aeliaachem ® Safety Data Sheet Ammonia, Anhydrous Date of Revision: 15 Aug 2019 Date of sue: 13 Nov 2014 Rev. No, 11 (Ete Aue ke 1.1 Product Identifier Product name ‘Ammonia, anhydrous EC number 231-6353 AS number 7664-41-7 (Chemical Formula NH Index No 007-001-005 1.2 Relevant identified uses of the substance or mixture ar uses advised against Product Use ‘Manufacture of substance / Synthesis and formulation of liquid or solid mineral fertilizers / Intermediate / Formulation / Distribution / developing agent in photochemical processes / Refrigerant / Insulation materials, other / Inks and ‘toners / Coatings and paints, thinners, paint removers / Industral use of reactive processing aids / Extraction solvent. / Treatment of gas (NOx and SOx reduction) / in nutrition / Neutralising agent / Textile dyes, finishing and products; including bleaches and other processing aids / Water treatment agent / Manufacture of textiles, leather, fur / Wood:-treating process / ‘Manufacture of pulp and paper / Surface treatment of metal, other / Washing and cleaning products (including solvent based products) / Manufacture of rubber products / Manufacture of electronic components Semiconductor / Manufacture specialist chemicaV/other products (e.g. adhesives, biocides, catalysts, cleaning products, etchant, cosmetics, coatings/paints, construction chemicals, corrosion) / Sealants and adhesives / Polymer preparations and compounds / Air care products / Preservative Uses advised against» Extreme heat (Products which require extreme heat in the process of manuifacturing) ‘© Incompatible substances (Products in which manufacturing processes are included one of the following substances: silver, acetaldehyde, boron, halogens, perchlorate, chloric acid, chlorine, monoxide, chlorites, nitrogen tetroxide, tin, and sulfur) '* Drugs fabrication (The use of the substance should be limited to those specified in the Chemical Safety Reports) ‘Areas of Application Industrial and Professional applications regenerate + through + solutions Page 2 of 23Pride-Chem Industries Pe Lid Safety Data Sheet: Ammonia, Anhydrous ev. 11 1.3 Details of the supplier of the Safety Data Sheet Pride-Chem Industries Pte Ltd 2 Tuas View Lane Singapore 637657 Singapore Tel: +65 6861 7641 / 5130 Fax: +65 6861 1055 Website: www.pride-chem.com.sg Es ‘address of competent person responsible for the SDS 1.4 Emergency telephone number Jimmylim@pride-chem.com.se Telephone number In emergency of any nature, call SCDF 995 (24/7, Singapore) Singapore +465 6861 7641 / 5130, +65 9848 3853 (mobile) Monday-Friday (except public holidays), 8 30 am —§ 30pm ae a n 2.1. Classification of the substance or mixture Product definition Mono-constituent substance 2.1.1. Classification according to Regulation (EC) No. 1272/2008 (CLP) ‘Hazard ‘GHS Hazard Classification Category ‘HCode Physical Flammable gas 2 H221 Gas under Pressure Liquefied gas H280 Health Acute toxicity (Inhalation) 4 H331 ‘Skin corrosion/irrtation 18 314 Serious Eye Damage/ Irritation 1 H318 Environmental Acute hazards to the aquatic Environment 1 400 2.1.2, Additional Information None 2.2. Label elements Hazard pictograme = Signal Word Danger Hazard statements He2t Flammable gas #280 Contains gas under pressure; may explode if heated regenerate «through « solution Page 2 of 24Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous fev. 11 1314 & 318 Causes severe skin burns and eye damage 4331 Toxicif inhaled 4400 Very toxic to aquatic lfe ‘Supplemental Hazard Information EUHO71 Corrosive to the respiratory tract, Precautionary statements Prevention 210 Keep away from heat / sparks / open flames / hot surfaces. - No smoking 260 Do not breathe dust / fume / gas / mist / vapours / sprays 273 ‘Avoid release to the environment 280 Wear protective gloves / protective clothing / eye protection / face protection Response 310 Immediately call a POISON CENTER or doctor/physician 363 ‘Wash contaminated clothing before reuse 377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely p38i Eliminate al ignition sources if safe to do so 391 Collect spillage P301+P330+P331. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P303+P361+P353, IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing, Rinse skin with water / shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Storage P403+P233 Store in a well-ventilated place. Keep container tightly closed 405 Store locked up 410 Protect from sunlight Disposal 501 Dispose of contents and container in accordance with all local, regional, national and international regulations 2.3 Other hazards Substance meets the criteria for PBT accordingto —N.A. Regulation (EC) No. 1907/2006, Annex Xl Substance meets the criteria for vPvB accordingto—N.A. Regulation (EC) No. 1907/2006, Annex XII Other Hazards which do not result in classification _Liquid can cause burns similar to frostbite Exposure to fire may cause tanks/cylinders to rupture / explode regenerate «through « solutions Page 3 of 23Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous fev. 11 3. Composition / information on Ingredients Substance / Mixture ‘Mono-constituent substance Product / ingredient name Adentifiers ‘Weight % content ‘Ammonia, anhydrous. EC: 231-635- >995 (CAS: 7664-41-7 Index No: 007-001-00-5 Water EC: 231-7912 <05 CAS: 7732-18-5 Eee General notes Inhalation Skin contact ‘Ammonia vapour/gas reacts with water or moisture to form caus hydroxide that causes severe burns. Remove contaminated clothing and shoes as quickly as possible. Remove jewellery or accessories that may restrict circulation. Flush skin with plenty of water for at least 20 minutes. Description of first aid measures The following applies to all of the below exposures / contacts (inhalation, skin, eye ‘and ingestion): Move victim from incident site to safe area with fresh air and keep at rest in a position comfortable for breathing. Seek medical attention immediately. Call a poison center or physician. Chemical burns must be treated promptly by 2 physician. Show this safety data sheet to the physician in attendance. ‘Ammonia vapour/gas reacts with fluid inside the body to form caustic ammonium hydroxide that causes severe burns. if not breathing, breathing is irregular or respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation without protective barrier (CPR mask is highly recommended). if heart hhas stopped, cardiopulmonary resuscitation (CPR) or automated external defibrillation (AED) should be given by trained personnel. If unconscious, place in recovery position. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. hospital for stomach cleansing as soon as possible. After inhalation exposure, observe for 24-72 hours as pulmonary edema may be delayed. {Lcontact with liquefied ammonia Do not remove clothing but flush frost-bitten areas with plenty of water. Clothi frozen to the skin should be thawed before being removed. Carefully cut around any clothing that sticks to the skin and remove the rest of the clothing. If possible, warm frozen tissues slowly with water and get medical attention. Do not rub affected area. lation is significant or prolong, send victim to the Immediately flush contaminated eyes with plenty of gentle flowing water. Continue washing for at least 20 minutes, occasionally lifting eyelids. Do not interrupt flushing. Remove contact lenses, if present and easy to do. Neutral saline solution ‘may be used as soon as itis available. regenerate «through « solutions Page 4 of 23Pride-Chem Industries Pe Lid Safety Data Sheet: Ammonia, Anhydrous fev. 11 Ingestion Self-protection of the first aider Inhalation ‘Skin contact Eye contact Ingestion If conscious, give victim water to rinse mouth. Do not induce vomiting unless directed to do so by medical personnel. If not breathing, breathing is irregular or respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation without protective barrier (CPR mask is highly recommended). Never sive anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Wash out mouth if possible. Ingestion of liquid can cause burns similar to frostbite. Send victim to the hospital for stomach cleansing. Chemical burns must be treated promptly by a physician. As this product rapidly becomes a gas when released, refer to the inhalation section. No action shall be taken involving any person without suitable training. Take proper precaution to ensure own safety before providing aid. Wear appropriate PPE (Refer to Section 8 for information on appropriate PPE) such as chemical protective clothing, gloves and breathing apparatus if ammonia is present on the victim or surroundings. ‘Most important symptoms and effects, both acute and delayed ‘Ammonia gas or vapour has strong pungent smell that is very irritating or corrosive to the respiratory system. Symptoms include dizziness, nausea and severe irritation of throat & upper respiratory tract with cough, wheezing, shortness of breath, chest ain, and vomiting. Prolong Inhalation may be fatal as a result of spasm, inflammation and edema of larynx and bronchitis, chemical pneumonitis and pulmonary edema. Cessation of respiration may lead to death if exposure continues. Serious effects may be delayed following exposure. ‘Symptoms may include redness, blistering, pain and irritation. Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite. Cooling effect may mask the extent of corrosive injury received. Long exposure may result in destruction of tissue. Symptoms may include redness, watering, irritation, swelling, excessive tearing, frostbite, pain and blurred vision, It may cause serious eye damage or even blindness. Liquefied ammonia causes burn to mouth, throat and stomach with symptoms Include dizziness, nausea and severe ritation of throat & upper respiratory tract, with cough, shortness of breath, chest pain and vomiting. Ingestion of liquid can ‘cause burns similar to frostbite. Serious effects may be delayed following exposure. Indication of any immediate medical attention and special treatment needed No special treatment. Symptoms may be delayed. The victim may need to be kept under medical surveillance for 48 hours after exposure. regenerate «through « solutions Page 5 of 23Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous fev. 11 Gaines 5.1 Extinguishing Media Suitable extinguishing For leaking gas fire, do not extinguish, unless leak can be stopped safely. Stopping the media flow of gas rather than extinguishing the fire is usually the best procedure to follow when escaping gas is burning. If ammonia gas/vapour is burning, use dry chemical powder or carbon dioxide for small fires and fine water spray / fog or dry chemical foam for large fires. These extinguishing agents should also be suitable forthe type of surrounding fire, Unsuitable Avoid using water jet directed inside the ammonia containers / tanks as violent extinguishing media reaction may occur 5.2. Special hazards arising from the substance or mixture Hazards fromthe Contains gas under pressure. Flammable, corrosive and toxic gas. In a fire or if substance of mixture heated, pressure buildup, auto-ignition or subsequent explosion of container may ‘occur. Ruptured cylinders may rocket. This material is very toxic to aquatic life. Fire water contaminated with this material is highly caustic, must be contained (eg. bund wall / absorbent / sandbags) and prevented from being discharged to any waterways, sewers or public drains. Hazards combustion The main products of combustion in air are water and nitrogen, with small amounts, products Of toxic and irritating nitrogen oxides (NOx). The combustion of ammonia in air is very difficult in the absence of a catalyst (such as platinum gauze), as the temperature of the flame is usually lower than the ignition temperature of the ammonia-alr mixture 5.3 Advice for firefighters ‘Special precautions Promptly isolate the scene by removing all non-emergency personnel from the for fire-fighters vicinity of the incident if there is a fire. Contact experts / supplier immediately for specialist advice. Eliminate all ignition sources if safe to do so. Shut off flow immediately if safe to do so. Move ammonia containers (portable tanks / cylinders) from surrounding fie if safe to do so. If the containers cannot be removed, spray cooling water to sides of containers that are exposed to fire until fire is out. This prevents heat from building up, resulting in container rupturing due to overpressure. However, do not get water inside container. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. Stay away from ends of the tanks due to exploding potential when tanks are involved in fire. Fight fire from protected location or maximum possible distance. If this is not possible, withdraw from area and allow fire to burn. Fighting fre with unmanned firefighting equipment Js highly recommended. Use fine water spray or fog to extinguish flames and suppress vapour. Do not direct water into spilled liquid ammonia unless more than 100 volumes of water are available for each volume of liquid ammonia. Addition of fire water will warm cryogenic liquid, resulting in greater gasification/evaporation Special protective _Fire-fighters should wear appropriate chemical protective clothing and self- ‘equipment for fire- contained breathing apparatus (Refer to Section 8) that is safe for use with ammonia fighters involved in a fire. Fire-fighters’ normal protective clothing (bunker gear) with helmets, protective boots and gloves does not provide adequate protection. regenerate «through « solutions Page 6 of 23Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous fev. 11 re Boe 6.1 Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Put on appropriate PPE (Refer to Section 8) when handling this product. Accidental release poses a serious fire and explosion hazard. A dangerous concentration of this gas in the air will be reached very quickly on loss of containment in confined space. Shut off main valve or flow if safe to do so. Evacuate danger area immediately and raise alarm. Keep people away from danger area. Do not breathe gas. When ventilation is inadequate, wear appropriate respirator (SCBA, full face respirator, escape set) during evacuation. If respirator Is not available, put wet towel / cloth over nose and mouth during evacuation. No action shall be taken by personnel involving personal risk or without suitable training. Stay upwind and out of low areas. Do not touch or walk through spill material. The released ammonia rapidly absorbs moisture in the air and forms a dense, visible white cloud of ammonium hydroxide. The dense mixture tends to travel along the ground rather than rapidly rising. This behavior may increase the potential for exposure of workers and public. 6.1.2. For emergency responders Put on appropriate PPE (Refer to Section 8) when handling this product. It may be necessary to wear full- body encapsulating chemical protective suit and positive pressure self-contained breathing apparatus (SCBA). For incidents involving large quantities or direct contact with liquefied ammonia, thermally insulated undergarments and cryogenic gloves (conforming to EN 511) should be worn. Fire-fighters’ normal protective clothing (bunker gear) with helmets, protective boots and gloves will not provide ‘adequate protection in ammonia incidents. If safe to do so, (1) remove casualties to safety, (2) shut off main valve or flow (3) eliminate all ignition sourres. No emaking ar Flam ventilation. Cantact expert / siipplier immediately for specialist advice. If you are competent, stop leak if you can without risk. Keep non- ‘emergency personnel from entering. in hazard area. Provide aden 6.2 Environmental precautions This product Is very toxic to aquatic life. Avoid release to the environment (waterway, sewer or drain). In addition, fire water contaminated with this product must also be contained (eg. bund wall / inflatable seals / absorbent / sandbags / drain covers) and prevented from being discharged to any waterways, sewers or open drains. Collect spillage and transfer to appropriate sealable containers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soll or ar). 6.3 Methods and material for containment and cleaning up 6.3.1. For Containment Spill Liquefied ammonia Liquefied ammonia will quickly vapourise when exposed to alr. top leak If you are competent and safe to do so. Shut off main valve or isolate valve upstream of leakage. For ammonia cylinders, emergency cap / containment vessels are other possible means to stop the leaks by competent emergency responders. Other appropriate specialised spill containment kit may also be used to mitigate the types of leak / spill. For small spills - Dike the spilled liquid as quickly as possible to prevent spreading. Use spill berm, absorbent socks, booms, inflatable seals, or sandbags to contain the spill and prevent from discharge to ‘any waterway, sewer or drain. For small spill, however, it’s highly likely that the liquefied ammonia would have completely vapourised before the spill can be contained. AmmoSorb™ Eco Ammonia Odor & Spill Removal Granules can be used to effectively absorb, neutralise and encapsulate ammonia as well as ammonium ions for safe disposal. AmmoSorb™ will rapidly absorb spills, cleanse the air of noxious ammonia odors, complement existing ventilation systems, and create a safer environment. regenerate «through « solutions Page 7 of 23Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous fev. 11 For large spills - Dike the spilled liquid as quickly as possible to prevent spreading. Use spill berm, absorbent socks, booms, inflatable seals, or sandbags to contain the spill and prevent from discharge to ‘any waterway, sewer or drain. Sp sed ammonia pump / vacuum equipment is required to transfer it to appropriate / approved carbon steel / stainless stee! tank. ‘Seill contaminated fire water For small spills - Dike the spilled liquid as quickly as possible to prevent spreading. Use spill berm, absorbent socks, booms, inflatable seals, or sandbags to contain the spill and prevent from discharge to any waterway, sewer or drain. Loose spill control materials (eg. absorbent pads) should be distributed over the entire spill area, working from the outside, circling to the inside to soak up the spilled liquid. Place used absorbent into suitable, covered, labelled containers / plastic bags for disposal. For large spills - Dike the spilled liquid as quickly a> possible to prevent spreading. Use spill berm, absorbent socks, booms, inflatable seals, or sandbags to contain the spill and prevent from discharge to any waterway, sewer or drain. Using suitable chemically-compatible pump or spill recovery vacuum equipment, the contaminated fire water can be transferred to sealable containers for disposal. 6.3.2. Forcleaning up Neutralization It’s not recommended to neutralise liquefied ammonia with acids which will ‘technique ‘generate violent reaction and heat. However, it’s possible to neutralise the fire water (diluted ammonia water). Use a weak acid such as 2% acetic acid, alkali nreutraliser such as SpilLX-C Caustic Neutralising Agent or NEUTRACIT®-2 Caustic Neutralizer (has built-in pH indicator) Decontamination Decontamination is best done by flushing with plenty of water (safety shower ‘technique ‘or decontamination shower for personnel). For small spill, AmmoSore™ Eco ‘Ammonia Odor & Spill Removal Granules can be used to effectively absorb, neutralise and encapsulate ammonia as well as ammontum tons for safe disposal. AmmoSorb™ will rapidly absorb spills, cleanse the air of noxious ammonia odors, complement existing ventilation systems, and create a safer environment. ‘Adsorbent materials Chemically inert polypropylene material, diatomaceous earth and clay in a granular form Cleaning techniques _Decontaminate the surface where the spill occurred using a mild detergent and ‘water, when appropriate ‘Vacuuming techniques Suck spill with appropriate portable vacuum spill recovery equipment so that it ‘can be transferred to approved metal containers (tanks / cylinders) Equipment required Equipment required for containment / cleanup of liquefied ammonia should be for containment/ approved pressure rated and chemically compatible material such carbon clean up steel, stainless steel. Chemically compatible elastomers are telfon (PTFE), EPDM, neoprene or butyl rubber. 6.3.3. Other information None 6.4 Reference to other sections Refer to Section 1 for emergency contact information Refer to Section 8 for information on appropriate PPE Refer to Section 13 for additional information on disposal, regenerate «through « solutions Page ® of 23Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous fev. 11 7.1 Precautions for safe handling Protective measures Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Avoid contact with eyes, skin and clothing. Do not breathe gas. Avoid release to the environment. Use only with adequate ventilation. Do not enter storage areas and confined spaces unless adequately ventilated. Store and use away from heat, sparks, open flame or any other ignition source. Empty containers retain product residue and can stil be toxic. Keep in the ‘original container or an approved alternative made from a compatible material and approved pressure rating. Keep tightly closed when not in use. ‘Measures to prevent fire Ensure adequate ventilation. Store and use away from heat, sparks, open flame ‘or any other ignition source. ‘Measures to prevent Not available aerosol and dust generation ‘Measures to protect the Avoid release to the environment. Rivers, waterway, drains and sewer must be environment protected from entry of product. ‘Advice on general Eating, drinking and smoking should be prohibited in areas where this material ‘occupational hygiene _is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking, Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.2 Conditions for safe storage, including any incompatibilities Technical measures Store in segregated, approved area which is in accordance to local regulations. and storage conditions Store in well-ventilated and cool dry place, preferably away from main building, out of direct sunlight, and away from sources of heat and other chemicals such as. acids, reactive metals (calcium, sodium, zinc, mercury, etc), oxidising agents (perchlorates, peroxide), combustible materials and halogens (F, Cl, Br, |). Bulk storage of ammonia isnot recommended. Packaging materials Carbon steel, stainless steel (S$304, $5316) Requirements for ‘Anhydrous ammonia should be stored in approved pressure rated carbon steel or storage rooms and stainless steel container. Keep container tightly closed. Storage roam should be vessels locked up. Facilities storing or handling ammonia are strongly recommended to be equipped with ammonia detectors, emergency response kit, escape set, first aid kit, safety shower, eye-wash, chemical spill kit and ammonia scrubber system. Practice good housekeeping and maintain handling equipment. Regularly check storage tanks, containers, piping and transfer equipment for evidence of corrosion or leakage. Storage class NA. 7.3. Specific end use(s) Recommendations Not available regenerate «through « solutions Page 9 of 23Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous fev. 11 Industrial sector Not available specific solutions Exposure Control / Personal Protection Preventive industrial medical exami tion/checkup is recommended to be carried out annually. 8.1 Control parameters Occupational Exposure Limits ‘Component | CAS-No. | Exposure Limit | Umit value Reference ‘ammonia, | 7664-61-7 | PEL(long term) |__ 25 pom | Singapore Workplace Safety and Health Act— anhydrous PEL (short term) | 35 ppm | First Schedule Permissible Exposure Limits of Toxic Substances TWA: Shes 50 pom | Criteria: USA OSHA Table Z-1 Limits for Air STEL-15mins | _35 mg/m? | Contaminants (Permissible Exposure Limits) TWA: hrs 25 pom | Criteria: USA ACGIH STEL-aSming 35 pom | (Threshold Limit Values) TWA-10hrs 25 pom | Criteria: USA NIOSH STEL-15mins '35 pom | (Recommended Exposure Limits) 1H '300 ppm Other Exposure Limits AIHA Emergency Response Planning Guidelines: ‘¢ ERPG-1: <25 ppm for 1 hour without objectionable odour ‘*EPRG-2: 25 - 200 ppm for 1 hour will create strong objectionable odour, some eye, nose and throat tation. ‘* EPRG-3: 200 ~ 1,000 ppm for 1 hour will cause severe eye and respiratory iritation without the development of life threatening health effects National Academy of Sciences 1987 Emergency Exposure Guidance Levels Up to 24 hour continuous exposure: 100 ppm Recommended monitoring procedures If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and Zor the necessity to use respiratory protective equipment. regenerate «through + solutions Page 20 of 2412 p tr beg SuonN}es « YBnowin » aes9Ua6a IN aw WN TreananonBe) jos WN TUBuIEO BBM Ul SUSIUERIOODIN wn ‘weu> poog wn SuBUE Ww (Aw 11000 TaeM SUE VN SUBUNITS TAEMGSON au Tt000 vem Weld DaNa qoErey uoRDaIOrd jeWaUIUONIAUE (s09Nd) suopenuaouo 32243 ON Pé aiyAUp pIETET OU AT POTTS BANTOERS OU 1 BTETETE TING OW ING POUTWTEPT PICTOU ITO TUN MN STIR TA AO RUNOTOY VFO BUS UPTUOD HINOUS HDS STATO DET aigerene ‘argeqrene aigeitene 73NG 73NQ ou 73NG ou ana pe nq paynuap! nq paynuep! 3nq paynuap! 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To keep ammonia concentrations within acceptable exposure and explosive levels, use appropriate ‘engineering controls: local exhaust ventilation, process enclosure system or general mechanical system. Engineering controls should be maintained to keep ammonia concentrations within acceptable exposure levels, otherwise respiratory protection will be required to reduce inhalation exposure. 8.2.2. Personal Protective Equipment Hygiene Wash hands, forearms and face thoroughly after handling product, before eating, measures smoking, using the lavatory and at the end of the working period. Never bring food, drink or smoking materials into vicinity of chemicals. Wash contaminated clothing thoroughly before reusing. Ensure that eyewash stations and safety showers are close to the location where ammonia is stored and handled. Eye and face Wear chemical-resistant and unvented goggles (conformed to EN 166) and full-face protection shield for basic protection. A full-face air purifying respirator with ammonia filter cartridges will offer full protection of the face. It is recommended that every worker carries a 250ml water-filled plastic squirt bottle in their shirt pocket for the first flushing of the eyes. It should be used immediately and is intended to give victim time to go to safety eye-wash if it’s not nearby. Body/Skin Clothing should be heavy duty and of a tightly woven fabric. Light weight. thin protection fabrics will not slow down or prevent anhydrous ammonia from passing through. ‘The clothing should be tightly closed at the cuffs and collar to restrict the entry of ammonia. Wearing chemical-resistant protective suit (EN 14605) and boots is recommended. However, the resistance of specific material may vary from product to product as well as concentration and degree of exposure. Consult manufacturer's specification for information. For IDLH conditions, wear full-body encapsulating chemical protective suit (level A) and positive pressure self-contained breathing apparatus (SCBA). Hand protection Ammonia Gas/Vapour - Wear suitable chemical resistant gloves conformed to EN374 Protection Index Level 6, > 480 min (breakthrough time) - Nitrile (ANSELL SOLVEX), Unsupported Neoprene (ANSELL 29-SERIES), Buty! Rubber. Liquefied Ammonia - Wear cold Insulated (cryogenic) gloves (conforming to EN 511) for maximum thermal protection in ultra-cold environment (eg. Tempshield Waterproof Cryo-Gloves or Cryo-Industrial Gloves). However, these gloves are not applicable and do not offer protection for immersion in liquid ammonia. Respiratory If ventilation and other engineering controls and work practices are not effective in protection controlling exposure to this material, wear approved respiratory protective equipment (RPE). NIOSH Recommendations for ammonia concentrations in air: = Up to 250 ppm: Full-face respirator with ammonia cartridge(s) to protect against ammonia = Up to 300 ppm: Fullface SAR operated in a continuous-flow mode; or powered air-purifying respirator with cartridge(s) to protect against ammonia; or full- face piece SAR (Supplied-Air Respirator) = Emergency or planned entry into unknown concentrations or IDLH conditions: regenerate » through + solutions Page 42 of 24Pride-Chem Industries Pe Lid Safety Data Sheet: Ammonia, Anhydrous Rev. £1 (APF = 10,000) Any self-contained breathing apparatus (SCBA) that has a full- face piece and is operated in a pressure-demand or other positive:pressure mode (APF = 10,000) Any supplied: respirator that has a full face-piece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus ‘Thermal hazards If there a risk of contact with liquid ammonia, all protective equipment worn should be suitable for use with extremely low temperature materials 8.2.3, Environmental exposure controls Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or ‘engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Penman oa ‘Appearance Odour Odour threshold pH ‘Melting point / freezing point Initial bolting point and boiling range Flash point Evaporation Rate Flammability (solid, gas) Upper/iower flammability or explosive limits (by volume) ‘Vapour pressure ‘Vapour density Relative density Solubility(ies) Partition coefficient: n-octanol/water ‘Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties 9.2 Other Information None Information on basic physical and chemical properties Colourles, liquefied gas under pressure Extremely pungent, intense, irritating, and even suffocating ‘odour. 5-20 ppm 12 (10% aqueous solution) “103 F(-77.7 'C) at 101.3 kPa 285 (33.4) at 101.3 kPa NA NA Flammable gas. Contains gas under pressure; may explode if heated. May be an explosion hazard in a confined space. Lower: 169% Upper: 25% 85 atm (130 psi at 20°C (68°F) 0.5967 (Air= 1) (0.682 (Water = 1) Highly soluble in water, alcohol 51 to 53.1 g/100 mi (20°C) Not available 652°C /1200°F -108.8°F 38.00 Lb/ft? at 70°F Not available Not available regenerate + through + solutions Page 43 of 23Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous Rev. 11 10. Stability and reactivity Reactivity/ Incompatible materials 10.1. Reactivity ‘Anhydrous ammonia has potentially explosive reactions with strong oxidizers. Anhydrous ammonia forms explosive mixtures in air with hydrocarbons, chlorine, fluorine and silver nitrate. Anhydrous ammonia reacts to form explosive products, mixtures or compounds with mercury, gold, silver, iodine, bromine, silver oxide and silver chloride. 10.2 Chemical stability ‘Stable at normal ambient temperature and pressure, Heating 2 closed cont pressure. Hazardous polymerisation will not occur. 5 caucee increase in vapor 10.3 Possibility of hazardous reactions Ammonia has potentially explosive or violent reactions with strong acids (nitric acid, hydrofluoric acid), strong oxidisers (sodium and calcium hypochlorite, perchlorate, peroxides, chloric acid, chlorine monoxide, chiorites), halogens (chlorine, fluorine, bromine, and iodine), metals (silver, gold, mercury, zinc, cadmium, boron and tin). Explosive products are formed by the reaction of ammonia with silver chloride, silver oxide, silver nitrate, silver azide and tellurium halides. Ammonia is incompatible or has potentially hazardous reactions with nitrogen oxide, nitrogen tetroxide and sulphur. Ammonia catalyzes the polymerisation of acrolein, acetaldehyde and other unsaturates, causing an increase in temperatures and pressure, which may ‘explode containers. Ammonia forms sensitive explosive mixtures with air and hydrocarbons. 10.4 Conditions to avoid ‘Avoid all possible sources of ignition (spark, flame and heat). Do not pressurise, cut, weld, braze, solder, drill, arin or expose containers to heat or sources of ignition. Water mixes with liquid ammonia will generate violent reaction and heat while ammonia gas/vapour readily dissolves in water generating heat as well. Avoid ‘contact with galvanized surfaces, copper, brass, bronze, mercury, gold and silver as corrosive reaction will ‘occur. Avoid contact with chlorine as it may form chloramine gas which is a primary skin irritant and 10.5 Incompatible materials ‘Strong Mineral Sulphuric acid, hydrochloric acid, hydrofluoric acid or nitric acid ~ reaction is exothermic Acids and violent and mixture becomes b Perchlorates, chlorates, hydrogen peroxide, chromic trioxide, calcium or sodium hypochlorite — reaction is exothermic and violent or explosive Heavy Metals Silver, gold, lead, mercury or zinc, especially halide salts - may form shock-sensitive and their Salts compounds that may explode when dry Halogens or Chlorine, bromine, fluorine or iodine, bromine pentafluoride, chlorine trifluoride ~ can Interhalogens react violently or form explosive chemicals Dimethyl Reacts violently Sulfate Acrolein, an react in a closed container that causes temperature and pressure to rise ‘Acrylic acid regenerate + through + solutions Page 14 of 24Pride-Chem Industries Pe Lid Safety Data Sheet: Ammonia, Anhydrous Rev. £1 Metals Non-Metals Corrosive to copper, brass, zinc, bronze, galvanized steel and their alloys. Do not use brazed joints in ammonia service. Polyvinylidene chloride (Saran), polybutylene terephthalate, polyethylene terephthalate, isophthalic acid and general purpose thermoset polyesters and polyurethane (rigid); and elastomers such as polyacrylate, polyurethane, natural rubber, synthetic isoprene, hard rubber and polysulfide 10.6 Hazardous decomposition products Under normal conditions of storage and use. harardous decomposition products should not be produced. Under high temperature, ammonia reacts with air to form oxides of nitrogen and water. Decomposition will ‘occur at lower temperatures in the presence of metals such as iron, nickel and zinc and, to a lesser extent, ‘catalytic surfaces, such as porcelain and pumice. In the presence of catalysts, decomposition begins as low as 300°C and is complete at 500-600°C. At 690°C or in the presence of an electric spark, ammonia decomposes into nitrogen dioxide and flammable hydrogen gases, which may form a flammable mixture in the air. Pro ee 11.1 _ Information on toxicological effects Acute Toxicity Product/Ingredie | Method ‘Species | Routes of exposure | Effective | Exposure nt Name Dose time ‘ammonia, Standardacute | Rat__| 0 S00ral somes | ‘Anhydrous, Standard acute | Rat__| LD 50 Dermal Not available | ~ Standard acute | Rat___| C50 Inhalation: 18600 mg/m® | 5 minute (3) ‘Standard acute | Rat__| LC50 Inhalation: 7040 me/m* | 30 minute (s), Standard acute | Rat 17401 ppm __| 15 minute (s) Standard acute | Rat ‘9500 ppm | 1 hour. Standard acute | Rat 2000 ppm | 4 hour(s) ‘Skin corrosion/irritation Corrosive to the skin Serious eye damage/irritation Corrosive to eyes Respiratory Corrosive to entire respiratory tract, ‘Skin sensitisation Not sensitizing Respiratory sensitisation Not sensitizing Germ cell mutagenicity No mutagenic effect Carcinogenicity No carcinogenic effect Reproductive toxicitv Not considered to be toxic to the reproductive system ‘Summary of evaluation of the CMR properties No teratogenic effect STOT-single exposure Not available ‘STOT-repeated exposure Not available Aspiration hazard 11.2. Information on likely routes of exposure Inhalation, dermal, eyes 11.3 Symptoms related to the physical, chemical and toxicological characteristics Inhalation Ammonia gas or vapour is very irritating, corrosive and causes burn to the respiratory regenerate + through + solutions Page 48 of 23Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous Rev. 11 1a 11s system. Symptoms include dizziness, nausea and severe irritation and pain of throat & upper respiratory tract with cough, cramps, wheezing, and shortness of breath, chest pain, and vomiting. Prolong Inhalation may be fatal as a result of spasm, inflammation and edema of larynx and bronchitis, chemical pneumonitis and pulmonary edema. Cessation of respiration may lead to death if exposure continues. Serious effects may be delayed following exposure. ‘Skincontact Symptoms may include redness, blistering, pain and irritation. Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or frostbite. Long exposure may result in destruction of tissue. Eyecontact Symptoms may include redness, watering, irritation, swelling, excessive tearing, frostbite and pain. It may cause serious eye damage Ingestion Liquefied ammonia causes burn to mouth, throat and stomach with symptoms include dizziness, nausea and severe irritation and pain of throat & upper respiratory tract with cough, shortness of breath, chest pain, and vomiting. Ingestion of liquid can cause burns similar to frostbite, Serious effects may be delayed following exposure. Delayed and immediate effects as well as chronic effects from short and long term exposure IDLH : 300 ppm Other Toxic Effects on Humans Hazardous in case of ingestion: may produce burns to the lips, oral cavity and possibly the digestive tract Hazardous in case of inhalation: may cause damage to respiratory tract Hazardous in case of skin/eye contact: may cause corrosive burn to skin/eye acute health effects Severely corrosive to the eyes. Causes severe burns. Contact with rapidly expanding gas ‘may cause burns or frostbite skin Severely corrosive to the skin. Causes severe burns. Contact with rapidly expanding gas ‘may cause burns or frostbite Inhalation Severely corrosive to the respiratory system Ingestion Ingestion is not a normal route of exposure for gases Potential chronic health effects Chronic effects May cause target organ damage, based on animal data ‘Target organs May cause damage to the following organs: lungs, upper respiratory tract, skin, eyes Chronic (long-term) toxic effects may include shortened life span, reproductive problems, lower fertility, and ‘changes in appearance or behavior in exposed animals. These effects can be seen long after first exposure(s) to toxic chemicals. Under natural conditions of pH and temperature, total ammonia has moderate chronic toxicity in aquatic life. Interactive Effects Not Available regenerate + through + solutions Page 16 of 24Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous Rev. 11 11.6 Medical conditions aggravated by over-exposure Pre-existing disorders involving any target organs mentioned in this SDS as being at risk may be aggravated by over-exposure to this product Pee ee 12.1. Toxicity ‘Acute (short-term) toxi ‘Component. Endpoint | Species ‘Exposure Limit | Test Result Fish cso Carp Cyprinus carpio ‘96 hours 0.44 me/t cso | Silver carp - Hypophthalmichthys | 96 hours 0.38 mg/l molitric Crustacea ECS0___| Daphnia ‘as hours 25.4 melt ‘Algae/aquatic plants | EC50 | Sea Lettuce 96 hours 29.2 mg/L Other organisms | NA. NA NA. NA. Acute Ecological Effects 12.4 ‘Acute (short-term) toxic effects may include the death of animals, birds, or fish, and death or low growth rate in plants. Acute effects are seen 2 to 4 days after animals or plants are exposed to ammonia. Under natural conditions of pH and temperature, ammonia has a moderate acute toxicity to aquatic life. | Shronic long-term) toxicity Component Endpoint | Species Exposure Limit | Test Result Fish NOEC | Sea bass Dicentrarchus labrax 131.3] 62 days (0.204 mg/l Fish NOEC | Catfish -Ietalurus punctatus ‘31 days 0.048 mg/l Crustacea noec__| Daphnia 4 days 0.79 mg/l ‘Algae aquatic plants | NOEC | Diatom Skeletonema 3 days ime Other organisms: NA. NAL NAL NA. Chronic Ecological Effects Chronic (long-term) toxic effects may include shortened life span, reproductive problems, lower fertility, and ‘changes in appearance or behavior in exposed animals. These effects can be seen long after first exposure(s) to toxic chemicals. Under natural conditions of pH and temperature, total ammonia has moderate chronic toxicity in aquatic life. Persistence and degradability Abiotic Degradation —_Physical- and photo-chemical elimination Biodegradability Not available ‘Not avaiable Readily Bioaccumulative potential Ammonia does not bioaccumulate due to its low log Kow (log Kow <4) and is a product of normal metabolism. ‘Octanol-water partition coefficient _Bioconcentration factor (BCF) Potential (log Kow) 0.23 Not Available low Mobility in soil Soil/water partition coefficient (K..) Mobility Not Available Not Available regenerate + through + solutions Page 47 of 24Pride-Chem Industries Pe Lid Sefety Data Sheet: Ammonia, Anhydrous Rev. 11 12.5. Results of PBT and vPVB assessment. ‘The substance is neither a PBT- or a vPVB substance. 12.6 Other adverse effects Not available Perens 13.1 Waste treatment method Dispose in accordance with all local regulations and should not be released to the environment. 13.1.1. Product / Packaging disposal Product disposal: The generation of toxic wastes should be avoided or minimised wherever possible. Disposal of this hazardous product, solutions and any by-products (eg. ammonium hydroxide) should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional & local authority requirements. In Singapore, disposal of these wastes is via a licensed toxic industrial waste (TIW) collector. Packaging disposal: This product and its container must be disposed of in a safe way and in accordance to local waste disposal legislation. Empty containers or liners will still contain hazardous ammonia residue, Do rot puncture or incinerate container. In Singapore, empty pressure vessels/cylinders should be returned to ‘the supplier or disposed via a licensed toxic waste (TIW) collector. 13.1.2, Waste treatment-relevant information ‘The classification of the product meets the criteria for a hazardous waste. 13.1.3. Sewage disposal-relevant information ‘Sewage disposal shall be discouraged. Significant quantities of waste product residues should not be disposed of via the sewer but processed in a suitable effluent treatment plant. 13.1.4, Other disposal recommendations regenerate + through + solutions Page 18 of 24Pride-Chem Industries Pe Ltd S2fety Data Sheet: Ammonia, Anhydrous fev. It POM ee ‘ADR /RID ‘ADN IMG tara 14.1 UN number uNt005, UN1005 UuN1005 uNz005 "AMMONIA, | AMMONIA, | AMMONIA, “Ammonia, anhydrous 14.2 UN proper awnyoRous | ANHYDROUS | ANHYDROUS. shipping name. Marine pollutant (ammonia, anhydrous) 2) 2@) 23 (8) 238) 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental Eeviron Yes Yes Yes Yes 186 Special precaution to Not available | Notavailable Not available Emergency | Passenger and Cargo Aircraft 14.7 Additional ‘schedules Quantity Limitation: Forbidden information | number ems Packaging Instructions: 262 Fosu Forbidden Limited quantity Cargo Aircraft Only ° ‘Quantity Limitation: Forbidden ‘Special Packaging Instructions: ‘Provisions Forbidden 23 Limited Quantities - Passenger ‘Tunnel Code Aircraft (c/o) Quantity Limitation: Forbidden Packaging instructions: Forbidden Label 13 regenerate «through + solutions Page 49 of 24Pride-Chem Industries Pe Lid Safety Data Sheet: Ammonia, Anhydrous Rev. £1 ‘Approved Transportation Hours of Ammonia in Singapore (09.00 ~17 00 hrs (except Sunday and Public Holidays) 148 ‘Transport in bulk according to Annex Il of MARPOL 73/78 and the IBC Code Not available Fearn ed 15.1 ‘Safety, health and environmental regulations/legislation specific for the substance or mixture EU Kegulations ‘Commission Regulation (EU) No 474/2014 of 8 May 2014 amending Annex XVII to Regulation (EC) No 1907/2006 ‘Commission Regulation (EU) No 94/2013 of 2 Oct 2013 (S"" ATP) amending Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures ‘Singapore Regulation ‘Workplace Safety and Health Act (WSHA) 2006 WSH (General Provisions) Regulations Environmental Public Health (Toxic Industrial Waste) Regulations 1988 The Environmental Protection and Management Act (EPMA) ‘The Environmental Protection and Management (Hazardous Substances) Regulations ‘Chemical Safety Assessment No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier Panne 16.1 Indication of changes Revision to SDS templates including GHS classification and label elements. Revision in all sections. Abbreviations and acronyms sos Safety Data Sheet PPE Personal Protective Equipment cP Classification, Labelling and RPE respiratory protective equipment Packaging Regulation (Regulation (EC) No 1272/2008) DNEL Derived No Effect Level SAR Supplied-Air Respirator EUH statement CLP-specific Hazard statement SCBA Self-Contained Breathing Apparatus IBC International Bulk Chemical Code APF Assigned Protection Factor PNEC Predicted No Effect Concentration PEL Permissible Exposure Limits IDLH Immediately Dangerous to Life & STEL Short-Term Exposure Limit Health ATE Acute Toxicity Estimate TWA _Time-Weighted Average Tw Toxic Industrial Waste LC Lethal Concentration NOEC No Observed Effect Concentration C50. Half maximal effective concentration WW Lethal Dose Key literature references and sources for data Literature data and/or investigation reports are available through the manufacturer regenerate + through + solutions Page 20 of 23Pride-Chem Industries Pe Ltd S2fety Data Sheet: Ammonia, Anhydrous fev. It 16.4 Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP] Classification according to Regulation (EC) Nr. 1272/2008 Classification procedure Flam. Gas 2, H221 Expert judgment Press. Gas Comp. Gas, H280 Expert judgment Acute Tox. 3, H331 Expert judgment skin Corr. 18, #314 Expert judgment Aquatic Acute 1, H400 Expert judgment 16.5. Relevant R-phrases and/or H-statements (number and full text) 221 Flammable gas. 20 ‘Contains gas under pressure; may explode if heated. 314 ‘Causes severe skin burns and eye damage. 331 Toxic if inhaled. 400 Very toxic to aquatic life. 16.6 Training Advice = Handling of this substance is restricted to competent and qualified personnel. Proper traini for personnel new to this substance Workers must be trained and educated in the proper use, care and maintenance of respirators. Fit testing of the respirators should also be performed by the users is required 16.7 Further information ‘Singapore Storage and Transport Requirements for Dangerous Goods (SS586 Part 1) ‘Storage Emergency Information Panel (SEIP) For all tanks and bulk stores not in a building, SEIPis to be posted on or adjacent to the tank or bulk store so that itis visible from all normal directions of approach. For bulk stores within a building or structure, an SEIP is to be posted at each entrance to the store. ‘Storage Emergency Information Panel Supplier Note: ‘The buyer assumes all risk n connection with the use ofthis material. The buyer assumes al responsibly for ensuring this materials used in a safe ‘manner in compliance with applicable environmental, heith and sofety laws, policies and guidelines. To the best of our knowledge, the information ‘contained herein is accurate. However, neither the above-named supplier, nor any of ts Subsidiones, ossumes any liblty whatsoever for the accurocy ‘or completeness ofthe information contained herein. Final determination of suitability of any material i the sole responsibility of the user. All ‘materials may present unknown hazards and shouldbe used with coution. Although certain hazard ore described herein, we connot quorentee that these are the only hazards that exist, regenerate «through + solutions Page 22 of 24