- General Instruction: 4 (2) All questions are compulsory. — (2) Q. No. 1 to 5 are very short answer type, carrying 1 (3) Q. No. 6 to 12 are short answer type, carrying 2 marks (4) Q. No. 13 to 24 are also short answer type, carrying 3 m (5) Q. No. 25 to 27 are long answer type, carrying 5 marks each. (6) Use of calculators is not allowed, use log tables wherever SECTION- A . If ‘a’ is the length of the side of a cube, what will be the d ‘between the body centred atom and one comer atom in a cube: oR phosphorous. Give reasons. . What is meant by critical micelle concentration? pungent smell is evolved which decolourises acid Identify the gas. | Write IUPAC name of the given compound: Scanned with ComScanner8) HS, tt) xeo, ‘Scanned with CamSeannerent with dentistry 10 g om* forms length of 3 X 10cm. What is the nature of the cubic atomic mass of the element is 81 gmol”? 12. Calculate the freezing point of solution when 2 g of Na,SO, ( mass = 142 g mol") was dissolved in 50 g of water, assuming Na,SO, — undergoes complete ionisation. (k, for water = 1.86 K Kg mot”) SECTION- C 13. The emf of a cell corresponding to the reaction Zn(s)+ 2H" (aq) > Zn" (0.1M)+ H,(g,latm) is 0.28 V at 25°C. write the half-cell reactions and calculate the pH of the solution at the hydrogen electrode. (Given: B2.,,, =-0.76V) OR Caloulate the cell emf at 25°C for the following cell: ‘Mg(s)|Mg* (0.0141) [Sn (0.11) [Sn [Given Beng» =-2.34v,E°Sn'™ = -0.136V, F = 96500em!"} the maximum work that can be accomplished by the operatis cell. : 14. Give reasons for the following observations: (i) Physisorption decreases with increase in ere a ‘Scanned with CamSeanner18. Give reasons for the followings: ©) Ethyliodide under (i) @)2-Butanol is (iii) bond 1 in cu,-x, Boes S,2 reaction faster than e thylbromide, optically inactive, “neth in halobenzene is smaller than C-X bond ‘Scanned with CamSeanner(a) propanal and propanone. (b) Butan 2- one and hexam-3-one (c) phenol and bengoic acid. 20. How do you convert the following: ( Aniline to benzene? (i) Ethanamide to Methanamine. (éii) Nitrobenzene to Aniline? 21. (a) give a example of i) Natural polymer. (ii) Chain growth polymerisation. attraction. Nylon - 6, Buna - S, PVC (c) What is meant by vulcanisation of rubber? 22. (a) What is the advantage of soap over detergent? (b) What are non-ionic detergents? Give their use.OR (a) For areaction, A+B ———-> P, the rate is given by Rate = k[A] [BJ (i) How is the rate of reaction affected if the concentration of B is doubled? (8) What is the overall order of reaction if A is present in large excess? (©) A first order reaction takes 23.1 minutes of 50% completion, Celculate the time required for 75% completion of this reaction. (log2. =0:3010,1og3=0.4771,10¢4=0.6021) SECTION- D 25. (a) Complete the following equations: (i) MnO; +¢,0? +” ——-> ~ (i) Cor +oH- —_s (b) Explain the following: (i) There is in general, an increase in the den: titanium (Z = 22) to copper (229). (i) There occurs much more frequent metal ‘compounds of heavy transition elements. Git) Most of the transition metal fons exhibit ir aqueous solution, se sity of elements ‘Scanned with CamSeannermembers in the middle of a transition ser agent but Mn’*ion is an oxidising agent. ign (iii) Actioned contraction is greater than lanthanoid contracti 26. (a) Although phenoxide ion has more number of reson: structures than carboxylate ion, still carboxylic acid is a stronger acid than phenol. Give two reasons. (b) How will you bring about the following conversions? (i) Propanone to propane. (ii) Benzoyl chloride to benzaldehyde. (iii) Ethanol to but - 2 - enal. & (a) Write the reactions involved in the following: () Btard reaction. (i) Stephen reduction. (b) How will you convert the following in not more than two steps: (i) Benzoic acid to benzaldehyde? (ii) Acetophenone to benzoic acid? (iii) Bthanoic acid to 2 - Hydroxyethanoic acid? 27. (a) Why does calculation based on lowering in fre solutions sometimes give abnormal molar man (b) How many the equations for the related ‘Scanned with CamSeanner01 duct ty of 0.2M Solution lculate its Molet Conductivity, °) How much elec Ctr ~ Lmol of Hy icity is Tequired j 1M co Oto x, (ii) 1 mol of Peg to F ‘Scanned with CamSeanner‘Scanned with CamSeannerGive reason for the following : ©) Nitti Oxide becomes brown when released in air, Gi) Ammonia acts as a Ligand, 10. State Henry's Law and mention Some of its important application? Ni. Vapour Pressure of pure liquids A and B are 70 mm of Hg and 90 mm of He respectively a 25°C. The mole fraction of A in the solution of A and B is 0.3 assuming ideal calculate partial pressure of A and B present in equilibrium with the solution, 12. How are polymer classified into different categories on the basis of intermole Explain three of them and give one example of each. (i) What is adsorption isotherm? ‘Scanned with CamSeanner(i) Silver atoms has completely filled d-orbital (44'°) in its ground that its transition elements? (ii) Ce* is used as an oxidizing agent in volumetric analysis why? (ii) Which transition metals of 3 series exhibits the largest number of 07 \Write down the IUPAC name for each of the following complexes and’ state and coordination number ofthe complex. @ [CrChy)s] (ii) KafMa(CN)o] (iii) Cs[FeCla} How will you convert : ‘Scanned with CamScanner1) //Fe* (0.01 My / Fe er=—0.75y; Entre =—0.45y) Se in order of boiling Points ;‘Scanned with CamScanner0) P meron? and pentanone-3, © Aniline and nitrobenzene, (@ Benzaldehyde and acetophenone, (©) Methanol and benzaldehyde, (@) Complete the following : @ eH cone.KOH 0 Gi) CH;-cooH —822_, CHO (ii) HNOs/H,S0, (b) Write down the chemical reaction () Clemensen Reduction ie ‘Scanned with CamSeanner(Write your Roll No. on the top immediately on receipt of this question paper.) General Instructions : (1) All questions are compulsory. (2) Question nos. 1 t0 5 are very short answer questions and carry 1 mark each. (8) Question nos. 6 10 10 are short answer questions and carry 2 marks each. (4) Question nos. 11 to 22 are also short answer questions and carry 3 marks Question nos. 23 is a value based questions and carry 4 marks. (6) Question nos. 24 to 26 are long answer questions and carry 5 marks (2) Use log tables if necessary, use of calculators is not allowed. Section-A ‘What is the formula of a compound in which the element Y fo occupy 2/3rd of octahedral voids? ‘Write the IUPAC name of the compound canned with CamScannerDefine the following terms : (@) Limiting motar conductivity (6) Fuel Cell Define the following terms : @ Activation energy ()_ Rate constant. ‘Complete the following chemical ‘equations ; Scanned with CamScanner= TUPAC name of the complex (6 iit ‘7 Draw the structures of the isomers. Resistance of a conductivity cell filled with 0.4 mol resistance of the same cell when filled with 0.02 mol / L KCL: solutior ‘the ity and molar conductivity of 0.02 moV/L KCL solution. TI mol/L. KCL'solution is 1.29 102 24cm. ‘A first order reaction takes 10 minutes for 25% decomposition. Calculate ty (Given Log 2 = 0.3010, log 30.4771, log 40.6021). . OR (@ Fora chemical reaction R —>P, the variation in the concentration, In [Rvs given as t{s] () Predict the order of the reaction, (i) Whats the slope of the curve? ii) Write the unit of rate constant for this reaction. R-7/Code-731/XI (ya wed with CamSeannerSbH). BiH, - (inereasing basic Character) Draw the structures of the following compounds : @ Xer, (ii) N,0, ed phosphorus, '$ 60 g/mol) has a density of 6,23 g/cm? Identify the type. Som. (>) Write structural difference between white and An clement X (molar mas unit cell, if the edge length of the unit cell is 4x10" (2) Write the Mechanism of the following reaction Alkene toAlcohols by acid catalysed hydration, (©) Wiite the equation involved in Reimer Tiemann reaction, Write the structures of main products when benzene diazonium chloride (¢ with following Teagents ; i) HBF,/A (i) Cusp Scanned with ComScanner@ Terylene (ii) Bakelite (ii) Buna-S 8] ee (i) What are disinfectants? Give an example. +1] (Gi) Give two examples of macromolecules that are chosen as drug targets, Gii) What are anionic detergents ? Give ane example. A Bam visited Shimla and while crossing an old bridge they observed a factory v chimney at river bank. He is wo:tied to see too much smoke coming out from chi bic being a science student gave some suggestions to the factory owner and Tocal B] regarding this dangerous situation. Answer the following = () What type of colloid is smoke? (ii) Ram suggested to use electrical smoke precipitator. Why? 1] (iii) Define electrophoresis. ae (iv) Write any two values shown by Ram. PA. (@) Define azeotropes. What types of azeotrope is formed by negath Raoult’s law? Give an example. (b) Calculate the mass of NaCl (molar mass 58.5 g/mol) to be dissolved in to lower the freezing point by 2°C, assuming that NaCl un dissociation. 7 iH (K; for water = 1.86 K kg/mol) Bevende V0 ‘Scanned with CamSeannerHow would you account for the following : —@) —_Actinoid contraction is greater than lanthanoid contraction, Gi) Transition metals form coloured. compounds, (i) The enthalpy of atomization is lowest for Zn in 3d series of the t elements, (©) How do you prepare KMn0, from Mn0,? OR (@) (Name the clement of 3d transition series which shows maximum oxidation states. Why does it show so ? ‘ (ii) Name a member of Transition series which is not consid element. (6) How do you prepare K,Cr,0; from FeCr0y, Bip: OH + Cl, (in presence of red P) Scanned with ComScanner‘Scanned with CamSeannerPaper No. 731 Time : 3 Hours Maximum Marks : 70 (rite your Roll No, on the top immediately on receipt of i uae General Instructions : (1) All questions are compulsory. a 8 @ Q. No. 1 t0 5 are very short answer questions and carry I mark each. Q. No. 6 to 10 are short answer questions and carty 02 marks each. Q. No. 11 to 22 are also short answer questions and carry 03 marks each. (5) Q. No. 23 is value based question and carry 04 marks, (© Q.No. 24 to 26 are of long answer questions and carry 5 marks each. (2 Use log tables, if necessary. Use of calculator is not allowed. ¥ (8) There is no over all choice in the paper. However there is an in question of 2 marks weightage and one question of 3 marks of 5 marks weightage. ‘What type of semiconductor is Ge doped with In ? ‘Write TUPAC name of Cumene. Arrange the following compounds in Scanned with ComScanner(Refor water is 1.86 K kg mo ') State Kohlrausch’s law, What is primary cell? Give an example, ; OR Define following terms : @ Re @) Molar Conductivity ‘What would be the units for K? ‘What is meant by rate constant K, ofa reaction ? (@) fora zero order reaction (ii) fora first order reaction Describe the role ofthe following; © NaCN in the extraction of silver ftom a silver ore. i) Todine in the refining of Titanium. What is the difference betwe example of each. Silver crystallites in a fee latice, Ifthe edge length of the unit cell 4.07 «10-8 of silver is 10.5 gem”. Calculate the atomic mass of silv en multimolecular and macromolecular col OR Scanned with ComScanner‘Scanned with CamSeanneraylose and amylopectin, Give an example of addition polymer, (i) Write also, monomer of PTFE, a Polymer used in Non-stick cookware, Give its il) Define Biodegradable polymer. Give example. Explain the following terms with an example : \® @ Disinfectant (ii) Artificial Sweetness (iii) Cationic detergents, 23. t solvent. However in spite of its benefits ‘o man, its impact on social S been questioned. Its considered as a curse in the lives of those, who sit lowers the metabolic rate and affects central nervous system, Now answer the following questions ; behaviour has alway: addicted to alcohol (® How denaturation of Ethanol is done? (i) Why Boiling point of ethanol is very high ? Git) As a student what initiative would you take fo "save life". Do not drink. (Any suggestions) 24. Draw the structures of the following : @ Xer, i) Holo, Complete the following reactions : ‘Scanned with CamScannertinoidWolf Kishner reaction, ‘Scanned with Camseanner‘Time : 3 Hours Maximum Marks : 70 + tet (Write your Roll No. on the top immediately on receipt of this question paper: General Instructions : () All questions are compulsory. (i) Question nos. 110 5 are very short answer questions and carry I mark each. (iii) Question nos. 6 to 10 are short answer questions and carry 2 marks each, i») Question nos. 11 to 22 are also short answer questions and carry 3 marks ae (0) Question no. 23 is a value based question and carry 4 marks. (x) Question nos. 24 10 26 are long answer questions and carry S marks each, (si) Use log table if necessary, use of calculator is not allowed. 1 ‘What is meant by the term ‘forbidden zone’ in reference to band theory of solids? 2-~ Which will react faster in SN? displacement, ‘-bromopentane or 2-bromopentane, eA why? Scanned with CemScannerCr(s) + Ca?* (aq) (eq) +3Ca(9), ree eee ork with respect oa esa, How i ts Concentration of the reactant is (i) doubled (ii) reduced to half? Oy" Draw the molecular Structures of the following compounds : (N05 (ii) XeoR, Le @) Write structure and TUPAC name of Aspirin, MG) Give preparation of Phenol from Cumene, Give mechanism of conversioa of alcohol into alkene, ; i Penner crystalises with face centred cubic unit cll, Ir the radius of co calculate the density of copper metal. (Atomic mass of Cu = 63.55 u and Avogadro's number Na = 6.02 Scanned with ComScanner‘Scanned with CamSeanner} the hybrid orbitals and the shape of the complex. iii) the magnetic behaviour of the complex. (iv) the number of geometrical isomers, (¥)_ whether there is an optical isomer also, and (vi) name of the complex. (At. no. of Fe = 26). 18. _Afiswer the following questions : Wat is meant by chirality of a compound? Give an eee G8) Which one of the following compounds is more easily hydrolysed by KO! CH3CHCICH)CH; or CH3CH,CH,Ct ‘Gii) Give the IUPAC name of the following compound : CHy=¢—CHyBr CH; 19. “Illustrate the following reactions gi Gabriel phthalimide synthesis ii) /A coupling reaction a a@- Tranquilisers GB) Food preservatives (ii) Synthetic detergents as thermal power stations, coal is bumt and steam is passed for el smoke produced is passed through electrostatic precipitators. Answer th om the basis of above information : i () Why is smoke passed through electrostatic precipitators ? (ii)_Inelectrostatie precipitator, which colloidal properties is used? iii) Which value is promoted by this use of electrostatic precipitators ? (iv) Mention ill effect of coal on environment, oa (a) Define the following terms : (i) van't Hoff factor {iy Mole fraction Eubullioscopic constantGi) MnOr+S0;2-4 H+ _, ; 2 Boplin the following observations: Transition elements and their compounds are known to act een Gi) The higher oxidation states are usually exhibited by the member s series of transition elements, Gi) "With same (4*) configuration Cr (iI is reducing whereas Mn OR Give reasons for the following : © Actinoids exhibit a much larger number of oxidation states than the (ii) There is hardly any increase in atomic size with j increasing atomic n transition metals, (iii) Zn** salts are white while Cu2* salts are blue, ; (iv) The enthalpies of atomization of transition elements are hi (v) Transition metals form a ‘number of interstitial ompo (a) Write a suitable chemical equation to Scanned with CemScanner(i), Benzaldehyde to benzophenone (b)/ Give reason: () Chiloro acetic acid is more acidic than acetic acid. f (ii) Carboxylic acid has more boiling point than corresponding alcohol. ‘Scanned with CamSeannerChemistry | Paper No. : 731 Time : 3 Hours Maximum Marks: 70 (Welte your Roll No. on the top immediately on receipt of this question paper.) Questions ‘Mention one property which is caused due to the presence of F-centres in a solid. Be Define cryoscopic constant or molal depression constant, 3. Why are powdered substances more effective adsorbent than their crystalline \ forms ? (OL 4. Why is it that only sulphide ore concentrated by froth floatation process? 1 5. Draw the structure formula of XeF4. 6. Give the disproportionation reaction of H3PO3.. a Write the TUPAC name of the compound : ° CHy—CH=¢— don CH ‘Draw the structural formula of the compound : 1-phenyl propan-l-one State the law co-relating the pressure of a gas its two application also, in ‘Scanned with CamScanner‘Write the mechanism of acid dehydration of ‘ethanol to yield ethene, Explain the following with an example : Reimer-Tiemann Teaction. Friedal - Crafts alkylation in anisole, Account for the following : ‘rmatic amines cannot be prepared by Gabriel phthalimide synthesis? PK value of aniline is more than that of methyl amine, OR How will you convert : Aniline into sulphanilic acid Toluene into p-amino toluene ‘Complete the following : wed with CamSeanner‘How do you explain : What are the Name of two purine base ? Account for the following Bithional is added to soap ? Diabetic patients are advised to take artificial sweetness instead sweetness. r Soaps do not work in hard water ? OR Explain the following with examples. ‘Tranquilizers Disinfectants, Narcotic analgesics. ‘the density of KBr is 2.75 g em. The length of edge of the u 654 pm, Predict the typeof cubic lattice to which unit cell of KBr belo [Atomic mass :K = 39, Br=80] Explain the following : Lyophilic sols Shape selective catalysis Aerosol. Explain the followin SF is kinetically inert Cf the nobel gases, only compound. canned with CamScanner[Cr (NH3)pCl, eay* Give one application of co-ordination compound in medicines, Describe the hybridization and magnetic Property of the following cor [Fe (H,0),]>* y The Government order directs the shopkeepers not to use polythene/PVC bg for delivering the customer's purchases, Name the different types of polythene available. Why did the Government impose such an order ? What are values involved in the Government order? Explain the following : Racemisation. Grignard's reagent should be Prepared under an hydrous conditions, OF the two bromo derivatives. CgHsCH(CH3)Br and CeHsCH( Which one is more reactive in Sy! reaction and why ? P ‘The rate of reaction, 2NO + Clz — 2NOCI is doubled when conce atratic Clz is doubled and it becomes eight times when concentration of b Cl are doubled. Deduce the order of reaction, Complete the following : (a) Crop +H*> (b) MnO4-+NO-+H* > wa29. (i) i} ‘Transition metals and their compounds catalysts. : ‘There is a greater range of oxidation state among the ; Janthanoids. OR Draw the structure of (a) Permanganate ion (b) —Dichromate ion ‘Assign reason for each of the following : (@) Zrand Hfhave almost identical sizes (b) Transition metal forms a number of interstitial compounds. (6) Among the lanthanoids, Ce (I) is easly oxidised to Ce (IV). siue Kohirausch's law of independent migration of fons and express the n conduetivity of ‘Magnesium chloride (MgCl) at infinite dilution in a ‘with Kohlrausch's law. Calculate the EME. of the cell. casca®* (0.10 M) | H* (0.20 M) /Pt, H9(0.5 atm) [Given : cd?*/Cd = - 0.403V] oR Give equation for the reaction taking place at cathode, reaction of lead storage cell when it is in use. ‘The conductivity of 0.001028 mol Le acetic aci¢ Calculate its dissociation constant if A°m for act Scanned with CemScanner(ii) | How will you bring about the following Conversions ; () Benzaldehyde to benzophenone (©) Benzoic acid from ethyl benzene (©) Butanoic acid from butanol,Question numbers I to 8 are very short answer questions, these in one word or about one sentence each. Question numbers 9 to 18 are short answer questions, question, C4 ‘Answer these in about 30 words each. Question numbers 19 to 27 are also short answer questions and carry 3 ma? Question numbers 28 to 30 are long answer questions carrying 5 marks these in about 70 words each. 6. Use Log Tables, if necessary. Use of calculators is not permitted. a Ee ‘A compound is formed by two clements X and Y. Atoms ‘of element Y (as : in cep array and atoms of clement X (as cations) occupy all octahedral voids of tetrahedral voids. What is the formula of compound? Naphthalene dissolve readily in benzene but sugar does not. Why? Fe(OH)s sol is more readily coagulated by NagPOq comparison to NaCl. 4, What is the main requirement for a metal to be refined by method of refining? 5 Name the state of hybridization of orbitais in XeF2 molecule. 6. Why does NO2 forms a dimer? Write the TUPAC name of the compound : (CH)3CCH:COOHL Draw the structural formula of 4-tetrabuty! State Raoult’ for a binary solution of jon as well how does it change‘Scanned with CamScanner20. Niobium erystalizes nee i the edge length of unit cell of niobium Qs Describe the following : (@ Dialysis i) Desorption ii) Peptisation 22. How will you account for the following corresponding period in group 15. (iii) All halogens are coloured. 23. Complete the following reactions : @ Fe+Hct + ‘Scanned with CamScannerline and rate constant? !) What is the order of reaction ? (ii) Derive the relation between half life of this reaction and the rate constant 28. (a) What is meant by lanthanoid contraction? What effect does it ( have on the chemi of the elements which follow lanthanoids? 4 (6) What happens when : @ Yellow coloured solution of potassium chromate is acidified, (ii) Dark green solution of p otassitum manganate is electrolytically oxidized, Aili) Green coloured Ferrous sulphate solution is treated with Potassium permanganate in acidic medium. Write relevant ionic equations only. ; OR "Assign reason for each of the following : (i) Transition elements exhibit variable oxidation states, (ii) Transition metal ions are usually coloured. ss Transition metals have high enthalapies of atomization, (iv) Cu* ion is unstable in aqueous solutions. (¥) ‘The E°Mn?*/Mn value for Mn is much more than expected from the t other elements in the series. Scanned with ComScannerfortis two compounds (B) and (C). Compound (B) a CIHKO which on oxidation with CrOs gives back compound Compound (C) is the sodium salt of the acid and when heated | yislds an aromatic hydrocarbon (D). Deduce the structures of (A), @ (D). Write the reactions involved. , (b) Describe the following giving linked chemical equations : (1) Aldol condensation, (i!) HVZ reaction. OR (a) Give chorafeal teste to distinguish between the following pairs of organic (i) Ethanal and propanal, (ii) Phenol and Benzoie acid. (b) How will you bring about the following conversions ? (i) Benzoie acid to Benzaldehyde, (ji) Bthanal to but-2-enal, (lil) Propanone to Propene. Scanned with ComScanner