an @ Oe = FOR NEET 2023 Haloalkanes & bikes 2 Haloarenes-03 / + © & Todays Goal Properties of Haloalkanes part 2 aes CE Ue oe EO + + Pes—osn' fa Effect of Solvent in NSR} pas — sn fav PAS PPS CPolor frtab'e Solvent ) ‘ola bic sohent fe (r 9 or Se Hina ° uda bh Q caaliee Oe DA Juda hows. ° S Drsd Dine Hay! E suid oR ethers H-d w-me Dith | Ws dl oa op Hi roe por ° ReA e Rearedt = Nor a CPTI iP Rebubsion Nu > oor” qo Ph 2. E? ( Abrendy done in Mop of, atkene) v ogee “O+6+ 0, © is me veactwe tan @) 4@ ™ OS P+ ®>® 3. E'cb Ce Via Conjugate Bate form Alk ¥y oben Stoble ae Munor Moye Biss Ay e op point Etc. © Carbamon intermediate @ move stable Carbouon will decile the Rey odd ® Yor x stability of, Conbownon @ +48 Ccaabomor)”a Ph-cH= HHL, esis —> Ph- Gk CH= OL Minow 4. Reaction with metals a. Wurtz Reaction 2 RIK SN, RR et Rt Ra RR b. Wurtz-fittig Reaction en}. Ca) —> 49) c. Fittig Reaction bytes (0 (5) d. Ulmann Reaction oth PSs 6) y® a oe ee BU Gy ate oe a a a oN gc He, Gal, Gore mS ® Nal 3Cd, hy er w/t ®+® ®VE sr ® [he Cyt phe pho, cu, a fi By Ce Mele Rr dy pov duble bongNucleophilicity RO > ROH 9 RS > RSH e ‘or 2 Hy, > WH > Our (PPS) Size CON FO>FE Choage —Jh - dui il SOS Solvoliom CoNrer>T (PAS) Size Feuceret iSize Feuceret OA 1 Onage PRIN IT ‘ 72> BY "7 as cope t deat F 7 RO ROT Solv F> Uoavrr ! Rebulsion Ff dseyoT Nu F H-o-H Figg > REE RY BER ReO-O-R } ROR5. Nucleophilicity is inversely proportional to steric hinder: On 3 So ' o aoc > OH ¢ —o oH, ho ben oon band , arr R-x Foc 8 corer Jenvin Leaving ability AstecHacrareHe BEY Lead Stronger is Ene conjugate ae acid better is the leaving ee SN; mechanism (Dorzen's Reactio,) Sod, pntraenalecale co fi SEER Rocke SO Tp HEED SOF KR Q Ww mech ft ° on O- See, FH HUT BO. \ op points TL Pyridine % ured the Inversion occurs — ° eV °op point + Ih Pywicine % ured the Inversion occurs +t O ° R-o-faeul Vig PES R-o- dat Hee Sale ° Q tt Pe or poe Ska > URt o= s+? Properties of Haloarenes 1. NSR in Aryl halide x () ne. No RanReasons 1. Due to partial double bond character b/w C and X ET Bax Halk” double Gond === ===> qe O adn Shong ond 3. Due to difference in hybridization of Carbon of C-X bond sch — +S Sp* sph Si Lxjo Lxwo Ti ze 3 St 4 “&- = 254. 33:33. so] 1ST ENT Addaty Sat —> Acid Dow’s Process Ps aH OH yack Naor a Co) Cana 4° OH iG = + n-n NO. Phong HO. phot 623K 00h 623K 200 aby a CS" e.g 0 on | o Bonds Os © in® “Ina S,2 substitution reaction of the type R-Br+cl —“! 5R-Cl +Br Which one of the following has the highest relative rate? (CBSE AIPMT 2008) © A.| CH, ~CH,~CH,Br CH, ~CH ~CH,Br CH; CH3 1 BY enon Hy [Question Which of the following undergoes nucleophilic substitution“&#etnttvely by(S, ) mechanism? (CBSE AIPMT 2005); Ph- HC A Benzyl chloride . Ethyl chloride [e] | Chlorobenzene . Isopropyl chloride Phe («Ce rs i A Question z Reactivity order of halides for dehydrohalogeffation is (CBSE AIPMT 2002) ; A.) R- F>R-Cl>R-Br>R-I [BY ttsn-neoncarnt C.] R-l>R-c>R-er>R-F [D.| R-F>R-1>R-Br>R-CI Question itis 2-bromopentane is rea ethoxide in ethanol. The major product obtained is Ms eK BSEAIPMT 1998) z “Vs A. | 2-ethoxypentane | pentene-1 Ir] [CY trans-pentene-2 .| — cis-pentene-2 Taian sl.The alkyl halide is converted into an alcohol by (CBSE AIPMT 1997) R-x~— R-OH A.| Addition [ substitution jocbinlae C. | Dehydrohalogenation D.| elimination Question The major product of the following chemical reaction is weerQo2i)) CHs {CoHgC0),0, >CH—CH=CH,+HBr 5 » CHs~ a Ati cnet CH, CH, A en oom Hy ot OH CHO COC Hs 3 3 CH. Chs. C. >CH-CH—CH; . >CBr—CHy—CHy CHy 1 CH Br 5 CH; —CH2 —CH-CH3 obtained by chlorination of n-butane will be cl a d-form 2} form (2001) ce of anhydrous [1993] A 3-propyl-1-chi@p cee 5 | n-propyibenzene aS a no reaction + B isopropylbenze AGS tb 0 Any Alt, Cumene —