Roll No. Series : SMA/I| ated. series Coden, 56/1/2 tae. attenel ais a Saya & Fa-TS| a Ft yt [3] 2]e lf ae sree fre 1 Candidates must write the Code on the title page of the answer-book. era sia ar ot fe ee wea A ae ye wrens aft ore at aie Rea me ats ae a ora See afta & STS wR fers 1 pret vita ae F fas ge ea 30 Wee PUI es Sr See Pe IS HTS Vee, Me eT eHiee sree fre | Fa wea St oes & fee 15 fre ar were fear ere wean a ferro yates F 10.15 Peat ore 1 10.15 at B 10.30 at cer ora Baer wea-wa TEM atte ee arafe & eh a ga. ‘fear oe aig Sere Het erat Please check that this question paper contains 11 printed pages. Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. Please check that this question paper contains 30 questions. Please write down the Serial Number of the question before attempting it. 15 minutes time has been allotted to read this question paper. The question paper will be distributed at 10.15 a.m. From 10.15 am. to 10.30 am, the students will only read the question paper and will not write any answer on the answer script during this period. Tar fart datas) CHEMISTRY (Theory) rater eer: 3 ey patheent ai : 70 Time allowed : 3 hours ] [ Maximum marks : 70 ‘ararer Feet 56/12 (web rer afrarte 1 (ii) arta ae ane? aiee cert ee (iii) WERT 8 8 cre athe eae seRTa Her E | eter mer & fear 1 see (iv) TRAIT 9 B18 cre erg-sere er E 1 ete wer a fer 2 sie 1 (vy) Fea 19 827 we at ore-seria wes E 1 wets eT far 3 str es (vi) were 28 & 30 aegis wer E 1 ele wer & heres see (vii) amrerverarerga eile 2arett ar wate ae 1 eapclent & seater at sega TEE 1 1 IP.T.O.General Instructions : () All questions are compulsory. (i) Marks for each question are indicated against it. (ii) Question numbers 1 to 8 are very short-answer questions and carry I mark each. (iv) Question numbers 9 to 18 are short-answer questions and carry 2 marks each. (%) Question numbers 19 to 27 are also short-answer questions and carry 3 marks each. (vi) Question numbers 28 to 30 are long-answer questions and carry § marks each. (vii) Use Log Tables, if necessary. Use of calculators is not allowed. 1, anda ata itt arate te & ate enter ora a fs att ww sie Get are rarer feafiae | Write a point of distinction between a metallic solid and an ionic solid other than metallic lustre. 2. PCT, aie PCI, HS fave a4 at eiorera et & site aa 2 1 Which one of PCI} and PCI; is not likely to exist and why ? 3 Rea Reta vet ce en er 1 ‘What is the role of graphite in the electrometallurgy of aluminium ? aC refetian ara a cfieRe (nucleophilic) are tiiraat a sae abr ae at art ores aie: die, site, a, a 1 ‘Arrange the following compounds in an increasing order of their reactivity in nucleophilic addition reactions : ethanal, propanal, propanone, butanone. 5. 2-Sferenitts-2-stter aioy a dear a Feat 1 1 Draw the structural formula of 2-methylpropan-2-ol molecule 6. refefan dite ar angattedt, arm dite 1 CH= C- CHBr CH, Give the IUPAC name of the following compound. CH, = C- CHBr CH, 56/12 2Lb eh STRUT Set ET HAART Ht (homopolymerisation) Ht wear BAT | 1 Define the term, ‘homopolymerisation’ giving an example. USC Prafefaa at seta fac a sae anda erred & wed et raters afar 1 CH,NH,, (CH,), NH, (CH,), N itv NH; Arrange the following in the decreasing order of their basic strength in aqueous solutions : CH NH,, (CH), NH, (CH); N and NH, 9, geaeinteelifear amet (CC/,COOH) * we 1.00 Atte siete fara a aaeraiar er anf ‘Fran rar & 1 aera an aarp 100.18 °C & | greacibiiealieer act % fer due ere are al are Sifter 1 (rer & fer K, = 0.512 K kg mol!) 2 erat wr act at afore feafiad (i) Bier wHieT (Mole fraction) (ii) atgtetfr fer (Isotonic solution) (ii) Deas eRe (iv) areet Facer A 1.00 molal aqueous solution of trichloroacetic acid (CC/,COOH) is heated to its boiling point. The solution has the boiling point of 100.18 °C. Determine the van't Hoff factor for trichloroacetic acid. (K,, for water = 0.512 K kg mol!) OR Define the following terms : (Mole fraction Gi) _Isotonic solutions ii) Van’t Hoff factor (iv) Ideal solution 10, ‘aibtigar ot wife & eet ore? atom x Fern a Frese eer ash & aife at wear aifirg : @ L' mots Gi) Lmor! s+ 2 What do you understand by the ‘order of a reaction’ ? Identify the reaction order from each of the following units of reaction rate constant @ ~~ L'molst Gi) Lmor' st S6/1/2 3 P10.LSet tae qa cue aac fefad : @) serifine Bice stterares ater F NaCl a Perera Preteen sina & 1 (Gi) Gar were fener er at Gee NaCl & faces 8 ya ae flee wee ater a PAT TT eI Describe a conspicuous change observed when (i) a solution of NaC! is added to a sol of hydrated ferric oxide. ii) a beam of light is passed through a solution of NaC! and then through a sol. 12, Bengt ster a ebes ar we AaeTa ater & 2 Pret efa fafteet a ate aiifore Para art ated ateit an cea fave oo ae & What is meant by coagulation of a colloidal solution ? Describe briefly any three methods by which coagulation of lyophobic sols can be carried out. 13. Prevfefiset ar avis sifiar ; 6) ef ees ata acter, Gi) wafer Free & after F ada tisisiiverss st after 1 Describe the following : (i) _ The role of cryolite in electro metallurgy of aluminium. (ii) The role of carbon monoxide in the refining of crude nickel. 14, wre attire fee Preafertian ar gem creed & (i) Fetes fords (ii) aa GAN (biocatalyst) ? ‘What is meant by (i) peptide linkage (ii) biocatalysts ? 15, Weta & ford afc are 8 ee Prifertac at emer afc : @) 0, aft F, St at erga at sea siete serearsit at fern wert eect F Ay tase 4 0, watt FF 1 Gi) ste eaten at eeernait at care eetorse sre welt a agi at oo Tae Explain the following giving an appropriate reason in each case. (G0, and F, both stabilize higher oxidation states of metals but O, exceeds F, in doing so. (ii) Structures of Xenon fluorides cannot be explained by Valence Bond approach. 61/2 416, Prefertian waratres attercnit st yt are 2 @ Cr,0F;+H+r> Gi) MnO, +NO;+H* > Complete the following chemical equations : @) Cr0F +Ht+r> (i) Mn NO} +H* > 17, refetian agerat & wets caer st ever artfiac sare: 2 (i) ARIS Gi) Westie Draw the structure of the monomer for each of the ‘following polymers @ Nylon 6 (ii) Polypropene 18, DNA ait RNA & ata ger deers aint fear 1 ct arat, eredis atte tiara, Ha ait te DNA H fea ete 8 2 2 Write the main structural difference between DNA and RNA. Of the two bases, thymine and uracil, which one is present in DNA ? reer ao ae ta Pie er A feetinn ato ae afte det & aie at ME 316.5 ppm 8 th reer ey wt Br aa nt? weet SIA 286,65 pm Aer are & arr arr Shae wa ae Sar are & | ERA HT TT 7.874 gem} & 1 8a Ge BI Sea ea ge Vali Gen at fewer Fhe (Fe #1 FaIAT = 55.845 u) 3 Tungsten crystallizes in body centred cubic unit cell. If the edge of the unit cell is 316.5 pm, what is the radius of tungsten atom ? OR Iron has a body centred cubic unit cell with a cell dimension of 286.65 pm. The density of iron is 7.874 g cm. Use this information to calculate Avogadro's number. (At. mass of Fe = 55.845 u) 56/12 5 [P.T.0.21. ‘Bo feratict (C,H,O,) FAT #1 500 g Het wer A geret uw facet ara Tare ea Farr ar aaUia 100.42 °C eter & wake aR oer aT Fai 100 °C & 1 Pevatet at feet arn ga faoren H gene me at 2 (K, 51 ® fer = 0.512 K kg mol!) A solution of glycerol (C,H,0,) in water was prepared by dissolving some glycerol in 500 g of water. This solution has a boiling point of 100.42 °C while pure water boils at 100 °C. What mass of glycerol was dissolved to make the solution ? (K, for water = 0.512 K kg mol!) fr afitfiear INO) + Clay) > 2 NOCH gy ‘a ferd freaferfene attend wad Pat re eett as 263 K we fer ae: . sre (Cl] Cl, Saga ew at anf weird, wrefisr [NO] (M) a) (Minin) 1 0.15 0.15 0.60 2 1s 0.30 1.20 3 0.30 01s 2.40 4 0.25 0.25 2 (a) whan a aire farted 1 (>) a feria ar am otefed sfay sit nae are afar | () wai 4 ACH, & aga a at ania a eT e? For the reaction 2NO pp + Clyyg) > 2 NOChgy the following data were collected. All the measurements were taken at 263 K Experiment sat ENO] QM) Initial (Ch) (Miia rate of disappearance No. of Cl, (M/min) 1 0.15, 0.15 0.60 2 ols, 0.30 1.20 3 0.30 0.15 2.40 4 0.25 0.25 2 Write the expression for rate law. Calculate the value of rate constant and specify its units. SSe What is the initial rate of disappearance of Cl, in exp. 4? 56/2 622, afar aren 3a ge Pretend a care aia : 3 wae fetus at safeatit Co arc & CoH sitaetiga a sree 1 (i) NH, 4 ate CO afer vac sincera sift t | Gi) Ni(CO), a1 steer sae [Ni(CN), > & war et eta F 1 State a reason for each of the following situations : 6 Co** is easily oxidized to Co** in presence of a strong ligand, (i) CO isa stronger complexing reagent than NH, Asi) The molecular shape of Ni(CO), is not the same as that of [Ni(CN),]?- 23. Preafetadt a ford erect arco Feria; 3 (@ Fam d-anfaecia fara (a4) & are Ce* arraree & safe Mn3* Soares 1 (i) Aeerest at otter ofetias afire den dt seer aaent vel ad € aa qe andar ae & at ont & 1 Gil) aterm dope angel & earera area facta H fare tr wafers aed F How would you account for the following ? (i) With the same d-orbital configuration (d*) Cr* is a reducing agent while Mn*+ is an oxidizing agent, . (ii) The actinoids exhibit a larger number of oxidation states than the corresponding members in the lanthanoid series. iii) Most of the transition metal ions exhibit characteristic in colours in aqueous solutions. ® % v 24, Preafefiaet erieeott 3 carafe atten afi 3 @) ARS at aster area Gi) Afar aetars a 2-SFreeaeta (iii) Ofte at Aster wecnieter AF Write chemical equations for the following conversions : () _Nitrobenzene to benzoic acid. Gi) Benzyl chloride to 2-phenylethanamine. (iii) Aniline to benzyl alcohol. S6/1/2 7 [P.1.0.257 26. 21. 28. 56/2 ‘Prafetan aan 2 oat a wee ar eae sereoT fae: ()— Fretey Ew (Tranquilizers) (ii) eer after (Food preservatives) (iii) FP aTAPFe (Synthetic detergents) What are the following substances ? Give one example of each one of them. ()—Tranquilizers fi) Food preservatives (iii) Synthetic detergents arr Prafetan tragic a sitet fear ore & at ava sere a arm site saat ea afin 1 ae arret afea at sitar at rat snftras AF soatr Fong ge 1 @ CH,CH,CH,CH,OH Gi) 2-aeRrer Gi) 2a otter Draw the structure and name the product formed if the following alcohols are oxidized, Assume that an excess of oxidizing agent is used. ()CH,CH,CH,CH,OH Gi) 2-butenol Gi) 2-methyl-1-propanol et aeittes eetagts arrears aes Te at F ey Fae tt ae ertaaiftaferey Uefess were aafataransit & sre, tr Piteran then 1 ere aifine Gar wat 1 Although chlorine is an electron withdrawing group, yet it is ortho-, para-directing in electrophilic aromatic substitution reactions, Explain why it is so ? 3 (a) Prrafetian arfttirensit at ot aie : @ Py+S80,Ch > (i) XeF,+H,0> (b) fed me ater (90° ar afer aT aH) site area at Fr a ee a afer aI () soy ait#mo0-s-o0 Gi) CIF, ate at F-CI-F Gil) XeF, ait sit F-Xe-F 2,3@ Fer carte ate a yt aif : * @ NaOH +Ch> (hot and conc.) Gi) XeF,+0,F, > (>) Pra omysit at diced ontfaa afr: (@) H,PO, (i) H,S,0, (ii) XeOF, (2) Complete the following chemical reaction equations : @ P4+S0,C, > (i) XeF,+H,O> (0) Predict the shape and the asked angle (90° or more or less) in each of the following cases : (i) SO% and the angleO-S-O (ii) CIF, and the angle F - Ci-F (iii) XeF, and the angle F-Xe-F OR (@) Complete the following chemical equations : @ NaOH +C1L,> (hot and cone) (i) XeF,+O,F, > (b) Draw the structures of the following molecules : 7 HyPO, Gi) H,S,0, Gi XeOF, Ye ‘ae waits aed fra ae at det t 2 as eit det are BAH a ath Tis, Seats ae ah aaftfanarsil at ite ger freee a act aioe a Rafe 1 (bo) eave ey a arch Ha are ete A sepaet eer Ger fs ative ee : Zing) + ABO) + HQ -> 20 We aifitivar & fora B® site AG? at are afaTT FTE : Egg igg = + O.B0V, B27 ,2t/7q =~ 0.76V) +2 Ag, +2 0H) 2,3 areret 5611/2 9 [P.7.0.@ 0) () @ () 30. (@) ) @ 56/12 aioe arora a afar an site sare aie frag ate war fae raza fea store areas Bina are Sa aka wie F 2 0.001 M KCI faras arct saree Ser ar verte 298 K WF 1500 Q & 1 ae aT Feria war af 298 KW 0.001 M KCI at ateraeAt 0.146 x 1078 ome! &? What type of a battery is the lead storage battery ? Write the anode and the cathode reactions and the overall reaction occurring in a lead storage battery when current is drawn from it. In the button cell, widely used in watches, the following reaction takes place 2 42 Ag - Zn) + Ag, + Hy0y) > Zng, +2 Aga +2 OH.) Determine E° and AG? for the reaction. (given : Bata =+ 0.80V, E%p,24:2, =— 0.76V) OR Define molar conductivity of a solution and explain how molar conductivity changes with change in concentration of solution for a weak and a strong electrolyte. The resistance of a conductivity cell containing 0.001 M KC/ solution at 298 K is 1500 ©. What is the cell constant if the conductivity of 0.001 M KCI solution at 298 K is 0.146 x 10°S em“! ? ‘Prafefad fa wet at fac caren aif @ Sharon at — NH, We 1 ert a ww o Sharda & Prater a aftaferr are (i) Braeitadie are} arr a aries aang % ey 2, 4, 6-geafreraract- ‘eats tar agi ara SP] GF CoH, 0 & area we arifee aires 2, 4 -DNP aH ara Zeta aire at avait aon & sit Stet afhfer aca t 1 dia are @ ae 1, 2- asineraritiatee ara tar 1 ea aifies et years Sia 2,3 waar Pret at wears & fed cera sitet at are @ tte att aie are Gi) aR ait tetet 10S6/1/2 (b) @ ® @) () Prefetan arfifasarait a yer searet at dizer fafa: Anhydrous AICI, @ + Cg,cocl cs, Hg*, H,SO, (i) H,C-C=C-H cH, 1, CrO, Cl; ii) _ 2. HO’ NO, Give a plausible explanation for each one of the following : (There are two — NH, groups in semicarbazide. However, only one such group is involved in the formation of semicarbazones. (ii) Cyclohexanone forms cyanohydrin in good yield but 2, 4, 6- trimethylcyclohexanone does not. ‘An organic compound with molecular formula CyH,,0 forms 2, 4, - DNP derivative, reduces Tollens’ reagent and undergoes Cannizzaro’s reaction. On vigorous oxidation it gives 1, 2-benzene-di-carboxylic acid. Identify the compound. OR Give chemical tests to distinguish between (i) Phenol and Benzoic acid (ii) Benzophenone and Acetophenone Write the structures of the main products of following reactions : Anhydrous AICI, @ + CHOC > _, cS, Hg?*, H,SO, Gi) H,C-C=C-H CH, 1. Cr0,C1, Gii) a? 2. HjO* NO, "