Diket :

Toluen Parameter vDW

T 400 K σ 0
P 10 bar Є 0
Ω 0.125
Tc 591.8 K Ψ 0.421875
Pc 41.06 bar Zc 0.375
α(Tr) 1.00000
Tr 0.675904
Pr 0.24355

q 4.993313

β 0.04504

iterasi ke Z tebak Z hitung Galat

1 0.04504 0.047160 -0.002119
2 0.047160 1.044109 -0.996949
3 1.044109 0.810655 0.233454
4 0.810655 0.863285 -0.052630
5 0.863285 0.851414 0.011871
6 0.851414 0.854091 -0.002677
7 0.854091 0.853488 0.000604
8 0.853488 0.853624 -0.000136
9 0.853624 0.853593 0.000031
10 0.853593 0.853600 -0.000007
11 0.853600 0.853598 0.000002
12 0.853598 0.853599 0.000000
13 0.853599 0.853599 0.000000

Z 0.853599
maka :
V 2838.727510
Diket :

Toluen Parameter vDW

T 400 K σ 0
P 10 bar Є 0
Ω 0.125
Tc 591.8 K Ψ 0.421875
Pc 41.06 bar Zc 0.375
α(Tr) 1.00000
Tr 0.675904
Pr 0.24355

q 4.993313

β 0.04504

iterasi ke Z tebak Z hitung Galat

1 1 0.775097 0.224903
2 0.775097 0.825678 -0.050581
3 0.825678 0.869473 -0.043795
4 0.869473 0.859624 0.009850
5 0.859624 0.861839 -0.002215
6 0.861839 0.861341 0.000498
7 0.861341 0.861453 -0.000112
8 0.861453 0.861428 0.000025
9 0.861428 0.861433 -0.000006
10 0.861433 0.861432 0.000001

Z 0.861432
maka :
V 2864.777912
Diket :

Toluen Parameter PR
T 400 K σ 2.4142
P 10 bar Є -0.4142
Ω 0.0778
Tc 591.8 K Ψ 0.45724
Pc 41.06 bar Zc 0.3074
α(Tr) 2.50527
Tr 0.675904
Pr 0.24355

q 21.783846

β 0.02803

iterasi ke Z tebak Z hitung Galat

1 0.02803 0.029649 -0.001616
2 0.029649 1.026114 -0.996465
3 1.026114 0.401879 0.624235
4 0.401879 0.783810 -0.381931
5 0.783810 0.549992 0.233818
6 0.549992 0.693039 -0.143047
7 0.693039 0.605504 0.087535
8 0.605504 0.659060 -0.053556
9 0.659060 0.626290 0.032770
10 0.626290 0.646340 -0.020050
11 0.646340 0.634072 0.012268
12 0.634072 0.641578 -0.007506
13 0.641578 0.636986 0.004593
14 0.636986 0.639796 -0.002810
15 0.639796 0.638076 0.001719
16 0.638076 0.639128 -0.001052
17 0.639128 0.638485 0.000644
18 0.638485 0.638878 -0.000394
19 0.638878 0.638637 0.000241
20 0.638637 0.638785 -0.000147
21 0.638785 0.638695 0.000090
22 0.638695 0.638750 -0.000055
23 0.638750 0.638716 0.000034
24 0.638716 0.638737 -0.000021
25 0.638737 0.638724 0.000013
26 0.638724 0.638732 -0.000008
27 0.638732 0.638727 0.000005
28 0.638727 0.638730 -0.000003
29 0.638730 0.638728 0.000002
30 0.638728 0.638729 -0.000001
 31 0.638729 0.638729 0.000001
32 0.638729 0.638729 0.000000

Z 0.638729
maka
V 2124.15743
Diket :

isobaten Parameter PR
T 323.15 K σ 2.4142
P 5 bar Є -0.4142
Ω 0.0778
Tc 408.1 K Ψ 0.45724
Pc 36.48 bar Zc 0.3074
α(Tr) 2.34634
Tr 0.791840
Pr 0.13706

q 17.414753

β 0.01347

iterasi ke Z tebak Z hitung Galat

1 1 0.764967 0.235033
2 0.764967 0.819927 -0.054960
3 0.819927 0.807083 0.012843
4 0.807083 0.810085 -0.003002
5 0.810085 0.809384 0.000702
6 0.809384 0.809548 -0.000164
7 0.809548 0.809509 0.000038
8 0.809509 0.809518 -0.000009
9 0.809518 0.809516 0.000002
10 0.809516 0.809517 0.000000
11 0.809517 0.809516 0.000000
12 0.809516 0.809517 0.000000
13 0.809517 0.809517 0.000000
14 0.809517 0.809517 0.000000
15 0.809517 0.809517 0.000000
16 0.809517 0.809517 0.000000
17 0.809517 0.809517 0.000000
18 0.809517 0.809517 0.000000
19 0.809517 0.809517 0.000000
20 0.809517 0.809517 0.000000
21 0.809517 0.809517 0.000000
22 0.809517 0.809517 0.000000
23 0.809517 0.809517 0.000000
24 0.809517 0.809517 0.000000
25 0.809517 0.809517 0.000000
26 0.809517 0.809517 0.000000
27 0.809517 0.809517 0.000000
28 0.809517 0.809517 0.000000
29 0.809517 0.809517 0.000000
Z 0.809517
maka
V 2692.12812
Diket :

Toluen Parameter SRK

T 400 K σ 1
P 10 bar Є 0
Ω 0.08664
Tc 591.8 K Ψ 0.42748
Pc 41.06 bar Zc 0.33333
α(Tr) 2.50527
Tr 0.675904
Pr 0.24355

q 18.288045

β 0.03122

iterasi ke z tebak Z hitung Galat

1 1 1.092870 -0.092870
2 1.092870 0.407777 0.685093
3 0.407777 0.799772 -0.391995
4 0.799772 0.575302 0.224470
5 0.575302 0.703730 -0.128428
6 0.703730 0.630230 0.073500
7 0.630230 0.672285 -0.042055
8 0.672285 0.648220 0.024066
9 0.648220 0.661990 -0.013771
10 0.661990 0.654110 0.007880
11 0.654110 0.658619 -0.004509
12 0.658619 0.656039 0.002580
13 0.656039 0.657515 -0.001476
14 0.657515 0.656671 0.000845
15 0.656671 0.657154 -0.000483
16 0.657154 0.656877 0.000277
17 0.656877 0.657036 -0.000158
18 0.657036 0.656945 0.000091
19 0.656945 0.656997 -0.000052
20 0.656997 0.656967 0.000030
21 0.656967 0.656984 -0.000017
22 0.656984 0.656975 0.000010
23 0.656975 0.656980 -0.000006
24 0.656980 0.656977 0.000003
25 0.656977 0.656979 -0.000002
0.656979 0.656978 0.000001
0.656978 0.656978 -0.000001

V 0.656978
maka
Z 2184.84704
Diket :

Toluen Parameter SRK

T 400 K σ 1
P 10 bar Є 0
Ω 0.08664
Tc 591.8 K Ψ 0.42748
Pc 41.06 bar Zc 0.33333
α(Tr) 2.50527
Tr 0.675904
Pr 0.24355

q 18.288045

β 0.03122

iterasi ke z tebak Z hitung Galat

1 1 0.428097 0.571903
2 0.428097 0.753311 -0.325214
3 0.753311 0.568620 0.184691
4 0.568620 0.673645 -0.105025
5 0.673645 0.613950 0.059695
6 0.613950 0.647891 -0.033941
7 0.647891 0.628596 0.019295
8 0.628596 0.639566 -0.010970
9 0.639566 0.633330 0.006236
10 0.633330 0.636875 -0.003545
11 0.636875 0.634860 0.002016
12 0.634860 0.636005 -0.001146
13 0.636005 0.635354 0.000651
14 0.635354 0.635724 -0.000370
15 0.635724 0.635514 0.000211
16 0.635514 0.635633 -0.000120
17 0.635633 0.635565 0.000068
18 0.635565 0.635604 -0.000039
19 0.635604 0.635582 0.000022
20 0.635582 0.635595 -0.000013
21 0.635595 0.635588 0.000007
22 0.635588 0.635592 -0.000004
23 0.635592 0.635589 0.000002
24 0.635589 0.635591 -0.000001
25 0.635591 0.635590 0.000001

Z 0.635590
maka :
V 2113.717498
Diket :

Toluen Parameter RK
T 400 K σ 1
P 10 bar Є 0
Ω 0.08664
Tc 591.8 K Ψ 0.42748
Pc 41.06 bar Zc 0.33333
α(Tr) 1.21635
Tr 0.675904
Pr 0.24355

q 8.879118

β 0.03122

iterasi ke Z tebak Z hitung Galat

1 0.03122 0.033229 -0.002010
2 0.033229 1.030138 -0.996910
3 1.030138 0.745933 0.284206
4 0.745933 0.824813 -0.078880
5 0.824813 0.802913 0.021900
6 0.802913 0.808992 -0.006079
7 0.808992 0.807305 0.001688
8 0.807305 0.807773 -0.000469
9 0.807773 0.807643 0.000130
10 0.807643 0.807679 -0.000036
11 0.807679 0.807669 0.000010
12 0.807669 0.807672 -0.000003
13 0.807672 0.807671 0.000001
14 0.807671 0.807671 0.000000

Z 0.807671
maka
V 2685.991802
Diket :

Toluen Parameter RK
T 400 K σ 1
P 10 bar Є 0
Ω 0.08664
Tc 591.8 K Ψ 0.42748
Pc 41.06 bar Zc 0.33333
α(Tr) 1.21635
Tr 0.675904
Pr 0.24355

q 8.879118

β 0.03122

iterasi ke Z tebak Z hitung Galat

1 1 0.721831 0.278169
2 0.721831 0.798562 -0.076731
3 0.798562 0.777423 0.021140
4 0.777423 0.783249 -0.005827
5 0.783249 0.781643 0.001606
6 0.781643 0.782086 -0.000443
7 0.782086 0.781964 0.000122
8 0.781964 0.781998 -0.000034
9 0.781998 0.781988 0.000009
10 0.781988 0.781991 -0.000003
11 0.781991 0.781990 0.000001
12 0.781990 0.781990 0.000000
13 0.781990 0.781990 0.000000

Z 0.781990
maka :
V 2600.587268
Diket :

Etil amina Parameter RK

T 400 K σ 1
P 10 bar Є 0
Ω 0.08664
Tc 456.2 K Ψ 0.42748
Pc 56.2 bar Zc 0.33333
α(Tr) 1.06794
Tr 0.876808
Pr 0.17794

q 6.009527

β 0.01758

iterasi ke Z tebak Z hitung Galat

1 0.01758 0.018211 -0.000629
2 0.018211 1.017452 -0.999240
3 1.017452 0.910109 0.107343
4 0.910109 0.921455 -0.011346
5 0.921455 0.920255 0.001199
6 0.920255 0.920382 -0.000127
7 0.920382 0.920369 0.000013
8 0.920369 0.920370 -0.000001
9 0.920370 0.920370 0.000000
10 0.920370 0.920370 0.000000
11 0.920370 0.920370 0.000000
12 0.920370 0.920370 0.000000
13 0.920370 0.920370 0.000000

Z 0.920370
maka :
V 3060.782399
Diket :

Etil amina Parameter RK

T 400 K σ 1
P 10 bar Є 0
Ω 0.08664
Tc 456.2 K Ψ 0.42748
Pc 56.2 bar Zc 0.33333
α(Tr) 1.06794
Tr 0.876808
Pr 0.17794

q 6.009527

β 0.01758

iterasi ke Z tebak Z hitung Galat

1 1 0.894029 0.105971
2 0.894029 0.905190 -0.011160
3 0.905190 0.904015 0.001175
4 0.904015 0.904138 -0.000124
5 0.904138 0.904125 0.000013
6 0.904125 0.904127 -0.000001
7 0.904127 0.904126 0.000000
8 0.904126 0.904127 0.000000
9 0.904127 0.904127 0.000000
10 0.904127 0.904127 0.000000
11 0.904127 0.904127 0.000000
12 0.904127 0.904127 0.000000
13 0.904127 0.904127 0.000000

Z 0.904127
maka :
V 3006.763121
Diket :

Etil Amina Parameter SRK

T 400 K σ 1
P 10 bar Є 0
Ω 0.08664
Tc 456.2 K Ψ 0.42748
Pc 56.2 bar Zc 0.33333
α(Tr) 2.23316
Tr 0.876808
Pr 0.17794

q 12.566453

β 0.01758

iterasi ke Z tebak Z hitung Galat

1 0.01758 0.018212 -0.000629
2 0.018212 1.017309 -0.999098
3 1.017309 0.792877 0.224432
4 0.792877 0.842484 -0.049607
5 0.842484 0.831518 0.010966
6 0.831518 0.833942 -0.002424
7 0.833942 0.833406 0.000536
8 0.833406 0.833525 -0.000118
9 0.833525 0.833499 0.000026
10 0.833499 0.833504 -0.000006
11 0.833504 0.833503 0.000001
12 0.833503 0.833503 0.000000
13 0.833503 0.833503 0.000000

Z 0.833503
maka :
V 2771.898829
Diket :

Etil Amina Parameter SRK

T 400 K σ 1
P 10 bar Є 0
Ω 0.08664
Tc 456.2 K Ψ 0.42748
Pc 56.2 bar Zc 0.33333
α(Tr) 2.23316
Tr 0.876808
Pr 0.17794

q 12.566453

β 0.01758

iterasi ke Z tebak Z hitung Galat

1 1 0.778743 0.221257
2 0.778743 0.827541 -0.048799
3 0.827541 0.816783 0.010759
4 0.816783 0.819155 -0.002372
5 0.819155 0.818632 0.000523
6 0.818632 0.818747 -0.000115
7 0.818747 0.818722 0.000025
8 0.818722 0.818727 -0.000006
9 0.818727 0.818726 0.000001
10 0.818726 0.818726 0.000000
11 0.818726 0.818726 0.000000
12 0.818726 0.818726 0.000000
13 0.818726 0.818726 0.000000

Z 0.818726
maka :
V 2722.756596
Diket :

Etil Amina Parameter PR

T 400 K σ 2.4142
P 10 bar Є -0.4142
Ω 0.0778
Tc 456.2 K Ψ 0.45724
Pc 56.2 bar Zc 0.3074
α(Tr) 2.23316
Tr 0.876808
Pr 0.17794

q 14.968558

β 0.01579

iterasi ke Z tebak Z hitung Galat

1 0.01579 0.016295 -0.000506
2 0.016295 1.015553 -0.999258
3 1.015553 0.775841 0.239712
4 0.775841 0.832510 -0.056669
5 0.832510 0.819112 0.013398
6 0.819112 0.822280 -0.003167
7 0.822280 0.821531 0.000749
8 0.821531 0.821708 -0.000177
9 0.821708 0.821666 0.000042
10 0.821666 0.821676 -0.000010
11 0.821676 0.821674 0.000002
12 0.821674 0.821674 -0.000001
13 0.821674 0.821674 0.000000
14 0.821674 0.821674 0.000000

Z 0.821674
maka
V 2732.559166
Diket :

Etil Amina Parameter PR

T 400 K σ 2.4142
P 10 bar Є -0.4142
Ω 0.0778
Tc 456.2 K Ψ 0.45724
Pc 56.2 bar Zc 0.3074
α(Tr) 2.23316
Tr 0.876808
Pr 0.17794

q 14.968558

β 0.01579

iterasi ke Z tebak Z hitung Galat

1 1 0.762960 0.237040
2 0.762960 0.818758 -0.055797
3 0.818758 0.805635 0.013122
4 0.805635 0.808722 -0.003087
5 0.808722 0.807996 0.000726
6 0.807996 0.808167 -0.000171
7 0.808167 0.808127 0.000040
8 0.808127 0.808136 -0.000009
9 0.808136 0.808134 0.000002
10 0.808134 0.808134 -0.000001
11 0.808134 0.808134 0.000000
12 0.808134 0.808134 0.000000
13 0.808134 0.808134 0.000000

Z 0.808134
maka :
V 2687.531159
Diket :

Etil Amina Parameter vDW

T 400 K σ 0
P 10 bar Є 0
Ω 0.125
Tc 456.2 K Ψ 0.421875
Pc 56.2 bar Zc 0.375
α(Tr) 1.00000
Tr 0.876808
Pr 0.17794

q 3.849188

β 0.02537

iterasi ke Z tebak Z hitung Galat

1 0.02537 0.026027 -0.000660
2 0.026027 1.025240 -0.999213
3 1.025240 0.925321 0.099918
4 0.925321 0.935084 -0.009763
5 0.935084 0.934130 0.000954
6 0.934130 0.934224 -0.000093
7 0.934224 0.934214 0.000009
8 0.934214 0.934215 -0.000001
9 0.934215 0.934215 0.000000
10 0.934215 0.934215 0.000000
11 0.934215 0.934215 0.000000
12 0.934215 0.934215 0.000000
13 0.934215 0.934215 0.000000

Z 0.934215
maka :
V 3106.826422
Diket :

Etil Amina Parameter vDW

T 400 K σ 0
P 10 bar Є 0
Ω 0.125
Tc 456.2 K Ψ 0.421875
Pc 56.2 bar Zc 0.375
α(Tr) 1.00000
Tr 0.876808
Pr 0.17794

q 3.849188

β 0.02537

iterasi ke Z tebak Z hitung Galat

1 1 0.902358 0.097642
2 0.902358 0.911892 -0.009534
3 0.911892 0.910961 0.000931
4 0.910961 0.911052 -0.000091
5 0.911052 0.911043 0.000009
6 0.911043 0.911044 -0.000001
7 0.911044 0.911044 0.000000
8 0.911044 0.911044 0.000000
9 0.911044 0.911044 0.000000
10 0.911044 0.911044 0.000000
11 0.911044 0.911044 0.000000
12 0.911044 0.911044 0.000000
13 0.911044 0.911044 0.000000

Z 0.911044
maka :
V 3029.766586
 TERMODINAMIKA 1
KELOMPOK 10

Anggota : 1.Andre Aprinanda

2.Feni Sri wahyeni
3.Muhammad Nurhadillah

Rumus Tr : Rumus Pr :
P
Pr 
T Pc
Tr 
Tc
Rumus q = Rumus β :
 Tr 1 / 2  3 / 2 Pr
q  Tr  
 Tr  Tr

Rumus z untuk uap : Rumus V

U ZRT
V 
(Z   ) P
Z  1    q
Z (Z   )
Rumus Z untuk cairan : Rumus V untuk cairan :
ZRT
1   Z Vl 
Z    Z ( Z   )( ) P
q
Dik:
T 25 deg C
298.15 K
P 12 bar
B -140 cm3/mol
C 7200 cm6/mol2
R 83.14 cm3/bar.mol

V ideal 2065.683 cm3/mol

Penyelesaian pers (3.40)

Irterasi ke Vi tebak Vi hitung Galat

1 2065.683 1929.168 136.5145
2 1929.168 1919.772 9.396125
3 1919.772 1919.078 0.694489
4 1919.078 1919.026 0.051594
5 1919.026 1919.022 0.003834
6 1919.022 1919.022 0.000285
7 1919.022 1919.022 2.118E-05

V 1919.022 cm3/mol
maka:
Z 82582.1