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  • 솔-젤 법으로 만든 Peo-liclo4에 기초한 고분자 전해질의 물성

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    12 views6 pages

    솔-젤 법으로 만든 Peo-liclo4에 기초한 고분자 전해질의 물성

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    Polymer (Korea), Vol. 27, No. 3, pp 265: 2003) 4-4 Yos WE PEO-LiCIO,a 712% DHA Daas] B49 wast Brats $43} i (20024 34 268 BF, 200341 54 152 AD Properties of Polymer Electrolytes based on PEO-LiC1Os Matrix Fabricated by Sol-Gel Process Young-Wook Park ' and Dong-Sung Lee Department of Polymer Science & Engineering, Engineering Research Institute, Gyeongsang National University, Jinju 660-701, Korea ‘e-mail : ywpark@nongae.gsnu.ac-kr (Recetved March 26, 2002;accepted May 15, 2003) 2B Des AS BE ole BESS HIE AM Ut 7 Ba heel de U.S SHE oe ees Yehael rz, aa, shal, a7] sles pet Sas ale St A) BAAS}, TAAL SAD IE De APSO) Aly Sol ge}. B AE PEOLICIO, (S = Hell 712 @ WAL DEA AeHzo) Lay e} La} ohd Da) Boe reas) WLS she Alebea} VPS WIAA le ALS} Aa SAS S71= oll ga Aoleh. ole ase Aeey deh ah SEF 7] AF 25-10" Ss cm! AES URSA Uebt etl, ole Val Wesllal 2aS ADS] GE 7H AS} MAM ol He oe ALES Q7] sale} chyeh BAF (600~ 8000) 71) AS EtrssAy, de} eto) Use Teich Bo} 27}s} asl Me} Beto] cle} ee Aas JAR PEO": FAQLE. why SC Bal tH VMs, TIE TS] ico. B71 BY DEA} Hd] IRS FAH t+ sAgket. AAS FAD ABSTRACT : In spite of high ionic conductivity, the polymer gels have poor mechanical propesties and high reactivity with Ihium metal anode. To solve these problems, the dry solid systems and polymer composites have been intensively studied, due to their good mechanical, thermal, chemical, and electrochemical stability. The objectives of this experiment were to improve ionic conductivity and mechanical properties of the solid polymer electrolytes based on PEO-LiCIO, To obtain higher ionic conductivity and beser mechanical properties, ceramic or rubber phase was added inthe PEO-LiCIO, (8 : 1) matrix. The results showed thet ionie conductivity and mechanical properties were improved. The fonic conductivity ofthe samples was as high as 10°S em. Tis value is similar to the best ionie conductivity ever reported inthe solid drying system. To obtain better results, we used PEO with various ‘molecular weights (600~8000) and changed the salt contens. By using DSC, we found that the addition of salt reduced the crystallinity of PEO. The mobility of polymer dependence on salt contents was examined by FT-IR Keywords : polymer electrolytes, polymer composites, PEO-LiCIOg ionic conductivity. 265 LAS 1973 Wright So} 28H Fekete R411) PRO, Wes F Bel) dee alae Sa Ff PEO 718 E EAp aside He ait AAA So) AES ARS) PAS 19789 Armandsl a4 yal Zehoaeette] B49 Hebe] Seo, ATA AS, 200348, pp 265.270 LIA FeAl olFoHok VISA Blas) Az] B82 = Alsace}? wright7} PEO-F-7] @ 4b Ug USES Me oF, PEO UIA oe AEA DYASA Busty tesla sea, PEO" ERE P71 B&F Belz, Hele fg & 2 olSA)21 Rt oh fe} PEOAHII7} C-C, C0, CH ARES PPAR glo} WS-do) oe woh seh, at 265, 266 Park and Lee A Bos Wasp] welch” Ase ee Ay AS 7h PEOR FQQOS Ala ole AS 57} xe R28) 2 ole TeAPE Pasa we A Aaias| SPA Vs} Sel Ase] Bad LS; a Ae] AS Se] WAM Boles 4 A ols] vi7| welch! aba AeHaell wleklaby eis} EAHeo] US PEGH Ze Mts] 7}2A1S PEO-F 7Ael AMA Bast 22S Ae lee VSD BEA AES) SAS STA OE ALES ¥e] = pve) Arsh] BH eo] Ye ole AeSe Ass] Shia + 24, 71a S49) Ach TALE, Lig W439) wed S74 se Se Hed Adel Azle, aa 7H eel AAS) He Goede clas yt Aas Aa) ey) a] aed ae} alias] Bala Sas MA ee, Aa) ee 4 Azle A > Bal act ay) AAS ave] dod] ole AS ES Sel7] Ae dee] apse, le ate] of d Ux a7)s] Za 7a tse Zee” PEO-@ 712e Ale] 7s ole AESS S7t AZ, Et NAA S48= S7vlale. S, stttah AWA Uo ee BVAS 719A FUsp War So] she ale}o] abs] S4he za] aes] 2a4 & Boze] ee) ole ALES S7y[zeh. zea} AAge| AASe) AI Ae ARS Bz AAS a 7) Heo) 7 S82) SS 7) Echt a Sa 9] ole ASA teahel ASS|e WE PEO-A 712 of tee) he teh BAl7la, eal he 2 Wy Sao] FBSA + V7) Heelch ole Ae ES MH 717] At HE Yuose Us] Sez A, FOU BS) SH, SU BAS Be EA Etehe ae] Be" weap Bella + she re] do) a7edeha aE Waa ole AE BE BAM ve AHF VS O12) 7b SRE 7| Beolep ebey Bea + Me Beh | Pe a °) Wo ole ASSES Bhshew, 2 OE a4al Be] BS let BA ASS] else) B Ls} 77h Uy) eehAID, AWA SSF VS ] Bee) YF S74 oles} bse) tetad zz, o] = spit WIAA 7hLS] AAS Ap) wheel HH As) EUS SAAS De} Alea) ole ASSES FV + ME, IAs PeO-S Jolie] S42] SS UH AAAS FVVLS BHA o} 251 15] 4H si ey] ded Aes Agyslea o. Cee: Bebo she alae Sashes ale 266 IS, 1S Polymer (Korea), Vo. 27, No. 3, 2003 HA lobe 7d A Bap }S} PEGE are 2} SARE ASHE lee Sy, be Babes} PEG. = HS EGS) PEON Heh AAS APs} eo} o} 29 SS Uae] be MSS hd BS Fo) ole AEE Sd $ Ve Belek BPE tetraethyl orthosilicate (TEOS)S *}8-8}9} PEO-LICIO, o] 7128 Ba] BRA AML oe) Sl BAL o} SAE Aeb2] AL Gilicay2} BAS} diethoxydimethy silane (DEDMS)S AHERE BF AE PDMS)S| Alo} BRE 2 oleh Mets] ALE ole: asxs} 7lalaiel He) Bb © SoH B71 sey Saleletsr, wy Ae 7a a 21 QS sel Salsighea ole ee Alesha ak 2 ae mS. ELFRE ZAPF (600,100, 2000, 8000) 7+4l poly(ethylene glycol) (PEG)3} 420] $x 10° 744) = poly(ethylene oxide) (PEO)S AHS}. Bis obi) EUED 09.8%, HE ASAS, ASIAS 3-alycidoxypropyltrimethoxysilane (98%) AHESESIEL 2.25 lithium perchrolate (LiCIO,)S AHESHRLM), 14- diazabieyclo [2.2.2}-octane (98%, triethylene diamine) &- & AHS}. PEO-LICIO, 7141 SoH H}e}2) 4 (SiO. 3 AVg417171 $13}¢4 tetraethyl orthosilicate (98%, TEOS)S ASAI, TR A (PDMS)S 4B494)7171 HH dieth- oxydimethyl silane (97%, DEDMS)& 18-2131¢4. ©}2]=i] ‘Zeke (9.5%)& TEOSS} DEDMSS] 74> YH SH BABE 2 BU] LE ALE Aldrich4hol) AL TURE ASS AHS Sha. PEO-ASBAS| WY. Ie] eb} Seis A AS] AP} FeAl Bao] eS PEOS #akyo] Ye PEGE YT, 70 CBee Baal ASAs LEAMA 244121 Stk ARAL F, Hone LAdia zabicyclof2.2.2joctane (98%) AA7HPSACL ol sh, SoH 7} SaHe RS We] she} SEE WE VIS HAVMCL AS F uber sepum2Z HAA eps, Als N27} AMA She LESAN Bach. Sule) oF MEMYIEDS FAVE 0]B844] PEOS PEG7} oF Qe Seta Ya, 50 TE 2g ea web) HVA BAF] SAH}zeh. SoHo] als] L8H PEO 3} PEG} Se] Re S4AAS WS wa) 4, ABBA 3-glycidoxypropyltrimethoxysilaneS 77+ ‘Bh. (PEO, PEG} AEA) UbsEo) Sel he Bees S 50~60 C3] 7H wel} AZ Sek BAY Belo}, 27a A328, 200348 Polymer (Korea), Vol. 27, No 3, 2003 “AA abs lz US 38h ZEA} Bd (nanocomposite polymer electrotytes)*} AI. (PEO, PEG)” 7) ehsEe) S o} LE Be}AZel) [EO] [LiJS] weed 8:1 Fh 161 9} SY) Licloc W717 12412 Sk USAC. 4 431 G2) TEOSS} DEDMSS 47}8}31, 7s} + MESS 41717] 98H acetonitriles] £24411 diethyl- amine2} Ee Ala Qube Beh o}ee whe ol ase) GA Me Ayes 2 CS Hal Bea} arly 1-212 Seb EM F YA ASE Bale Rs, 80 TS yaa WSAz 2 olAl 244121 Sb HA1AIA PEO-LICIO, 71220 2eN7t 3} PDMS7} B48 USA ea we} aaaS ae Re. ae} zal DEA} Aaa Sool qe 24 S Se)7] AW SoH AS AMeehed, E ATMA = ASVAS Peos} ZF WS)7/7) Fai, aaa $7 S45] DE TUS 1A BUS ALSshaeh. HP} RelA] ASAS LES Bel Bos shad] seeu] Selo) Ae LAS gel Wesel ARGS 4 S98 ey) Wi ASAS 2B Based. AIRE] LARS 717], FT-IR #15} MattsonA}2} Genesis Tl FTAR B971E lSeto] Hy EAS sch. Soy FOS) ARS NaCl Ho Se]st AeA1Al Fol] IRS SIS FI. NaCHS Ahh HRS Aad F, Bale 2 HOe ays dela +s Ae zbss] ach 89 49] ARS ob ve Fo) AGAMA toy 1— 212 BE FO] SoS Bas) AAA! Fol Sse} AM. DSC : #}5% TA Instruments2} DSC 20108 AHE-3}3h Sal, 50 C 74] LES Hel7] sete} al WAS o} Seth HS BS Be] ARS AeA), S 4 SS WANE 0-10 T, Se FEE HY 10 TH AGARLA, Wa AAS BS 50mLE Se] Hsieh oe ASE: AWE AE AV 4s S aA ole ASSES S¥eiga, ARE Uae PS 7H AS Ble Wedd oe Aes Sas At al abe 4 (D7 eh ‘Thickness (em) (Siem = Thickness (em) Se) = Rea Area (on) a) oA, oF HRAEES YEH, RE SAR AD WS Yebdet. Bajo, A278 AB#, 200318 Properties of Polymer Electrolytes 267 3. 23} BE FT-IR 49. PEOS} Sit} PDMS22} @13}¢}e] ¢F 28 5 Ae Mache ASVA) Base, ASS A\7} 4445) PEO Scheme 1ei]4] 83 ¥}S} Ze] PEO HF ARAN U9] WSOs yc WSS TF ao} al eb] Hay Suilel Ezlolel cholopele zest ROM, SIZE evIEUEAS Asset LS 2) PAS Hal 60 TS 7A 2~39 Sek es] Beh PEO-AS AT USSE Use] Bal aS AAA] BX7) HE ©] FPgoAy A] HPSS °] Sahat} AAS} BE AUS Re Wes Bp ath ols} HE wos Used] AVES Assay QU AW )S 7H Peo} S44, 0] Bebe 7 ee ¥ Figure 194] Bole ube} Zo] Atal FZ SiO, PDMSS}2] SR} MES OS ABA} 724) Aah & EAN AH leh Figure 19] (a PEO-S ALE Ap) tHE] FRE Uebel Weed, agit 7 wal ARS shn PEOV} WHZEQS FRE sz gh SS BolECh (OE PEO-oIs}4] deb 4 4}7H9]) DEDMS 2} 34541 oligomeric PDMSE 47HE B43 Gepac, (y= (a)*] FE] PDMS} F Beto BA B+, Su ade 24, 242 28bb] de 374] Beh shoe aL + gaan rs fear ata ie eat o-acat-ot- faa bau ‘A om ‘Foca ahon atta -ct-ar-ct- Fon, ‘Scheme 1. Synthesis of PEO with epoxysilane coupling agent. 7 ro IN & oo. Nao (@)PE0-poeslne compose (2) PEO-ponslne compose wih POMS Figure 1. The Condensed Proc of PEO

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