eee = & Mole Concept NCERT EXE] RCI tS eruahe fs msi onda on Present in sodium sulphate (Na,SO,). le : ; can © of iron which has 69.9% iron and 30.1% oxygen by alculate the amount of ioxi 3 ¢ carbon dioxide that could be produced when : (i) 1 mole of carbon is burnt in air, Gi) 1 mole of carbon is bumt in 16g of dioxygen. (ii) 2 moles of carbon are burnt in 16g of dioxygen 4, Calculate We ass of sodium acetate (CH,COONa) required to make 500 mL of 0.375 molar aqueous solution. Molar mass of sodium acetate is 82.0245 g mol! 5, Calculate the concentration of nitric acid in moles per liter in a sample which has density 1.41 g mL" and the mass percent of nitic acid in it being 69%. 6, How much copper can be obtained from 100 g of copper sulphate (CuSO,) ? 7, Calculate the atomic mass (average) of chlorine using the following data : %NaturalAbundance Molar Mass *Cl 75.77 34.9689 Cl 24.23 36.9659 8, In three moles of ethane (C,H,). Calculate the following : (i) Number of moles of carbon atoms. (ii) Number of moles of hydrogen atoms. Gii) Number of molecules of ethane. 9, What is the concentration of sugar (C,H,,O,,) in mol L" if its 20 g are dissolved in enough water to make a final volume up to 2L? 10, If the density of methanol is 0.793 kg L-!. What is its volume for making 2.5 L of its 0.25 M solution? 1. Inareaction A+B, — > AB, dentifiy the limiting reagent. If any, in the following reaction mixtures. () 300 atoms of A + 200 molecules of B, (ii) 2mol A+3 mol B, 5 mol A + 5 mol B. 719JEE-Chemistry 12. 13. 15. 16. 17, aay | | ‘| Dinitrogen and dihydrogm react with each other to produce ammonia according to the I chemical equation : N, (g) + 3H, (g) + 2NH, (8) (@ _Caleulate the mass of ammonia produced if 2.00 x 10° g dinitrogen reacts with 1.99 , lo, of dihydrogen. (ii) Will any of the two reactants remain unreacted? (iii) If yes, which one and what would be its mass? If ten volume of dihydrogen gas reacts with five volumes of dioxygen gas, how many Volumes water vapour would be produced? Which one of the following will have largest number of atoms ? @ = 1g Au(s) Gi) 1gNa(g) Gi) 1gli) Gv) 1g of Cl, Calculate the number of atoms in each of the following (i) 52 moles of Ar (ii) 52 u of He iii) 52 g of He. Calcium carbonate reacts with aqueous HCI to give CaCl, and CO, according to the reaction CaCO, + 2HCKag.) ——> CaCl(aq.) + CO) + HOW What mass of CaCO, is required to react completely with 25 mL of 0.75 M HCI? Chlorine is prepared in the laboratory by treating manganese dioxide (MnO,) with aqueox hydrochloric acid according to the reaction, 4HICI (aq.) + MnO, (s) ——> 2H,0(@) + MnCl,(aq.}+ — Cl, (g) How many gram of HCI react with 5.0g of manganese dioxide?Mole Concept EXERCISE -I [JEE Mains Pattern] nic mass of Sodium i 7, _ If the atomic mass of Sodium is 23, the number of moles in 46 g of sodium is : (Al ; (B)2 ©23 (D) 4.6 2, 2 moles of nitrogen atoms at 273K temperature and Latm pressure occupy a volume of : (A) 1.2L. (B) 44.87 © 224L (D) 5.6L 3, / The weight of a molecule of the compound C,H, is (A) 1.09 x 107! g, (B) 1.24 x 107'g (©) 5.025 x 10g (D) 16.023 x 10g |. Which of the following contains the greatest number of atoms ? [Given : gram atomic mass of Ag = 108g, C =12g, H= 1g, (A) 1.0 of butane (C,H,,) 14g] (B) 1.0 g of nitrogen (N,) (© 1.0 g of silver (Ag) (D) 1.0 g of water (HO) 5, Which of the following has the highest mass ? (A) LgatomofC — (B) Amole of Cy (C) 10 mL of water (D) 3011x107? atoms of 0 6 Four one-litte flasks each are separately filled with'the gases H, He, O, and O, at the same temperature‘and pressure. The ratio of total number of atoms of these gases present in different flask would be : (irdsdil (B)1:2:2:3 (©2:1:2:3 (D)3:2:2:1 7. Weight of oxygen in 32.2 g Na,SQ,. 19H,0 is 2.4y¥ lo? (A) 20.8 g (B) 22.4. (© 2.248 (D) 2.08 g 1: zx1ot! 8 The total number of protons in 10 g of calcium carbonate is (N, = 6.023 x 10°) 22x07 (A) 1.5057 x 10% = (B) 2.0478 x 10% = (C) 3.0115 x 10" = (D) 4. 0956 x 10° Txt From 392.n¢ of H,SO,, 1.204 x 10" alpen are removed, How many moles of H,SO, are let? (a0 x 102 wy 12x10° 9 MC\40x 10 Be) 15 10° 10. A person adds 1.71 gram of sugar (C;jH».0;,) in order to sweeten his tea. The number of carbon atoms added are : [Given : Molar mass of sugar = 342, Na = 6 1073] (A) 3.6 x 1022 (B) 7.2 x 107! (C) 0.05 (D) 6.6 x 107 IL, Density of ozone relative.to methane under the same temperature & pressure conditions is : @l (B) 3 (C) LS (D) 2.5 lay (B) © (14) The relative density of a gas A with respect to another gas B is 2. The vapour density of the gas B is 20, the vapour density of the gas A is : “ (A) 30 (B) 40 (©) 50 (D) 60 13. The empirical formula of a compound of molecular mass 120 is CH,O. The possible molecular formula of the compound is : : (A)CH,O, (B) CHO, (©\C,H,O, (D) all of these 81: aay 1 JEE-Chemistry Say 30% of carbon, and its V.D. = 15 then the hydrocarbon is - ©) CH, hydrocarbon contains “ rn & ®) CH, OCH. ‘ ‘An oxide of metal M has 40% by mass of oxygen. Metal M has atomic mass of 24. The eng, cal formula of the oxide (A) M,O (B) M,O, (C) MO . (D) M,O, 16. A given sample of pure compound contains 9.80 g of Zn, 1.8 x 10 arms ot chromium ana o « mol of oxygen atoms. What is the simplest formula : (At. wt Zn = 65.3, Cr = 52) | (A) ZnCr,0, (B) ZnCr,0, (©) ZnCrO, (Py ZnC10, 17. Insulin contains 4 % sulphur, The minimum molecular weight of insulin is — (B) 1200 (© 1600 (D) 2000 (A) 800 in (i) Volume of CO, obtained at 1 atm, 273 K by the complete decomposition of 9.85 g. Baco, i (At. wt of Ba = 137) (A)2.24L @)112L If 0.5 mol of BaCl, is mixed with 0.1 mole of Na,P (C)0.84L (D)0.56L 0, the maximum number of mole of BaP) Ms that can be formed is:- (A) 0.7 (B) 0.05 20. The volume of gas at 1 atm , 273 K produced by 64 g of CaC; with excess of water will be: CaC,(s) + H,0(£) —> Ca(OH)3 + CyH,(g) (A)70L (B)35L. (©17.5L (D) 22.4L (i) impure 7 g of NaCl is dissolved in water and then treated with excess of AgNO, solution The weight of precipitate of AgCI is found to the 10 g. The % purity of NaCl is : (A) 58.23 (B) 83 Ox en What weight of CaCO, must be decomposed to produce the sufficient quantity of carbon dioxide to convert 21.2 kg of NaxCO, completely in to NaHCO,, [Atomic mass Na = 23, Ca = 40] (© 0.30 (D) 0.10 22, CaCO, —+ Ca0 + C0, Na; CO, + CO, +H,0 —> 2NaHCO, (A) 100 Kg (8) 20Kg (©120Ke wae * ae grams of NaOH are needed to prepare 250 cm? of 0.4 M NaOH solution ? 24, the vm weight of an 9 SEG )4g luo 2°04 i898. The weight of the acid in 400 mL of 0.1 M solution is g 8) 3.2 g (©) 450 ¢ oe,Mole Concept 36 g glucose (C,H,,0,) are dissolved in 300 mL solution which has density 1.32 g /mL. The molality of the solution is (A) 14m (B) 18m (©) 0.55 m (D) 0.88 m If 500 mL of 1 M solution of glucose is mixed with 500 mt of 1M solution of glucose final molarity of solution will be : (AIM (B) 05M (©2M (D) 15M What approximate volume of 0.40 M Ba(OH), must be added to 50.0 mL of 0.30 M NaOH to get a solution in which the molarity of the OH ions is 0.50 M? (A) 33. mL (B) 66 mL (© 133 mL ) 100 mL. Mole fraction of A in H,O is 0.2. The molality of A in HO is : (A) 13.9 ®) 15.5 © 145 @) 168 The molarity of the solution containing 2.8%( mass / volume) solution of KOH is : (Given atomic mass of K= 39) is: (A) 0.1M (B)0.5M (02M (@)1M The total number of ions persent in 1 mL of 0.1 M barium nitrate Ba(NO,), solution is - (A) 6.02 x 10" (B) 6.02 x 10” (©) 3.0x 6.02 x 10 (D) 3.0 x 6.02 x 10== Ay se6-Chemisey EXERCISE -l SINGLE CORRECTANSWER TYPE ga g of carbon, 12 8 of hydrogen 9, yy mixing 04, produced 1g to piven reaction, is 1. Mass of sucrose Cy Hao 561 O, at 1 atm & 273 K accord 0.9 ls) + Hy) + 2 (9 Cant (A) 138.5 g (B) 155.52 (©) 172.58 (@) 9.58 2, The percentage by mole of NO, in © mixture of NOG) and NOCE) having average mole, (D) 75% mass 34 is + (A) 25% (B) 20% (© 40% 3, The minimum mass of mixture of Ay and B, required to produce at least 1 kg of each produet ig; = 120) 10 ; At. mass of 'B' [Given : At mass of 'A' 5A,+2B, — 2AB,+4A2B (D) 1660 g (B) 1060 g © 5608 and 54 g of HO. The molecular (A) 2120 g stion gives 132 g CO, 4. 74g of a sample on complete combu: formula of the compound may be (ACH (B)CyHyo0 (OCHO; ‘An iodized salt contains 0.5 % of Nal. A person consumes 3 g of salt everyday. The number of () CH ” iodide ions going into his body everyday is (A) 10+ (B) 6.02 x10+ (©) 6.02 x 1019 (D) 6.02 x 1073 6. The mass of P,Q, produced if 440 g of P,S, is mixed with 384 g of O, is P,S; + O, — P,O,9 + SO, (A) 568 g (B) 426 g (© 284g @) 396 g 7. g. ce The mass of Mg,N, produced if 48 g of Mg metal is reacted with 34 g NH, gas is Mg + NH; —> Mg,N, +H, , 200 o> py 00 al 3 (B) 3 © > (D) no 8. The number of carbon atoms in : 1S present ig if asi ep in a signature, if a signature written by carbon pencil weigh (A) 12.04 x 10°° (B) 6.02 x 10° (©) 3.01 x 1019 (D) 6.02 x 10°° 9. — The average atomic m: lass Of a mixture containin; y ; ; 79 2 of 25Mg and *Mg , is 24.31. % mole of 2°Mg oe mole % of 4M and remaining 21 mole (A) 5 (B) 20 ©10 ors Se Pe 8412. 14. 15. LEM Mole Concept umes sh i ‘What vol ‘ould you mix of 0.2 M NaCl and 0.1 M CaCl, solution so that in resulting lution the concentrati Ee solt tration of positive ion is 40% lesser than concentration of negative ion. Assuming total volume of solution 1000 mL, (A) 400 mL NaCl, 600 mL Cac, (B) 600 mL NaCl, 400 mL CaCl, (©) 800 mL NaCl, 200 mL Cac, (D) 200 mL NaCl, 800 mL CaCl. ; Ly For the reaction, 2X+3Y +4Z—>+ 5w Initially if 1 mole of X, 3 mole of ¥ and 4 mole of Z is taken. If 1.25 mole of W is obtained then % yield of this reaction is : (A) 25% (B) 50% For the reaction (C) 60% () 75% 2A +3B4+5C—> 3D Initially if 2 mole of A, 4 mole of B and 6 mole of C is taken. With 25% yield, moles of D which can be produced are : (A) 0.25 (B) 0.50 (©) 0.60 MULTIPLE CORRECT ANSWER TYPE (D) 0.75 X+Y IXY, Above reaction is carried out by taking 6 moles each of X and Y respectively then : (A) X is the limiting reagent (B) 1.5 moles of X,Y, is formed (©) LS moles of excess reagent is left behind (D) 75% of excess reagent reacted Solution(s) containing 40 g NaOH is/are (A) 50 g of 80% (w/w) NaOH (B) 50 g of 80% (w/v) NaOH [4,,j, = 1.2 g/mL] (©) 50gof20MNaOH [4,,,=1 g/mL] (D) 50 g of Sm NaOH The incorrect statement(s) regarding 2M MgCl, aqueous solution is/are [Given : d,oiiion= 1-09 g/mL } (A) Molality of CI is 4.44. m (B) Mole fraction of MgCl, is exactly 0.030 (C) The cone, of MgCl, is 19% wiv (D) The cone. of MgCl, is 19 * 104 ppm Solution(s) containing 30 g CHjCOOH is / are (A) 50 g of 70% (w/v) CH,COOH [4,,.-= 1.4 g/mL] (B) 50 g of 10M CH,COOH [4,, = 1 g/mL] (©) 50 g of 60% (s/w) CH,COOH (D) 50 g of 10m CH,COOH [in EE 85JEE-Chemistry 2s Ligy T1001 M NaNO, and 500 mi of 0.1 M-ABNO, Wes ming 17. 18. 20. 21. 22. 23. o™~ Te tion would be 500 mL of 0.1 M KCI, 200 ml in the solu 0.04, [NO,1 molarity of K*, Ag’, Cis Na‘, NOs vou (A) [K+] = 0.041, [Ag'T = 0.042, [Na‘] = 0.002 a 1= = NO, = 0.04 BB) [K*] = 0.041, [Na‘] = 0.00166, [NOs ; S te = 0.041, [Ag'] = 0.05, INa‘] = 0.0025, [CH = 0.05, [NO,] = 0.0525 (D) [K*1 = 0.05, [Na'] = 0.0025, [NO,-] = 0.0525 COMPREHENSION TYPE Paragraph For question no. 18 £0 20 to produce AgBr for use in photography can be self prepared as follows : = 0.042 NaBr, used Fe + Br, —>FeBr, FeBr, + Br, —> FesBrg Fe,Brg + Na,CO; —> NaBr+ CO, +FesO4 ~ ii) roduce 2.06 x 10° kg NaBr i) (not balanced) (not balanced) Mass of iron required to pr (A) 420g (B) 420 ke (42x 10° kg (D) 4.2 x 108g If the yield of (i) is 60% & (ii) reaction is 70% then mass of iron required to produce 2.06 x 193 kg NaBr (A) 10° kg. (B) 10° g (©) 10° kg (D) None of these If yield of (ii) reaction is 90% then mole of CO, formed when 2.06 x 10° g NaBr is formed (A) 20 (B) 10 (40 (D) None of these Paragraph For question no. 21 and 22 ‘A mixture is prepared by mixing 20 g SO, in 30 g H,SO,. Find mole fraction of SO (A) 0.2 (B) 0.45 (C) 0.6 (D) 0.8 Determine % labelling of oleum solution. (A) 104.5 (B) 106 (©) 109 (D) 110 MATRIX MATCH TYPE One type of artifical diamond (commonly called YAG for yttrium aluminium garnet) can be represented by the formula Y,A1,0,9-[¥ = 89, Al =27] Column I Column I Element Weight percentage AY (@) 22.73% (B) Al (Q 32.32% (R) 44.95% Oo 86Mole Concept 24, The recommended daily dose is 17.6 milligrams of vitamin C (ascorbic acid) having formula CgH,O,- Match the following. [Given : N, = 6 x 10°] Column 1 (A) O-atoms present (B) Moles of vitamin C in its 1 g sample (© Moles of vitamin C that should be consumed daily 28, Match the column: Column (A)20VH,0, (B) 17.45 % w/v H,SO, (d= 1.1745 g/mL) (C) Pure water () 5 % wiw NaOH (d=1.2 g/mL) Column I (P) 10+ (Q 5.68 x 10 (R) 3.6 x 107° Column IL @) 178M (QL78m ®1L5SM (8) 55.5My JEE-Chemistry EXERCISE II NUMERICALANSWER TYPE {A gaseous alkane (C,H,,,. ) is exploded with oxygen. The moles of O, for complete com, a i ti ind CO, formed is in the ratio 7:4, Find x on A fluorine disposal plant was constructed to carryout the reactions : F,+2Na0H —+ 30,+2NaF+H,0 2NaF + Ca0 + H,O —> CaF, + 2NaOH As the plant operated, excess lime was added to bring about complete precipitation of the fluoride as CaF, Overa period of operation, 1900 kg of fluorine was fed into a plant and 10,000 ke of ing was required. What was the percentage utilisation of lime ? [ At mass F = 19 ], [Lime : Cag) 3. (i) K,Fe(CN), +3H,SO, + 2K,SO, + FeSO, + 6HCN (ii) 6HCN + 12H,O + 6HCOOH + 6NH, Git) (@) ONH, + 3H,SO, > 3(NH,), SO, (b) (HCOOH 882, 6CO + 6H,O Above steps of reactions occur in a container starting with one mole of K,[Fe(CN),], 5 mole of H,SO, and enough water. Calculate sum of maximum moles of CO gas and (NH,), SO, that can be foduced. 4/ 4.5 g of compound A (MW = 90) was used to make 250 mL of its aqueous solution. The molarity f the solution in M is x x 10-1. The value of x is__. (Rounded off to the nearest integer) Find the Cl- concentration in solution which is obtained by mixing one mole each of BaCl,, NaCl and HCI in 500 mL water. 6. — Based on the following set of reactions to prepare H,SO,, FeS, + O, > Fe,O, + SO, SO, +0, > SO, SO, +H,0 > H,SO, Find the maximum weight (in kg) of H,SO, which can be obtained when 120 kg of FeS, (irom pyrite) is used. 7. 100 mL of H,0 (density : 1 g/mL) and 40 mL of methyl alcohol (density : 0.8 g/mL) is mixed 0 form a binary solution. If density of resultant solution is 1.1 g/mL, calculate molarity of solution considering methyl alcohol as solute. a Calculate the molarity (M) of CIF ions in the resultant solution which is made by mixing 400 ml- 0.1 M NaCl (aq) 100 mL, 0.2 M AgNO, (aq.) and 500 mL water. (Assuming no volume cliange in mixing process) 9. If ahydrated salt A,SO,.xH,O undergoes 45% loss in mass on heating and becomes anhydravs find value of x. (Atomic mass of A = 7) i 10. If relative density of a gseous mixture of CO,(g) and H,O(g) at 25° and 1 atm pressure vi respect to He(g) under similar con: 7.5 then mole % of CO, gas in the mixtu 88Mole Concept EXERCISE-M [Previo : . z us Years JEE Mains Questions] A. The weight of 2.01 x 103 molecules of CO is [AIEEE 2002] (1) 9.3 & Q)72¢ @i2e oer In an organic compound of molar mass 108 g mol-! C, H and N atoms are present in 9 : 1 by weight. Molecular formula can be : [AIEEE 2002] o CoN 2) CHygN (3) CSHpN3 (4) CyHgN3 3. 6.02 x a molecules of urea are present in 100 ml of its solution. The concentration of urea solution is - [AIEEE 2004] (4) 0.001 M (2)0.01M (3) 0.02 M (4) 10M va How many moles of magnesium phosphate, Mg,(PO,)» will contain 0.25 mole of oxygen atoms? [ATEEE 2006] LL. 3.125 x 10-2 (2) 1.25 x 102 (3) 25x 102 (40.02. * In the reaction, 2A, + BCI aq) > 2AP* (44) + OCU (aq) + SHAS)- [AIEEE 2007] (J) 6L HC\,4) i8 consumed for every 3L Hy(e) produced (2) 33.6L Hap is produced regardless of temperature and pressure for every mole Al that reacts (3) 67.2L Noeay at STP is produced for every mole Al that reacts (4) 11.2. L Hyg at STP is produced for every mole HCl,,.) consumed ‘ip 4.5.2 molal aqueous solution of methyl aleohol, CHOH, is supplied. What is the mole fraction of methyl alcohol in the solution ? [AIEEE 2011] (1) 0.086 (2) 0.050 (3) 0.100 (4) 0.190 /) the density of a solution prepared by dissolving 120 g of urea (mol, mass = 60 u) in 1000 g of water is 1.15 g/mL. The molarity of this solution is :- [AIEEE 2012] (1) 205 M (2) 050M (3) 1.78 M (4) 1.02 M 75 the ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1 : 4. The ratio © of number of their molecule is : [JEE MAINS 2014] 16 @)l:4 (4) 7: 32. (1:8 The molecular formula of a commercial resin used for exchanging ions in water softening is C\H,SO,Na (Mol. wt 206). What would be the maximum uptake of Ca?* ions by the resin when expressed iny mole per gram resin? [JEE MAINS 2015] 1 1 1 2) 3) 4) Q m2 ®) 793 306The most abundant elements by mass in the body of a healthy human adult are Oxygen (61.4%) ; Carbon (22.9%), Hydrogen (10.0%) ; and Nitrogen (2.6%). The weight Whi xygen (61.4%) 5 7 2 ; 75 ky on would gain if all 1H atoms are replaced by 7H atoms is a75 kg pers (2) 37.5 kg VEE MAIns 2017 (1) 15 kg (3) 7.5 kg (4) 10 kg Xe f a carbonate (M,CO3) on treatment with excess HCI produces 0.01186 mole of co, ~ 1 gram of a ca x ; ue the molar mass of M,CO; in g mol! is :- UEE MAINS 2017) 4) LL (1) 1186 (2) 84.3 (3) 118.6 (4) 11.86 The ratio of mass percent of C and H of an organic compound (C,HyO,) is 6 : 1. If one molecule a ,) contains half as much oxygen as required to bum one molecule of the above compound (C,H,O,) cont xy ean of compound C,H, completely to CO, and H,O. The empirical formula of compound C,H,0, is. (EE-Mains.2018) ()CH,O, (2)CH,0 (3) C,H,0, (4) C,H, (3. A sample of NaCIO, is converted by heat to NaCl with a loss of 0.16 g of oxygen. The residue is dissolved in water and precipitated as AgCl. The mass of AgCl (in g) obtained will be : (Given : Molar mass of AgCl = 143.5 g mol-!) [JEE-Mains.2020_(nline) (1) 0.54 (2) 0.35 (3) 0.48 (4) 0.41 Kh An unknown chlorohydrocarbon has 3.55% of chlorine. If each molecule of the hydrocarbon has one chlorine atom only; chlorine atoms present in 1 g of chlorohydrocarbon are : (Atomic wt. of Cl = 35.5 u; Avogadro constant = 023 x 1023 mol-!) [JEE-Mains.2018_(Online)] Lon 6.023 x 1021 (2) 6.023 x 1023 (3) 6.023 x 1020 (4) 6.023 x 109 Assuming ideal gas behaviour, the ratio of density of ammonia to that of hydrogen chloride at [JEE-Mains.2018_(Online)] () 0.64 2) 1.64 @) 1.46 (4) 0.46 a For the following reaction, the mass of water Produced from 445 g of CsjHy90g is : 2Cs7Hy10e(8) + 1630,(g) + 114CO,(g) + 110 0) Same temperature and pressure is : (Atomie wt. of C1=35.5 u) (1) 495 g (2) 490 g 3) 890 g (4) 445 9 [JEE-Mains.2019_(Online)] * The percentage composition of carbon by mole in methane is : [JEE-Mains.2019_(Online)] (1) 80% (2) 25% 3) 75% ~ (4) 20% i inkaMole Concept $$ SSS Concept 1g. Ferrous sulphate heptahydrate is used to fortify foods with iron. The amount (in grams) of the salt required to achieve 10 ppm of iron in 100 kg of wheat is [JEE-Mains.2020_(Online)] ‘Atomic weight : Fe = 55.85 ; S = 32.0; O= 16.00 19, NaClOsis used, even in spacecrafts, to produce O,, The daily consumption of pure O» by a person is 492L at 1 atm, 300K. How much amount of NaCIO,, in grams, is required to produce O, for the daily consumption of a person at 1 atm, 300 K ? [JEE-Mains.2020_(Onlline)] NaClO;(s) + Fe(s) > O,(g) + NaCl(s) + FeO(s) R = 0.082 L atm mol! K+! 20. The molarity of HNO, in a sample which has density 1.4 g/mL, and mass percentage of 63% is __.. (Molecular Weight of HNO, = 63) [JEE-Mains.2020_(Online)] 21, When 35 mL of 0.15 M lead nitrate solution is mixed with 20 mL of 0.12 M chromic sulphate solution, ___ x 10-5 moles of lead sulphate precipitate out. (Round off to the Nearest Integer). [JEE-Mains.2021_(Online)] 22, Complete combustion of 750 g of an organic compound provides 420 g of CO, and 210 g of H,0- ‘The percentage composition of carbon and hydrogen in organic compound is 15.3 and __ respectively. (Round off to the Nearest Integer) [JEE-Mains.2021_(O1 23, A 6.50 molal solution of KOH (aq.) has a density of 1.89 g cmr3. The molarity of the solution is mol dm-3. (Round off to the Nearest Integer). [Atomic masses: K :39.0 u; O :16.0 u; H :1.0 u [JEE-Mains.2021_(Online)] COOH ‘00H 24, + Br, PBs, + HBr Br Consider the above reaction where 6.1 g of benzoic acid is used to get 7.8 g of m-bromo ine)| benzoic acid. The percentage yield of the product is___. (Round off to the Nearest integer) [Given : Atomic masses : C = 12.00, H : 1.0u, O: 16.0u, Br = 80.0 u} [JEE-Mains.2021_(Online)| 28, Complete combustion of 3 g of ethane gives x x 10° molecules of water. The value of x is —__.. (Round off to the Nearest Integer). [Use : Ny = 6.023 x 10%; Atomic masses in u: C: 12.0; 0: 16.0; H: 1.0] [JEE-Mains.2021_(Online)| meee eee o1JEE-Chemistry 1 EXERCISE-A [Previous Years JEE Advance Questions] sty of liquid water is 1.0 gem “3 and that of water vapo ecules in I L of steam at that tempera At 100° C and 1 atm, if the de Our ig : » volume occupied by water mol 4 0.0006 g cm-, then the volume ocoupic a (A) 6om? (B) 60cm’ (©) 0.6cm? (D) 0.06 em? HEE "2001 (Ser), 1 How many moles of e~ weigh one Kg ? IJEE'2002 (Ser), 1 1 6.023 yo (my) (A) 6.023 x10? ®) S08 x10"! © 9708 * 9108x6023 * 108 . 3 é Calculate the molarity of pure water using its density to be 1000 Kg m”. (SEE'2003 Calculate the amount of Calcium oxide required when it reacts with 852 g of P,O,9. 6CaO + PO, —> 2Ca;(PO4)2 [JE 2005} Given that the abundances of isotopes “Fe, “Fe and “Fe are 5%, 90% and 5%, respectively, the atomic mass of Fe is : [JEE 2009) (A) 55.85 (B) 55.95 (© 55.75 (D) 56.05 Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g [JEE 2011] mL. The molarity of the solution is: (A) 1.78 M (B) 2.00 M (© 2.05 M @) 2.22 M ‘A compound H,X with molar weight of 80 g is dissolved in a solvent having density of 0.4.g mL", Assuming no change in volume upon dissolution, the molality of a 3.2 molar solution is [JEE 2014) The mole fraction of a solute in a solution is 0.1. At 298 K, molarity of this solution is the same as its molality. Density of this solution at 298 K is 2.0 g cm”. The ratio of the molecular MW, weights of the solute and solvent, (=), is [JEE 2016] solvent The mole fraction of urea in an aqueous urea solution containing 900 g of water is 0.05. If the density of the solution is 1.2 g cm’, the molarity of urea solution is __ [JEE 2019] (Given data : Molar masses of urea and water are 60 g mot and 18 g mol", respectively) a reacts with sulfuric acid to form aluminium sulfate and hydrogen. What is the volume o : ee gas in liters (L) produced at 300 K and 1.0 atm pressure, when 5.4 g of aluminium .0 mL of 5.0 M sulfuric acid are combined for the reaction ? [JEE 2020] (Use molar mass of aluminium ag 27.0 g mol", R = 0.082 atm L mol-1 K"). i =le ANSWER KE RT EXERCISE Na = 32:39, % S = 22.54, % O= 45.07 if 1 Oe Fy ad am. 3G) 22 gm. 5 (ii) 22 pm, 3b 4 538m © (01544 molfit. « 398le 7, 3545 s 634i) 18 ; (iii) 3N, , 0.029M 0, 25.22 mL ; yt. @B, + Gi) A 3 Gil) B, s GA 12. (2.428 x 10° gm Gi) Yes (iii) H, is in excess. Remaining wt. of H, = 0.2857 x 10° gm. 13. 10vol. 14 1gof Li (s) will have the largest number of atoms. 18, (2) 52N, ; (ii) 13 atoms ; (ili) 13 N, 16. Wer, =0.9375 2 11, 839g EXERCISE -I [JEE Mains Pattern] 1 (B) 2 = (C) 3. (B) 4, (A) 5.° (A) 6 (©) 7. (B) 8 (©) 9. (A) 10. (A) IL, (B) 12. (B) 13. (B) 14. (C) 15. (C) 16. (B) 17. (A) 18. (B) 19, (B) 20. (D) 21. (A) 22, (B) 23. (D) 24. (B) 28. (C) 26. (A) 27. (A) 28. (A) 29. (B) 30. © EXERCISE -II [JEE Advance Pattern] LB) 2. (A) Ea) 4 (©) 5 © 6 (B) % (A) 8B) 9 © 10. (D) 1. @) 12. @) 3. (BYC) (Dy 14. (ACC) 18 (B)(D) 16. (B)(C) + (By 18. (B) 0. © 20. (B) 1. (By 2 © 23. (A)-R; (BYP; (C)-Q 24, (A)-R 5 (B)-Q: (CP 2 S(A)-P: (B)-PQ: (CS; D)-R —JEE-Chemistry EXERCISE -Il 2 5. 8 A 1 2 2 28 3. 8 4. 1969) 7. 83M 8 0.02 9 5 10. 46.15 EXERCISE -M [Previous Years JEE Mains Questions] L 2 @ 3. (4) 4. (1) 5. (4) 6 7 () 8. (4) 9. (2) 10. (3) UW. (2) 1% @, 13. (3) 14. 3) 15. (4) 16. (1) 7. (4) 18, (4.95 to 4.97) 19. (2120 to 2140) 20. (14.00) 21. (925) 22-3) 23. (9) 24. (78) 25. (18) EXERCISE -A [Previous Years JEE Advance Questions] . © 2 (D) 3, 55.5 mol L# 4. 1008 g 5. (B) 6. (©) 7. 8 a) 9. 2.98 or 2.99 10. 6.15L