JUGRAN CHEMISTERY CLASSES SUSHANT JUGRAN (9811605228) CLASS=XII COURESE CO-ORDINATOR CHAPTER= ALCOHOLS, PHENOLS AND Ad INCLUDING 1. Chapter Notes. 2. NCERT Text-Books Question [solved]. 3.NCRT EXEMPLAR PROBLEMS [solved] FREE CLASSES FOR GOVT. SCHOOL GIRLS ALWAYS BELIEVE IN HARD WORK SASTAEITE Teaeneeee, Scanned with CamScanner“s JUGRAN CHEMIst ht ULosro 5 foaussszens SUSHANT JUGRAN = - BEFOBBE20 Ricohois, Phenols and Ethaxs. h= Alcohols =* gE tay Hee nee tt __ Shyvelose of lesbols i= In aleolol, hols ra cevbon aboms BF Rand onygen olom of =o # group are sp ? hy buidr2ed.. ba C-OH bond oe Is slighty lass Hen ot Be, _ tvahodyal angle (109%) dus to Woe 7 Lxepulsion bf Tene pis ofelactsons of 2 2 a onyge? atom. _ — —Maehdaisme -— 1a) Pxotonation of glkene [b) No clesPhi I blak ofssok»an aoe te ee { ae —pue +h bb 4 ©) beProtonohins - yo —2 —l-9g5 ©) By hydsobo sation ~exiclahen! Addition secur in And” Mark suniKov's Usay. Ay, 3440, Bion cach, + cunt 8 BH er mb } H~CH-OH + Jay we NR Scanned with CamScanner if tite emai2s From Caxbony! compound + Jue hi Ip and Ke dongs é (ad By vedectton of aldehyde and ed oe Re CHO Hy TS Rech OH 7 - Nab My’ _ R= co-p th, a ee (b) ey vedueton af cavboxy lie acids ; (hy Lily Lie Bo woon ina oO LiAlHy is an axpensive weagent anc Here fo 72, Used foy Prepasing. spacial chensicels' enky, - Commercialy,.acids tham to the. 8. Feom Uh vignaacl.redg ants i, Thavecehion of lratonard 's | weogents wits “faema dahode PrPdo eta prima rya leoLel, ta ihe elle y aldalyde H+ pradoces Secondary alcoho) anc Hevhiasy aleole) suai. ke tones. 0) F028" Pxtmarry- We CoG ” one fier otal! Haley EP of 4 A any Cb) For #eeondary Alcoha) s | Rix red 825 nf, tg Scanned with CamScannerfor texhary aicoholss- ° ony jon ‘s dit t= Physical Propextas of Alcohols =X 4. Lower maubers cf alolols are colourless, volatile lavids. te Solubilitys-C4) Al cohe!s axe Soluble 1h watdy because hey fowm infareolecdax hy dsogen bord s wills wofey mro/ecudes . ye Buk Solubility doc. Wilts the incxsane) foot in molatvlor mass beravse hydrocxton | — AC pe port nes wo hed rs hydvophabre in | ‘ ib S foy iL natpres . a (by Boiling potnts:~(0)8.P: tempwm ofalcolsis axe hry has F compeiee non - polar rolecule. oe (1) Bue. ircveases WIM Me ine rcase “0 malecolay mass because Svefaca ore incxease due to tohich Yon dar hsaa!s : foxa@ ine yeasas. wine. ft . pe "Chemical Propextes ef Alcohols = x Hey t nes. = Reaach'on to volving cleavage of OH bend. —* ; 4. Acidity of aleehels- Blesle! reset esits ach'xa motels Such as Sed/um > potassionm ete dp git alkoxide. DRoo-H +4Na —> 2f-0-Na + Hy Sedium alka rick Scanned with CamScanner0 -b Heo > Reo- + oH” ee Bose Act Tris veactin shows Hetteater 'S 6 Strong ecret Thor Readity 6f alahols:- Seong acid \- In this case elactsan density ovex oxygen atom 1s” lé0 dus to this polarity of OH inc xeases. (oeok ecide- In i's case alactmndensity over ox artery is ie dun tothis poloxity of 6 —H cleczeases. Dee veating ouch of addie st xang the P22° £2.39 alcoho! 4 Prion amy. -alcole) i's a strong aco! aye only ona eLachianclonating alky | guoupis paeseak Ae clea te Hw's electron _cleosi. we ova + eaygen ate, is love. - Pyridine i fe wu e750 a5 | in nauvalise HCLand shifts. eauil, hsium. to the igh hand sid A— Resch'on to volving cleavege poe ae =Oxyge lo Jy “¢q? Reaction Gi Hy hydrogen hal icp z= = Reon +HO 2%he R-C) + HO ! The diflevanes th waochvily of ff sand? A aleole lewifis H. Ccditting ish them firora aach ote 9( LUCAS TEST),.lucas Reogand= 2nel, + cones He) (b) Reaction with phosphorus halicht~ R-oH Pd, —S — R-¢] Cle] Acidee ~ Dahyduotiont a Hy C= CH, On artes 4,C=ch, + £O k Keane. Scanned with CamScannerCham} y : nami co) Vvopesh'es of Pha nol Psnalss (0 Aeidily gy ; ONG d +aNq ——} +h, oH Soders phanoride ONG 2 a + Noadh os ey +hoOo aia Phane) ise “3 ocd as compaire to allel - dege 40 fo loo) WOO ser Benrane wing act as $ gloctmon titel wave ing and decreoses te eeclron clamsity avex teeny fn atom. 3 tite ae tae if li se" H. fa) Geo aly a er th Gre Le (6) Phanexida ion is vesonancaly Stobilisad uk alkoxide [on is not wesonancaly Stabilised. % Effect onthe acidre st angie of phenol by oe ~ fa.) Elactson usithdrqwing voupi- Th ineweases the acidre Stren git hacoz alactyen “density decreases. fH oH (6) Elactson donah. woupi- Tt dacveases the acide St xanghh hecoz elector dansity inc veases. Scanned with CamScannerAO o-Alityophene |” P-nitvoplarg yy) : : ; ortho nitrophenol js 6 sheam volotl> Secoase doa fo lotsa molaculas hyd segon bandit oan” * 4 Tana molecvlay ny d 9092" & es a (b) forees rid sop hana | not a volahle dire 5. thtaxmoloc ola y hydrogen bonding. po-Z_ ak, noX_ythe- . En te vrolawley hyd segen bored on oH A prey Nos, () bones : ( y 4 Ca, '46 Feinitsophano!] CPiewie acid ) : han t- eq i He.logenatian on 4 y 6 283 By + 3 5, Wat LY RK oy cb) Minoy Ba a pt aH poey oy mola (4+ Bm 3 Yay Ga cy (a I Last, 6-Trikvorepharnol 7 7 Scanned with CamScannerfo, 2 1 - YO. a (b } Fou ony of caxhocations- bolas ocations H Yop LIne y re ay, alae hfe be +O a to Gl and y" * . (@ ) peP plo 4 he ae jn! = pdm etl +H? ois enidising a C5503 nO 3 evicting agen hice ee aes bla y — brsek aaa] agen tim CxO; Conlyduoes) oy ee, _ — a ~hhumek, — —— kno, | Roch -oH - Le OrogPl wo Re eyo mK | ,~ | R-CHTR —S5ic dv = Ot z a oky St Ree fC Brae cn; *= Physical Properties of Alcohols =x (a) Tha lowe x member of alcohols ave celourlass,vola He | Wauids . (b) Solubility of aleobelsz- “ (1) Aleolels axe soluble in wetes because Koay foxrs itor — melacvlax hydveqen hond usiths center, | (i) The sekebility dac rer ses mass because hyd! wits Heine veese Ine molacolar shy ample | part Sreveses oh Scanned with CamScanner\ ai In Matese. WB (<) Boiling peints:-riy Bs? of Gleohols ave high Sue Hon pone palay mele coles. CY BoP ie reases with Ie ineseose mo moleccley ne because suxfoee avea incveases dus. to fis mo: of Von dey, Woals fowastrerensas-- p “ 5 (ii) BP decreases usifty Hae branching becouse soy fag axvaa decreases. be x Phanals a Prroparection of phenols~- (1. Fromm jreloa wena sz Na oH) To ARK 6 ————> oo ‘ eibdeieieest= cos) oe o> a Phare} + From hanzena.. Aelphoric ecids- on l Oa cleum a “neon i ay Ae Benaanesu phonicorid a (i) Prorg dia 2oniom eh ng - oft f) ramg/Pel CO Mb jroaven QO a On 5 2 Phanal a (iv ) Feom comene t- 1 8 1B It | -— cH on cecil ty pe | oe / thelr chy Be | Comang . ; Vy tve prone ( Scanned with CamScannerihe ar Roiomar ~ Tramann Yeacthisns- , Na oe on lex oe, Js) eneyt Maoh , Lena i pease a cme fonda Gen fen, eye, Oy hano! suv boe Phono os Salicylalde lyde . “Wydvory honral do ly de | 5. Kolho’s Roachen ge : ele on Wyn? SS [satighicracid 74 \ Ca-nydeoxy bensole acid F 6 Recchog, with ziec do stim. — Oo 7 — - 5 4 —Oridehion i- 7 == - ~ Ja,Ge07 : 4 oe : Pe . on | 9 Ben202vinéne | P= Some Commercially Im poxtint Gripounds = % . 20-405 H, (—o HH | eit ee COTM, footooatm gC~e | 55 -67IK Ishighly polsonovs in nateve. Th sused asa soluek in | B 7 P | points, varnishes. | ch, Be Ethenoli- Cis My Oy F Hy 0 > G Hy Og + Gly % Sucyo so. Crletose Fsvetose i " CoH iy 0, 222 IG HoH + atlo, : Litespeed Pe ane — Scanned with CamScannerHW 1S6s0d rn caine matting « Deveder gos The comme sleshel Morcade ont ore fox drinking |, mixing ini} some ceppos Sulphate Vien and Py midida . 18 Knduan as clenate xa tan of aleoho) yes OE thaxs = ™ Prapa ration of ethers s- (i) By acide dahbydweton of aleohels3~ io Th tis method df mole of primary alcolel 1s convork In to Ssymmetzical other. a "ase ; H+ we — CH eres! ~ChH ~6 ~ CH Hy (Cty ~-OH > tec -0- Ch, + Hy O Gigk a 7 ° i Limitahionz- Ty thts mathe a 2° and 8°aleohe)™ 7 . : are bsed bacousg: elimination compates Ovex substitution ond okkenes axe fox mad. mo 1ii) Williamson Synthesis t Ih this xeachon Primary alkyl Lelia oe och With sediem alkoxide oxphenovide to form etias Th this mathed symmetrical as well as on. atlers avafoxmed. hO-Cl + hO-ONG —s Hy; —O— Che sy meetaical hy Ona + tC— C1 —S bg Co Ch, <0 -Chy (Ns Che ho- G-ena ATH I (—¢-0- ch, er Chg &i Om Syria o-cH pos <9 + coe) — © DT .. \ wa 5 Wee tt y This tuochon follows He Sag BAK. os ache bro Scanned with CamScannerS Lidetiont Tn His meted 9° and rn ora rol used because alis hate fHonvend clkene Jeesbse), . 4= Phy sical Properties of offay = alkyl helices 5 Gy sobshte - Won Cran po Slee Covered fi} Ethers ave Polax but thers polarity i vsak dus Jotte prasenca of two olky! groups 1) Botling point > “B-Raf aliay ave lou as / comperixe to oleobo! duc Jo the took dipole -~dépele | 0 hy Noe i (ti) Solubilifve- Soluble in wouter dus te te formettien 4 Hy Oo of inter molecu lay by claegen -bond. —f tole) FS Shamita! Pro par tras of eter 2%. oh . ( (i) Reachion & Wo itte hydvegén @idi>. In casa sf primary aHes Sad mechanism follews amd in cate ck 2%, Bete s S02 mrechaniem: Fellas, ae, 2 y) Lelie! _ 3) hC-o- Ub aT > cont mem + chs ony i hO~ Enoch, thl —> he—d-7 + hyC—OH o> che OH ! iv] 9 i CO tHE —s oO + he“ LT om @D) 5 . iQ & ! a : i. rl Scanned with CamScanner| a (hy Ehelve philic Sup shi Johor wee flor s— Een 7 a chy “s CL» 6 Z vies! (ar) Hagens te = Lol Ch; pre oO By, Pts Clay) s e daqrh I. z + ee a uM Br (6) Nibedtion ¢ Ochs eon “Othe } ~ AS HN Le a ho ap oe HR Eyiedel—Csaft ecbens- (2) Alley lecfior “3 CH. _ 3 : 5 . pace _ c chy (OCs + hc anny ZL tH emet Larbys (J + Y% ; <2 : on . . ¢ 05) Acy lation: g 3 AlCl, O¢hy - / $F Mh,C-00 1 LZ O-Ch Uses of Ehexss a 5 ¥as!'P Se b et used as sohent By oils, gas /8) Dtsosed as solvigce yeni, Scanned with CamScanner | D EXA " A An Ao