Sree Ayyappa Public School Sector V, Bokaro Steel City, Jharkhand ~827006 PREBOARD - 01 EXAMINATON : 2022 23 SUB:- CHEMISTRY (043) SET-A F.M.:70 ‘Timing : 03 Hrs Date : 05.12.2022 General Instruction Read the following instructions carefully. There are 36 questions in this question paper with internal choice, SECTION A consists of 18 multiple-choice questions carrying 1 mark each. SECTION B consists of 7 very short answer questions carrying 2 marks each. SECTION C consists of 5 short answer questions carrying 3 marks each SECTION D consists of 2 ease- based questions carrying 4 marks each SECTION EF consists of 3 long answer questions carrying S marks each. {All questions are compulsory. Use of log tables and calculators isnot allowed SECTION Ql. Which of the following test/ reaction is given by aldehyde as well as Ketones? Upretingstert ()Tollen's Reageticst_ —(©)2,4DNP Test (6) Canizzaro reaction Q. — Theoxi ‘of totuene to benzenaldehyde by chromyl chloride is called (enescion(®)Ricier— Tiemann reaction (c) Stephen's reaction (2) Cannizao's eacton 3. _Themajor product of acid catalysed dehydration of 2-methyleyelohexane! is (a) 1 —methyleyclohexane (b) 1 —_methyleyclohexene (©) 1 cyclohexyl methanol (@) 1 methylene cyclohexane Q4. Which set of ions ‘exhibit specific colours? ‘Se =21, Ti= 22, V = 23, Mn =25, Fe = 26, Ni 18, Cu = 29 and Zn = 30 (@) So", Ti", Mn” (b) Se”, Zn”, Ni" (VV Fe" @m1 QS. KMnO, is colour due to: (a) d—d transition (b) charge transfer from ligand to metal (©) unpaired electrons in d — orbital of Mn (4) charge transfer from metal to ligand 96. Which ofthe fllowing wil give a white presipte upon reacting with AahOS? (@)Ki{Pr(en).Ch]_—_—_(b) [CoNH)Ch] G][CHHO)ICh _—_(@) [Fe(HOsCh] Q7. Rate constant ‘K’ for a certain reaction is 2.3 x 10° L mol" S* order of reaction is @o On 2 @3 Q8. The slope of the line shown in graph is equal to ee loe—| R Tine —_ K K b) ©) -— @-K S) © 3308, oats io Q9. The cell potential of cell 2 Ca(s) +2H"(0.1014)M > Ca*(0.1M)+ (0s) 4B SEED =-0.40 volt (@)040V. (b)044V () 048 V. (@050V Q10, The order of radioactive disintegration is (a0 (byt (2 (d)3 QU. The half cell reactions for the rusting of iron are 2H + HOrt 26 “> 10: E?= 123 V Fe" +28 > Fete) B= OY ‘AG? (in KJ mol!) > Fe+ 40g) + 29 Pe" + ROR (-76 (b)-322 @-12 12, Which ofthe following does not give HVZ reaction? (a) HCOOH (b) CH;COOH (c) CHsCt ffi:(c) change wit trol} (qd) remains constant for a ce! (@)change with temperature of lettO}Y um when alkaline KMnO. is treated with KI Todine ion (6) 105, (d) 100" tatement of a reason is given choose the correct out answer out of the following choices {@) Bott Azsertion (A) and Reason (R) are tru and Reason (R) isthe correct explanation of Assewt0t A). (3 path Assertion (A) and Reason (R are true but Reason (R) i nt the correct explanation of ‘Assertion (A) (©) __ Assertion (A) is true but Reason (R) is false (@)__ Assertion (A) is false but Reason (R) is tue, Q1S. Assertion (A): Mercury cell does not give steady potential Reason (R): Inthe cell reaction, ions are not involved in solution Q16. Assertion (A): If the activation energy of a reaction is zero, temperatu constant. Reason (R): Higher the activation energy faster is the reaction, Qi. aw RGD ‘square planar and diamagnetic. ceason (R): It has no unpaired electrons due to pressure of strong ligand. QI8. Assertion (A): Proteins are made up of ce ea ea eA, Reason (R): During denaturation, secondary and tertiary structure of proteins are destroyed. west SECTION B ‘A solution is obtained by mixing 400 gm of 30% and 50 gram of 20% solution by mass. Calculate the mass percentage of resulting solution. Calculate the mass of a non —rolatile solute (Molar mass 40 gram mol) which should be dissolved in 114 gram ‘octane to reduce its vapour pressure to 80% zero order. ‘A reaction is 2 order in A and zero order in B. (@ Write the differential rate equation. How is rate affected on increasing the concentration of A three time and B four times Write the electronic configuration of Ce" & Lr’* and calculate its magnetic moment on the basis of spin only formula. (Ce, Z= 58, Lr, Z= 103) Write structure of the product of the following reactions (lh 0- Cay : fo fn @ I aK ‘Arrange the following compounds in inereasing order their reactivity in nucleophilic adition (i) Ethanal, propanal, propanone, Butanone (i) Benzaldehyde, P~ Telualdehyde, P~ nitro benzenaldetyde Aceptophenone Write the IUPAC name of the following organi compounds (3) HiN-{CH.)-NH> (ii) (CH) NH SECT ire will have no effect on the rate reaction Cateulate the depression inthe freezing point of water, When 10 gram of CHsCH:CHCICOOH is aed 10250 gram of water. Kb = 1.4 x 10°, Ky= 1,86 K Kg mol, A first order reaction is 50% complete in 25 minutes. Ca (logs = 0.6990) Give the reasons for the following: ()____ The enthalpies of atomization of the transition metals are highs (6) Transition metals and many of their compounds show pramagneti. behaviour. (@) Cu ion is not stable in aqueous solutions. 29, Write only chemical equation ofthe following name reaction, Pek (a) Rosenmund reaction (b) Finkelstein reaction (c) Hoftimann bromamide degration reaction. Q30, What happens when D glucose is treated with the following reagents? (a) NH.OH (b) HNO,(Cone) (Hl ‘SECTION=D. “The following question ae case based question, Read the passage carefully ond Goi, Passage: Polysaccharides contain a large number of mead le slyeosidic linkages. These are the most commonly encoun are starch & cellulose. They mainly act as the food storage OF SH Pn culate the time 80% completion of the reaction.pape 33. @ ® @ (b) (a) (b) Answer the followi @ questions: Define aly linkage at are the components of. S of starch? Where at alveogen present in human body? Bisesile linkage held between two unit of glucose inthe cellulose? ire dependence of 1; ia ae Cf rate constant is described by Arrhenius equation K = Ae™ ‘Temperatu ‘The equation clearl : ly shows that incre increase in the rate of fiat Increase the t temperature or lowering of Ea will lead to an Creaeton and presence of catalyst lowers the activation energy by ‘Path for the reaction. According to collision theory, another factor Pe ieisr Which refers tothe orientation of macciia ae ‘modified Arrhenius equation, In a chemical ic is " changed? aon with rise in temperature by 30° then. How many times the rate constant is nearly What are the Arthenius parameter? Write the conditions of effective col ion. a SECTION —E Define Primary and Secondary cell. ‘Write only equation of the reactions which take place in lead storage battery OR Calculate the potential of hydrogen electrode in contact with a solution whose PH is 10 Define fuel cell. Write only chemical equation which are take place at cathode & anode in fuel cel. Define : (i) Chelating ligand i) Speetrochemical series Draw all isomers (geometrical & Optical) of (@[Cocixen);" (ii) [Cofen),]*" Gi) [Co(NH).CL]" OR ‘Write the an example of homoteptic and hetroleptic complex. Discuss the bonding nature, hyloridisation structure & magnetic property on the basis of V.B.T. (Any two) @ [Co(ox)s]* Gi) [Fe(CN) J Gi) [Ni(CO).} Give simple chemical tests to distinguish between the following pairs of compounds. (@ Phenol and Benzoic acid ii) Benzaldehyde and Acetophenone Give the formula / structure of A, B and C in the following reactions @ CH, - CH, - ee eee aaa CiH4NO, BIH Os yp SHH 9 OR Describe the following, () Aldol Condensation (i) Decarboxylation ‘An organie compound (A) (molecular formula C,Hjs03) was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and alcohol (C), oxidation of (C) with chromic acid produced (B), (C) on dehydration gives but-1-ene, Write equations for the reaction involved, feSree Ayyappa Public School presen telat Sey, tarand-2708 il = 01 EXAMINATON : 2022-23 SUB:- CHEMISTRY (04 Srp. :xi oe pate : 05.12.2022 F.M.:70 ‘General Instruction == vi Ter stented Read the lowing intrecions cre : re are 3 questions inthis question paper with intemal ct SINC PCRreNGA Getiesor thiniechoc questonscoryine oe gi vesyalan caress gertees cepa morta Ree iniiccuascryeg smc: a Saati a Se case- based questions avg 4 mat Ae me 2 snsists of 3 long answer questions: ‘ing Ti ca - al + __Useof og tables and calculators i not allowed QI. Which of the following aqueous solutions ere thet 2 aR sR ce SORES 51720 eee rrr etion was compete 32 minutes, 50% ofthe same reaction would completed in ee (©) 16min (@) 24min (a) POs, is reduced to PbSO,, at the cathode. is oxidis (POs eeeO PASO te gals ca, Ate sove se B : : x solution of H:S0. (4) All the above are true Q4. Which ofthe following alkyl halides will undergo Sy’ reaction most readily? = @CHACE OHNE a (©(CHsC-Br__(@) (CH), CL , oe conf Oc. tion element X in +3 vor state is [Ar]3d°. What is its atomic ‘number? _ é (6) 27 (24 Ee oxidising agent in alkaline medium, When alkaline KMnO, is teated with KI, iodide fon is @b (b)10" e) 105 a) 106 Q7, Ethanol can be converted into ethanal by ee a. (@) catalytic hydrogenation (b) treatment with LiAIH, (6) treatment with pyridinium chlorochromate (@) treatment with KMnOy app ‘acids present in insulin (a): (b) 25 (©) 50 (d) 51 Q9. EDTAisa {@) monodentate ligand (b) bidentate ligand (© ambidentate ligand (4) hexadentate ligan Q10. The formation of cyanohydrin from propanone is which type of reaction’ a (a) Electrophilic subs fitution (b) Nucleophilic substitution (c) Electrophilic addition (d) Nucleophilic addition QI1. The reagent which does not react with both, acetone and benzaldehyde (a) Sodium hydrogensulphite _ (b) Pheny! Ihydrazine (c) Fehling’s solution (4) Grignard reagent 12, The correct IUPAC name for CHy-CHCH, NHCH it (p Alglmethylamine (b)2-amino-tpentene (c) 4-aminopent |e (a N-methylprop-2-en-I-amine Q13. Which of the following naturally oceurring «aminoacids is optically inactive? (a) Glycine (b) Alanine (c) Leucine (@) Valine Q14. A solution of chloroform in diethyl ether: (@) obeys Raoult’s law (b) shows positive deviation from Raoults law (behaves like a near ideal solution Assertion and Reason {in the following questions (Q. No. 15 ~Q. No» of the following choices ‘Both Assertion (A) and Reason (R) are true Both Assertion (A) and Reas' put Reason (R) is not the correct explanatio “Assertion (A) is true “Assertion (A) is false @ (b) © () {@) shows a negative deviation from Raoult law 18), a statement of a reason is given and Reason (R) isthe correct explanation of Assertion (A). son (R) are true tion of Assertion (A) but Reason (R) is false. ‘but Reason (R) is true. choose the correct out answer out‘Oxalate ion is bidentate ligand. (Oxalate ion has two donor atoms. ‘Acetaldehyde undergoes aldol condensation with dil. NaOH. ‘Aldehydes which do not contain a-hydrogen undergoes aldol condensation, Assertion (A): Reason (R): Assertion (A): p-nitrophenol is more acidic than phenol. Nitro group helps in the stabilisation of the phenoxide fon by dispersal of negative ch. to resonance. Assertion (A): Osmotic pressure is a colligative property Reason (R): Osmotic pressure is directly proportional to motarty SECTION =B b formed by negative deviation from Raoul’s law? Give « Define azcotropes. What type of azeotrope example How much charge is required forthe following reduction: ie GI mol of Cu" to Cu? Gid] mol of MnO¢ to Mn"? For a chemical reaction R > P the variation in time (t) plot is given alongside. (@ Predict the order ofthe reaction, ii) What is the slope ofthe curve? InfR] Time Complete the following chemical reaction equations: (@ MnO, (aq) + T (aq) + H (aq) > (ii) Cry OF* (aq) +Fe™* (aq)+ H’ (aq) > Using IUPAC norms write the formulae for the following: (@ tris(ethane-1, 2-diamine) chromium (I1}) chloride (ii) Potassium tetrahydroxozincate(II) Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions. (@—Ethanal, Propanal, Propanone, Butanone (ii) __ Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone Predict, giving reasons, the order of basicity of the following compounds in @) gaseous phase and (Gi) in aqueous solutions (CHs)3N, (CHs): NH, CHsNH2, NH SECTION —C Calculate the boiling point of a solution when 3 g of Na;SOy, (M = 142 g mol) was dissolved in 50 g of water, assuming Na,SO, undergoes complete ionisation, (Kb for water = 0.52 K kg mol) Calculate the emf of the cell in which the following reaction takes place: Ni(s) + 2Ag” (0.002 M) >Ni** (0.160 M) + 2Ag(s) Given that E°cell = 1.05V [Given: log 2 = 0.3010, log 4= 0.6021] Give simple chemical tests to distinguish between the following pairs of compounds: (i) Propanal and Propanone (ii) Phenol and Benzoic acid (iii) Methylamine and dimethylamine The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co Ni Cu Zn Answer the following: (a) Which element has the highest m.p. and why? (b) Which clement is a strong oxidising agent in +3 oxidation state and why? (©) Which element is soft and why? Write the name, the structure and the magnetic behaviour of each one of the following complexes: (i) [PtONHs),CK(NO;)] ii) [Co(NHs)\Ch]CT Gili) [Ni(CO).) (i (At. nos. Co=27, Ni= 28, Pt=78) SECTION=D A ‘The following questions are case ~ based question, Read the passage carefully and answer the questions that follow: Q31. Passage: ; : Carbohydrates, proteins, nuclic acids, ee, form the ‘basis of fe and. are responsible. for the growth and maintenance of living systems. Therefore, they are referred to as biomolecules. Carbohydrates are widely distributed in nature, Carbohydrates are optically active polyhydroxy aldehydes or ketones or the ‘compounds which produce such units on hydrolysis. Glucose, fructose, suerose, starch, cellulose, ete. are some naturally occurring carbohydrates. 5 3 " They act as the major source of energy for animals and human beings: arena! are ic fcele carbohydrates that cannot be broken further into smaller units on hydrolysis, €8> 8 ae eee me etc, Oligosaccharides are the carbohydrates which on hydrolysis give two to ten units of monosaes “te at 25EE 5, cartoon, numberof monosaccharide aie seg Answer the following questions: ra ein Gi fh ranccbarde i found only in animals and not it pli carbohydrate is the main ea ane (6) White tne mana te tn conan of pnt ci wa on osetia aed yi of aoe sum Botetertt ere ne oF secu value of Kb. oy acl fletons on nitrogen atom due to which they behave as Lewis base. Larger the Pee nee agcE (Der fhe vale ot th stop eh ter, Amine ea er Basie Hn leholy thers, estes, ce: The nie chaste of alphatt amir hull nce ih he ieee of allyl subsituion. But k dors no ocr i eae manner t's cones auphatic “amine is unexpectedly more basic than a tertiary amine in solutions Aromatic amines ate weaker tases tan ammonia and aliphatic anincs. Elston donating troup sch sos OCH ew, Ss nsrease the basicity while electon-witiawing abnucns nich g-NOr-CN, hopes cs eco the basicity of amines. The effect of these substituents is more at p- than at m-positions. Answer the following questions (i) Arrange the following compounds in increasing order of their acidic strength: Methylamine, dimethylamine, aniline, N-methylaniline 6 Rearange the fllwing in inccaig are of hbase eng: Piolidne,NN-dimet-poludng penning, sine PRReeraeS cclaina omer (CHs),:NH is more basic than (CHs):N in an aqueous solution. Give reason. SECTION ~E State Kohlrausch law of independent migrs ‘What type of a battery is lead storage battery? Bata elie somone Rava wo Henry's aw? Define Order of reaction. Be carom contiurin ofc. oR ‘Arrange each set of compounds in the order of increasing boiling points. GN cer, Caeconahare, Dito chane ial eet ica (i) n-butyl chloride is treated with alcoholic KOH, (ii) bromobenzene is treated with Mg in the presence of dry ether, {ieee stresed with aqecous KOH, (iv) Write IUPAC name of isopropyl chloride. A first order reaction is 50% completed in 40 minutes at 300 K and in 20 minutes at 320 K. Calculate the activation energy of the reaction. log 2 = 0.3010, log 4= 0.6021, have been lysacchatides are the carbohydrates which 1 carbohydrates which produce a larg. ©, starch, cellulose, et. : a instant energy to the body? rate of formation of __Dimol L" min“ 01 I 60x 10 03 E 72x10" 2.88 x 107 2.40 10 Determine the rate law and the rate constant forthe reaction. Carry out the following conversions: Prnitrotoluene to 2-bromobenzoic acid __(b) Propanoic avid to acetic acid (ii) An alkene with molecular formula C;Ho on ozonolysis gives a mixture of two compounds, B and C. Compound B gives positive Febling test and also reacts with iodine and NaOH solution. Compound C does not ive Febling solution test but forms iodoform. Identify the compounds A, B and C with reaction.@®) Sree Ayyappa Public School Sector V, Bokaro Stee iy, harkhand - 827006 PREBOARD - 01 EXAMINATON : 2022 -23 SUB:- CHEMISTRY (043) STD. : XI Date : 05.12.2022 te F.M.:70 ‘General Instruction Timing : 03 Hrs Read the folowing i 2 case- based questions carrying 4 marks each SECTION E consists of 3 long answer questions carving S marks each, All questions are compulsory. : Use of log tables and calculators is not allowed SECTION—A ‘QI. Which of the following test / reaction is given by aldehyde as well as Ketones? (@)Fehling’stest' —_(b) Tollen’s Reagent test. (c)2,4DNP Test. (4) Cannizzaro reaction 2. The oxidation of totuene to benzenaldehyde by chromyl chloride is called {@)Etardreaction __(b) Riemer Tiemann reaction (c) Stephen's reaction (d) Cannizzaro’s reaction Q3. The major product of acid catalysed dehydration of 2-methyleyclohexanol is (@) 1~methyleyclohexane (b) 1 ~ methyleyclohexene (©) l-cyclohexyl methanol (@) 1 methylene cyclohexane ‘Which set of ions exhibit specific colours? Sc=21, Ti= 22, V =23, Mn =25, Fe = 26, Ni= 28, Cu=29 and Zn= 30 (@)Sc™, Ti", Mn™ —(b) Sc™, Zn”, Ni?* (Vv, V™, Fe* @ Ti, Ti it NE QS. KMn0, is colour due to (@) é—4—transition (b) charge transfer from ligand to metal (©) unpaired electrons in d orbital of Mn (@ charge transfer from metal to ligand ‘Which of the following will give a white precipite upon reacting with AgNOs? (2) Ka{Pt(en);Ch]___(b) [Co(NH)Chs] ()ICHHO}ICh (4) [Fe(H20):Ch] Q7. Rate constant *K’ for a certain reaction is 2.3 x 10° L mol S order of reaction is @o (b)1 ©2 @3 Q8. Number of amino acids present in insulin @27 (b) 25 ©50 @st Q. EDTAisa (2) monodentate ligand (b) bidentate ligand (©)ambidentate ligand (d) hexadentate ligand Q10. The formation of eyanobydrin from propanone is which type of reaction? (2) Blectrophilic substitution (b) Nucleophilic substitution (©) Electrophilic addition (d) Nucleophilic addition QII. The reagent which does not react with both, acetone and benzaldehyde is (a) Sodium hydrogensulphite _(b) Phenyl hydrazine (ec) Fehling’s solution (4) Grignard reagent Q12. The correct IUPAC name for CH;=CHCH; NHCH; is (a) Allylmethylamine (b) 2-amino-4-pentene (c) 4-aminopent-l-ene (a) N-methylprop-2-en-1-amine Q13. Which of the following naturally occurring oc- aminoacids is optically inactive? (a) Glycine (b) Alanine (0) Leucine (@) Valine QI4. A solution of chloroform in diethyl ether (@) obeys Raoult’ law (b) shows a positive deviation from Raoult’s law (©) shows a negative deviation from Raoults law (d) behaves like a near ideal solution feason In the following questions (Q. No. 15 ~ Q. No. 18), a statement of a reason is given choose the correct out answer out of the following choices . (a) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct (6) Both Assertion (A) and Reason (R) are true but Reason (R) is not the (©) _ Assertion (A) is true but Reason (R) is false. (@) Assertion (A) is false but Reason (R) is true,, should have a positive value for the cell to function. QIS. Assertion (A): Ecen id Reason (8): Eats Ni* (0.160 M) + 2Ag (s) reentage of esutng solution, Es Eatalte the mass ofa non rote solute (Molar mass 40 gram mol) which shouldbe dissolved in 114 gr (ii) Given that E*cell = 1.05V [Given: log 2 = 0.3010, log 4= 0.6021] Q28. Give simple chemical tests to distinguish between the following pairs of compounds: JMethylamine and dimethylamine (@ Propanal and Propanone (ii) Phenol and Benzoie 29. The elements of 3d transition series are given as: Se Ti V CrMn Fe Co Ni Cu Zn Answer the following: (2) Which element has the highest m.p. and why? (b) Which clement is a strong oxidising agent in +3 oxidation state and why? (©) Which element is soft and why? Q30. Write the name, the structure and the magnetic behaviour of each one of the follo (i) [PX(NHs),CIQNO>)) (ii) [Co(NH3),ChJCL [Ni(CO)) (At nos. Co= 27, Ni=28, Pt=78) D The following questions are case ~ based question, Read the passage carefully and answer the questions that follow: Q3l. Passage: Polysaccharides contain a large number of monosaccharides units joined together by glycosidic linkages, These are the most commonly encounted carbohydrates in nature. These are starch & cellulose, They mainly act as the food storage or structural material, Answer the following questions: (i) Define glyosidic linkage ‘What are the components of starch? Where are the glycozen present in human body? ‘Where are the glycosidic linkage held between two unit of glucose in the cellulose? te Q32. Passage: ‘Temperature dependence of rate constant is described by Arthenius equation K = Ae *” . The equation clearly shows that increase the temperature or lowering of Ea will lead to an increase in the rate of reaction and presence of catalyst lowers the activation energy by io complexes:33. 34, Qs. Answer the folloy @ b) @ ©) Carry out the following conversions: Providing an alte ate path forthe reaction. According to collision theory, another factor P called steric fac fi ee ‘I ee itor. Which refers to the orientation of molecules. questions:- Write modified Arrhenius equation, He achemical reaction with rise in temperature by 30" then. How many times the rate constant is nearly changed? ee if ‘What are the Arthenius parameter? ‘Write the conditions of effective collision, SECTION —E State Kohlrausch law of independent migration of ions. What type of a battery is lead storage battery? What is the similarity between Raoults law and Henry's law? Define Order of reaction, Write down electronic configuration of Cr. OR Calculate the potential of hydrogen electrode in contact with a solution whose PH is 10. Define fuel cell. Write only chemical equation which are take place at cathode & anode in fuel cell Define : (i) Chelating ligand (ii) Spectrochemical series Draw all isomers (geometrical & Optical) of (@[CoCk{en)sJ” Gi) [Cofen)s}* (ii) [CooNH).CLy" oR ‘Write the an example of homoteptic and hetroleptic complex. Discuss the bonding nature, hyloridisation structure & magnetic property on the basis of V.B.T. (Any two) (@ [Co(ox);]* Gi [Fe(CN)I Gi) [Ni(CO).) Give simple chemical tests to distinguish between the following pairs of compounds. (@ Phenol and Benzoic acid (ii) Benzaldehyde and Acetophenone Give the formula / structure of A, B and C in the following reactions @ CH,-CH, leet BC (i) C,H,NO, #1, 4 a. BEHOE SC OR (2) pnitrotoluene to 2-bromobenzoic acid _(b) Propanoie acid to acetic acid (Gi) An alkene with molecular formula CsHyo on ozonolysis gives a mixture of two compounds, B and C. Compound B gives positive Fehling test and also reacts with iodine and NaOH solution, Compound C does not give Fehling solution test but forms iodoform, Identify the compounds A, B and C with reaction, dee