Safety Data Sheet

Plant-Prod 10-52-10

SECTION 1. IDENTIFICATION
Product Identifier Plant-Prod 10-52-10
Other Means of 10484, 10482, 12778
Identification
Product Family Plant-Prod
Recommended Use Water Soluble Fertilizer for Plants.
Manufacturer/Supplier Master Plant-Prod Inc., 314 Orenda Rd. , Brampton, Ontario, Canada, L6T 1G1, Canada
Identifier
Emergency Phone No. CANUTEC, 1-888-226-8832 (North America) or 1-613-996-6666 (International), 24 Hours

SECTION 2. HAZARD IDENTIFICATION

Classified according to Canada's Hazardous Products Regulations (WHMIS 2015).
Classification
Carcinogenicity - Category 2; Reproductive toxicity - Category 1
Label Elements

Signal Word:
Danger
Hazard Statement(s):
H351 Suspected of causing cancer.
H360 May damage fertility or the unborn child.
Precautionary Statement(s):
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P308 + P313 IF exposed or concerned: Get medical advice/attention.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents and container in accordance with local, regional, national and international regulations.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Mixture:
Chemical Name CAS No. % Other Identifiers Other Names

Product Identifier: Plant-Prod 10-52-10 - Ver. 2

Date of Preparation: January 25, 2021
Date of Last Revision: January 09, 2023 Page 01 of 06
Boric acid 10043-35-3 <0.15
Nitrilotriacetic acid, disodium salt 15467-20-6 <0.20

SECTION 4. FIRST-AID MEASURES

First-aid Measures
Inhalation
Move to fresh air. If breathing has stopped, trained personnel should begin rescue breathing. Call a Poison Centre
or doctor. If ammonia gas is inhaled from heated fertilizer and breathing has stopped, begin artificial respiration.
Skin Contact
Immediately wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 15-20 minutes. Take
off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Call a Poison Centre or doctor if you
feel unwell. Thermal burns require immediate medical attention.
Eye Contact
Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for at least 30 minutes, while
holding the eyelid(s) open. Immediately call a Poison Centre or doctor.
Ingestion
For large amounts immediately call a Poison Centre or doctor. Rinse mouth with water. Never give anything by
mouth if person is rapidly losing consciousness, or is unconscious or convulsing. Do not induce vomiting.
Most Important Symptoms and Effects, Acute and Delayed
May cause mild irritation.
Immediate Medical Attention and Special Treatment
Special Instructions
See first aid information above. Note to Physicians: Provide general supportive measures and treat
symptomatically.
Medical Conditions Aggravated by Exposure
None known.

SECTION 5. FIRE-FIGHTING MEASURES

Extinguishing Media
Suitable Extinguishing Media
Use flooding quantities of water or other suitable extinguishing agent.
Unsuitable Extinguishing Media
DO NOT use water jet.
Specific Hazards Arising from the Product
Mild oxidizer. May intensify fire.
In a fire, the following hazardous materials may be generated: corrosive, flammable ammonia; very toxic carbon
monoxide, carbon dioxide; corrosive, oxidizing nitrogen oxides; corrosive phosphorous oxides; metal oxides.
Special Protective Equipment and Precautions for Fire-fighters
Wear SCBA and full protective clothing.
Fire-fighters may enter the area if positive pressure SCBA and full Bunker Gear is worn.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures
Use the personal protective equipment recommended in Section 8 of this safety data sheet. Remove or isolate
incompatible materials as well as other hazardous materials. Eliminate all ignition sources. Use grounded,
explosion-proof equipment.
Environmental Precautions
Do not allow into any sewer, on the ground or into any waterway.
Methods and Materials for Containment and Cleaning Up
Product Identifier: Plant-Prod 10-52-10 - Ver. 2
Date of Preparation: January 25, 2021
Date of Last Revision: January 09, 2023 Page 02 of 06
Methods and Materials for Containment and Cleaning Up
Contain the spill. Collect using shovel/scoop or approved HEPA vacuum and place in a suitable container for disposal.
Avoid generating dust. Avoid contact with combustibles, organics and ignition sources.

SECTION 7. HANDLING AND STORAGE

Precautions for Safe Handling
Do not breathe in this product. Do not get in eyes, on skin or on clothing. Avoid exposure during pregnancy and while
nursing. Only use where there is adequate ventilation. Avoid generating dusts.
Conditions for Safe Storage
Store in an area that is: cool, dry, well-ventilated. Keep out of reach of children. Store in a closed container. Keep
separate from acids, alkalis, reducing agents and combustibles.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control Parameters
ACGIH TLV® OSHA PEL AIHA WEEL
Chemical Name TWA STEL TWA Ceiling 8-hr TWA TWA
Boric acid 2 mg/m3 6 mg/m3
Appropriate Engineering Controls
General ventilation is usually adequate. Use local exhaust ventilation and enclosure, if necessary, to control amount in
the air. Provide eyewash and safety shower if contact or splash hazard exists.
Individual Protection Measures
Eye/Face Protection
When handling dry concentrated product: wear protective safety glasses. When handling dissolved product: wear
chemical safety goggles.
Skin Protection
Wear chemical protective clothing e.g. gloves, aprons, boots.
Respiratory Protection
Use an appropriate NIOSH approved particulate respirator. Monitor dust levels within working area and ensure
adequate ventilation.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Basic Physical and Chemical Properties
Appearance Blue fine powder. Particle Size: Not available
Odour Slight ammonia odour
Odour Threshold Not applicable
pH Not available
Melting Point/Freezing Point Not available (melting); Not available (freezing)
Initial Boiling Point/Range Not applicable
Flash Point Not applicable
Evaporation Rate Not available
Flammability (solid, gas) Will not burn.
Upper/Lower Flammability or Not available (upper); Not available (lower)
Explosive Limit
Vapour Pressure Not available
Vapour Density (air = 1) Not available
Relative Density (water = 1) Not available
Solubility Not available in water
Partition Coefficient, Not available
Product Identifier: (Log Kow)
n-Octanol/Water Plant-Prod 10-52-10 - Ver. 2
Date of Preparation: January 25, 2021
Date of Last Revision: January 09, 2023 Page 03 of 06
Partition Coefficient, Not available
n-Octanol/Water (Log Kow)
Auto-ignition Temperature Not available
Decomposition Temperature Not available
Viscosity Not available (kinematic); Not available (dynamic)
Other Information
Physical State Solid
Molecular Formula Not applicable
Molecular Weight Not available
Bulk Density Not available

SECTION 10. STABILITY AND REACTIVITY

Reactivity
Not reactive under normal conditions of use. May intensify fire.
Chemical Stability
Normally stable.
Possibility of Hazardous Reactions
None expected under normal conditions of storage and use.
Conditions to Avoid
Heat. Water, moisture or humidity. Open flames, sparks, static discharge, heat and other ignition sources.
Incompatible Materials
Strong acids, strong alkaloids, oxidizers, organics.
Hazardous Decomposition Products
Under normal conditions of storage and use, hazardous decomposition products should not be produced. In a fire, the
following hazardous materials may be generated. Corrosive, flammable ammonia; corrosive, oxidizing nitrogen oxides;
corrosive phosphorous oxides; very toxic carbon monoxide, carbon dioxide; metal oxides.

SECTION 11. TOXICOLOGICAL INFORMATION

Likely Routes of Exposure
Inhalation; skin contact; eye contact; ingestion.
Acute Toxicity

Chemical Name LC50 LD50 (oral) LD50 (dermal)

Boric acid 2660 mg/kg
Skin Corrosion/Irritation
Irritation could occur with prolonged exposure to dry fertilizer or fertilizer solution. Contact with heated material may
cause thermal burns.
Serious Eye Damage/Irritation
Irritation or burn could occur if fertilizer solution is splashed in eyes or dry product contacted.
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
Very low vapour activity. May cause coughing and sneezing may cause nose and throat irritation, lung injury.
Skin Absorption
Not absorbed through skin.
Ingestion
If large amounts are swallowed symptoms may include nausea, vomiting, stomach cramps and diarrhea.
Aspiration Hazard
Product Identifier: Plant-Prod 10-52-10 - Ver. 2
Date of Preparation: January 25, 2021
Date of Last Revision: January 09, 2023 Page 04 of 06
Aspiration Hazard
No information was located.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
No information was located.
Respiratory and/or Skin Sensitization
Skin sensitizer.
Carcinogenicity

Chemical Name IARC ACGIH® NTP OSHA

Boric acid A4
Nitrilotriacetic Acid (NTA) and its salts were determined to be "possibly carcinogenic to humans" by IARC, a compound
which "may reasonably be anticipated to be a carcinogen" by NTP and a "select carcinogen" by OSHA.
Reproductive Toxicity
Development of Offspring
Boric acid may cause birth defects, based on animal data.
Sexual Function and Fertility
Boric acid may impair male fertility, based on animal data.
Effects on or via Lactation
No information was located.
Germ Cell Mutagenicity
No information was located.
Interactive Effects
No information was located.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Acute Aquatic Toxicity
ErC50 Aquatic
Chemical Name LC50 Fish EC50 Crustacea ErC50 Algae
Plants
Boric acid 11100 mg/L
(Oncorhynchus
mykiss (rainbow
trout); 96-hour)
Persistence and Degradability
No information was located.
Bioaccumulative Potential
No information was located.
Mobility in Soil
No information was located.
Other Adverse Effects
There is no information available.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal Methods
Contact local environmental authorities for approved disposal or recycling methods in your jurisdiction.

Product Identifier: Plant-Prod 10-52-10 - Ver. 2

Date of Preparation: January 25, 2021
Date of Last Revision: January 09, 2023 Page 05 of 06
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG regulations. Not regulated under US DOT Regulations.
Special Precautions Not applicable
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15. REGULATORY INFORMATION

Safety, Health and Environmental Regulations
Canada
WHMIS 1988 Classification
Not a WHMIS controlled product.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL.

SECTION 16. OTHER INFORMATION

SDS Prepared By MPPI Technical Department
Phone No. 905-793-8000
Date of Preparation January 25, 2021
Date of Last Revision January 09, 2023
References CHEMINFO database. Canadian Centre for Occupational Health and Safety (CCOHS).
Registry of Toxic Effects of Chemical Substances (RTECS®) database. Dassault
Systèmes/BIOVIA (“BIOVIA”). Available from Canadian Centre for Occupational Health and
Safety (CCOHS).
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither
Master Plant-Prod Inc., nor any of its distributors, assumes any liability whatsoever for the
accuracy or completeness of the information contained herein. Although certain hazards are
described, we cannot guarantee that these are the only hazards that exist. Final determination
of suitability of any product is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution.

Product Identifier: Plant-Prod 10-52-10 - Ver. 2

Date of Preparation: January 25, 2021
Date of Last Revision: January 09, 2023 Page 06 of 06