40 HRFASSHSIA HTPB/AP/Butacene #414] 54 87 aay + za + Bae. aa Properties of HTPB/AP/Butacene Propellants Changkee Kim* - Jichang Yoo - Gabsung Hwang* - Yoojin Yim** ‘ABSTRACT In the present work, the effect of formulation on friability of HTPB/AP propellants including Butacene and Cr,Os has been studied. ‘The mechanical properties and burning rate of the propellants were measured using Inston tensile tester and strand burner, respectively. Friability was calculated from shot-gun and closed bomb test data. The result showed that friability was higher, as the content of Butacene or AP 6 ym in the propellant formulations was increased. & s B Apoye ALFeye) Butacenes} CrOss Wish HTPB/AP #24] ZY) FAL alo] friabilityo] o]3]= GBS ZALSACh. Inston tensile testers} strand burners o]-4-8}o} HTPB/AP FAY AA SAM AaFES SAsaieh. H2lalo] Teel a}S shot-guns} closed bomb +) By ARSHE FAA friabilityS Adda. AEALS, FAA ZY F Butacenes| Heo} Be Hala] HE AP 6 wm] PFO] GS FAIAt friability7} FS SY + UAC. Key Words: Hydroxy Terminated Polybutadiene(HTPB), Ammonium Perchlorate(AP), Butacene(%- ¥}4), Mechanical Property(71412} $8), Burning rate(@2-¢%=), Friability(s}¥ 4) LA fe f 2005! 481 199) 1% ~ 2005H 5a 9 WHR ade deq ate al Fees +2 + AUslal, Baste 1-4-5 ats) Fesp AAAs] caph aPsla eeele etree daage Qe FAG As dad Aaaee BeS BS, bnant inckornaatcom vials dal dake fale) Aas 2 abelMIA Al2B 2005. 6. HIPB/AP/Butacene #2IA| Ba St 41 Alz15| HIPB/AP #2lA|29] ASS ZA ae WSSe aa AP 4) Bada aE Sate WY ada desde este W Sol sal, 2h. aaGE OFE A % Ff A7]9] AP S Be] ASW 7hs shy °] AF FAA] PEt ele BAe] eh. BsSoo] ASS od A= ES hast + MS Bet ole} AP A} 27). Eee + ME ASses asa S+ Ud ee at Sus ASt 2F F8 7s AU F xshel Ae BAM Det BEAoyey. # AFE HIPB/AP +2laj9] ASSES AM + LE Butacene, CrOs 8 AP 6 ymS] H BS Ads ARG FAA Sag aye} | oS AYO] +41 a)o] friability o} rjale oy OS Zea. be Table 1. List of raw materials of propellants Ingredient Funetion Vendor Hiydreny terminated polybutadiene(trTPs) -‘P**Polymer ATOCHEM Butacene (BucN) —Prepolymer & spp Burning Cat cus Burning Cat Isophorone diisocyanate ; Thorson (pny Curative ‘Chem. Diocty! adipate (DOA) Plasticizer HAVENS 2.7-Mathylene bis (G-methyl6--butylphenel) Antioxidant Cyanamid (ao2246) Bonding TEPANOL ra M Buming ac Buming Hestarck ‘Ammonium perchlorate (AP) Oxidizer Kerr McGee Tripheayl bismuth (TPB) Cure Catalyst SHARPE. 2a a 21 ala) AZ APB QE Fe], 7s Zs Lo} Bead. Hala] aye Se 7 wth, “ee AP 9] Bt 200 m3} 6 pm FF SHS ASAD ASE FAME FAM 64, CrO) S AHS} AS APS FMM 559 HSS Asespalcp. Table 26) +2] AIS ets] Azestsic. a & ¢UQAZ ASP] ZC S AGatgaon gs 1 0.90e1 —- HITPB/IPDI, DOA, 02246, TEPANOL, 3! TPB & AbSato} HITS 7-9 SAG. BuCN 3} CO; & BPHE WES HIPB % 2]@e}ich. 1S ARE AAD EA ol 1a} 50 ~ 60 TZ RAE 4 liter BB] AEH] (Baker Perkins vertical mixer, 2 2 4PU) AA Sesto] HAAS Aza AF BAZ FAUT FAA ARS SOT OBA BW =} V8aH a a7) Asstshch. Table 2. Formulation of HIPB/AP Prooallants. Sample Burning HTPG+ AP DOAsAO206+Z1C rnumber Catalyst IPDI-200/6ya #TEPANOLSTPB A BuCN 00% 9635 6/4 33% Bo 30% 6635 c+ 43% 5:35 D> 55% 4135 E 65% 3135 FiO, 05% 9135 5/5 3365 22 ala) $d 38 AS? MEA FAA IAA HIS 2 0 ol] JANNAF 4)312.2 INSTRON 2 1122 1B AMIS ASS} 50mm/ming] ys ER A8IVD, BEC Shore-A BEAL S AAAt. Asad Haale] At SEE ARS AA 6mm, Zo} WOmm2z UE] WEB oy UE Lucitez Az] FH strand burner} GA42 2g7| - RAS - Bas: aaa te aalzealal a 1S We Ale yo) GAGES | aS steph B+ gle. AE Fig. 1 of YeHy ABAoo| Arad ys} PIS ay AS Ah — gMevis} Go] HIPB wet of o}al Saha} yyy Sao] 4 ~ 14 MPa YelAbofoh Ay 2A aC Friability *1QJ2 shot-gun test 3! closed bomb test(CBI) = aE + Astejop ep. 4) 7°) 18 mm, Fi 9g e] USB HAA) ABS 57 20 mms] 24L sol] 130 ~ 170 m/sec FE = SST # Se Fads BA 2 8 4219] AAS HAAS CB so} alzhs VHS Saad. Asad daus aye Te Az Op Baths Absa friability, (4P/d)noc FERC}. YSZ UN Test Series 79) BIDS (Extremely Insensitive Detonating Substance) 7}A]t 4 150 m/s lA] friability, (AP/dt)mue® 15M Pa/ms °13}°] OB, 4]. HOCH CH, {CH,cH-CH-OHL 01 CHeCH, wo-Fonon—onendapprendponong om ye cH=cH, Hy SCH (Cire Fig. 1 Molecular structure of HIPBIA) and Butacane(®, Fe: ferrocene). ae 2g duund sich dates wae, Ua $0] BUCNS| SHP0} SSH wee Bae] Sich. ol HIPB ulate] 87513 BuCNo! 2] S787] eos Bess 7hes} ASHSJON 8h Mx A}o]2] SEO] S7} @ as, & Wale HIPB 71a sgl] HTPBS} 88-7191 -OH7} Rt AASMS 7heaolcp o} = 7p) a2) 85 ada days BE eg So] PAE F Ute Aztohy Wego} rst ae. age] ec. az] BF WIS fAl7t slolok sian Sxhe] BH vealed aH A ADVE} PAYS WHS] S7ps}ojoy BP] HEOTHE). 17] A vial Aloe Aleks} & AS wielejs ra) Fda) AP A}o}o} & AZM F7t Ue}. BuCN 9] B7pHo 24) vieicist AP Afo]9} aleigleje] yto}ale}at WAS BY FAAS] UAE, CAS DZ WBS ZH ae & Bola, 8). S22 Bes a ya) ALAS el BF BOS 4}B3}o} BUCN °] Aa Wy Alas) AA So) Aspen we esy 714 54 a 2 hlge oe aad 1 BAYS WS Rez Bes YEL BUCN 9} QS (102 g/ca) 7} HTPB (0.90 g/ot) BO 7| Heo] BUCN 9] PBs} gr) FAlaIo] WES BUS UF sch Table 3. Mechanical properties = of = HIPBYAP Propellants at 20°C Sample Max Stats Simin YOU"E® Deity number (bar) (*) (bar) (efor) 888 fr a cot ow ow ; Da ee eee ee ee ee ee) 32 a4 54 Figure 2 o] 48 YE A oA] F 2) Yao) BUSSES SNAG eet Salas) ei EAS 1 Aloe Sale] AE et oh aS Azl#(n), AB wa) 8 1000 psia Wa} ASEHow AZ 2005. 6. ‘& Table 4 of YEA} Fig 3 2 Se Ga SSS 12} 24S BuCN Beto) ape} Baye a ¥olth BuCN 2] PY) BH aagEe AVILES SATS A F Eel 1000 psia ee SES ELS BuCN o] 0%IA] 65%E 37} GFF 300% Sz a + ach BuCN & HIPB/AP #214) 3S + NE UA Soh Fe:Os, CriOy, SE Ute 21719] FeiOs 9} ¥1 L8H EAL] ME FFE SLAVS V+ 3h Gt 8aIFE BUCN & 4G ZB, D, Ast a] BS AALS vale] Bq Meizlpe Wes BuCN 2} Seo] S7}sel4y shales at TPIS. SER AP 200 3} 6 um 5/5, CrsOs 05% Ast Fala] AFG ease} 2195 mm/s=4] BUCN 2.8 $2149] BP 23% AE FRAY US ELSES AF MSS al = + Ue. Fig. 2 Strand buring rate as a function of pressure at 20 Table 4, Burning rate and pressure exponent of HTPBIAP Propellanis at 20°C(Rh = a’) Sample Ry at 1000 psia » a number (mm/s) (rom/s) ry 1274 05079038151 B mr oats amar c 3078 0.3900 20797 > 3555 3947 232689 E 37.98 ous 235534 Fr 2195 03950 143388 HIPB/AP/Butacene 42! Xi Fig 3 Burning rate and pressure exonent as a function of Butaoene contents 32 Friablity Friability = AG S44 Sala lala S Ax datz Bde Wat Is. we SE = Pop sage] Beste] B22 Fal AL ASS CHF AHS VAYsh7) We) SS Ale lala Slo], CBT AVE GAGE7+ SRUUFE Ba. SB BIAS Falalel #3} friability | A AES NAySAS D aay ste}. Figure 4 oi] A) A, B, D, F 2} friability 379 Aas SESEo Ge GFE Erle. ae SS 48s] G2 a Hala] wo AS a St BFA FS F Saal} SESE OS friability $7}2 3 ke FS U + We A D PAA BF SESE 135m/s ay Bass} SE A) G47} Motori ole slope] Bes} vstel Sh my Sole BPoleH3, 4]. o] gel 2B ferrocene SNES AP 9} Zo] ALE A] cbato] He ede] Sze 2[o-11]s} Feta) Sryat Bzpalch. Fig. 5 te Aas mol wpe S BSE 10m/s M4 friabilityS Salsa}. Aa SET} SIHMES(A, B) friability 7} S7HNS # Nt. SE GASES S741717] Mah BuCN S| US S778 ole Bet zi Sgo] BLAA. F FAA] BF AtdS=r; B Hala) en AA SA ee aa aol} ya ay 2e1S BPs}st friability 7} EA Fasied44 Us + HAF - Bas - AKA eRe ssl A cle @&Go We oe} AP 6 un 9) BBO) friability o) At BRS elas Ae ab F QLO0} A, ASE UN test series 72] EIDS 7] € Whee Ada GA we UF Ue. ‘ ¢ sy.) MPa 2 Impact vlety mis Fig. 4 Friablty as a function of propellant. impact velocity vue ee oe rab a 150m, Mame turing rate 000i, Fig. 5 Friabilty of HTPBVAP propellants as a function of buming rate at 1000 psia (20°C) 42,2 HTPB/AP #4lajo] G2 HAS ZA871 A 3 APSE BuCN 3} CrOy 8 AP 6 mo] aay S28 wale ase Zabel. BuCN 9} ato] Ses Falale] 71a HAS AIIAT AASEE Bgl easel S7IAG. BuCN Heso] S7HIS friability SHHIOM Ne Pasert Sse a olf7t Uh. BR We Aages rele AA BAH SAAS) AP 6 ym 9} V0] WE AF friability 7+ FS D+ sale. 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