CHEMICAL BONDING DPPs 01 TO 14

ANSWER KEY
DPP-1
1. A 2. B 3. B 4. A 5. D 6. ABC 7. AB
8. ABC 9. B 10. B 11. D

DPP-2
1. A 2. D 3. D 4. B 5. D 6. A 7. ABCD
8. BD 9. ABCD 10. AB

DPP-3
1. D 2. D 3. B 4. A 5. B 6. ABC 7. D
8. CD 9. AC 10. A

DPP-4
1. D 2. C 3. B 4. B 5. ABD 6. AB 7. ABCD
8. ACD 9. AB 10. 2

DPP-5
1. C 2. C 3. B 4. ABCD 5. AC 6. ABCD 7. BCD
8. ABCD 9. ABCD 10. 3

DPP-6
1. C 2. D 3. D 4. A,B,C 5. C,D
6. A,C,D 7. A,B,D 8. A,B 9. A,B
10. AP,R,S ; BQ,S ; CP,R ; DQ,S,T 11. 3

DPP-7
1. D 2. C 3. C 4. A 5. D 6. A 7. A
8. ABCD 9. ABCD 10. [A - Q , B - S , C - P , D - R]

DPP-8
1. A 2. D 3. B 4. A 5. ABC 6. AB 7. ABC
8. (A)–Q, S ; (B)–P, Q, T ; (C)–Q, S ; (D)–Q, R, S 9. 134 10. 3

DPP-9
1. B 2. C 3. D 4. C 5. A 6. B 7. C
8. BCD 9. AB 10. BD 11. (A) → (P) ; (B) → (Q) ; (C) → (S) ; (D) → (R)
12. 6 13. 0 14. 2 15. 5
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 DPP-10
Fajans Rule
Sol. 1. NaI > NaBr > NaCl > NaF 2. LiCl > NaCl > KCl > RbCl > CsCl
3. AlCl3 > MgCl2 > NaCl 4. AgF > KF > RbF > CsF
5. K2S > K2O 6. Ca3N2 > CaO > CaF2
7. ZnCl2 > CaCl2 > KCl 8. Most ionic is RbCl while least ionic is BeCl2
9. LiF < LiCl < LiBr < LiI

Inert pair effect

1. (1) Ga+1 < In+1 < Tl+1 (2) Ga+3 > In+3 > Tl+3
(3) Ge+4 > Sn+4 > Pb+4 (4) Ge2+ < Sn2+ < Pb+2
(5) CX2 < SiX2 < GeX2 < SnX2 < PbX2

2. (D)
PbI4 does not exist
3. (D)
Bi+3, In+1 and Sn+2 are ions which have (18 + 2) electronic configuration while Ga+3 has Pseudo
inert gas configuration.
4. Tl+1 and I3–

5. GaCl2 exist as , it means gallium is present in +1 and +3 oxidiation states

6. Pb+4 is less stable than Pb+2, so Pb+4 reduces into Pb+2 easily as Pb+2 is more stable while Sn+4 is
more stable than Sn+2
7. SnCl2 is good reducing agent so it react with HgCl2 to produce mercury
SnCl2 + 2HgCl2  Hg2Cl2 + SnCl4
Hg2Cl2 + SnCl2 (excess)  2Hg + SnCl2

Thermalstability
1. BeSO4 < MgSO4 < CaSO4 < SrSO4 < BaSO4
2. LiOH < NaOH < KOH < RbOH < CsOH
3. Ag2CO3 < Na2CO3 < K2CO3
4. LiHCO3 < NaHCO3 < KHCO3 < RbHCO3 < CsHCO3
5. Na2O2 < K2O2 < Rb2O2 < Cs2O2

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6. Be(NO3)2 < Mg(NO3)2 < Ca(NO3)2 < Sr(NO3)2 < Ba(NO3)2
7. Li3N > Na3N > K3N
8. NaF > NaCl > NaBr > NaI
9. BeCO3 < MgCO3 < CaCO3 < SrCO3 < BaCO3
10. CdCO3 < CaCO3 < Rb2CO3
11. Li2O > Na2O > K2O > Rb2O > Cs2O

Solubility
1. BeSO4 > MgSO4 > CaSO4 > SrSO4 > BaSO4
2. BeX2 > MgX2 > CaX2 > SrX2 > BaX2 where (X = Cl, Br, I)
3. BeCO3 > MgCO3 > CaCO3 > SrCO3 > BaCO3
4. BeS2O3 > MgS2O3 > CaS2O3 > SrS2O3 > BaS2O3
5. BeSO3 > MgSO3 > CaSO3 > SrSO3 > BaSO3
6. LiBr > NaBr > KBr > RbBr > CsBr
7. Li2CO3 < Na2CO3 < K2CO3 < Rb2CO3 < Cs2CO3
NaHCO3 < KHCO3 < RbHCO3 < CsHCO3
8. MgC2O4 < CaC2O4 < SrC2O4 < BaC2O4 < BeC2O4
9. LiOH < NaOH < KOH < RbOH < CsOH
10. Be(OH)2 < Mg(OH)2 < Ca(OH)2 < Sr(OH)2 < Ba(OH)2
11. LiF < NaF < KF < RbF < CsF
12. MgF2 < CaF2 < SrF2 < BaF2 < BeF2
13. LiCl > NaCl > KCl < RbCl < CsCl or LiCl > CsCl > RbCl > KCl > NaCl

Nature of oxide2
1. BaO < SrO < CaO < MgO < BeO 2. Tl2O3 < In2O3 < Ga2O3 < Al2O3 < B2O3
3. Li2O < BeO < B2O3 4. In2O < In2O3
5. PbO2 < SnO2 < GeO2 < SiO2 < CO2 6. N2O < NO < N2O3 < NO2 < N2O5
7. As4O10 < P4O10
8. Na2O < MgO < Al2O3 < SiO2 < P4O10 < SO3 < Cl2O7
9. MnO < MnO2 < Mn2O7
10. CrO < Cr2O3 < CrO3

Nature of oxide
11. (B) 12. (C)
13. (D)
NO, CO & N2O all are neutral oxide
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 DPP-11
1. D 2. C 3. A 4. A 5. C 6. D 7. D
8. A 9. AC 10. ABD 11. 5 12. 3

DPP-12
1. C 2. C 3. A 4. C 5. B 6. D 7. A
8. A 9. A 10. C 11. A 12. C 13. ACD 14. BD

Subjective type
15.

16. KO2 > O2 > O2 [AsF4]

17.

18.

19.

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 DPP-13
1. A 2. C 3. C 4. BCD 5. ABCD 6. ABCD 7. B
8. C 9. B 10. (A)-P,R ; (B)-R,S ; (C)-Q,R,S ; (D)-P

DPP-14

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C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 6
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C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 7
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C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 8
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C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Ph. 0744-2799900 9
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