*OOESZESE YO INIS AEO “Nazarbayev Intellectual Schools” Nazarnayey Cambridge International Examinations Intellectual ‘Schools CHEMISTRY Grade 12 Qualitative analysis data and Periodic Table For use from 2016 in Paper 3 for the above syllabus. 12CHEM/03 This document consists of 4 printed pages. NIS_G12_CHE_OADIFP ‘© Center for Pedagogical Measurements, CAMBRIDGE [REO Nazarbayev intalloctual Schools? 2010, Tternational Examinations [Turn over1 nakoaiez0N, 03 wBobepo 10511109. avoaHOrt9IsIN 902 .s0049s 1 siowoins = ese |p| eta pm ag [api ee eer ese | goes |= scion | anaes Jarvorsune] annum, [unemaue | npn | aryves | ure | uneseue | unvant | unui | seem lasnme| Seed | amace ZT | ON | PW | Wa | sa] 5D | xa | wo | ww | ng | aN | om | ed | a | ov sprougoe sor_| av_| ion | on | os | 6 | 6 | 06 | 6 | w | co | os | we | os | oo peut [reer | eer [evs | Sve | sear | wes | evsi | veer | vos | —-—| rem | eon | von | eon sien | enewat | sms | unos | sims Jarmove | tnem | unvae | unm | ursoor |unomune | unui: tionine] umes | weary m [aa | us | ug | on | fa | a | po | na | ws | wa | pN | ag | eo | ey spiovewue, wij | o |» |» | w» | wo | ow | oo | o | | oo | os | ow | is Ww se Boer I a ee 48 se 2s D “ ver 4 6 -equina we or, Foxy haste H i ui [oT st oT et an C Taw ‘swuowielg Jo 2192 aIpOUSY OY,[Key ppt = precipitate] 1 Reactions of aqueous cation cation reaction with NaOH(aq) NH,(aq) aluminium, white ppt white ppt. AL (aq) soluble in excess insoluble in excess ‘ammonium, ‘no ppt. - NH."(aq) ‘ammonia produced on heating barium, Ba*'(aq) | no ppt. no ppt. {if reagents are pure) calcium, Ca**(aq)_| white ppt. with high [Ca™(aq)] no ppt. chromium(IID, | grey-green ppt. grey-green ppt cr*(aq) soluble in excess giving dark green insoluble in excess solution copperi tl), pale blue ppt. blue ppt. soluble in excess giving dark Cu" (aq), insoluble in excess blue solution iron), Fe**(aq) green ppt. turning brown on contact with air insoluble in excess green ppt. turning brown on contact with air insoluble in excess. iron(tt), Fe*(aq) red-brown ppt. insoluble in excess. red-brown ppt. insoluble in excess lead(II), Pb*(aq) white ppt. soluble in excess white ppt. insoluble in excess magnesium, Mg"(aq) white ppt insoluble in excess white ppt. insoluble in excess manganese({1), off-white ppt. rapidly turning brown on off-white ppt. rapidly turning brown on. Mn**(aq) contact with air contact with air insoluble in excess insoluble in excess zine, Zn’*(aq) white ppt white ppt. soluble in excess soluble in excess {[Lead(II) ions can be distinguished from aluminium ions by the insolubility of lead(II) chloride.] (© Center or Pedagosical Measurements AEO “"Nazarbayov itolloctual Schools" 2016 NISIGT2ICHEIQAD [Turn over4 2 Reactions of anion ion carbonate, COs” CO; liberated by dilute acids chromate(V1). yellow solution turns orange with H(aq); cr0.* (aq) gives yellow ppt. with Ba*"(aq): ives bright yellow ppt. with Pb*(aq) chloride, Ct(aq) _| gives white ppt. with Ag’(aq) (soluble in NHs(aq)); gives white ppt. with Pb (aq) bromide, Br (aq) gives cream ppt. with Ag’(aq) (partially soluble in NHs(aq));, gives white ppt. with Pb*'(aq) iodide, I-(aq) gives yellow ppt. with Ag’(aq) (insoluble in NH3(aq)); gives yellow ppt. with Pb**(aq) nitrate, NOs(aq) _| NHs liberated on heating with OH (aq) and ALfoil nitrite, NO; (aq) NHs liberated on heating with OH (aq) and AL fil; NO liberated by dilute acids (colourless NO > (pale) brown NOz in air) sulfate, SO,” (aq) gives white ppt. with Ba”*(aq) or with Pb”*(aq) (insoluble in excess dilute strong acids) sulfite, SO;*(aq)__| SOz liberated with dilute acids; gives white ppt. with Ba™(aq) (soluble in excess dilute strong acids) 3 Tests for gases gas ammonia, NHs turns damp red litmus paper blue carbon dioxide, CO, | gives a white ppt. with limewater (ppt. dissolves with excess CO2) chlorine, Cle bleaches damp litmus paper hydrogen, He ‘pops’ with a lighted splint oxygen, O2 relights a glowing splint sulfur dioxide, SO _| turns acidified aqueous potassium dichromate( VI) from orange to green ermision fo reproduce ems where thd party owned mater protected by copyright incuded has been sought and cleared where posse, Every Cerner (aot nas toon mace by tne publahor (CLES) to race copyrght heer. but any Kors requng darance have unwitinay boon inde, the [obisher wt be pleased to make amends he ear! poesble cpporunty. cambridge ntematignl Examinations is pat ofthe Camtxge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge [etal Betminatone Syrscate (UCLES), which ss ele cepariont of he Univers of Cambie, (© Center for Pedagosical Measurements [AEO "Nazarbayev Intebocval Schools” 2016 NISIG12/CHE/QAD