnet eta ‘Vg jae hue Cw Tre 43, $505 aL chi? -ha') = mMwhy ous = g.arx 2 Xs 5 fete roa geet ——)s 6764 me \ae CY sa) = © pee 2 _ 5oxlo? : eg ete 9 3tlie Bz eae Go ee Ww - me MAM ray 9001484 hare GT + Qmare mc cht he) -rmhe = s.nis3a4 Ue : 3 Qint a dae ; Qine meCha-hi)= % astlt ZH ASN Bp at Ny = 376 Maire (0.79 Ma oat Hoe) “ne i Noy 2B. 25006 fn 9 | Mair Nain - 2:08268% vy Fe Mair” Ul = OF asec x? ell gy titans Mh Avie ONAN s WSt477 ot ae oFfto-2\ Ware = 9.4494 eoAs) © SSIS Nae 27 Nor , Mw = Wo 7 4.borkon* eee = ie 1g 0K 9. 0285 26 Ks ws Mus 2 4.60 Ft 004 x10 # ML Keg = 0.0 6088 Aafyet 2B Guse sop szyr® epergerm dT Me jel” enter oF 25°C > ameret T3? 297° aan a SLeeeea a Cys 04+ 3.30024 3.46N2) 7? 2C0,+ 3420+ 9.3 Opt 12408 Na ah complet? > dzl + 3H,0 + VE No Cosol 43 0, 4 3: 76Mle) > 2D. a 200, + 3H20 calisot 302 on \ Cege Ag Voor Rent Dinan? Vere Fae™ Une tae) + (333579) 49 3K 24.355) Hlneres 29-125) 5 2 Le COSA) 17-70% 2 Boe tt® wie yeok Xp,o? “76 = Q.l6ials Ck, 9 = 44 a L Psat will aot Hy 9 = 164 AG 5 10 3 TA yes grote® gsié — 83) Bes (3x -241. 929) — el 272.64 1234335 Debs V3 BS 8 [fener | pl Ty e% "fact waded oh Deshausy = 2 Ruane 3 a 2 \7-709« 3079418 Xta ( Tg - 29) 7 ih Phos emeg "yy MOE, qanes. Ata Aga 7 wt” 16708 = Aare tue Mor = ve save 2.10724 | Apt 2 opie] Khel: oe fo oc Atul = Ett as Auth, bs 16208 | Caled & Ror ae por 16,208 323. S¥st) Kram gueshen oe Fore a FN oquarinlD ~ exhaust 3 S2.405 84 a cena g- Tswr) Anth/ Aguel 2 17-709 [Aenh= 2 2.25455 eae) | D> Tg = 1053.28SED oremns Res A Fact Ey: 4 Aga VER Pe ((Te- Ta) - (Ta a ie) Ee = 17-708 x ao.72s8en'0>( (053.222 - (25 1273.15) “Afael — (2542Bs La 1052.22 )) 254 2FBUS = 206.0314 “Zi ca Ad, = 2004 % Arles (-110:524 x2) + C2X 343.522) = + (2x At653) — (2x 213.495) BeS°s 20S. Beers gee ses UE, 7 : : Ks ped = beck Tacs? SI4-44883 Fy yp or PES, Llp = -21075 28% oO ae a a J. exanws) 955 Unk 2-434 [222 9 3i? Ko ip is very yur small $8 tune Productd ae also wey sma ¥ps Xoo K@, PtSS|S @® c4\ According $0 principle of chaselér He eguilioruioe Campasihin of eadothermic reach is ShiPied towards Me products ve the eM. 15 anc reases , Ya Here AW? SO > SFO fon, $0 Mat the “‘yeathn tS endotnermic mofe CO Ts Pradued if the Temp. ps tacceased ,roasia1S \ © \. Fuel el Pypozlbu > bu 70.03 W, > 202 > H29 a 2 . > Foot s.= o.unes A) ortd poversibale = Exergy = Gibs [osseumt H20 g | 0° fame at Ta2s°S and 1790 mtx dendin 7 “ur Ener Mehyeed -241.62} Fra| at BcStetez \8B,838 7m AUG RW for 1225°° wr a r S oe brSby% = -PAKNISS ae pve dthaste Ne occa for 12 BC ee = BW gop c= brhiere a2 (90-25) x19 (33.597 BU 5x2738) LHD BT ha 0 ey 3 Boren AS ArSgo2c SOS 269 * (4824S) KIO EI 25¢273IS- 9 atte) 2x 2 7 t Fral. i 210 eT BGyecz 7 $465 > Fal we can get % a5 br Gin gers > br G \9e< weate useful energy vy highet temp. prefer weet (ate?oO \e Fuel cell W440, > H,0 at bar eae yeversible = Exergy = oe Deh ' . se t —. : Avi Cp = BR Bee + 2 I tase) = tee mak ay 1228°6 2 0 uselul wie ar JF toc 90-25) - (254273.1S) A ao Spy [ 0, O44 91S PE = = - wre 2 T2B0r% ArhOe -24 27 “Bros readin Al Favor the ZT pseber Ve Pressure Increase the faa productng lower 0. of Moles Lowi Fring jo He products) as pressure decreast shiF® fo a reachian producing rag ht ng. of Mes (oni Ping to the oducts)Stes @ as the re renal OFF ciency 7 in t = > wher Pps pes es Pi Pa as fp increase the Nth increase ag as Trt he Nin increrse hale mens as Pes >P2 md Te) > Ta TB > twa but Waeitg< Waenoa o5 the ara enclosed in the cgcie decreased SR A fi aws His ® Problems (iJ aie Tysto®c 120-4 GA Nie Hak mixed with steum ot [iz Moor ZI Ty 250°C ae - (4) mK: 2494 LX, _0.622.4 04 12276 - fo-00B 061 =) 19.0 - COUR 2276) Grom Steam tale bas y= 3278.2 4 tot onc Pz lov 1 rere) ye eat iach aa x, (searcerns)} =h : he s C004% (a)t 0.00, 2500-4 ( BFAl9) * et WX — (1.004% 50) — X) hh = [2500 +0. 27x5a)) —hd) Xa We - (1.004x50) = iho Xr = (2500 + (97 %S0 — hb DhE = aw ey 4 < ‘ 0287 10° 0, 903 o my xX mye ME St 2.093.) Pace! > Vo. 5 0.giees & mes 440x198 v9 my = 73.%9 7 o¥¢ i \p= 0.93178-'S mye 0.5302® 4 ae) eee Tyas? asna WUE removed fram 2-3 X2=Xe bur G,=\ X)=%3 = 0,06 205F = o.62a Poaty oe 100 -Psat3 Psaty . J. 071F Pe Tye 4S + Seah 1593 : 455032 F394 1S) 7 43.82 PC kK hes 204 1239 ries Pei az a = (X3-%y) to Xe 0 913057 ) Dyz' Ye 0.622 x oo Pau = 056 ealtta Cfo) “99 - Peary, yz Se phe fe (Babe Je 35% Tuac 2o+ 2.0% - 2334 fe9) P63 % A (FOS ~ 0334 Ty 220°s Y= 0 013087 z or62en 233 94 2 4 joa -G x2.339) 133057 — 0: 03054 D, = L4S4tst Fe o- £749 y 4 ja there will be Ar° rayws 446 © 5. gd T2202 Psat = 2-339 PA Or\ to tes ge¢ maxunum Wee condensed A J Yas 622k 2339 . 0.01489? 1Qo- 2.33% ™ eee eee eee ae = X3-Ky (mics g-o2seot RAT: cRT Vv c: 100,009 4, 314. 300 s Peel as \ Coe GO = 4909 mune Far fr? Nyop = 49,909 Mmos ANore dermal NDA Agar — i092 39 IPE Pero br 3,38 Kates rave 2 9949 HW R-o + _ J XNor- 9, 9091 — —o mat. & rT = Z-,Lopoo La Yoni Smix 7 £0, 1997 UY 9119) = 3% JS. Fo S&perae Noa Pom Tmin? avd NO, ou need 9,34 - Fe, 3,35 mmol o 3h x BIEMMe! po agsT uy moi ae netad) Gin € Cad, tHe Chaitsu : T Vv egy gwifis ba iets Ceducts) For presse c Qin = dew at aT inp = aan mit PVs NQF tun Kp = btn Vv ps — Arh’, pz exp i) with _ pH? ged 0 prsosue f > exp AES Kp BY _5 feactian shitfs bo tt ducts oon 2 Wow ; 1FC:443 yk CAA MEIC3 problem) @ ) 10 + BB MYM +450, G Het 4 (0,13 76) > 3Or4+ 3H 2) Moz Up = 44.34 me) hil) + (45x 99-355) + (33-84 24-125) + (3x84) 3 Cpe ie a3 x (BD OAHRS = i 2418at So, = ors? Fark es cdl = yah ) Ler phe (3x-241327)4 GR 393.522) # - 2.0.42 1926-467 “& YS 78105934 Tix = (Sanger Moth 4) Bane -12 6.467 + 10° (105-25) (aaa 13.29.7485) = ray \B200H2 ay estate a -loo KWe fuel > -er.oeti? By uel” es 3 a.o023 4 Meer? Muct Mfuee = 2.3199 2 = Maire (vaBad Mus Vorta t Yup M ue) sae Kg - 6A fob - 0.06% . s : $ s é 2) dowpown + Fens fsar 2 P20 eas Petgg = Mto0 P Xyyoz 0106 - 676589 ke ; 6.765 - F324 Cue-F72 : 6765 = B.B 24 egr Tacs WOO Gagy- 5.00 2 3B 24 FCcus me? ee Met 8 ee Sntemtess ©, me Wak > 2 Fl os oF a= pce p= Vp Afue = 2436/2928 ol a = UAH x BATIK IS? (loo ~105) F036 5244 Lu Az WLd= 2x O06KT heat (oss 8: (Go tS) ipa soca ee 0.434 9.92 - fe to ome A Dy OK ATKr HEE eae “ Reine x SKOOCKT = 0106631455 EE Yo ror oer oe 0.318308 Rhos = 9. 74 vy ro ae “ we Or THE ba R < Arequiral xhickabsg ecw tsa easuyh Ty oe ‘ ) zeae SSpe ap Cg tn Be a 3654p - 9365 Hi ; = 2g atten - Sy sire ASR a 2 OATES THs 3 G63 Eye tue F543 W 7 OL Te Eye BAU ag — r \ SUK Ie Ack obs ie ( loa +273 = 4342 Ww» problem 3 8) ) stake ©) mts a ps2 T5=20°% grate (4) Bir0.g Tr oal® Staiey Bay 20.6 T4e2 2S 22-25 (3,)69- Xy= eee ae perce Bet * [00 ~ 2.671 x06 25-29 2-337) = 0,.9)01305 - 2s6Fl eh =X3 a“ Vie Gee Golee 0.2 oles iat 0.00 30867 | eples eee - 49 s PAx0 / Ko Seated up Vo hg _ YPB3l1s Ms ie 4 4 po We? 20.04 ie : i ee = Mairs Nokes We -he on ia cae Xr he -h5 erin Mas = Boro Xie \oo0 % 2000 Ki > 2990 Xz Pemin ooo Yack rt ocerrtt 3.00 1S2B5 Z 2 =e gs - he Sa= ¥ 4 Bs") h3euo “‘Ykg che 0-9101305 = 627 x Psat : \oo- Psst Psat= 9016 to? — 0.0)6 Psat Psat 26009 C EIS ve 6+ (Gor 17051 (1542) 2 y3.g2are 1-705 - 22#6 ae hate ag-57214 “Yieg om 8 8095 er a Qe a (ap -ha)= Sie Cp - ed = wr ae (hy -M) 2 awhe$14 » he SIDS BELL EEE ESE {aa | : \t=50°C. r | i \ | [s°c | (ag y | YY; y 40" S Ze kaw Oc wa, 1 e Xe \ ew NG Z< | 08 | 7 } eS \ ox | \ : Nb | est Ys, fy LN Re | Ne [ ad | | ce . ' So, el Ne. eo | Nee 2 |B NG S r | “ Y AY X- Diagramm Ul | fir feuchte Lut | AN Neo a mV D P= 100 kPa <2) lel SNe ae G05 Gon GOS 00a «0 «DSK ——_ 0 0008 400 ss aoe a7} AW/dX —= SOS ES SS“ CCGG EHH EB Seu /\~ 08:03-20)Y WSsi3l4y , Critical paint TF Te The slope af the melting curve is sheeper as Mat of We sublimmartrn curve 09° S tope: & adbS - Bherary heePteans BY Terau "TOY T O-v) as ae CHMIE IN volume berveen solid and Mrpuld phases YS BO Small malecay athe melting curve slope the Dips Pocarss : dh) 2 (Ge) p he Ta +ude dh: : as dhe Tds (ath 2 “79 \ Ts) oe AL slope@ 2. — ts0laghy isa¥herM MS2 -9nji RmLA Kj mK = ana Rin laXa % Rm bX = Mages Ri C&p Ua - XB La YB) 2. Ln Ko) =- V8 Kp ond Ke <0 (Henry 7° cisemerren BSmix = S° >O0 ». Eyso BEMgy%e0 fF, betwen a. i depends ON dp Temperatur Lif onl md 2 and pressure pastaw1304 & 5 Cy tg Cote +Hr ned Beg? -129-)$5 +3 2% i z mo z Kp = exp fae reenact BBS yo? 909 ire = 034332 =lex Nias Keune. ae te Ome \-2 Xca ig = 4 O34 ~ 324 E> 2h Zz 9.5055 Xcuty = OB2e4r Keety= Xwe 01335 FB9134 C 25cm 20.05% ie SLO. 005 In? v As th gi xol= 2 gSUxIO? i eee TAH = Qrm> Ages orm + 2x 0/0078SY = OLE me are ST Te [BS Q * Bées ] o 2,004 wor Ges = 2 ~gaaxgut * oui a y2y x200 Josue * gee _ K = AS OQ sertass = PMYESKW 2 IDDW wie 2. 2901 mn» 194 “Lara veda ry = 134 Jy = Ieaw 0 ved + Qvertust = peritag a Ges 5Ws ly Oo Na, 5 ot Tabgas = 370K CyH,0 + 34 O83 FONg)> 200+ 3,0 + 2-6 0p B53 A, NE thanaidaumpe 7 yo? 2FH6F + (® 3% 244, 82) #0 VK -393,529 > -1234.938 Ahr 2 EV Cp=[(C ob x 24. 355) + (15413839) 403.133.57) + (UxZFA0) Xo? a - 9.5968 aE Behe (234835 + (370 ~ 24815)% 0.5368 oe HW 42s 67 342 a He Agel = aa _ 842x107 6275494 156100 F | : Arh VAG 2.67300 met | 7 Musp 2 7 0:2)Ma, + 74 MN, Uhl Ha 2%-8S 08 7 - Batu Yuush. Muth 2 ees i Luft= 273.1) W— Se. 9.5868x Is grasxretx, (970-23) cst sy ee Daan” 4 thy py) }O 2WS 1B ( o © Fe "engi ee Jae cya Ts 20° =X 209) X1=%2 (2) ture (BJMK 3= 292% Tre 348 [4] Khockentl Klerduny + Wabser Te= 20°C Cy, at on [3] Pa pcatieen = 667 3 Ts = 23°C \. X= Xo 2 9/0 v1 raw ~ > _ jooa¥e = Mroceent me echt reridurg 2} a 9 My 2 333 2 20.04?S Z br 2 Xp= YO 3 %372ar8 mr Amd boy S S TAS ™ 3. ze Eth. \ |S Qt mclht -hd) <0 WS. Ch 004 420) + 9,01 (25004 (LEFT 20) ) 5 S454 ha® 22 . | a | = 10S. 96 Sw - Xa-%e 7 met in hake (1,004RN 34) 4 ga28( 2500+ Cr 87x 34)@ fy Chat -ho®) = Mywid Gee (Ts lq) 4 Carry (Tr Ta) Cty C1514) - Curw (Ts - Te) ae ee . waht= mh - me bap a 105.41 a Ree Cue Us Ty) + Cur (Ts-Ty) Pe 10>: Sudo i, : Ox t tn CME te? = es Dan 2 SESH aah 4. Hag 2 engera CHucTSey + Cw rw (TS TH) 2 143ehe ee we Ks = 20952875 braleo - STOR S i y of wo led PGs 8, fo DO” | of 4 / ja (20°C AN lead | a\, i i ‘ e| Ne. ' 7 «4 we iN fea} (| " nh’ X- Diagramm a\ 4 Se, | fiir feuchte. Luft fea S AVN t \ p+ woxra Va | . ke 005 9,010 O06 4,020 0025 030 XX —— OD B085 0,050 0,060 G70) Ae/aX —— Ne SSS Sees Se — = we\ @ $3 \3 ws - > Tinix = Trait 7 Be i Po mix = Fonihay probien \ ghaser Nein chMe Spased Nain mix Piz2 wa SS Noy) + RT Pry, | Pog QT LN Xenixny, oe of ee Xie “y a ao T- a LoWBHE ag 7 OUSF Bal - : V2. gays NS = 57637727 ASz $,-5 > Rmin Ve = Bas tng Wore 52 -]H92878 LT AEs -TuAds = = 25 12TB 1B SS im =513) = problem | 1p 8 Py x AY Raul Law Pressutt PELK Pours 3 i Mele oe Prachmal A | B But BS “Le 6 * tn 22 2 Se, tn TRO Py A TN ty fue BS yy GY DBRS jooxgg® — B3uus xia?" SORRBNS Pez: \3,6:555 moar 4\ PA Badd 5, af : : Qadd 4 bi C ‘ are, . Ore) t 5 ssSsi3 z’ pressure Para of v Py st i“ = ‘Utep = \- ey* (~~ Lat wert) WU alga depetds 0” Yy t i ings V7 (hy aut Yt — Ss = GY Op arco 29% Sa Loa S Aone Keo Chakeleu ¢ Th anc) equ ght to prada is” Cor Pressut Zunke = ac? 27Tt at b Lake = - des j, _ Xca, noe ev ae X o coe vp 2 C8 (bees) we cpt 7 eT A equalitn ate ka Woe ducts WE Pressure BU} with lead 49 -To Vie [7 tut ern | Ach?z (2x _\\0.524) + fe - suum | . 44 ENde rah ga \Fe 4 G5,S313 @ @ “yspl3 peabiern(2) eine oe Re 19 Gos oe ! I -oO z a 34 $ 0.04.6 6K6 * yoooKe ooh ee Giuc- & go, -232.7619 wv R Que ow Ay (B® -25) 227d Ke ays Ov - Bcese= 2 301SL- TEM 2) Ayr 4-434B 4260, Co, + VHD + 4. Gt. Net 9-62 sch -g02.303 eS 230.132 761 OM = net |P PUB PDA 3 es Qyeg = Be (rx 24ysr7Dt (393-529) pons 392503 \o? (100 25) (¢29:355* a.6)+ (290% 4 gq) + (2433 st) 4 C3) FA .t0 7775 Ae | matagt = Mey > 0-06 Mat oad MceyPeablam 3 55) a 3 ® t ‘ Fy = 29 ae yes a ca Rearee ae coom Tez 25°C oe 24 fs oe Xy=%3 Bi MESS / . noe ZA : 9.00 74857 12 ge 2s ENGR D eG 5 Joo - 2B BibT KEY h&= 4s.u3zs7 ZF ae 3) 29 Kw 2 my ChE ha) = a gain x(S7'D) | _ Wye SBE UT Coca s 2 a CE ie 114.2037 9? X,eka7 Xs — F051 2 bt Pa I ° (oot 4254 mos CB, 1.7951) dine ae u yO bady B75) np wenier conten nar air g.oea 1705) Me meet OS) 067434 * Fron diagram hy * 3a Was 36.2482 By y * ww ie i, = 151688 2ho. 204d 3 eA SSI © Qsy? me Che -h3) 2Fas 3m Ke _ hee 60a nGK SUZ 2 Q O27 377 Xjpz 622A 100 = 0.6.x 5.628 Sta 40 Was32F — 2. Ss@ S513 | 15°C |wWS1212 04.03.2083 © problem | ds Co, = 60 + 1 Oo, pc) when Preseure of equiliaruimn is squat be tine pressure of he reference | har ad when % tae Prodact of Me mol? Fractias of the products is equal to frat af the react’ : Me Vyes= OS as: pz Kol or) (5) 4 X cog P° as Kos aArH Np P= exp ( oy ) weohibt to reach™ hobiing Ft bo as PA He Cquilibraim wi 7 ear galled. of mares & (bata) 9° ie wh sh reac han hairy “a y shift to tne @ i Woh Lim will shen an. af ene cforvvs) $9 TE With Shier to He peodachy 32> hin = howt Pine TooKPe Cu cere Te Are = > Fou | Eye ty Boer Asirr = BSqas3 Sean flaw — hates z <0 linc hawt . = => Tous ses) wn es Q tn four op DAP es = 914893 ie Eye TAbsill = 59-6199 AL 9WS 1213ws Ir) As0d > 201% ® a Proview > coal 3 Stone cool = 649 He 64% 7! ? Jee 499 Or » 48%/H> 93 \e Cyy iy 0 0 82 3095 5 43° 6 mayo, ), + Hd! ae panne BG 13) » HH ¥b8 here (FPanir) 1 C44x 1) rCaxidye [029 2 fuel = 59 mg vat ; pee Log Hup = 2ERM Mize = 0-21 Mort Oe 2, a muse = fat @ussl Meyers VR230F 9 Mfutd oe ee ee Bhe = Hajgec = °0" Hg © [OoOx I ete . a Bhes-3lgoo (roteerenel > Ro fem cancel han | Shee piloa + 2VAKE veo ations oe 400i + [2% Ted ae eC S | Bare - 3\600 + wdervish- -9s)\ = 2UAe PEI al = 31609 az Auer She z+ 15 BO. UMW)Ye how Rew Af @ 51213 : Doze 1th H Ber = Vee iin! th Hw = mafuel x 0-36x 3h 6 KIO” 3bao rrguet = @3bkgyZ fuel 2 3.164558 Xtar real C02 produced 1,0402 2 5s Z - 9.332 pha Pijos 44074 KPA Pook = 0 232 Tyee 39+ 4577? = $026 035 -y)= 32.4664 % 5.628 - 4.244 Psahco. = F160 KPa Up = 6434 129 Veonke 100% 3% © calbtx 64g), PONS Res foo- 3.16% | % wer condensed 2 NE = 236 259% | 32 ? 2 (28% | hoo hus Visa Dhoyp, hocass) = 32- 218ES — yog3e ee = DAE | he i be. 2 jhe bhede ~ IS By yo00 X10"? ZCp Up = Px 4428) + 294X944 14) t see oi anaes RN EE ies C fino Docs = 32162 Die ose \ + Bi.cx10?) aiswWsi2 13 Peabhe3 @ (3 Te 21%C D295 moist aie V) > 4000 24, . 9G ; (2) Ty: 2% Xz= QZ 002tE Mia = 9 bry X3=Xy4 sre 3 is mx 2 : ——— a \ 109 - Psqty a-5 a Rea = 316d + eS ONO 2-339) 25-20 2.505 KPa = aoe at (x, 0.007 #844 : BVi- 9.287 G1 735) (tt 0.00781 | x 9. 9549°Z 7 jao Ougtea ie i 198 ars erat dees zaaurse #2 | Pia 17 Lee? Z L M707 HZ ite sume AY yo me> ; a Mri = \.45455 2 ths SX thy= HHS| i s woke rod = Kee Ke os << 3 Wye 1H15 me ¥g -%? uns “eT Wale of) 0434476 ZF hat= 7-516 * E5 teg - 0.6% Be 9% — Daz oP LOS — 900M = \ao— OH53 De Potae OBFU + 2-5 CO.g72l~ O4i3)= 715306 S- 99) X32 Q.004487H WE Ks J h§= 20-447 a4WS 12)3 F ora .3 3 mas qdded 2 MS eis wx (of pend Oy ge a Zoe Xgz%y = 0-00 4unsye—> ha = 2RINY azy Shean ; Way = 2675S AE ; Pook oom’ | be ae Sten a wy ng3, ho. hy + CX5 -Kq) hoeum = ee = Chooe Ts) + o-0075 (259° tener ts) Vem h& — (a.a07s y2s09) = 15 ante Cg4x 0.0075) Tes 22. anti. °C ; O = muy . Of Us Ya Qs! = muyhs - mi ht 4 mu lT | ene is : e Wg = Mey (v5 -Ay) = $ B4365 v9 r & SMU ke on A Be Ly hy +, ms! og tant Free Za ad sas / s he x hs wrsyssone 6 2 4324 et (nfs | eo | s ~Qsi= my hst I = 4 ast a 1508 Pe fom ine SE BTRSA | wen k 10$5 Flo ome air ° L a Yo mei Qs =~ @ WSN 09.93.2085 Me n3 X- Diagramm fir Fevch fe |Luth p= . Yoo kPa | CAS ei ea 4055. 4060 = 085 Se We Go is Be EEO problem \ as ASm\x = 7 Rm (na unr) - Rem (ne Lax) = Shor ( Entrepy of nected ns . gases 1G. -*s Bsmix >0 E : Turing ming). Fy 2O exe a 3 by moa oto et ws Tig wate npper heating aS we pins purse ae reve sib i Wolk no vt doesnt carb rads i : ic as oh Wag rere dynownt oo -" i i- Br & 70 ? — je)» biG dee Nye Dk 2 exothe yy combats C has fo be 7 waste Hs J u ce wetproblem L Hy = Cay? 2H + Beer 524 x2) 359394) X19 ) p=? kyed 22? 9 - 2415) Ce sie renee ee 6229021 ie : gf -6224071 Bo DS 2 -1862564 6.298 + (2x130,884) F (co aan xe) + B52 =a Sasai) tie oF ioe \2b 2915 298d 2 a54 ra le bry r= ah a a . 4 Fae js ech- fared = —Seseet Noo K 2 peal Ssaae OE ie 3.4, 32733 ashe nee fe o 7 de® Xu? & tou re Nee Be ne Kr = (xn) > (Ker) eke (=) * 34,688 vad ae 3p. 6b8 = (3578 . | ae we) Ve ara?) i yer ce re ure 2-9 $5312 39.69% ABA 6EE I” =) Q= Ach = 8214:305395 4 Ac: _|*/s 2 mal Je Oiyxta > eee 3) av, 20.4 3.t6M2) —s 2,0 +20, +30, Xqo2 Ot901! ie 5 e yo Bes & - BBUF — OP CW=25)K LAS OP gs Mhaauy Here + a3 (109-25)( 33.5774 4x 29.255 + 3:76. 25125) a - 253.10 71% u) 1%. May: 2.76% ep est mye 66.064 2