SAFETY DATA SHEET Product Name: R10-103 Revision Date: January 2021 1. PRODUCT AND COMPANY IDENTIFICATION Trade Name: R10-103 Chemical Name: Unsaturated Polyester Resin in Styrene Recommended use: Fiberglass and similar composites Restrictions on use: All others COMPANY IDENTIFICATION POLYMER PRODUCTS PHILS. INC. 14 JOE BORRIS ST., BAGONG ILOG, PASIG CITY PHILIPPINES 1600 Telephone No.: (+632) 8671-9837 to 39 Email: info@polymerprod.com 2. HAZARDS IDENTIFICATION GHS Classification (due to solvent) Flammable liquid, (Category 3), H226 ‘Acute Dermal Toxicity (Category 5), H313 ‘Acute Inhalation Toxicity (Category 4), H332 ‘Skin Corrosion/iritation (Category 2), H316 Serious Eye Damage/Eye Irritation (Category 2), H319 Specific Target Organ Toxicity on Repeated Exposure (Category 1), H372 Aspiration Hazard (Category 1), H304 ‘Acute Hazard to Aquatic Environment (Category 2), H401 Chronic Hazard to Aquatic Environment (Category 3), H412SAFETY DATA SHEET Product Name: R10-103 Revision Date: January 2021 GHS Label Elements Hazard Statement H226: Flammable liquid and vapour. 304: May be fatal if swallowed and enters airways. H313: May be harmful in contact with skin. H315: Causes skin initation. H319: Causes serious eye irritation. 332: Harmful if inhaled H335: May cause respiratory irritation, H372: Causes damage to organs through prolonged or repeated exposure, H411: Toxic to aquatic life with long lasting effects. Precautionary Statement P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking, P260: Do not breathe dust/fume/gas/mist/vapors/spray. P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing, 331: Do NOT induce vomiting P370+P378: In case of fire: Use sand, carbon dioxide or powder extinguisher to extinguish. P403+P233: Store in a well-ventilated place. Keep container tightly closed P403+P235: Store in a well-ventilated place. Keep cool.SAFETY DATA SHEET Product Name: R10-103 Revision Date: January 2021 3. COMPOSITION/ INFORMATION ON INGREDIENTS: This product is a mixture. Component CASRN Unsaturated Polyester cer Resin Styrene 100-42-5 28-27 *Components declared as CBI are inert. 4. FIRST-AID MEASURES Description of necessary first-aid measures If inhaled: Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional treatment. Ifon skin: Remove contaminated clothing. Flush exposed area with water and follow by washing with ‘soap if available. If in eyes: Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention, If swallowed: If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. Wash out mouth and lips with water. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Most important symptoms and effects, both acute and delayed: Skin contact causes irritation, redness and pain. Repeated exposure may cause skin dryness or cracking. Eye contact may cause slight irritation, watering, redness and pain. Inhalation of vapors may cause drowsiness or dizziness. Ingestion may cause irritation of the mouth and digestive tract. If swallowed, aspiration into lungs may result in chemical pneumonia Indication of any immediate medical attention and special treatment needed In case of accident or if you feel unwell, seek medical advice immediately. If swallowed, patient should be monitored for signs of breathing difficulty as effects of aspiration maybe delayed for up to 48 hours. If breathing is labored, qualified personne! should administer oxygen.SAFETY DATA SHEET Product Name: R10-103 Revision Date: January 2021 5, FIRE-FIGHTING MEASURES Suitable extinguishing media: Water spray, BC-powder, Carbon Dioxide Unsuitable extinguishing media: Do not use a direct water jet Specific hazards arising from the chemical: Flammable liquid and vapor: Vapor may form explosive mixture with air. Vapor is heavier than air and may accumulate in confined spaces. Vapors may travel considerable distances to ignition sources where they can ignite, flash back or explode. The product will float on surface water and can re-ignite. Containers exposed to heat may burst due to increase in pressure. Combustion may liberate toxic fumes: Carbon monoxide, carbon dioxide, various hydrocarbons, nitrogen oxides, sulfur oxides. Special protective actions for firefighters: A self-contained breathing apparatus and suitable protective clothing should be worn in fire conditions. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures for non-emergency personnel: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharge. Use only non-sparkling tools. Use explosion-proof electrical, ventilating and lighting equipment. Caution — spillage area may be slippery Keep upwind. Ensure adequate ventilation. Avoid inhalation of vapors. Avoid contact with skin and eyes. Wear suitable personal protective equipment. Wear appropriate respirator when ventilation is inadequate. (See Section 8). Personal precautions, protective equipment and emergency procedures for emergency responders: Keep unnecessary personnel away. Wear suitable protective clothing (See Section 8), Contaminated clothing should be thoroughly cleaned. Environmental precautions: Collect spillage. Do not allow to enter drains, sewers or watercourses, Spillages or uncontrolled discharges into watercourses must be alerted to the Environment Agency or other appropriate regulatory body. If spill occurs on water, notify the appropriate authorities and advise shipping of any hazard. Methods and materials for containment and cleaning up: Stop the leak if itis safe to do so. Contain the spillage with sand, earth or any suitable adsorbent material. Use sand, earth or any suitable non- combustible adsorbent material to adsorb spillages. Using non-sparking tools transfer the contaminated absorbent material into a container for disposal. For spillages on water, remove use appropriate methods such as skimming, booms or adsorbents. For spillages onto soil, remove contaminated soil for remediation or disposal in accordance with local regulations. Waste containers used should be plastic-lined sealable drums. Containers should be sealed before being disposed of via an authorized waste disposal contractor. welfinw & le LS He... | be BeeSAFETY DATA SHEET Product Name: R10-103 Revision Date: January 2021 7. HANDLING AND STORAGE Precautions for safe handling: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparkling tools. Take precautionary measures against static discharge. Use only outdoors or in a well-ventilated area. Provide adequate ventilation, inoluding local extraction, to ensure occupational exposure limits are not exceeded. Avoid breathing vapors/spray. Avoid contact with skin and eyes. Wear suitable personal protective equipment (See Section 8). Do not eat, drink or smoke in the vicinity of the product. Wash thoroughly after handling. Take off contaminated clothing and wash it before reuse. Contaminated clothing should be thoroughly cleaned or disposed of as hazardous waste. Conditions for safe storage, including any incompatibilities: Keep away from heat and sources of ignition. Keep away from direct sunlight. Store locked up. Store in a well-ventilated place. Store at 25°C or below. Keep container tightly closed. Keep cool. Empty containers retain product residue and can be hazardous. Keep away from oxidizing agents, reducing agents. This product must never be stored in buildings ocoupied by people. Drums and small containers should be stored in well-ventilated areas, flameproof cabinets or stores. Keep in a bounded area with a sealed floor to provide containment against spillage. Stack drums to a height not exceeding three meters without the use of racking. Seek specialist advice for the design, construction and operation of bulk storage facilities. Use explosion-proof electrical/ventilatingllighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Contro! parameters Data below from IDESA Styrene SDS Exposure limits Component: Styrene CAS-No.: 100-42-5 Identifier: VLE ‘TWA: 20mgim3 STEL: 40 ppm Source: NOM-010-STPS Remarks: TWA- time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours’ time-weighted average ‘STEL-— short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period unless otherwise specifiedSAFETY DATA SHEET Product Name: R10-103 Revision Date: January 2021 Human Health Values _ _ Endpoint __| Threshold Level Route of Exposure Exposure Time DNEL 85 mgim* inhalatory Chronic Systemic Effects DNEL 289mgim? _———_inhalatory ‘Acute Systemic Effects TDNEL —_| 306 mg/m* inhalatory Acute Local Effects _ | DNEL 406 mg/kg bwiday __ dermal _____ Chronic Systemic Effects *DNEL — Derived No-Effect Level Environment Values Endpoint | Threshold Level Organism Environmental Exposure Time Compartment PNEC 0.04mgil Aquaticorganisms water Intermittent release PNEC 0.028mgl — Aquaticorganisms freshwater Short-term (single instance) PNEC 0.014mgl Aquatic organisms Marine water ‘Short-term (single instance) PNEC 5 mg! ‘Aquatic organisms Sewage treatment |Short-term(single plant (STP) instance) PNEC (0.614 mg/kg Aquatic organisms Freshwater sediment [Short-term (single instance) PNEC 0.307 mghkg Aquaticorganisms Marine sediment Short-term (single instance) PNEC 0.2mgkg —_Terrestrialorganisms Soil Short-term (single instance) "PNEC — Predicted No-Effect Concentration Appropriate engineering controls: Provide adequate ventilation to ensure that occupational exposure limits are not exceeded. Local extraction may be required. Eyewash and quick-drench shower facilities should be available in the work area. Contaminated clothing and shoes should be thoroughly washed before reuse. Individual protection measures Eyelface protection: Goggles or safety glasses with side shields giving complete protection to eyes. (EN 166). Depending on conditions of use, close-fitting eye protection and a face shield may be necessary. Skin protection: Chemical-resistant gloves. (EN 374). Suitable glove material: nitrile, neoprene or PVC (breakthrough time > 240 minutes). Contact glove supplier to confirm suitable glove material, thickness and breakthrough times. Long sleeve protective clothing. Nitrile, neoprene or PVC apron. Rubber boots ~6~ XxSAFETY DATA SHEET Product Name: R10-103 Revision Date: January 2021 Respiratory protection: Where airborne levels below the exposure limits cannot be maintained, wear an air-purifying respirator (EN 140) with a Type A/P2 filter or better suitable for organic gases and vapors with a boiling point above 65°C. (EN 14387). Thermal hazards: Wear suitable temperature resistant gloves and protective clothing if the product is heated. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state Color Odor Odor threshold pH Melting point/ Freezing point Initial boiling point and boiling range Flash poi Evaporation rate (Butyl Acetate = 1) Flammability (solid, gas) Upper! Lower explosion limits Vapor pressure;(mm Hg)(styrene) Relative vapor density (air = 1)(styrene) Relative density (water = 1) Water solubility Partition coefficient: n-octane/water(log Kow) Auto-ignition temperature Decomposition temperature Viscosity; (Gardner-Holdt) Explosive Properties Liquid Purple Characteristic Typical Styrene odor No data -31°C (based on solvent) Above 145 °C 31°C (based on solvent) 3.85 mg/l, 21d Microorganisms/ Effect on activated sludge Not determined. ~9~SAFETY DATA SHEET Product Name: R10-103 Revision Date: January 2021 Persistence and degradability Carbon dioxide generation: Degradation rate >50%, 33 d Bio-accumulative potential Data are not available. N-octanoliwater (log KOW): 2.96 (25°C) (ECHA)BCF: 74 (ECHA) Mobility in soil Data are not available. Henry's Law Constant: 231.6 Pa-m’fmol The Organic Carbon normalized adsorption coefficient: 2.547 (ECHA) Additional information Not available 13. DISPOSAL CONSIDERATIONS DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OFWATER Waste disposal of substance Solvent may be reclaimed/regenerated. Do not empty into drains. Avoid release to the environment Refer to special instructions/safety data sheets, Container disposal Only packaging is which are approved (according to local and national regulations) maybe used. Completely emptied packages can be recycled. Handle contaminated packages in the same way as the | substance itself. 14. TRANSPORT INFORMATION Land transport ToS Proper Shipping Name: RESIN SOLUTION Hazard Class: 3 UN/NA: UN1866 Packing Group: Ii Information reported for product/size: 200 L Sea transport IMDG Proper Shipping Name: RESIN SOLUTION Hazard Class: 3 UN/NA: UN1866 Packing Group: Il ~10~SAFETY DATA SHEET Product Name: R10-103 Revision Date: January 2021 Information reported for product/size: 200 L Marine Pollutant: Yes Airtransport IATAIICAO Proper Shipping Name: RESIN SOLUTION Hazard Class: 3 UNJNA: UN1866 Packing Group: I Information reported for product/size: 200 L 15. REGULATORY INFORMATION Statutes, regulations and standard: The regulatory information is not intended to be comprehensive. Other regulations may apply to this material PICCS (PH): Listed PCL (PH) : Not listed CO (PH): Not included. PDEA (PH): Not listed. PNP (PH) (Explosives Control): Not listed PICCS — Philippine Inventory of Chemicals and Chemical Substances PCL-Priority Chemicals List CO - Chemical Control Orders PDEA Philippine Drug Enforcement Agency PNP Philippine National Police 16. OTHER INFORMATION Revision Version 1, February 2, 2011, R&D Engr/R&D Manager, 16 pt GHS Version 2, June 2, 2020, Product & Process Engr/DFD, GHS New Format References PICCS - http:/ichemical.emb.qov.ph/?page_id=138PCL - htto://chemical.emb gov.ph/?page_id=52 CCO - htto://chemical mb. gov ph/?page id=44 PDEA - http //pdea.gov.phicomponent/content/article ?layout=edit&id=55 PNP - www.ico.ora.oh/wp-content/uploads/2016/02/IRR-of-RA-9516-on-Chemicals-and- Accessories-as-of-Feb-2-2016.doox