Section A 1. Whatis Etard Reaction? ‘The rates of a reaction starting with initial concentrations 2.0 x 10-3 M and 1.0 10-?M are equal to 2.40 x 10-* M s-! and 0.60 x 10-* M s~t, respectively. Calculate the order of the Teaction with respect to the reactant and also the rate constant. 3. Arrange the following compounds in the increasing order of their reactivity in nucleophil addition reactions. (a) Ethanal, Propanal, Propanone, Butanone (b) Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone Section B 4. Account for the following: (a) Electrophilic substitution in case of aromatic amines takes place more readily than benzene. (b) CHsCONH2 is a weaker base than CH3CH2NH2. (c) Nitrocompounds have higher boiling points than hydrocarbons having almost same ‘molecular mass. 5. (a) Calculate number of unpaired electrons in complex [Ni(H20)2(NH3)4]?*. (b) What type of isomerism is present in [Pt(NHs)sClz]Br2 and (Pt(NH:)«Br2]Cl. (©) What is the geometry of Ferrocyanide ion? 6 {@) Name two transition elements which show +1 oxidation state. (b) Name the transition element which does not exhibit variable oxidation state. (©) Transition elements show catalytic properties. Why?oR (@) Write the steps involved inthe preparation of NaxCrO, from chromite ore. (b) Whatis the effect of increasing pH on KaCr107 solution? () Draw the structure of dichromate ion indicating the bond angles and bond lengths. (8) Ethanol reacts with acetic acid inthe presence of conc. HiS04 to give sweet-smelling substance. Give the equation involved in the reaction. ()Writea note on () Rosenmund’s reduction (i) Hell-Volhard-Zelinsky reaction ‘8, Explain the term with a suitable example: (@) Alcosol (8) Aerosot (©) Hydrosol ‘9. An organic compound with the molecular formula CsHicO forms 2, 4-DNP derivative, reduces Tollens' reagent and undergoes the Cannizzaro reaction. On vigorous oxidation, it fives 1, 2-benzene carboxylic acid. Identify the compound. oR (@) How will you convert acetaldehyde tothe following compounds? (9 But 2-enal (jf) But-2-enoie acid (b) Write a chemical test to distinguish between propanal and propanone. 10-The rates ofa reaction starting with initial concentrations 2.0» 10-1 M and 1.0 109M are ‘equal to 2.40% 10-1 M sand 0,60. 10- M s-, respectively Calculate the order ofthe reaction with respect to the reactant and also the rate constant. 11.Give reasons: (2) The radius of Fe (2 = 26) i less than that of Mn (Z= 25). (b) Chemistry of actinoidsis more complicated than that of lanthanoids (6) Gu" ion isnot stable in aqueous solutions. Section € 12, Leclanche cell isa primary cell Itconsists ofa cylindrical inc container which acts as the ‘anode. A graphite rod surrounded by a paste of manganese dioxide acts asthe cathode. ‘These are in contact witha thick paste of ammonium chloride and zinc chloride which acts asthe electrolyte. (a) What isthe reaction taking place atthe anode? (b) How much electricity in terms of F is produced by the oxidation of one mole of Zn? (6) Why Leclanche cell i considered asthe primary cell? (€) What are the uses of Leclanche cell?” (©) Write the other example of primary cell”