Class: 11 Subject: Chemistry

Name____________________________ Date: _____________

WORKSHEET -2

PLANKS QUANTUM THEORY AND HYDROGEN SPECTRUM

1. The wavelength of a spectral line for an electronic transition is inversely

proportional to :
(1) number of electrons undergoing transition
(2) the nuclear charge of the atom
(3) the velocity of an electron undergoing transition
(4) the difference in the energy involved in the transition

2. The transition from the third shell to any other shell is known as
(a) Balmer series
(b) Paschen series
(c ) Pfund series
(d) None of the above
3. Atomic hydrogen displays
(a) Emission spectrum
(b) Absorption spectrum
(c ) Dispersion spectrum
(d) None of the above
4. Wavelength of spectral line emitted is inversely proportional to
(a) Radius
(b) Energy
(c) Velocity
(d) Quantum number

5. What is the wavelength of light emitted when the electron in a hydrogen atom
transitions from an energy level with n = 4 to an energy level with n = 2?
(Ans: 𝝀 = 4.86 X 10−5 cm)
𝝀 = 486 X 10−9 m)
6. The energy of a photon of red light is 2.84×10−19J. What is its frequency?
(A: 4.29×1014Hz)
 Absorption and Emission Spectra:
7.Calculate the wavelength of the spectral line in Lyman series corresponding to n 2
=3.
A: ( 102.6nm)
8. Calculate the wavelength of the spectral line obtained in the spectrum of Li2+ ion
when the transition takes place between two levels whose sum is four and difference
is 2.
A : (1.14x10-6cm)
9.Calculate the frequency and wave number of the radiation emitted when an
electron in hydrogen atom returns from fifth energy level to second energy level.
A: ( 6.91 x1014Hz, 2.30x 106 m-1)
1. Emission transitions in the Paschen series end at the orbit n=3 and start from
orbit n and can be represented as ν = 3.29 x 1015 [1/32 -1/n2]. Calculate the value
of n if the transition is observed at 1285nm. Find the region of the spectrum.
A: (n=5, infrared region)