Safety Data Sheet According to Regulation (EU) No. 1907/2006 (REACH), Annex I Version: 1.0/EN Rovision date: 12/08/2016 Product name: CHLORINATED POLYETHYLENE (CPE) Printing date: 12/08/2015 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.4 Product identifier ‘Trade Name: CPE CM3565N Product description: Odorless powder with white color. 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Used in the plastics industry as an additive to modify a range of properties. Also used in rubber industry, Uses advised against: Not available. 1.3 Details of the supplier of the SDS Company name (Manufacture): ETKINKIMYA ‘Addross: Deri OSB Mah. Etleme Sok Ist. Deri OSB Sites XIX ve XX Blak Apt. No:1/19-13 Tala/stanbul E-mail satis@etkinkimya.com Telephone: 19071649363 63 Fax: 190716493 63 2 Company name (Importer): Address: E-mail Telephone: Fax: 1.4 Emergency telephone number +90 216 493 63 63 (Only office hours available.) ‘SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008[CLP] ‘The product is not classified as hazardous under Regulation (EC) No 1272/2008{CLP]. Classification according to Council Directive 1999/45/EC ‘The product is not classified as hazardous under Council Directive 1999/4S/EC. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP] 'No label information available. The product is not classified as hazardous under Regulation (EC) No 1272/2008 [CLP], Labelling according to Council Directive 1999/45/EC 'No label information avaliable, The product is not classified as hazardous under Council Directive 1999/45/EC, 2.3 Other hazards No information available, SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS: 3.1 Substance information Classification according to Regulation Chemical Name CASNo. | EC No. (ee) No tz7zt008 Concentration % Chlorinated polyethylene 64754.90-1_| Not available. | No classification 390 Talc (Mg3H2(Si03)4) 14807-96-6 | 238-877-9 | No classification. <7 Calcium carbonate 471-34-1__|207-839-9 | No classification os Calcium distearate 1592-23-0 | 216-472-8 | No classification. 03 Page 1/8Safety Data Sheet According to Regulation (EU) No. 1907/2006 (REACH), Annex I Version: 1.0/EN Revision date: 12/08/2016 Product name: CHLORINATED POLYETHYLENE (CPE) Printing date: 12/08/2015, Classification according to Chemical Namo CASNo. | EC No. SvareeC Concentration % Chlorinated polyethylene 64754-90-1_| Not avaliable. | No classification 390 Talo (Mg3H2(Si03)4) 14807-96-6 | 238-877-9 | No classification <2 Caleium carbonate 471-34-1 | 207-439-9 | No classification os Calcium distearate 1592.23-0 | 216-472.8 | No classification 03 SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures General notes: In all cases of doubt, of when symptoms persist, seek medical attention Following inhalation: Move victim to fresh air. Seek medical advice immediately if adverse symptoms such as chest tightness, respiratory initation, coughing or breathing dificulties develop. If breathing has stopped apply artificial respiration. Following skin contact: Remove contaminated clothing and footwear. Wash affected areas with soap and plenty of water. Decontaminate footwear and wash clothing before reuse. Seek medical advice if skin iritation develops. Following eye contac Ifthe dust go into eye, can rinse eyes with water for atleast 5 minutes. Following ingestion: I swallowed do NOT induce vomiting. Rinse mouth thoroughly with water. Seek medical advice. Notes for the doctor: ‘Troat symptomatically and supportvely. Treatment may vary with condition of victim and specifics of incident. 4.2 Most important symptoms and effects, both acute and delayed It may cause minor irritation with eye or skin contact due to mechanical effects, but is not absorbed through the skin, Dust may cause irritation to the upper respiratory tract. 4.3 Indication of the immediate medical attention and special treatment needed ‘Attending physician should treat exposed patients symptomatically First Aid Facilities: Have eyewashes, safety showers and normal wash room facilites availabe in the vicinity where exposure may occur. SECTION 5: FIRE-FIGHTING MEASURES. 5.1 Extinguishing media Suitable extinguishing media: Use water, foam, dry chemical or carbon MEDIA dioxide to extinguish fr. Unsuitable extinguishing media: No information available. 5.2 Special hazards arising from the substance or mixture Oxides of carbon, hydrogen chioride, organic acids, aldehydes and alcohols, Dust ofthis material is capable of producing explosive mixtures with air 5.3 Advice for fire-fighters Do nat stay in dangerous zone without self-contained breathing apparatus. In order to avoid contact with skin, keep a safety distance and wear suitable protective clothing Prevent fire-fighting water from entering surface water or groundwater, SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Dust of this material is capable of producing explosive mixtures with air. ‘Wearing full PPE isolate hazard area, increase ventilation and restict access. Remove all ignition sources. Take steps to reduce dust generation as this material is capable of producing explosive mixtures with air. ~Page2/8—Safety Data Sheet According to Requlation (EU) No. 1907/2006 (REACH), Annex I Version: 1.0/EN Rovision date: 12/08/2016 Product name: CHLORINATED POLYETHYLENE (CPE) Printing date: 12/08/2015 6.2 Environmental precautions Prevent from entering sewer system, surface water or soll 6.3 Methods and material for containment and cleaning up ‘Sweeping or vacuuming techniques. ‘Small Spills: Wear suitable respiratory protection. Use a dry cleaning procedure and avoid generating dust. Sweep or ‘vacuum up the product and place in sealable containers. Label the containers to ensure appropriate disposal Large spills: Wearing the personal protective equipment listed in Section 8 use a dry clean-up procedure. Vacuuming is the preferred method. Altematively, sweep up product with a broom. Take steps to minimise generation of airborne dust. Place Contaminated material in suitably labelled, containers. Prevent substance from entering drains, waterways or groundwater. 6.4 Reference to other sections ‘See Section 7 for information on safe handling, ‘See section & for information on personal protection equipment, ‘See Section 13 for information on disposal SECTION 7: HANDLING AND STORAGE 7.4 Precautions for safe handling Practice sound industrial hygiene. Wash hands before work breaks and at the end of a shift, When handling minimise contact with product by always wearing the recommended personal protection equipment (See Section 8). Avoid dust generation - material is capable of forming explosive mixtures with ait. Avoid breathing airbome dust. Avoid contact with, or inhaling vapour emanating from molten material 7.2 Conditions for safe storage, including any incompatibilities Store in a cool, well ventilated place, Avoid exposure to direct sunlight or heat Store away from incompatible materials (see Section 10). Protect against physical damage, 7.3 Specific end use(s) Not available. ‘SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Occupational exposure limit values: CHA (MAC):1 mgim? cas # Occupational exposure limit values. (Hydrogen chloride may be generation under 14807-96-6, Long term/ Eight hours thermal degration conditions) U.S (TWA): 10 mgim? (Calcium carbonate); ‘Austria 2 mgim? respirable aerosol arise Canada 3 magi Long term/ Eight hours. Denmark (0.2 mgim? respirable aerosol Canada 40 mg/m? ‘Hungary 2 mgim3 respirable aerosol France 10 mgim’ inhalable aerosol ‘Spain ‘2 mgim* respirable aerosol Hungary 10 mgim? inhalable aerosol Sweden 2 mgim? inhalable aerosol Poland 10 mgim® 1 mg/m? respirable aerosol Spain 10 mgim? inhalable aerosol ‘Switzerland 2 mgim? respirable aerosol ‘Switzerland 3 mg/m? inhalable aerosol ‘The Netherlands 0.25 mgim? respirable aerosol USA - OSHA 15 mgim* total dust USA - NIOSH 2mgim? 5 mgim? respirable dust United Kingdom 1 maim? respirable aerosol United 10 mgim* inhalable aerosol Limit value - Short term [nadom ‘4 mgim* respirable aerosol Denmark 0.6 mgim? respirable aerosol Page 3/8 ~Safety Data Sheet According to Regulation (EU) No. 1907/2006 (REACH), Annex I Version: 1.0/EN Rovision date: 12/08/2016 Product name: CHLORINATED POLYETHYLENE (CPE) Printing date: 12/08/2015 8.2 Exposure controls ‘Appropriate engineering controls: Use only in well ventilated areas or use good general mechanical extraction ventilation to maintain air concentrations below exposure standards. Personal protective equipment: Eye and face protection: Safety glasses should be sufficient for most operations; however, for dusty operations wear ‘chemical goggles. If vapor exposure causes eye discomfort, use a fullface respirator, ‘Skin protection: No precautions other than clean body covering clothing should be needed Respiratory protection: Use a dust respirator. Thermal hazards: Not available, Environmental exposure controls: ‘Should not be released into the environment. Prevent from entering sewers, basements and workpants, or any place where its accumulation can be dangerous. Consumer exposure controls: Handle in accordance with good industrial hygiene and safely practice, Wash hands before breaks and at the end of workday. No adverse effects are expected as a result of normal contact with them. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance: Powder Colour: White Odour: Odoriess pH No data available, Melting pointtreezing point: No data available. Bolling point No data available, Flash point No data available, \Vapour pressure: No data available, Density: 1.44.3 glem? Bulk density 0.45-0.6 glem? Solubilty(ies) Insoluble at 20°C Partition coefficient (n -octanoliwater): No data available, ‘Thermal degradation temperature: ‘App. 160°C. Viscosity No data available, Oxidising properties: No data available 9.2 Other information No data available, SECTION 10: STABILITY AND REACTIVITY 10.4 Reactivity No data available. 10.2 Chemical stability ‘This material is stable under normal ambient and anticipated storage and handling conditions. 10.3 Possibility of hazardous reactions No data available. 10.4 Conditions to avoid ‘Strong heating, open flames. ~Page 4/8Safety Data Sheet According to Regulation (EU) No. 1907/2006 (REACH), Annex II Revi Printing date: Version: 1.0/EN Product name: CHLORINATED POLYETHYLENE (CPE) n date: 12/08/2016 12/08/2015: 10.5 Incompatible materials Oxides of carbon, hydrogen chloride, organic acids, aldehydes and alcohols, 10.6 Hazardous decomposition products lnrtating gases may be emitted upon the temperature 160°C. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Toxicokinetics, metabolism and distribution CAS # 64754-90-1 CAS #471-34-41 No data available, After ingestion /of CaCO3 tablets, it are converted to sol calcium salts in bowel, and calcium is thereby made available for absorption. Using radioactive tracer techniques in rats, mice, guinea pigs, and hamsters, no intestinal absorption or translocation of ingested tale to the liver and kidneys was detected No data avaliable, CAS # 14807-96-6 CAS # 1592-23-0 11.2 Information on toxicological effects Acute toxicity The product is not expected to be acutely toxic. CAS # 471-34-1 Acute Oral toxicity: ‘Acute Inhalation toxicity ‘Acute Dermal toxicity Skin corrosionlirrtation: May cause slight skin itritation on prolonged or repeated contact. Serious eye damagelirritation: Not an eye irritant. ritation and possible scratching of the comea due to the mechanical action of the material may occur. Respiratory or skin sensitization: Exposure to high levels of dust may iritate the respiratory tract. CMR effects (Carcinogenicity, Mutagenicity and Toxicity for Reproduction): ‘To the best of our knowledge, the toxicological properties have not been thoroughly investigated. No classification data on carcinogenic properties ofthis material is available from the EPA, IARC, NTP, OSHA or ACGIH. STOT-single exposure and repeated exposure: Repeated breathing of dusts over many years may result in adverse lung effects. Aspiration hazard: No data available, LLDso = 6540 mgikg (rat) (IUCLID); LDo = 0.0812 mg/kg (rat) (IUCLID}; No data available, SECTION 12: ECOLOGICAL INFORMATION 12.4 Toxicity ‘The product is not expected to be acutely toxic. ‘Acute toxicity Effect dose Species Method GAS # 64754-90-1 No data available, CAS#A71-34-1 Acute fish toxicity: NOEC> 200 mgii24h Poecilia atipinna Other CAS # 14807-96-6 CAS # 1592-23-0 ‘Acute daphnia toxicity: Acute bacteria toxicity: Acute fish toxicity Acute daphnia toxicity: ‘Acute bacteria toxicity No data available. No data available, No data available, Lesa> 100 gfi24 h No data available, No data available, Brachydanio rerio Other: NF T90.303, 12.2 Persistence and degradability No biocancentration is expected because of high molecular weight (MW>1000). In the terrestrial environment, this material will sik and remain in the sediment, ‘This water insoluble polymeric solid is expected to be insert in the environment. Surface photodegradation is expected. = Page 5/8—Safety Data Sheet According to Regulation (EU) No. 1907/2006 (REACH), Annex II Version: 1.0/EN Rovision date: 12/08/2016 Product name: CHLORINATED POLYETHYLENE (CPE) Printing date: 12/08/2015 12.3 Bioaccumulative potential Based on best current information, there is no data known associated with this product. 12.4 Mobility in soil Based on best current information, there is no data known associated with this product. 12.5 Results of PBT and vPvB assessment Based on best current information, there is no data known associated with this product. 12.6 Other adverse effects No data available, SECTION 13: DISPOSAL CONSIDERATIONS. 13.1 Waste treatment methods ‘Bur in an approved industrial incinerator or bury in an approved industrial landfil in accordance with applicable federal, state, and local requiations. SECTION 14: TRANSPORT INFORMATION 14.1 Land transport (ADR/RID/GGVSE) ‘This product is not regulated as a hazardous material or dangerous goods for transportation, 14.2 Sea transport (IMDG-Code/GGVSee) ‘This product is not regulated as a hazardous material or dangerous goods for transportation, 14.3 Air transport (ICAO-TMIATA-DGR) ‘This product is not regulated as a hazardous material or dangerous goods for transportation, 14.4 Additional information ‘According the intermational transportation regulation, this product is suitable to sea transportation, SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulation: ‘Authorisations: No information available. Restrictions on use: No information avaliable, EINECS. All the ingredients of the product are listed in the Inventory. DSD (67/548/EEC): Al the ingredients of the product are not listed in the Annex |. US federal and state regulations: USA - TSCA: Al ingredients are not required to be listed on the TSCA inventory SARA hazard category: This product has been reviewed according to the EPA" Hazard Categories” promulgated under section 311 and 312 of the superfund Amendment and Reathorization Act of 1986(SARA Tie Il) and is considered, under applicable definitions, to meet the following category: not have met any hazard category. OSHA hazard This product is not a "Hazardous Chemical" as defined by the OSHA Hazard communication communication standard: Standard, 29 CFR 1910,1200, Other chemical regulation: Canada-DSLINDSL: All the ingredients ofthe product are listed in the DSL inventory. Australia - AICS. Al the ingredients of the product are listed inthe Inventory. Korea- ECL: Al the ingredients of the product are listed inthe Inventory. Japan - ENCS: All the ingredients of the product are listed in the Inventory except of CAS # 14807-96-6. China - IECSC: Al the ingredients of the product are listed inthe Inventory. China: ‘According to the standard of China, “Classification and code of dangerous goods” GB. ~-Page 6/8Safety Data Sheet According to Regulation (EU) No. 1907/2006 (REACH), Annex Il Version: 1.0/EN Product name: CHLORINATED POLYETHYLENE (CPE) 2108/2016 12/08/2015: (6944-86, This product does not belong to dangerous goods. 15.2 Chemical Safety Assessment No Chemical Safety Assessment has been carried out for this substance. SECTION 16: OTHER INFORMATION 16.1 Revision Information: Date of the previous revision: Not applicable. Date of this revision: 12/08/2016 Revision summary: New SDS 16.2 Abbreviations and acronyms Gus: Globally Harmonized System of Classification and Labelling of Chemicals. cup: EU regulation (EC) No 1272/2008 on classification, labelling and packaging of chemical substances and mixtures, cas: Chemical Abstracts Service (division of the American Chemical Society) EINECS: European Inventory of Existing Commercial Chemical Substances. NIOSH: The National Institute for Occupational Safety and Health of United States. IARC: Intemational agency for research on cancer. RID. European Rail Transport. IMDG: International Maritime Code for Dangerous Goods. IATA: International Air Transport Association. Dsp: Dangerous Substance Directive (67/548/EEC). TSCA: Toxic Substances Control Act, The American chemical inventory SARA: The Emergency Planning and Community Right-o-Know Act. OSHA: The United States Occupational Safety and Health Administration HMIS: Hazardous Material Identification System. NFPA; The National Fire Protection Association of United States, DSLINDSL: Domestic Substances ListNon-domestic Substances List, The Canadian chemical inventory AICS: The Australian Inventory of Chemical Substances. ECL: Existing Chemicals List, the Korean chemical inventory ENCS: Japanese Existing and New Chemical Substances. PICCS: Philippine Inventory of Chemicals and Chemical Substances, IECSC: Inventory of existing chemical substances in China 16.3 Key literature references and sources for data IUCLID Dataset. HSDB Hazardous Substances Data Bank, United States National Library of medicine. 7.4 Relevant R-phrase(s) and H-statement(s) No data available, 7.5 Training advice No data available. 16.6 Declare to reader ‘The information in this Safety Data Sheet (SDS) was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibilty and expressly disclaim lability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SOS was prepared and is to be used only for this product. Ifthe product is used as a component in another product, this SDS information may not be applicable. ‘According to REACH Article 31(5), the SDS shall be supplied in an official language of the Member State(s) where the substance or mixture is placed on the market, unless the recipient Member State(s) concerned provide otherwise. It should ~Page7/8~Safety Data Sheet According to Regulation (EU) No. 1907/2006 (REACH), Annex I Version: 1.0/EN Rovision date: 12/08/2016 Product name: CHLORINATED POLYETHYLENE (CPE) Printing date: 12/08/2015 ‘also be noted that this SDS is applicable to the countries with English as an official language. End of the SDS —- Page 8/8 ~