Cuenca Kivertres y Kale of a Reatlious - A— 6 7 ; 2 G (Rat), = -aen (Rate), = + a at deve con be owe for Prrsoune » aw Ub “sual fropoutional. tone” 4 cout @) (a) a c\ aby nn hime heme Cutera AAs = 6a -A = [6-4\- te om (424 ak ce ownage sae (5-4) Ae (Canon aad = “de tuatawanou dat = - de i refteceas he alec f Ce” yaw TP gaps se tow eules unit de de = (du) Fone mole } alt ol & v\ * Oe 0S ae eh i mast B sel C = mel fd aR : 7 Rett of Aeakliow = —-1 dey | oa of a WE 6 oe "ote a+ Ec d dunner ek A > ~ Ca Rae of alte fhe 5 dee de Rat af appearanee at C= me +Que Not BH NH, 1 kat sara arias af ih @ i 42 Mae! Uuhat wcll fo Aale “f ean" » Hu,» Man, 2 : Sot” (R) = 2 My, - Gy Ha. aS = 2 ho => R= Y Mace = Fey, Hye B Move! | y xate of ceaction dipemol fou s— a) Concentialien b) Tem puattve c) Plessine da) pt af accutton e) cottelyar a) Concenibiatleone ¢ — Rate ox ( cowerntiation) ” whare tau? is Hie @eellA of the Acaclion . eo fy delimined only om tne st0%anio. £4 ak + bBo — > eC + AD foe = dt = dq sbdee =I x a de bate Ae “po = Kent oof MOU ob reali ce i nr satay d Toy eR uty yo Go, tty é [o, 3] % Ovex OF teax” con be ealeulotta oefsbmrentall wa dbs wncrhanunn of Mie tour" i f x KB dubivsl ar te salt rovelant ay velo conntout ofeerfie Aeaction Late, ity x a h— 6 7 vdce = x Lal" 2 unit of K = fet ace | 7 alte Ue aia tk a on 0 on > (molt [ut ) ate. | Apr 1 owt 9 aces! Velie 4 9 ondul DOE wal! sectae Oda Kinetics * RK —— Vee teo Co =t ee Cy t de, . k (ta) > - atm = & Salt de iG ° hr x A os produ tro a Y tet a-% % . flan) . e(a-x) 5 “See op (at . moe] x , r (6) (t ‘ - Sf: ke Ae ; dt bine = lo + we wil K ? Wome gone ended2 Qf Ante of olerociilon to Co = ke eb Ce t : —da = ke 3 (te\nke re oa * fe fot orals y half tife Au (& = key, » ty = dn2 K + Thus, ch a of ental com” hee. . “4 7 ie (4) comcentlalton af 7) | hall bus = «(Ly Quo - OA % 26 — 7 G+ 4D At 1 bee what will be come of A awl & at wha will be dod, uf : re hat abatol be the twilink rnole © tatie [es ‘ (ty) = {i 7 wa fot A ae | dot” oF oe oe q | i tee Ss teo aQ b tt Qt b- 3% 2x Half aif (ty, ot ty, ot toe ) 7 Whew Aa of tne Acacldnt qe Aeoekd an Leow” ce 5 oe 2 a to > fo-@ = Kty, 2) ty a too’, : 7 aty 5 fos gow oealua f Pity Gepe 9 OG = ey > Vo” AR| Quis, Jor a eax", Aatt = klaf. af fvikial ton" t A ae Wo, tm C= 2 24 — prodel gol" a rey ae ce “Eds : kt G- Gs 2kE (ee= G-2ke| Que Sa a Aux", Gak),: [A]. of [A] i ee 2 procuct wal" -di ke D tela ake de Quus eS ee : Roti = k fen]? Eee]? RA ames, B= bral! Sunol Abe (tn), dad (ty) . Mae, oH yur Arawne (On), - (ty), > Ham fed Aakie ath.dol”. toe — ~ a b tet a-h& b- ue = (de) ek a E 2 de FD re rkk [ale a- 2k [eles be ake fen ty > we ve {aly % : [éley, -b Be A-2kby > (hy), = 4 (ty), an qe , a = b- > 22 Te a — | + Fao Qi Kew ilic A — produuel * tao | =t Ce . : -déen x(a) 9 me Cid alk Ff (a) . : m tO tet a-% “dan 1) ae &,~[beta-2) | a ee £na Sct > go ao i A iio) CE * é) w= get . ote (I-74 | | | i tat, = ful, ~ Kt Di Agee = Log c — ke 2.303 ae ( dma. jo Noa Ima - ke = Anla-x) # A ft od Pindie Acactiou wer ye completid ‘Half we iy Hrelepiodinl af balial Yeove + a 2A > PP 4 salt of tea KOH GG cco -Ldé .ke 2qe » <1 tme)* = : 7 y ke) Mn (4) = 2ktSom aw ® a= a(l-e 7) . Lale= ae (a- ae GL = (g(ene™)) ob BC feos £20 [ee “REG. ~2kE . = ae 2k = Oke fe (a, > bbw (0 ) 2 ke > 2K . - bla ( 4 ty = m/ 3a I C ~ ( sa) 2k fe ley)a es (ty), 3 Maz tna ( ). L 2e Za-b/ 2k 9 24 c = 3a-b 7 = = * Seeowd Olu Ciniliew * A——> P dt, uae to be tom nplitiow re = _ toe le ak Or: TEE Ce G * A | 5 oo 4 Sede ter a-y By | aK aJali K (o, ot c 5 core” * key = 2-1 a Vane & Se be ec | x : : i. Sq = a oe or 2h 3 f , uw t=0 be : R= K len) - Mee 2 (ae de eve t G Lr Side me 2 (4)( $ Puls Jeut Oda Rear} + Sopulint Cowes 4.26 2 ap t=0 a b (to ba t Ce coeoa ab ee ee Kae (ax) (b 0) > AG oe “as, > kid cn 4b iy J Ca-b) ) y-a (b-4) g . Lm awh @-b) | alb-x) x Fb se x Ym, by? 7a ke = (Lo im (Goh a-b Cb) ta) Thu, Hie 40K" Brae ao fle ous wt, A? * Sf A fy ww tpt 5 ) h(a) = kt Ce ¥ > | kt Thue, fhe neon” Ahante 00 fisat owls Wat, ©B’ 2 e Tew, he wet Bie mew, dm tar” b oA wiht. Poh EE Ano am Overy y Hun Acar” Riot ola wa B®, Qtunalt eroliu wor pteowal, , dun — OK” one talltal pouole fot aol Aenclion , ag fotta’s ‘tyasolyab Saarwn Meth Older Kieetids = lo -dt. a ; te He) Ger) “hen = -kfdt ean \" =I [ [ ba + 6 x S i a 7 SG) | OE a) + a t © (lo)” (ey Gayk ye tpt KC)” (n-) [a""-4] The , & y & ta) ae (ty) & ® to f — MUM i ee ms om say, . (e'™ + Oeln a Reaéliou ‘rlloaig ant Me netiadls tH elite orl of iG Guia “eat Pa fin — Grs- Ulhadl ©) Hott dde Method (4? papi AM ethad © oturala's daolalion Mettid(@) Awidtiat Race Caw Method Quo. oA + BB tC RP a, A ta te) Ee gate (M oe) ‘) 0.02 0.02 0.02 exloe a) 0,02 0,04 0.02 6 Ko” %0\ 0.02 9.02 2x1 4) 9.02. 0,02. 0.08 3.9 xlo™ a what wit be fu groli of Mht Aton ee ae al, Tela tel oud ourall § ool of dean” | b) What wlll be cat af aed aoe aa C KR], [2 ] : (c] cow ep tach «TAT, UBD, [ed & 008%, ec) What ts Mie value a | oporifer dunt’ Anke /, att (OF: es a> ysl o-$ =] a3 *=0 N R fi euall sath = 2 i >, aac = [aT £87" Ce]! (fy Cro: kK (0. 02) (0. 02) Dk = 2X/o7% mol Uae? ff a 2 yr. 6 4 ( 4 t( “dts ) R=(1) ( ( 2x10?) (0.02) © = 36X10 Mote » x10) (0.08) " AK 6X 10% M ote! Re = R= (5) + Recemuere + ( 2x10?) (4 not) 2 sxig to? Hac? yu ao 2 y mat at den whigat tat dau Metts, (-Rat Ala) Niboon t= eee tea er oun :- C Ce het ye alin east ree els ie es (a2) fet fot orn s- R= Lil) oF woe k= tomlawt, Hom wel Amal ola(c) Malf- Lye M ether ty, & GC) | « wt te dp ahltt 2 ent pene = & \( ta up n > ( a z= \Cb a | wpb > Cy Us 2 Mis etod , vat Lom only, coludali oval, Ova Akt toe” @ Sap kat Methisol > clone taxdin ©) Catuatd — Yaolalidn Method ak + ba 7 paduet Rati = K (¢,)% (eye ry Oar = kK CO)T yh 7 Be dh antim , Role = ke Ctn)™ 3 gh Thue, we get fir sale Aer A Mastdag Mf Roetin fs fit os dt x “ os OMY UTIL, wT =wolank An tg) > why data will b too a Antat Premmee fe ay anne a na Kone : og . pee ee ehmhULULD Now, ac P, : am eM & PE , mA o& Peo fo- fy - KE Ue a) Aya = pe Oe] ico — VE4 Tonge eye * a) “Tempualine Couf feivtt O- ke Ho ge define av i alia | at ie ole —cowslowt> of ——— ke wsluat Hurnpuatone ‘Luma Le 40 upsla » | Ain, Fg to = kr tle =f Cw 1 don { i Ke Mall isis ; i | Que Kate wwolavt at 250 & 4X10 Set, What wil be salt tomtant at 55°C 4 6-27 ol" tae sXe ipcd 2 XX 7 16 X10 a me «x10? 25°C 35°C 45°C, at TC 9 29703 toh i aot oo La, = o9(0) | (b) A svhemutio ae 7 te an aoa Ui a funy els fonds funsting ovduli a awd sia ie wroluentle , Fovaa® with — be wl. AB, the calunier murt kt affedlut. Fox tata, aaa “ale aloud. owe euch — anova af anny suiitaleu, B a N,0y of 2NO, | oo @ pit 4 7 tie 2 Anatote - @) drindaltin , § (D vat ni The fn rea f* fa Min aay We 7 ras whut Fa > ee ennay ok ioe 4 “Aefpatatia dy fae -etponeridial fain) Auypemity Fics Ae Per | gfiiong foamx» Wheneves aot aventionel, Anke tony ol artiuation fn A foward ACK”, ve b iw Hf tu, tw my ¢ : a e b ay, 5 fay Eay / om — AN?O AM i, bdo R = ‘ Liaeliou pogqun Raalion psy Fay = An + Eq, rq a H+ fap ch x i he Pale > taketh -B. | eT | = Ea + yk Uae Qh Bie, (UU MBs a Ae L—O a a _ a oa Ke = Le ae Re 2zwosR tT = : ei alt wovstint =4X10 oe! . At 34 Gus, AC me, sat ela OO ed ; K war SKIT aes : 4 tee ee 7 t (2.303) 183) L Blo | > Gaz 0.3) 29)(E.3) (soe)Csie) = 532417 lo : hak oe . ae £ 4 ae | Ea Jeree 0, ct? ‘I pe of Keaclions OA Rearliou s— a ing step oy ie ic x” ywdlt be se e — Ataction , p tht dA He aun of the alorelowmelue carppccud ao wll av Ue Wroliecelduitty, Of Mae ua” Wilh be War aura f atocelondteé © 4b A 0 ae ~ECeomeulay tie ovolrl fate= k (en) (cs) . _ (MERE) ts, a J : 7{>x ee, 7 a aa y ig i | Le « lev Wwe] al | dD bh) Wultr- step zs oval dua”, we, coonrt — detiivrvane anoles ae Hie seattion - For Foe calowtatiion #f ovolur eax, wt wal vonsidir alow” atip an the salt ducing the ttn ah xcoae” till be He own of placchiomeise voufh of Ane alowust of. x salou” atip Ay wow” of ilunrdiakt , then olin bk thre Leon" cam dy o. nud com be delved by aur eglb™ Aton” iby tog We tam lennnale inGmdiale comenvitroiy,® du comple Aan", We haw Arfiine pearerres | { hc atips Aut ot fon Min ourralh avax", 9. 0. Se ot 4 ( foot) Onto Ki 5 20, ( ofr) ve Lalted > [ol= ki Cos] = Cox} ke Fay -l L i am tol [oJ 0 4 2 Bee AK = 4 aeleeulacity, = anol Amin * Wattoula sig wut be Lins Linton / Ws a tyuak & 5. * 7 Hy ae x ut @ e dt Me ae ut 3 chy Rah ad [rx] et SN, react. & Ruatut Vinettn CK ki, g (x) x A a Key ¢ eo (4) tet am% ~i -Ad¢ >» Alas 7 dy Mi sete 9 Get Sie de] ekycn » A. Km ak at D> Keys HC th> fm (4) ake > [Tale ae” | + Sagar = 5 woe ih = at C eo rey Tele [ an fas ae | 4 BL. a vo KEK EK Cet, Led me = nr &imd = Tay Te te (Tih th), * hy ye x Ounall activation otha Ea KE, t KE esi ae Kak, ca 4 Cc ~ ¥ Bato Kinet x Ae ¢ Cee feats [al, = ce ky [a|- i ie ti ae qe te] 5 ial 5 . ale] ies le Og fe | = fa [> "Tele | Kae at edt 2 E : : bee 4) & CeJent b0,) l i \e}. s Aa | ¢ eat og Hk | ae i . vale Naw, aipjocatin tie [Cle & fine onan, it Cees Vime when [8] & awk = (uta = tak 7 Jat) wl * [Al = = lates Cele +L], Equclibriioon Reartiove A Kes B ky teo Qa “Che eaph™ eee _ ums a + en 2 faq akn [8] i dGa-y) = 4 (aa) ~ ket) sera ‘ oa = ake - Cy + Ite) x Soa 7 SH aks mas thoy fon akg — (ep th) - (kg tke) ) ee +k) [ug ke + a HIB sees ) ~ (kg + ke)t Ms akg (\ [ee Ogre 5) (i +k)| X= ak > bg eee x CD ta Yeaks a k 4 = ; a x(t tee oe ark Catdiyot > aubitamca whith coe Yncredot sate al he AL Wht. 4 ce fnewdrls Hae date ef dua” M0 duacose the alt gf eae” vuliuee oa Reackion spre A (peas eetalyst duarae He £1) fasts « Tau, Eq? will Mov fe fot forwail anal Backward ken” Ke Ae Feler x2 he By _p? ic TC. oS ) Ha. ty ‘)