x Claro _ wee cme nee ates IVo@ FIA: Buning v ky S scrieo + § Or70" Tap into millior 0-H S20u documents, : sone Bung of Mode! Compound ead oristen at ee (ere a Hs +0; GOH: +0 . Retnciien Recommended Hes cl He reo = rco,= 43 (CO}(08) Toy = O= 2k (Oa)- kz {O-)(H20) + ka (44-)(02) he Helen i, Fogler: solucionario de la tercera edicién ow 21.2014 13Tes + TEAzvlews Digitaizado com CamScanner— AS ] ka(O2)> ks (HCH) |) P73 (conta) + then "b"is positive $8 w 9 = (04) + 3ka(H-(0 PCr)=3&(0,)0y, P=3k(0,) «=44(0,) ™ ODS Sscrieo + { Tap into mill documents, Readorttenany Recommended easton Pasay wn HO of} —o. # © om On co Niet] [oor co BL The reaction sequence i ss cH,cHO—S+cH,.+cH10- Cy +CH,CHO + CHt,-+C0+ CH, nitki Cae CHO-ACH.CHOS-SCH.a900 2 Fr (cou'’) MEET N#D © by Cae a Cae Cone + bs Cue Cone Cae [ha +h Cone + bs Cdyo} a BHCie + Calon, — Cone Cae IaCucCem, +48, = AGie tCseCon,~ Wee Cie + FAC, FOO = tH = by Chet Cone. Creed < ss20to03 > Fogler: solucionario de la tercera edicién aan Digitaizado com CamScannerLe Bo) a} fiz oe] fe] tos 1 + SB scnno+§ ‘| al\ F Tap into millior oF documents, # oe extern any i on . t it | ee cst 7 nr | [cor co. Recommended fs en quences ' cH 514. 4cH0- tt,-+CH.CHO—* scH,-+C0+ CH, nike CH0-s01.cHO—S seth 907. Fr4(enrs) HETERAD = h Guess Cae Cole ths ue Conp = Caclts +2 Conn by Cre} . a 1 > civ irae CH», cre tacnenele ao "Not Kn ie hCaen EA, : AAA Can ~ haw Cat HRC, ® : fOE = 1 = ki Goer hs Cove. Caen © Cayo. «BL - ® 7 ‘Stoinsng @) in) ges: i kG, NEE" NGieh Cow- Cae = a Cae+ by Cae = 2h Cag =. Cony. = aac} = i vorefeen(afiest] =k, Je feg+k} . Wah) Mae PPL Oe >> 1, tc elCae Pp? en ss surzssed by egecion 9.2, ay Gas phase reaction 2N0+0,—"42N0, crete inc mR wit ied ore netic ana Fogler: solucionario de la tercera edicién Digitaizado com CamScanner2 Claro ~ VOR ‘ § scriso + § ons ‘nto mi marion Tap into million bore S Rent t documents, : Readorkten any Ro, Roe ROANHOMDANTS . PROPAGATION (9 Rope nat™ Root ome . (Rano Hawenerouer Jp rene FI ou’ . ‘LOW TEMPERATURES - NO ANTIOXIDANT. ' en» meted cua : ” A. ceseen-tateoniteag © i A tn (8103 ROrITRH-k(ROe? © : a Gq = RIRHIEE - ky (RJfOn) + key (ROz)} (RE) oy 1 PSSA... 70» HARKIN bo [RTO +t fRO¥i LRH) t all - , (RH . t w Mealh) + bp, [ROp-}{RH)| = LARC ai cose: a SP <0 wiRiton-sninoriien-uito Seton tre: | © alt -tlROeF = 0 Eu Now sai sai Hovsinineseegrsinfrteicsoe expen ere epton st [ROv} P77 (cont'd) 52 ecaantes en iR(031 kn (ROKR) ae $28 6 css tattnor) bal aslROr] 4221 © ttm ap (Ror ‘ply SSH: eo Oa < ss20t905 > aan Fogler: solucionario de la tercera edicion Ne 21.2014» 13s «6,84 vews Digitaizado com CamScannera $ 0 5 1.0 = [i 83 Bali ROR GEL. fey. Baldetnltontig GOA) oo eat kl ROrP Akar AHILROE) + KlROP- 2k [AH][ROP] ~ 2kg(h] = 0 KAROPP + (2kqn[AHD[ROr] -2ho{la] = 0 Quadra in (RO) hor = lA Foe ee Now NALLY, tine an SEH 28) 6-4, (14[R]-¥9,[ROrIRH) (ROp} MUST be postive fon 1 a ABIEROr} = kas [an] =2at (At) + fk [AHI Beto _— IVD S scrieo + § Tap into millio documents, eadortitenany Recommended a P7-7 (cont'd) (ODE tobe soved- low emperarre, no antioxidant: LSE aig «PN! Ga HIGH TEMPERATURE, NO ANTIOXIDANT aan & 7 HUE kr,{ROz|IRH - kp, RO-}LRH} - kp [OH[RH) risa g = Uelh} HIF} = 0 = rl a oute -tninozitni-etRovP 2 ete 2 ote RH) kn RL Oa! ~ kes ROp ERE] +H, + hy (OF]LRE] 5 eo » Ky[ROOH!- ke, (RO-ERHT outs Ge" Bs{ROOH, - ke SOK ZRH] ss2efo0 > Fogler: solucionario de la tercera edicién aang Digitaizado com CamScanner2 Claro Ho,) ‘P7-7 (cont'd) Nort oe $82 quien EY anata) b(n Polts = ha [ROHN fRooH)- ROH) Remember we aio hve 2. sot ofa tbew Now, lets look at the sitstion with anti-oxidants present: LOW TEMPERATURES WITH ANTLOXIDANTS. Adtiroal reions: kat RO +AH + ROOH +A a (10) Ar+ROp inactive products 77.7 ons) HIGH TEMPERATURES WITH ANTIOXIDANTS a, a a0 [l= ie CS ete 0] $821 5 -KinooH-tn.(norjan) = $28 oo sutton sn inetfor) OH: legate 1 = ean SF wre bp imsion «| 203] TE * RnR] be [ROyiERH ROY: Py H+ ke, ROH{RH] «ky (O¥]{RH) 1 [ROpifAH)-kalROriC4) $21 stor) -kualRordzay a < sszeto0s > aa Fogler: solucionario de la tercera edicién Digitaizado com CamScanner — IDS B scrip + § Tap into millior documents, Resdor sen ay2 ~~ Claro “tage BolbictefAOsI RH eR = fH ker E F i P77 (cond) HIGH TEMPERATURES WITH ANTIOXIDANTS 1.9 of. Bal Grom Pleo -bincott-mninosien = fro = ‘ylto9H ous —— $081 5 0 » k,{RoOK- nRANOH) Kony = HlROOH SEL (atm (R0%) -buRO>)p0} mmvrsx Bg Now nt 822] apie: ale + he (RO]RH] +b, FH] [RH] (ROP - Akar ROPILAR) «0 Mall} + 2k [ROOH)-K(ROyi?* Bea ROeILAH) = 0 M(ROPP + kas {ROr]AH-(Aho{l] +k, (ROOHID = 0 Uy « as (At as TARP DTT > TROT = 0 P11 (cont'd) Roy] « 2 ANI Vain AH = RegIn = ROOH = © Now aay, fe {RH eH =A [ROFRI =, OHH Dey Ae ag AF RTE] [ROO] i = $0 «at. (t00Hanie i BET te H 008 noe R0= ROE OO ROOM hae RNY Ly ANOS! Fay EOE [Ron «fp RH + ay at SEAL LARIEV aif bole Foy < sszeto0s > aan gler: solucionario de la tercera edicién Digitaizado com CamScanner — IDS B scrip + § Tap into millior documents, Resdor inten ay2 Claro BLE Given: tess mechani 6 HST sk tei peo pin & re ae . seas fom il person) IaH new aw . : 4 Peon ss wel) Ia estat) (person ies) ork) ‘APie ret sty sae pees tol: © 4 649-14 Se LHD eC alt= 0 oe (ett et a oe a ome hay be be FEST 0 = 28 ede me teane tne is eaigueniag calle ne ES oy = ef gC) hy = te fee est ag + -to<0 This, (0-0) 1 String with te deg equson or ch eacar an" nate om Go-G{i-&) Seem nf 1 BL9 cont'd ‘Using the data t 40°F and 45°F the following graphs are made: Finding k, T=40 _— IVD S scrieo + § Tap into millio documents, eadortitenany Recommended ss2efon > solucionario de la tercera edicién Digitaizado com CamScanner2 Claro _— IHD pea be EsS@Ess 0 SB scriso + § Estee Tap into miltio 2) Compessve eben documents, 7 Readortsenary Ess SE+P © ‘Assuming (1) and (2) 0 be equim steps: = E ® sf o Rate of preduson formation fp = t+} © Coating a oy oy» SAE 3 Toalenme bales (Ea) = (EJ+(E-S}+(E-] From (05 and a = (] + ES 0 © t= —Lo) ro 00) Equations) and (0) can be combed ve: = tess kn (3) +Eagn an " Let Vaa * fl) (©) Uncompesive Inhibion Pr-12 (cont'd) k IsE+SeT-E+s a E+S 4E+P ‘Assuming (1) and (2) 1 be equilibrium steps: (S} fan (E-S) = (IE-s) io Ke (l-E=5] fee bles) From (4) and (6: ty = EA(EIES) ‘Total enzyme balance: (Eq) = [E]+{E +S] +{I+ E+] fe) From (4), (5), and (8): (Ea) = ES), WES) tt T ss2efon > Fogler: solucionario de la tercera edicién @ eo ® 6) © Recommended aang Digitaizado com CamScannergo Claro: ~ So Er © ODS ge ules) © S serie +f Tap into millic From (and (6: 1, = ZA(EI(S) o “documents, ‘Total enzyme balance: [Eo] = (E]+{E +S] +[I+ E+ S} @) seer ip From 4,9), ana (Ee) = (e}+ELS1 LEIS] (0 se» Soe ¢ 1+ a +H) (10) Recommended ‘From (7) and.(10) we ger: Keats e * cael ay Let) = Vous 1, 2—Yenls] a2) ' i tebe " : IAD (coord) . . fe: ( Noncompetive tntiBon Y YS . \ ss a + unin, stole neler se: Teter Fe Nominee i abe - ES-ES o = = a . he tye HESS) o ' om sat tp = MEST ° toa camp tac: [Ea = (E]+[E+S}+(1+E}+(1°8 S15) ea 1g EL (of ESL © : From equations (6) and (6) combined give: E12 Givente reaction sequence: EssSeees EsS+SeS-E.5 « ss20to03 > aa Fogler: solucionario de la tercera edicién OE Digitaizado com CamScannerzo Claro BL12 Givenbe reaction sequence: EtSee-s EsstSeseEes EsSeeer Theplecet a, is shown below. ‘Fm protiem F715. he mechanism forthe abore react is: “Teese For Cy <1: t= kG, Einqualiaive agement wid he gagh at Doves, ForC,>> 1-5 0 EEL. Ky Gy * This also in agreement with the graph. fe), ke KG +a KOEN MLE), kell) g PeRi rR GP (+ KG oF SKECK, | 2e ELI Ko CHIN) + 2K2 Gy i eK Gsm GF | lek Gen oP he “ee + RELIG winct « Le, nemmennr tomes 7143 conto (0) Fora CSTR oping wih V= 10001: © 321i wolCaa- Ca} = -t4V oF fa, = Sats; te & =m = 313 min, = 30-Ca. iis cineae) equation is ploned on the . with Coo" sSOmeiest, = $9;-SHs hs oe puton i econ ohh utente) 8 Cy eure om he ae of acon at cams, 4, = oosrmgale; c= gamma, vn Ona cy = 21 = seme Sabi pins: assume hata perurbation Gy = Cyy Cy occur wher the verter designs ‘he seady atte eondion. Mate balance fr any ime: VEL av ecm ef ene scyg-Cy ”) Combining i wot Seal -n)Hln-O é 0 atr4 ines j Using a Talo sees expansion about Ty tolineaa rs ae oo Gal (c-Si = & sand sbi Csi tt Mh ns ss20F903 > Fogler: solucionario de la tercera edicién IPOS § scris0 + Tap into millio documents, Readortien ny Recommended Digitaizado com CamScannergo™ Claro: LLY Given te resetin sequence: EsSeess EsSeSes-E.5 Esseesp Tepotet«, w, stow below, ‘rm pote P75, th mechanism forthe above raion et we kGE TR remy’ PCS = BC Binge agnor wie pape Now aloes fC, For, >>. + Thi i also in agreement with the raph = EE RGEC] REMI TRG Ueki GK (eKiG+ RF PREC K | BEN Ke CHIE + 2K Cy Wek G+ KP (1+ Ki G+ Kr GP Hed wefan cK +8 ag Seas ES RSS with Cf = Le, tne numerator becomes P. con’) (0) Fora COTR operating with Ve 10001: up = 32Uiin 2c vole Cal = tAV org = S82E8: gw Lo AMM w 313 min with Cay 50m moles, -1 = 22-CS: this dines equation i ploned on the accompanying 3 ph the quan inc the) v8 Cy curve rom he eof reacon at Coes, = oosrmugalt: = 94mm, ony = onsemaals, cro OUI, cy » 21 UmBES , « o1se ml : Suto pias: sssume that pertin Oy » Cia Cyocten wher te over desi te setysecoten nee ye VIG vec oe rthe nee cya-Cy ) Combining semeady sate Ebay 6 O atyt+Tw+Ts 4 j Using Taylor seis expansion about to lieasie 5 - \, Osa sebriting cre, < ss20t903 > Fogler: solucionario de la tercera edicién — IPD scriso + § Tap into millior documents, Readertistenany Recommended Digitaizado com CamScannerSS MN GH = he, the numerator becomes Pr-3 com'd) (0) Fora CSTR operating wih V #10001: v9 = 32Unin ee ee wa CaesOmewiet, a £9204: ws loan eon plod on he compet ph be equnon iene hel Gy cue fom of econ at cyeDemmss, = casa; G = 94mene, wolCao-Cal = AV oF og = SZ, sno ous c, « 21 mm = semua ‘ Sebi ofpas: sme ara prion Cy» Cyy- econ whee vee desi Seedy ameonion, Matec ry me EGE w wv ecinus- come whe rec cy") Condi weney te Hen, -2¥ lH O ate TiesZs Using Tayler sees expansion about to lieaier- 30) ey.0y) = [22] and sts wet Gah Fe, enemies og (2) sores st#0,05 00 j Fer this souion ofthe above equaon be stable: jose PL cere Ee) ea P73 con's) A. G21 mmole 4 20154 mmole Reb meted meee ey tol pe a eaten a ae pine Denim an FosTahoce a ay acre pt ACCs © 9.4 mmotesn, 262) 2 OH. 012s 076 aus, 8Cs Ie 94 BCy 10 = BO int (ate) fie (22nin]13 ni) = 2401 4 poi Cy 9.4, ny .192 unl C421 amet, fl acs 2 Sto) . ones. ay TR = OE AOI 00085 it y ota 3a eS 7 FOS mins] « 0775515 sable Ces molest = osemnnies, ROIS appearsio be be bu mor seca aan Fogler: solucionario de la tercera edicion — IHD S scrip « § Tap into millio, documents, Feadorlisenany Recommended Digitaizado com CamScanner