(1／4)

SAFETY DATA SHEET

MSDS: 2011025111EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Yellow

1. Identification of the substance/mixture and of the company/undertaking

Product Name: REACTIVE DYE INK TYPE-P Yellow
Identification of the Konica Minolta, Inc.
supplier:
Address: 2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN
TEL : +81-42-589-3739、FAX : +81-42-589-3868
Emergency Telephone Poison Control Center Berlin (only for Germany, France, and Slovenia)
Number: 49-30-30686-790(24-hour Counseling-service in German and English)

2. Hazards identification

POTENTIAL HEALTH EFFECTS

Eye Effects : May cause eye and mucous membrane irritation.
Skin Effects : May cause slight skin irritation.
Ingestion Effects : May be harmful if swallowed.
Inhalation Effects : No identified health effects.
Chronic Effects / None of the components in this material is listed by IARC, EU or
: ACGIH as a carcinogen.
Carcinogenicity :

3. Composition/information on ingredients
Substance/Mixture: Mixture
Ingredients and Concentration
Concen
Ingredient Name tration CAS# R-Phrase EINECS
wt.%
Ethylene glycol 20-25 107-21-1 Xn R22 2034733
trisodium 5-[[5-[[4-chloro-6-[(3- 10-25 84045-63-6 Xi R43 2818653
sulphonatophenyl)amino]-1,3,5-triazin-2-yl]
amino]-2sulphonatophenyl]azo]-1-ethyl-1,2-
dihydro-6-hydroxy-4-methyl-2-oxopyridine-3-
methanesulphonate

4. First-aid measures
Inhalation: No exposure expected under normal conditions. Large amount of
vapor or mist if inhaled, move victim to fresh air immediately.
If symptoms occur, get medical attention.
Skin Contact: Wash with water and mild soap for 15 minutes. If symptoms occur,
get medical attention.
Eye Contact: In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
Ingestion: Wash out mouth with water. Drink one or two glasses of water. Get
medical attention immediately. ONLY induce vomiting at the
instruction of a physician. Never give anything by mouth to an
unconscious person.
 (2／4)
SAFETY DATA SHEET
MSDS: 2011025111EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Yellow

5. Fire-fighting measures
Suitable Extinguishing Media:
Extinguishing Media to Avoid:
Fire Fighting:
Water spray, dry chemical, carbon dioxide, alcohol-resistant
foam.
No information.
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Apply cooling water to
sides of containers that are exposed to flames. Combat fire out
of sheltered position.

6. Accidental release measures

Personal precautions, protective
equipment and emergency procedures:
Environmental precautions:
Methods and materials for
containment and cleaning up:
Wear personal protective equipment(See Section 8).
No information.
Absorb spill with inert material(e.g. dry sand or earth), then
place in a chemical waste container.

7. Handling and storage

Handling
Technical Measures: Avoid contact with eyes, skin and clothing. Wear personal
protective equipment (See Section 8). Wash thoroughly after
handling.
Ventilation Use with adequate ventilation.
requirements:
Precautions: No information.
Precautions for safe Do not breathe dust/fume/gas/mist/vapours/spray.
handling:
Do not eat, drink or smoke when using this product.
Storage
Storage Conditions: Keep container tightly closed. Store in a cool and dry place.
Keep away from incompatible substances(See Section 10).
Safety adequate No information.
container materials:

8. Exposure controls/personal protection

Appropriate engineering controls: Use process enclosures or local exhaust ventilation.

Control parameters
ACGIH EU - OEL
Ingredient Name
TLV-TWA TLV-STEL STEL TWA
Ethylene glycol None 100mg/m3 40ppm, 20ppm,
establis [C] 104mg/m3 52mg/m3
hed
trisodium 5-[[5-[[4-chloro-6-[(3-sulphonatophenyl)amino]-1,3,5- None None None None
triazin-2-yl] amino]-2sulphonatophenyl]azo]-1-ethyl-1,2-dihydro- establis establis establis establis
6-hydroxy-4-methyl-2-oxopyridine-3-methanesulphonate hed hed hed hed
 (3／4)
SAFETY DATA SHEET
MSDS: 2011025111EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Yellow

Personal Protective Equipment

Respiratory Protection: Not required under normal conditions.
Hand protection: Impervious gloves should be worn.
Eye/face protection: Splash goggles should be worn.
Skin Protection: Not required under normal conditions.

9. Physical and chemical properties

Product
Physical state: Liquid
Form: Liquid
Color: Colored
Odor: Slight characteristic odor
pH: Approx.6－8
Flash point: None
Specific Gravity: Unknown
Solubility: water：Completely soluble.

10. Stability and reactivity

Chemical stability: Stable.
Possibility of hazardous No Information.
reactions:
Conditions to avoid: No Information.
Incompatible materials: Oxidizers
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:

11. Toxicological information

Product
No Data
Ingredient
Ethylene glycol
Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]
Skin corrosion/irritation: Mild [rabbit]
Serious eye damage/irritation: Mild [rabbit]
Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative
 (4／4)
SAFETY DATA SHEET
MSDS: 2011025111EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Yellow

12. Ecological information

Product
No Data
Ingredient
Ethylene glycol
Ecotoxicity
Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]
Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]
Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]
Persistence and degradability： Readily biodegradable

13. Disposal considerations

Disposal When disposing of the waste or recovered material, consult federal, state and/or local
methods: regulations for the proper disposal method.

14. Transport information

UN Class UN ---
classification：
UN number： ---
Proper shipping ---
name：
Packing group： ---

15. Regulatory information

Labeling according EEC-Regulations: No labels required.

16. Other information

Disclaimer The above information is believed to be accurate and represents the best
information currently available to our company. However, our company make
no warranty with respect to such information, and our company assume no
liability resulting from its use. Users should make their own investigation
to determine the suitability of the information for their particular
purposes.

Product Name:
1. Identification of the substance/mixture and of the company/undertaking
Product Name:
Identification of the
supplier:
Address:
Emergency Telephone
Number:
2. Hazards identification
POTENTIAL HEALTH EFFECTS
Eye Effects
Skin Effects
Ingestion Effects
Inhalation Effects
Chronic Effects /
Carcinogenicity :
3. Composition/information on ingredients
Substance/Mixture:
Ingredients and Concentration
Ingredient Name
Ethylene glycol
4. First-aid measures
Inhalation:
Skin Contact:
Eye Contact:
Ingestion:
(1／4)
SAFETY DATA SHEET
MSDS: 2011025121EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10
REACTIVE DYE INK TYPE-P Extra-Magenta
REACTIVE DYE INK TYPE-P Extra-Magenta
Konica Minolta, Inc.
2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN
TEL : +81-42-589-3739、FAX : +81-42-589-3868
Poison Control Center Berlin (only for Germany, France, and Slovenia)
49-30-30686-790(24-hour Counseling-service in German and English)
: May cause eye and mucous membrane irritation.
: May cause slight skin irritation.
: May be harmful if swallowed.
: No identified health effects.
None of the components in this material is listed by IARC, EU or
: ACGIH as a carcinogen.
Mixture
Concen
tration CAS# R-Phrase EINECS
wt.%
20-25 107-21-1 Xn R22 2034733
No exposure expected under normal conditions. Large amount of
vapor or mist if inhaled, move victim to fresh air immediately.
If symptoms occur, get medical attention.
Wash with water and mild soap for 15 minutes. If symptoms occur,
get medical attention.
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
Wash out mouth with water. Drink one or two glasses of water. Get
medical attention immediately. ONLY induce vomiting at the
instruction of a physician. Never give anything by mouth to an
unconscious person.

Product Name: REACTIVE DYE INK TYPE-P Extra-Magenta
5. Fire-fighting measures
Suitable Extinguishing Media:
Extinguishing Media to Avoid:
Fire Fighting:
6. Accidental release measures
Personal precautions, protective
equipment and emergency procedures:
Environmental precautions:
Methods and materials for
containment and cleaning up:
7. Handling and storage
Handling
Technical Measures:
Ventilation
requirements:
Precautions:
Precautions for safe
handling:
Storage
Storage Conditions:
Safety adequate
container materials:
8. Exposure controls/personal protection
Appropriate engineering controls:
Control parameters
Ingredient Name
Ethylene glycol
Personal Protective Equipment
Respiratory Protection:
Hand protection:
Eye/face protection:
Skin Protection:
(2／4)
SAFETY DATA SHEET
MSDS: 2011025121EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10
Water spray, dry chemical, carbon dioxide, alcohol-resistant
foam.
No information.
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Apply cooling water to
sides of containers that are exposed to flames. Combat fire out
of sheltered position.
Wear personal protective equipment(See Section 8).
No information.
Absorb spill with inert material(e.g. dry sand or earth), then
place in a chemical waste container.
Avoid contact with eyes, skin and clothing. Wear personal
protective equipment (See Section 8). Wash thoroughly after
handling.
Use with adequate ventilation.
No information.
Do not breathe dust/fume/gas/mist/vapours/spray.
Do not eat, drink or smoke when using this product.
Keep container tightly closed. Store in a cool and dry place.
Keep away from incompatible substances(See Section 10).
No information.
Use process enclosures or local exhaust ventilation.
ACGIH EU - OEL
TLV-TWA TLV-STEL STEL TWA
None 100mg/m3 40ppm, 20ppm,
establis [C] 104mg/m3 52mg/m3
hed
Not required under normal conditions.
Impervious gloves should be worn.
Splash goggles should be worn.
Not required under normal conditions.
 (3／4)
SAFETY DATA SHEET
MSDS: 2011025121EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Extra-Magenta

9. Physical and chemical properties

Product
Physical state: Liquid
Form: Liquid
Color: Colored
Odor: Slight characteristic odor
pH: Approx.6－8
Flash point: None
Specific Gravity: Unknown
Solubility: water：Completely soluble.

10. Stability and reactivity

Chemical stability: Stable.
Possibility of hazardous No Information.
reactions:
Conditions to avoid: No Information.
Incompatible materials: Oxidizers
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:

11. Toxicological information

Product
No Data
Ingredient
Ethylene glycol
Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]
Skin corrosion/irritation: Mild [rabbit]
Serious eye damage/irritation: Mild [rabbit]
Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

12. Ecological information

Product
No Data
Ingredient
Ethylene glycol
Ecotoxicity
Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]
Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]
Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]
Persistence and degradability： Readily biodegradable
 (4／4)
SAFETY DATA SHEET
MSDS: 2011025121EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Extra-Magenta

13. Disposal considerations

Disposal When disposing of the waste or recovered material, consult federal, state and/or local
methods: regulations for the proper disposal method.

14. Transport information

UN Class UN ---
classification：
UN number： ---
Proper shipping ---
name：
Packing group： ---

15. Regulatory information

Labeling according EEC-Regulations: No labels required.

16. Other information

Disclaimer The above information is believed to be accurate and represents the best
information currently available to our company. However, our company make
no warranty with respect to such information, and our company assume no
liability resulting from its use. Users should make their own investigation
to determine the suitability of the information for their particular
purposes.

Product Name:
1. Identification of the substance/mixture and of the company/undertaking
Product Name:
Identification of the
supplier:
Address:
Emergency Telephone
Number:
2. Hazards identification
POTENTIAL HEALTH EFFECTS
Eye Effects
Skin Effects
Ingestion Effects
Inhalation Effects
Chronic Effects /
Carcinogenicity :
3. Composition/information on ingredients
Substance/Mixture:
Ingredients and Concentration
Ingredient Name
Ethylene glycol
4. First-aid measures
Inhalation:
Skin Contact:
Eye Contact:
Ingestion:
(1／4)
SAFETY DATA SHEET
MSDS: 2011025131EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10
REACTIVE DYE INK TYPE-P Cyan
REACTIVE DYE INK TYPE-P Cyan
Konica Minolta, Inc.
2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN
TEL : +81-42-589-3739、FAX : +81-42-589-3868
Poison Control Center Berlin (only for Germany, France, and Slovenia)
49-30-30686-790(24-hour Counseling-service in German and English)
: May cause eye and mucous membrane irritation.
: May cause slight skin irritation.
: May be harmful if swallowed.
: No identified health effects.
None of the components in this material is listed by IARC, EU or
: ACGIH as a carcinogen.
Mixture
Concen
tration CAS# R-Phrase EINECS
wt.%
20-25 107-21-1 Xn R22 2034733
No exposure expected under normal conditions. Large amount of
vapor or mist if inhaled, move victim to fresh air immediately.
If symptoms occur, get medical attention.
Wash with water and mild soap for 15 minutes. If symptoms occur,
get medical attention.
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
Wash out mouth with water. Drink one or two glasses of water. Get
medical attention immediately. ONLY induce vomiting at the
instruction of a physician. Never give anything by mouth to an
unconscious person.

Product Name: REACTIVE DYE INK TYPE-P Cyan
5. Fire-fighting measures
Suitable Extinguishing Media:
Extinguishing Media to Avoid:
Fire Fighting:
6. Accidental release measures
Personal precautions, protective
equipment and emergency procedures:
Environmental precautions:
Methods and materials for
containment and cleaning up:
7. Handling and storage
Handling
Technical Measures:
Ventilation
requirements:
Precautions:
Precautions for safe
handling:
Storage
Storage Conditions:
Safety adequate
container materials:
8. Exposure controls/personal protection
Appropriate engineering controls:
Control parameters
Ingredient Name
Ethylene glycol
Personal Protective Equipment
Respiratory Protection:
Hand protection:
Eye/face protection:
Skin Protection:
(2／4)
SAFETY DATA SHEET
MSDS: 2011025131EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10
Water spray, dry chemical, carbon dioxide, alcohol-resistant
foam.
No information.
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Apply cooling water to
sides of containers that are exposed to flames. Combat fire out
of sheltered position.
Wear personal protective equipment(See Section 8).
No information.
Absorb spill with inert material(e.g. dry sand or earth), then
place in a chemical waste container.
Avoid contact with eyes, skin and clothing. Wear personal
protective equipment (See Section 8). Wash thoroughly after
handling.
Use with adequate ventilation.
No information.
Do not breathe dust/fume/gas/mist/vapours/spray.
Do not eat, drink or smoke when using this product.
Keep container tightly closed. Store in a cool and dry place.
Keep away from incompatible substances(See Section 10).
No information.
Use process enclosures or local exhaust ventilation.
ACGIH EU - OEL
TLV-TWA TLV-STEL STEL TWA
None 100mg/m3 40ppm, 20ppm,
establis [C] 104mg/m3 52mg/m3
hed
Not required under normal conditions.
Impervious gloves should be worn.
Splash goggles should be worn.
Not required under normal conditions.
 (3／4)
SAFETY DATA SHEET
MSDS: 2011025131EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Cyan

9. Physical and chemical properties

Product
Physical state: Liquid
Form: Liquid
Color: Colored
Odor: Slight characteristic odor
pH: Approx.6－8
Flash point: None
Specific Gravity: Unknown
Solubility: water：Completely soluble.

10. Stability and reactivity

Chemical stability: Stable.
Possibility of hazardous No Information.
reactions:
Conditions to avoid: No Information.
Incompatible materials: Oxidizers
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:

11. Toxicological information

Product
Mutagenicity: Ames Test:Negative

Ingredient
Ethylene glycol
Acute toxicity (oral):
Skin corrosion/irritation:
Serious eye damage/irritation:
Mutagenicity:
LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]
Mild [rabbit]
Mild [rabbit]
Ames Test:Negative, Chromosomal aberration test:Negative

12. Ecological information

Product
No Data
Ingredient
Ethylene glycol
Ecotoxicity
Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]
Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]
Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus ]
Persistence and degradability： Readily biodegradable
 (4／4)
SAFETY DATA SHEET
MSDS: 2011025131EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Cyan

13. Disposal considerations

Disposal When disposing of the waste or recovered material, consult federal, state and/or local
methods: regulations for the proper disposal method.

14. Transport information

UN Class UN ---
classification：
UN number： ---
Proper shipping ---
name：
Packing group： ---

15. Regulatory information

Labeling according EEC-Regulations: No labels required.

16. Other information

Disclaimer The above information is believed to be accurate and represents the best
information currently available to our company. However, our company make
no warranty with respect to such information, and our company assume no
liability resulting from its use. Users should make their own investigation
to determine the suitability of the information for their particular
purposes.

Product Name:
1. Identification of the substance/mixture and of the company/undertaking
Product Name:
Identification of the
supplier:
Address:
Emergency Telephone
Number:
2. Hazards identification
POTENTIAL HEALTH EFFECTS
Eye Effects
Skin Effects
Ingestion Effects
Inhalation Effects
Chronic Effects /
Carcinogenicity :
3. Composition/information on ingredients
Substance/Mixture:
Ingredients and Concentration
Ingredient Name
Ethylene glycol
4. First-aid measures
Inhalation:
Skin Contact:
Eye Contact:
Ingestion:
(1／4)
SAFETY DATA SHEET
MSDS: 2011025141EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10
REACTIVE DYE INK TYPE-P Sky
REACTIVE DYE INK TYPE-P Sky
Konica Minolta, Inc.
2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN
TEL : +81-42-589-3739、FAX : +81-42-589-3868
Poison Control Center Berlin (only for Germany, France, and Slovenia)
49-30-30686-790(24-hour Counseling-service in German and English)
: May cause eye and mucous membrane irritation.
: May cause slight skin irritation.
: May be harmful if swallowed.
: No identified health effects.
None of the components in this material is listed by IARC, EU or
: ACGIH as a carcinogen.
Mixture
Concentr
ationwt. CAS# R-Phrase EINECS
%
20-25 107-21-1 Xn R22 2034733
No exposure expected under normal conditions. Large amount of
vapor or mist if inhaled, move victim to fresh air immediately.
If symptoms occur, get medical attention.
Wash with water and mild soap for 15 minutes. If symptoms occur,
get medical attention.
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
Wash out mouth with water. Drink one or two glasses of water. Get
medical attention immediately. ONLY induce vomiting at the
instruction of a physician. Never give anything by mouth to an
unconscious person.

Product Name: REACTIVE DYE INK TYPE-P Sky
5. Fire-fighting measures
Suitable Extinguishing Media:
Extinguishing Media to Avoid:
Fire Fighting:
6. Accidental release measures
Personal precautions, protective
equipment and emergency procedures:
Environmental precautions:
Methods and materials for
containment and cleaning up:
7. Handling and storage
Handling
Technical Measures:
Ventilation
requirements:
Precautions:
Precautions for safe
handling:
Storage
Storage Conditions:
Safety adequate
container materials:
8. Exposure controls/personal protection
Appropriate engineering controls:
Control parameters
Ingredient Name
Ethylene glycol
Personal Protective Equipment
Respiratory Protection:
Hand protection:
Eye/face protection:
Skin Protection:
(2／4)
SAFETY DATA SHEET
MSDS: 2011025141EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10
Water spray, dry chemical, carbon dioxide, alcohol-resistant
foam.
No information.
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Apply cooling water to
sides of containers that are exposed to flames. Combat fire out
of sheltered position.
Wear personal protective equipment(See Section 8).
No information.
Absorb spill with inert material(e.g. dry sand or earth), then
place in a chemical waste container.
Avoid contact with eyes, skin and clothing. Wear personal
protective equipment (See Section 8). Wash thoroughly after
handling.
Use with adequate ventilation.
No information.
No information.
Do not breathe dust/fume/gas/mist/vapours/spray.
Do not eat, drink or smoke when using this product.
Keep container tightly closed. Store in a cool and dry place.
Keep away from incompatible substances(See Section 10).
No information.
Use process enclosures or local exhaust ventilation.
ACGIH EU - OEL
TLV-TWA TLV-STEL STEL TWA
None 100mg/m3 40ppm, 20ppm,
establis [C] 104mg/m3 52mg/m3
hed
Not required under normal conditions.
Impervious gloves should be worn.
Splash goggles should be worn.
Not required under normal conditions.
 (3／4)
SAFETY DATA SHEET
MSDS: 2011025141EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Sky

9. Physical and chemical properties

Product
Physical state: Liquid
Form: Liquid
Color: Colored
Odor: Slight characteristic odor
pH: Approx.6－8
Flash point: None
Specific Gravity: Unknown
Solubility: water：Completely soluble.

10. Stability and reactivity

Chemical stability: Stable.
Possibility of hazardous No Information.
reactions:
Conditions to avoid: No Information.
Incompatible materials: Oxidizers
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:

11. Toxicological information

Product
Ames Test : Negative (Data of similar product)

Ingredient
Ethylene glycol
Acute toxicity (oral):
Skin corrosion/irritation:
Serious eye damage/irritation:
Mutagenicity:
LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]
Mild [rabbit]
Mild [rabbit]
Ames Test:Negative, Chromosomal aberration test:Negative

12. Ecological information

Product
No Data
Ingredient
Ethylene glycol
Ecotoxicity
Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]
Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]
Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus ]
Persistence and degradability： Readily biodegradable
 (4／4)
SAFETY DATA SHEET
MSDS: 2011025141EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Sky

13. Disposal considerations

Disposal When disposing of the waste or recovered material, consult federal, state and/or local
methods: regulations for the proper disposal method.

14. Transport information

UN Class UN ---
classification：
UN number： ---
Proper shipping ---
name：
Packing group： ---

15. Regulatory information

Labeling according EEC-Regulations: No labels required.

16. Other information

Disclaimer The above information is believed to be accurate and represents the best
information currently available to our company. However, our company make
no warranty with respect to such information, and our company assume no
liability resulting from its use. Users should make their own investigation
to determine the suitability of the information for their particular
purposes.
 (1／4)
SAFETY DATA SHEET
MSDS: 2013048010EU
Date Prepared: 2013/09/26
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Black

1. Identification of the substance/mixture and of the company/undertaking

Product Name: REACTIVE DYE INK TYPE-P Black
Identification of the Konica Minolta, Inc.
supplier:
Address: 2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN
TEL : +81-42-589-3739、FAX : +81-42-589-3868
Emergency Telephone Poison Control Center Berlin (only for Germany, France, and Slovenia)
Number: 49-30-30686-790(24-hour Counseling-service in German and English)

2. Hazards identification

POTENTIAL HEALTH EFFECTS

Eye Effects : May cause eye and mucous membrane irritation.
Skin Effects : May cause slight skin irritation.
Ingestion Effects : May be harmful if swallowed.
Inhalation Effects : No identified health effects.
Chronic Effects / May cause sensitization by skin contact. None of the components
: in this material is listed by IARC, EU or ACGIH as a carcinogen.
Carcinogenicity :

3. Composition/information on ingredients
Substance/Mixture: Mixture
Ingredients and Concentration
Concentr
Ingredient Name ationwt. CAS# R-Phrase EINECS
%
Ethylene glycol 20-25 107-21-1 Xn R22 2034733
pentasodium 4-amino-6-[[5-[(4-amino-6-chloro- 1-20 68259-02-9 Xi R43 2695053
1,3,5-triazin-2-yl)amino]-2-
sulphonatophenyl]azo]-3-[(2,5-
disulphonatophenyl)azo]-5-hydroxynaphthalene-
2,7-disulphonate

4. First-aid measures
Inhalation: No exposure expected under normal conditions. Large amount of
vapor or mist if inhaled, move victim to fresh air immediately.
If symptoms occur, get medical attention.
Skin Contact: Immediately wash with water and mild soap for 15 minutes. Remove
contaminated clothing. If symptoms occur, get medical attention.
Eye Contact: In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
Ingestion: Wash out mouth with water. Drink one or two glasses of water. Get
medical attention immediately. ONLY induce vomiting at the
instruction of a physician. Never give anything by mouth to an
unconscious person.
 (2／4)
SAFETY DATA SHEET
MSDS: 2013048010EU
Date Prepared: 2013/09/26
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Black

5. Fire-fighting measures
Suitable Extinguishing Media:
Extinguishing Media to Avoid:
Fire Fighting:
Water spray, dry chemical, carbon dioxide, alcohol-resistant
foam.
No information.
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Apply cooling water to
sides of containers that are exposed to flames. Combat fire out
of sheltered position.

6. Accidental release measures

Personal precautions, protective
equipment and emergency procedures:
Environmental precautions:
Methods and materials for
containment and cleaning up:
Wear personal protective equipment(See Section 8).
No information.
Absorb spill with inert material(e.g. dry sand or earth), then
place in a chemical waste container.

7. Handling and storage

Handling
Technical Measures: Avoid contact with eyes, skin and clothing. Wear personal
protective equipment (See Section 8). Wash thoroughly after
handling.
Ventilation Use with adequate ventilation.
requirements:
Precautions: No information.
Precautions for safe Do not breathe dust/fume/gas/mist/vapours/spray.
handling:
Do not eat, drink or smoke when using this product.
The routine use of neutral or weak acid type of hand cleaner and
regular cleaning of working surfaces, gloves, etc. will help
minimize the possibility of a skin reaction.
Storage
Storage Conditions: Keep container tightly closed. Store in a cool and dry place.
Keep away from incompatible substances(See Section 10).
Safety adequate No information.
container materials:

8. Exposure controls/personal protection

Appropriate engineering controls: Use process enclosures or local exhaust ventilation.

Control parameters
ACGIH EU - OEL
Ingredient Name
TLV-TWA TLV-STEL STEL TWA
Ethylene glycol None 100mg/m3 40ppm, 20ppm,
establis [C] 104mg/m3 52mg/m3
hed
pentasodium 4-amino-6-[[5-[(4-amino-6-chloro-1,3,5-triazin-2- None None None None
yl)amino]-2-sulphonatophenyl]azo]-3-[(2,5- establis establis establis establis
disulphonatophenyl)azo]-5-hydroxynaphthalene-2,7-disulphonate hed hed hed hed
 (3／4)
SAFETY DATA SHEET
MSDS: 2013048010EU
Date Prepared: 2013/09/26
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Black

Personal Protective Equipment

Respiratory Protection: Not required under normal conditions.
Hand protection: Impervious gloves should be worn.
Eye/face protection: Splash goggles should be worn.
Skin Protection: Not required under normal conditions.

9. Physical and chemical properties

Product
Physical state: Liquid
Form: Liquid
Color: Colored
Odor: Slight characteristic odor
pH: Approx.6－8
Flash point: None
Specific Gravity: Unknown
Solubility: water：Completely soluble.

10. Stability and reactivity

Chemical stability: Stable.
Possibility of hazardous No Information.
reactions:
Conditions to avoid: No Information.
Incompatible materials: Oxidizers
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:

11. Toxicological information

Product
Skin sensitization: Positive LLNA [mouse]

Ingredient
Ethylene glycol
Acute toxicity (oral):
Skin corrosion/irritation:
Serious eye damage/irritation:
Mutagenicity:
LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]
Mild [rabbit]
Mild [rabbit]
Ames Test:Negative, Chromosomal aberration test:Negative
 (4／4)
SAFETY DATA SHEET
MSDS: 2013048010EU
Date Prepared: 2013/09/26
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Black

12. Ecological information

Product
No Data
Ingredient
Ethylene glycol
Ecotoxicity
Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]
Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]
Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]
Persistence and degradability： Readily biodegradable

13. Disposal considerations

Disposal When disposing of the waste or recovered material, consult federal, state and/or local
methods: regulations for the proper disposal method.

14. Transport information

UN Class UN ---
classification：
UN number： ---
Proper shipping ---
name：
Packing group： ---

15. Regulatory information

Labeling according EEC-Regulations: Symbol : Xi

R : 43
S : 2-24-37
Contains : pentasodium 4-amino-6-[[5-[(4-amino-6-chloro-1,3,5-
triazin-2-yl)amino]-2-sulphonatophenyl]azo]-3-[(2,5-
disulphonatophenyl)azo]-5-hydroxynaphthalene-2,7-disulphonate

16. Other information

Disclaimer The above information is believed to be accurate and represents the best
information currently available to our company. However, our company make
no warranty with respect to such information, and our company assume no
liability resulting from its use. Users should make their own investigation
to determine the suitability of the information for their particular
purposes.
 (1／4)
SAFETY DATA SHEET
MSDS: 2013048020EU
Date Prepared: 2013/09/26
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Gray

1. Identification of the substance/mixture and of the company/undertaking

Product Name: REACTIVE DYE INK TYPE-P Gray
Identification of the Konica Minolta, Inc.
supplier:
Address: 2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN
TEL : +81-42-589-3739、FAX : +81-42-589-3868
Emergency Telephone Poison Control Center Berlin (only for Germany, France, and Slovenia)
Number: 49-30-30686-790(24-hour Counseling-service in German and English)

2. Hazards identification

POTENTIAL HEALTH EFFECTS

Eye Effects : May cause eye and mucous membrane irritation.
Skin Effects : May cause slight skin irritation.
Ingestion Effects : May be harmful if swallowed.
Inhalation Effects : No identified health effects.
Chronic Effects / May cause sensitization by skin contact. None of the components
: in this material is listed by IARC, EU or ACGIH as a carcinogen.
Carcinogenicity :

3. Composition/information on ingredients
Substance/Mixture: Mixture
Ingredients and Concentration
Concentr
Ingredient Name ationwt. CAS# R-Phrase EINECS
%
Ethylene glycol 20-25 107-21-1 Xn R22 2034733
pentasodium 4-amino-6-[[5-[(4-amino-6-chloro- 1-20 68259-02-9 Xi R43 2695053
1,3,5-triazin-2-yl)amino]-2-
sulphonatophenyl]azo]-3-[(2,5-
disulphonatophenyl)azo]-5-hydroxynaphthalene-
2,7-disulphonate

4. First-aid measures
Inhalation: No exposure expected under normal conditions. Large amount of
vapor or mist if inhaled, move victim to fresh air immediately.
If symptoms occur, get medical attention.
Skin Contact: Immediately wash with water and mild soap for 15 minutes. Remove
contaminated clothing. If symptoms occur, get medical attention.
Eye Contact: In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
Ingestion: Wash out mouth with water. Drink one or two glasses of water. Get
medical attention immediately. ONLY induce vomiting at the
instruction of a physician. Never give anything by mouth to an
unconscious person.
 (2／4)
SAFETY DATA SHEET
MSDS: 2013048020EU
Date Prepared: 2013/09/26
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Gray

5. Fire-fighting measures
Suitable Extinguishing Media:
Extinguishing Media to Avoid:
Fire Fighting:
Water spray, dry chemical, carbon dioxide, alcohol-resistant
foam.
No information.
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Apply cooling water to
sides of containers that are exposed to flames. Combat fire out
of sheltered position.

6. Accidental release measures

Personal precautions, protective
equipment and emergency procedures:
Environmental precautions:
Methods and materials for
containment and cleaning up:
Wear personal protective equipment(See Section 8).
No information.
Absorb spill with inert material(e.g. dry sand or earth), then
place in a chemical waste container.

7. Handling and storage

Handling
Technical Measures: Avoid contact with eyes, skin and clothing. Wear personal
protective equipment (See Section 8). Wash thoroughly after
handling.
Ventilation Use with adequate ventilation.
requirements:
Precautions: No information.
Precautions for safe Do not breathe dust/fume/gas/mist/vapours/spray.
handling:
Do not eat, drink or smoke when using this product.
The routine use of neutral or weak acid type of hand cleaner and
regular cleaning of working surfaces, gloves, etc. will help
minimize the possibility of a skin reaction.
Storage
Storage Conditions: Keep container tightly closed. Store in a cool and dry place.
Keep away from incompatible substances(See Section 10).
Safety adequate No information.
container materials:

8. Exposure controls/personal protection

Appropriate engineering controls: Use process enclosures or local exhaust ventilation.

Control parameters
ACGIH EU - OEL
Ingredient Name
TLV-TWA TLV-STEL STEL TWA
Ethylene glycol None 100mg/m3 40ppm, 20ppm,
establis [C] 104mg/m3 52mg/m3
hed
pentasodium 4-amino-6-[[5-[(4-amino-6-chloro-1,3,5-triazin-2- None None None None
yl)amino]-2-sulphonatophenyl]azo]-3-[(2,5- establis establis establis establis
disulphonatophenyl)azo]-5-hydroxynaphthalene-2,7-disulphonate hed hed hed hed
 (3／4)
SAFETY DATA SHEET
MSDS: 2013048020EU
Date Prepared: 2013/09/26
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Gray

Personal Protective Equipment

Respiratory Protection: Not required under normal conditions.
Hand protection: Impervious gloves should be worn.
Eye/face protection: Splash goggles should be worn.
Skin Protection: Not required under normal conditions.

9. Physical and chemical properties

Product
Physical state: Liquid
Form: Liquid
Color: Colored
Odor: Slight characteristic odor
pH: Approx.6－8
Flash point: None
Specific Gravity: Unknown
Solubility: water：Completely soluble.

10. Stability and reactivity

Chemical stability: Stable.
Possibility of hazardous No Information.
reactions:
Conditions to avoid: No Information.
Incompatible materials: Oxidizers
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:

11. Toxicological information

Product
Skin sensitization: Positive LLNA [mouse]

Ingredient
Ethylene glycol
Acute toxicity (oral):
Skin corrosion/irritation:
Serious eye damage/irritation:
Mutagenicity:
LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]
Mild [rabbit]
Mild [rabbit]
Ames Test:Negative, Chromosomal aberration test:Negative
 (4／4)
SAFETY DATA SHEET
MSDS: 2013048020EU
Date Prepared: 2013/09/26
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Gray

12. Ecological information

Product
No Data
Ingredient
Ethylene glycol
Ecotoxicity
Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]
Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]
Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]
Persistence and degradability： Readily biodegradable

13. Disposal considerations

Disposal When disposing of the waste or recovered material, consult federal, state and/or local
methods: regulations for the proper disposal method.

14. Transport information

UN Class UN ---
classification：
UN number： ---
Proper shipping ---
name：
Packing group： ---

15. Regulatory information

Labeling according EEC-Regulations: Symbol : Xi

R : 43
S : 2-24-37
Contains : pentasodium 4-amino-6-[[5-[(4-amino-6-chloro-1,3,5-
triazin-2-yl)amino]-2-sulphonatophenyl]azo]-3-[(2,5-
disulphonatophenyl)azo]-5-hydroxynaphthalene-2,7-disulphonate

16. Other information

Disclaimer The above information is believed to be accurate and represents the best
information currently available to our company. However, our company make
no warranty with respect to such information, and our company assume no
liability resulting from its use. Users should make their own investigation
to determine the suitability of the information for their particular
purposes.

Product Name:
1. Identification of the substance/mixture and of the company/undertaking
Product Name:
Identification of the
supplier:
Address:
Emergency Telephone
Number:
2. Hazards identification
POTENTIAL HEALTH EFFECTS
Eye Effects
Skin Effects
Ingestion Effects
Inhalation Effects
Chronic Effects /
Carcinogenicity :
3. Composition/information on ingredients
Substance/Mixture:
Ingredients and Concentration
Ingredient Name
Ethylene glycol
4. First-aid measures
Inhalation:
Skin Contact:
Eye Contact:
Ingestion:
(1／4)
SAFETY DATA SHEET
MSDS: 2011025161EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10
REACTIVE DYE INK TYPE-P Orange
REACTIVE DYE INK TYPE-P Orange
Konica Minolta, Inc.
2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN
TEL : +81-42-589-3739、FAX : +81-42-589-3868
Poison Control Center Berlin (only for Germany, France, and Slovenia)
49-30-30686-790(24-hour Counseling-service in German and English)
: May cause eye and mucous membrane irritation.
: May cause slight skin irritation.
: May be harmful if swallowed.
: No identified health effects.
None of the components in this material is listed by IARC, EU or
: ACGIH as a carcinogen.
Mixture
Concentr
ationwt. CAS# R-Phrase EINECS
%
20-25 107-21-1 Xn R22 2034733
No exposure expected under normal conditions. Large amount of
vapor or mist if inhaled, move victim to fresh air immediately.
If symptoms occur, get medical attention.
Wash with water and mild soap for 15 minutes. If symptoms occur,
get medical attention.
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
Wash out mouth with water. Drink one or two glasses of water. Get
medical attention immediately. ONLY induce vomiting at the
instruction of a physician. Never give anything by mouth to an
unconscious person.

Product Name: REACTIVE DYE INK TYPE-P Orange
5. Fire-fighting measures
Suitable Extinguishing Media:
Extinguishing Media to Avoid:
Fire Fighting:
6. Accidental release measures
Personal precautions, protective
equipment and emergency procedures:
Environmental precautions:
Methods and materials for
containment and cleaning up:
7. Handling and storage
Handling
Technical Measures:
Ventilation
requirements:
Precautions:
Precautions for safe
handling:
Storage
Storage Conditions:
Safety adequate
container materials:
8. Exposure controls/personal protection
Appropriate engineering controls:
Control parameters
Ingredient Name
Ethylene glycol
Personal Protective Equipment
Respiratory Protection:
Hand protection:
Eye/face protection:
Skin Protection:
(2／4)
SAFETY DATA SHEET
MSDS: 2011025161EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10
Water spray, dry chemical, carbon dioxide, alcohol-resistant
foam.
No information.
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Apply cooling water to
sides of containers that are exposed to flames. Combat fire out
of sheltered position.
Wear personal protective equipment(See Section 8).
No information.
Absorb spill with inert material(e.g. dry sand or earth), then
place in a chemical waste container.
Avoid contact with eyes, skin and clothing. Wear personal
protective equipment (See Section 8). Wash thoroughly after
handling.
Use with adequate ventilation.
No information.
Do not breathe dust/fume/gas/mist/vapours/spray.
Do not eat, drink or smoke when using this product.
Keep container tightly closed. Store in a cool and dry place.
Keep away from incompatible substances(See Section 10).
No information.
Use process enclosures or local exhaust ventilation.
ACGIH EU - OEL
TLV-TWA TLV-STEL STEL TWA
None 100mg/m3 40ppm, 20ppm,
establis [C] 104mg/m3 52mg/m3
hed
Not required under normal conditions.
Impervious gloves should be worn.
Splash goggles should be worn.
Not required under normal conditions.
 (3／4)
SAFETY DATA SHEET
MSDS: 2011025161EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Orange

9. Physical and chemical properties

Product
Physical state: Liquid
Form: Liquid
Color: Colored
Odor: Slight characteristic odor
pH: Approx.6－8
Flash point: None
Specific Gravity: Unknown
Solubility: water：Completely soluble.

10. Stability and reactivity

Chemical stability: Stable.
Possibility of hazardous No Information.
reactions:
Conditions to avoid: No Information.
Incompatible materials: Oxidizers
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:

11. Toxicological information

Product
No Data
Ingredient
Ethylene glycol
Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]
Skin corrosion/irritation: Mild [rabbit]
Serious eye damage/irritation: Mild [rabbit]
Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative

12. Ecological information

Product
No Data
Ingredient
Ethylene glycol
Ecotoxicity
Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]
Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]
Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]
Persistence and degradability： Readily biodegradable
 (4／4)
SAFETY DATA SHEET
MSDS: 2011025161EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Orange

13. Disposal considerations

Disposal When disposing of the waste or recovered material, consult federal, state and/or local
methods: regulations for the proper disposal method.

14. Transport information

UN Class UN ---
classification：
UN number： ---
Proper shipping ---
name：
Packing group： ---

15. Regulatory information

Labeling according EEC-Regulations: No labels required.

16. Other information

Disclaimer The above information is believed to be accurate and represents the best
information currently available to our company. However, our company make
no warranty with respect to such information, and our company assume no
liability resulting from its use. Users should make their own investigation
to determine the suitability of the information for their particular
purposes.
 (1／4)
SAFETY DATA SHEET
MSDS: 2011025171EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Blue

1. Identification of the substance/mixture and of the company/undertaking

Product Name: REACTIVE DYE INK TYPE-P Blue
Identification of the Konica Minolta, Inc.
supplier:
Address: 2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN
TEL : +81-42-589-3739、FAX : +81-42-589-3868
Emergency Telephone Poison Control Center Berlin (only for Germany, France, and Slovenia)
Number: 49-30-30686-790(24-hour Counseling-service in German and English)

2. Hazards identification

POTENTIAL HEALTH EFFECTS

Eye Effects : May cause eye and mucous membrane irritation.
Skin Effects : May cause slight skin irritation.
Ingestion Effects : May be harmful if swallowed.
Inhalation Effects : No identified health effects.
Chronic Effects / None of the components in this material is listed by IARC, EU or
: ACGIH as a carcinogen.
Carcinogenicity :

3. Composition/information on ingredients
Substance/Mixture: Mixture
Ingredients and Concentration
Concentr
Ingredient Name ationwt. CAS# R-Phrase EINECS
%
Ethylene glycol 20-25 107-21-1 Xn R22 2034733
trisodium 1-amino-4-[[3-[[4-chloro-6- 10-25 72214-18-7 Xi R43 2764818
[(sulphonatophenyl)amino]-1,3,5-triazin-2-
yl]amino]-2,4,6-trimethyl-5-
sulphonatophenyl]amino]-9,10-dihydro-9,10-
dioxoanthracene-2-sulphonate

4. First-aid measures
Inhalation: No exposure expected under normal conditions. Large amount of
vapor or mist if inhaled, move victim to fresh air immediately.
If symptoms occur, get medical attention.
Skin Contact: Wash with water and mild soap for 15 minutes. If symptoms occur,
get medical attention.
Eye Contact: In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
Ingestion: Wash out mouth with water. Drink one or two glasses of water. Get
medical attention immediately. ONLY induce vomiting at the
instruction of a physician. Never give anything by mouth to an
unconscious person.
 (2／4)
SAFETY DATA SHEET
MSDS: 2011025171EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Blue

5. Fire-fighting measures
Suitable Extinguishing Media:
Extinguishing Media to Avoid:
Fire Fighting:
Water spray, dry chemical, carbon dioxide, alcohol-resistant
foam.
No information.
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Apply cooling water to
sides of containers that are exposed to flames. Combat fire out
of sheltered position.

6. Accidental release measures

Personal precautions, protective
equipment and emergency procedures:
Environmental precautions:
Methods and materials for
containment and cleaning up:
Wear personal protective equipment(See Section 8).
No information.
Absorb spill with inert material(e.g. dry sand or earth), then
place in a chemical waste container.

7. Handling and storage

Handling
Technical Measures: Avoid contact with eyes, skin and clothing. Wear personal
protective equipment (See Section 8). Wash thoroughly after
handling.
Ventilation Use with adequate ventilation.
requirements:
Precautions: No information.
Precautions for safe Do not breathe dust/fume/gas/mist/vapours/spray.
handling:
Do not eat, drink or smoke when using this product.
Storage
Storage Conditions: Keep container tightly closed. Store in a cool and dry place.
Keep away from incompatible substances(See Section 10).
Safety adequate No information.
container materials:

8. Exposure controls/personal protection

Appropriate engineering controls: Use process enclosures or local exhaust ventilation.

Control parameters
ACGIH EU - OEL
Ingredient Name
TLV-TWA TLV-STEL STEL TWA
Ethylene glycol None 100mg/m3 40ppm, 20ppm,
establis [C] 104mg/m3 52mg/m3
hed
trisodium 1-amino-4-[[3-[[4-chloro-6-[(sulphonatophenyl)amino]- None None None None
1,3,5-triazin-2-yl]amino]-2,4,6-trimethyl-5- establis establis establis establis
sulphonatophenyl]amino]-9,10-dihydro-9,10-dioxoanthracene-2- hed hed hed hed
 (3／4)
SAFETY DATA SHEET
MSDS: 2011025171EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Blue

Personal Protective Equipment

Respiratory Protection: Not required under normal conditions.
Hand protection: Impervious gloves should be worn.
Eye/face protection: Splash goggles should be worn.
Skin Protection: Not required under normal conditions.

9. Physical and chemical properties

Product
Physical state: Liquid
Form: Liquid
Color: Colored
Odor: Slight characteristic odor
pH: Approx.6－8
Flash point: None
Specific Gravity: Unknown
Solubility: water：Completely soluble.

10. Stability and reactivity

Chemical stability: Stable.
Possibility of hazardous No Information.
reactions:
Conditions to avoid: No Information.
Incompatible materials: Oxidizers
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:

11. Toxicological information

Product
No Data
Ingredient
Ethylene glycol
Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]
Skin corrosion/irritation: Mild [rabbit]
Serious eye damage/irritation: Mild [rabbit]
Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative
 (4／4)
SAFETY DATA SHEET
MSDS: 2011025171EU
Date Prepared: 2011/12/27
Date Revised: 2013/09/10

Product Name: REACTIVE DYE INK TYPE-P Blue

12. Ecological information

Product
No Data
Ingredient
Ethylene glycol
Ecotoxicity
Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]
Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]
Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]

Persistence and degradability： Readily biodegradable

13. Disposal considerations

Disposal When disposing of the waste or recovered material, consult federal, state and/or local
methods: regulations for the proper disposal method.

14. Transport information

UN Class UN ---
classification：
UN number： ---
Proper shipping ---
name：
Packing group： ---

15. Regulatory information

Labeling according EEC-Regulations: No labels required.

16. Other information

Disclaimer The above information is believed to be accurate and represents the best
information currently available to our company. However, our company make
no warranty with respect to such information, and our company assume no
liability resulting from its use. Users should make their own investigation
to determine the suitability of the information for their particular
purposes.
 (1／4)
SAFETY DATA SHEET
MSDS: 2013038010EU
Date Prepared: 2013/09/10
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Pink

1. Identification of the substance/mixture and of the company/undertaking

Product Name: REACTIVE DYE INK TYPE-P Pink
Identification of the Konica Minolta, Inc.
supplier:
Address: 2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPAN
TEL : +81-42-589-3739、FAX : +81-42-589-3868
Emergency Telephone Poison Control Center Berlin (only for Germany, France, and Slovenia)
Number: 49-30-30686-790(24-hour Counseling-service in German and English)

2. Hazards identification

POTENTIAL HEALTH EFFECTS

Eye Effects : May cause eye and mucous membrane irritation.
Skin Effects : May cause slight skin irritation.
Ingestion Effects : May be harmful if swallowed.
Inhalation Effects : No identified health effects.
Chronic Effects / None of the components in this material is listed by IARC, EU or
: ACGIH as a carcinogen.
Carcinogenicity :

3. Composition/information on ingredients
Substance/Mixture: Mixture
Ingredients and Concentration
Concentr
Ingredient Name ationwt. CAS# R-Phrase EINECS
%
Ethylene glycol 20-25 107-21-1 Xn R22 2034733
2,7-Naphthalenedisulfonicacid,5-[[4-chloro-6- 5-20 72829-25-5 Xi R43 2769114
(ethylphenylamino)-1,3,5-triazin-2-yl]amino]-
4-hydroxy-3-[2-(2-sulfophenyl)diazenyl]-
,sodium salt (1:3)

4. First-aid measures
Inhalation: No exposure expected under normal conditions. Large amount of
vapor or mist if inhaled, move victim to fresh air immediately.
If symptoms occur, get medical attention.
Skin Contact: Wash with water and mild soap for 15 minutes. If symptoms occur,
get medical attention.
Eye Contact: In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
Ingestion: Wash out mouth with water. Drink one or two glasses of water. Get
medical attention immediately. ONLY induce vomiting at the
instruction of a physician. Never give anything by mouth to an
unconscious person.
 (2／4)
SAFETY DATA SHEET
MSDS: 2013038010EU
Date Prepared: 2013/09/10
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Pink

5. Fire-fighting measures
Suitable Extinguishing Media:
Extinguishing Media to Avoid:
Fire Fighting:
Water spray, dry chemical, carbon dioxide, alcohol-resistant
foam.
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes. Apply cooling water to
sides of containers that are exposed to flames. Combat fire out
of sheltered position.

6. Accidental release measures

Personal precautions, protective
equipment and emergency procedures:
Environmental precautions:
Methods and materials for
containment and cleaning up:
Wear personal protective equipment(See Section 8).
No information.
Absorb spill with inert material(e.g. dry sand or earth), then
place in a chemical waste container.

7. Handling and storage

Handling
Technical Measures: Avoid contact with eyes, skin and clothing. Wear personal
protective equipment (See Section 8). Wash thoroughly after
handling.
Ventilation Use with adequate ventilation.
requirements:
Precautions: No information.
Precautions for safe Do not breathe dust/fume/gas/mist/vapours/spray.
handling:
Do not eat, drink or smoke when using this product.
Storage
Storage Conditions: Keep container tightly closed. Store in a cool and dry place.
Keep away from incompatible substances(See Section 10).
Safety adequate No information.
container materials:

8. Exposure controls/personal protection

Appropriate engineering controls: Use process enclosures or local exhaust ventilation.

Control parameters
ACGIH EU - OEL
Ingredient Name
TLV-TWA TLV-STEL STEL TWA
Ethylene glycol None 100mg/m3 40ppm, 20ppm,
establis [C] 104mg/m3 52mg/m3
hed
2,7-Naphthalenedisulfonicacid,5-[[4-chloro-6-(ethylphenylamino)- None None None None
1,3,5-triazin-2-yl]amino]-4-hydroxy-3-[2-(2- establis establis establis establis
sulfophenyl)diazenyl]-,sodium salt (1:3) hed hed hed hed
 (3／4)
SAFETY DATA SHEET
MSDS: 2013038010EU
Date Prepared: 2013/09/10
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Pink

Personal Protective Equipment

Respiratory Protection: Not required under normal conditions.
Hand protection: Impervious gloves should be worn.
Eye/face protection: Splash goggles should be worn.
Skin Protection: Not required under normal conditions.

9. Physical and chemical properties

Product
Physical state: Liquid
Form: Liquid
Color: Colored
Odor: Slight characteristic odor
pH: Approx.6－8
Flash point: None
Specific Gravity: Unknown
Solubility: water：Completely soluble.

10. Stability and reactivity

Chemical stability: Stable.
Possibility of hazardous No Information.
reactions:
Conditions to avoid: No Information.
Incompatible materials: Oxidizers
Hazardous decomposition Carbon monoxide, Carbon dioxide
products:

11. Toxicological information

Product
No Data
Ingredient
Ethylene glycol
Acute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]
Skin corrosion/irritation: Mild [rabbit]
Serious eye damage/irritation: Mild [rabbit]
Mutagenicity: Ames Test:Negative, Chromosomal aberration test:Negative
 (4／4)
SAFETY DATA SHEET
MSDS: 2013038010EU
Date Prepared: 2013/09/10
Date Revised:

Product Name: REACTIVE DYE INK TYPE-P Pink

12. Ecological information

Product
No Data
Ingredient
Ethylene glycol
Ecotoxicity
Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]
Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna]
Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]
Persistence and degradability： Readily biodegradable

13. Disposal considerations

Disposal When disposing of the waste or recovered material, consult federal, state and/or local
methods: regulations for the proper disposal method.

14. Transport information

UN Class UN ---
classification：
UN number： ---
Proper shipping ---
name：
Packing group： ---

15. Regulatory information

Labeling according EEC-Regulations: No labels required.

16. Other information

Disclaimer The above information is believed to be accurate and represents the best
information currently available to our company. However, our company make
no warranty with respect to such information, and our company assume no
liability resulting from its use. Users should make their own investigation
to determine the suitability of the information for their particular
purposes.