Problem set # 12 ‘Chemistry 200 Thermodynamics Name: 1, Automobile airbags solid azide, NaNs, that reacts to produce nitrogen 2NaNa(s) — 2Na(s) + 3No(g) Calculate the value of work, w, for the following system if 39.1 g of NaNs reacts completely at 1.20 atm and 24°C. W=- RSV V met wan B94 Mans x coed = 0.6 02 mel Van, 0+ 602 mel Nang x —S eve Deel wow PVEMRT my 120 tmx Vy, = 0-903mel x 082 SERE y 297K = Vvzigl = 0-903 med Mr . 3235 ee 2-1 a HUG atm Lb x ONE? 5.918855 2-2190 We ~%, AV = -)2eate x (18-04) = nana 3 y 2. 25.1 g sample of methanol, CH3OH, was combusted in the presence of excess oxygen in a ‘bomb calorimeter conaining 3600 g of water. The temperature of the water increased from 25°C to 65°C. The heat capacity of the calorimeter was 2657 J/°C. The specific heat of water is 4.184 Wg°C. Calculate the intemal energy change (AU) for the reaction in kI/mol. Heat gainesl by Water = MxCpxAT= B6ooyx 4.184 x (652-252) 2 C0245 3 se = boo Ky Heat gaineh by calenimeter = Cx OT = 265Fy x (656-252) = 062807 enous Total heat evelved = books + Noks eFloky 25.14 CHyon x peseicew = 0.784 aos ao Hees, = tees 906 Mt Aue = woe HS, oa 3. Calculate the molar heat capacity of copper given that 204.75 J of energy raises the temperature of 15g of copper from 25° t0 60°C. VS 5 cor ye NSH = 0.24 mel Cu BE RCH Fan KAT a> 204.755 = 124 mol x Cp x (60 b= 25e) = a ee as Dr. Behrang Madani Chem 200 We4. A piston confines 0.36 mol Na(g) in 2.3L at 25°C. Two experiments are performed. (a) The gas is allowed to expand through an additional 2.3L against a constant pressure of 0.960 atm. (b) The gas allowed to expand reversibly and isothermally to the same final volume. Which process does more work? fe 4013235 A) We - Pe AV =-O:960atm x (MGL~ 2-3 LIE ~E Patel x Goa = Lr0F Sy 298Kx Ln (HE bY we-na4ddn Vie a5 w= 0-36 mol x 8314 a ay we - 685 = -820T The veversidle proccess cloer move werk than Constant Pre ssure 5, Calculate the heat that must be supplied to a 600.g ice at -10.0°C to raise its temperature to the boiling point of water, 100.0°C (the molar heat capacity of liquid water is 75 J.K"'mol" the molar heat capacity of ice is 37.6 J.K'' mol, and enthalpy of fusion of ice is 6.0 kJ.mol". ‘The melting point of ice is 0.00°C. 1 6004 Ho x Wre = 33.3 mal Hio (ice) BSt0 x\o0 =\28005 \ G@) Best sol. ¢ eme cy x AT © 35.3 mol x 97-6 5 ee oe &OKT . yooos _ 5 @) Fusion : 33.3 me\ tho x Tan ige * “Ege = Reoonle S @ Hest Wail ten eg AT =33.3meln ¥5 Toy * lioo'e 0°) = 2:50 x8 J H total = Mest ad+ By y+ Heat CSolict) = 2.50 (e854 2 oextfSe125005 BAS KIS T 6. Calculate the heat that must be supplied to a 18.0g of liquid mercury (Hg) at 26°C to raise its temperature to 390°C. (the molar heat capacity of liquid mercury is 28.0 J.K"|mol the molar heat capacity of vapor mercury is 81 J.K"!.mot", and enthalpy of vaporization of liquid mercury is 59.1 kJ.mof'. The boiling point of bromine is 356°C. Amt HS x 0.0897 mel H too. Hy O° 5 @ Heat lig ¢ GenxCea x OT 1805 Hy x £0089 Fmely 23-0 x (3860 -260) = 8305 e Z) Vap, & cc BIFmal Nyx ZAK , Weed . 5.smtot ® ver, a Shy * Tey 3 CD) Wrest Yap 2 4 enn Cyn AT 2d $20.06 9Fmolx BS y (3902-3560) 2 LAFF mobi Hy cea Meat (lig.) + SH + Mene(vap) = 8305 + S.Boxte' Se UF = 63807 De. Behrang Madani Chem200 vc7. For the following reaction: CHa(g) + 202(g}> CO2(g) + 2H20(g) 1f 650 kJ of heat energy is released per mole of methane (CHa): 8) What is the enthalpy of this reaction if 342 g of methane reacts? Amel CHy - 650 KS Amel Sxl KT | QHs —blewie ky 16 § chy A mmel CY, Buds CMY x ‘b) Find the enthalpy of reaction when sufficient methane is bumed to produce 0.56 mole of water vapor? Amel Cty — — 650 KS x = (oly AW = So KS Del yo 1 mel CHy 0-56 mel Ho x 8. Calculate AH? for the reaction: Naz0(s) + SOs(g) > NaxSO«(g) given the following information: AH® (1) Na(s) + H:0(0) > NaOH(s) + 1/2 Fh(g) “146 kd (2) Na2SO.(s) + H20()) > 2NaOH(s) + SOs(g) +418 kd (3) 2Na.O(s) + 2Ha(g) ~> 4Na(s) + 2H2O() +259 KT step 1: we clivide veaction(3> by 2: asks @ ~a206s) «Wy > ewalsd © HeM) — OH SRBES Le IB0 KT Step 2: Reverse veaction(@) : e 2 4S @ rnaowls) + Sos(s) > Marsoqcsr# Hre0) ABE a a Po Q Ane 4 BonKts = 288 Ae —AWazols) + trl) + Waotl(s) + Sony) —> rWals) 4 NagS04(5} # ZHLOC1) Step 3% to cancel UnWantesl VACH, He, Va, and Heo, muleiply readin 1 Bee vals) ZrO Cl) > LvaoW(s) + Hs) As 2x L-WGp— 292 Wy 49 = e =292KS 2 - $80 STER4 2 Combine CAD => Ans 28845 Sgr $805 Dr. Betrang Madani9. Calculate the standard heat of formation, AH, for FeS2(s) given the following information: 2FeS2(s) + 5O2(g) >2FeO(s) + 4S02(g) AHP nxn = -1370 kJ AH? for SOx(g) = -297 ki/mol OH/ foro, = 0-0 KAZ) AH? for FeO(s) = -268 kJ/mol AW = EN Aue” (predects) — Endy,” (reactants) f AW on = [CR mel) (iy Fe) 4 (amet) e (engso,)}- [C0 (ony FeS2) + (Smet) (ony? on) | H\BFoks = [Com)x (- 2 63Ky) + Camel) * cuir )]- [camry x (AME Fe) + (Seayx(o-o¥sy,) | (BFo Kye HIRE KT - ( 2moleDHy Fese) B54 IT = Lele AW Fesy => AL Fes, = +1FF by Dr. Bebrang Madani ‘Chem 200 ve