Solutions for Chapter 3 - Rate Law and Stoichiometry P3+1 Individualized solution P3-2 (a) Example 3-1 For E = 60k/mol For Ey = 240kI/mol 6 ex nf 790000 vs. (2400007 = 0" el = 240000F" k=132x1 on RT ) AL = 1.3210" ent } P3-2 (b) Example 3-2 Yes, water is already considered inert. Digitaizado com CamScannerascribd company \ TSG Resolucao fogler 4ed. Oo & Jéssica Kulhavy 07 de Jun de 2015 - 40 gostaram - 17.768 visualizagdes 3-2 (c) Example33 ‘The ston tothe example a comersion of 204 would vein unchanged. Fo 90% conressions of the ‘xsi ods the final concerti of yer tert instead ofa negative conrentaton. Therefore 90% of eau sodas pose. P3-2 (d)sampies4 A+ 2B Ec+4D wate ss tesinabettrenne e033 P3-2 (€) Example 3.5 Fe aremerdecttatcain eet mma 0.5(1-0.14X)" Tnas-a5m) 1 ‘The rato reaction decent drastically with nceae in comveson a higher conversions 3-2 (0 xample 36 ora piven conversion conentaton of Bis ower ia lw race tha a coma volume bath eset ‘Therefore the fevereeacon ecencs Cy comnts inet ae vai NO, 4 20, rene tiem contin ent: Ke = 2 Swoichiomeuy: € = Y4q5= Yqq(2—1)= Yo ‘Constat volume Bach Digitaizado com CamScanner2,9KB/s —— a Seribd company (esauisar ) Resolucdo fogler 4ed. oO «& Ii Jéssica Kulhavy 07 de Jun de 2015 + 40 gostaram - 17.768 visualizagées x = 2C 9X 2X _ 2X week) (4ek) wo (+X) om 1 Cg = Bal yg 0071 7) ae ay 07178 Conn mt bac ox. EXD Ca ALE Ly. (REX RY Ca Cotter Ya See Polymath program POLMATIE Res ‘NLES Report ene Noningar equator (1 Oat) aXe = et eaytecan}70 $20 121 fo eet: ee tsep ea eCaa705 «0 Expt equations Lt pest 12) tee Digitaizado com CamScannerSUT a scribd company Pesquisar Resolucdo fogler 4ed. oO 2. Jéssica Kulhavy 07 de Jun de 2015 - 40 gostaram - 17.768 visualizagées ‘39|——aase| oar ca 93[—essi7| ‘08 aes | 07 ‘o5| asso] 001] oa |—assue| og ‘03|—oeess| ora 22: o7| ——o7s2 ‘o1| gana} —oxzia| mo aes] easy oo 3956 | ——oou| ena] 0800] P3-2 (2) tang wtb en P32) neal artns te 1 du? Reet: =F, AC Cy an ky = 2544 neers (=) A a8c,'c, = i ~nasi{) ‘s\ mot 7320) Av3D-92C Rac lw =r = CC oben eee Aegan Gen nag. _ Se 2c? -Se=0 Ken TGF Cac Ain urtsnmcnneana =r, ( 6,6," Ee) asited,ce=0 & < 71desss > iy Solucionario Fogler se Digitaizado com CamScanner2 Cc, eee Cy CrCoe Bans ufc. - 5} Cr ‘which satisfies both the initial conditions and equilibrium rate law. 3 Hence 1, ~tfese, So a +) erin te ; 3-3 solution is inthe decoding agoitim avaiable separtely from the autor, P3-4 (a) Note: This problem can have many solutions 2s data fitting can be done in many ways. Using Anthenius Equation For Fie fies: Plotting In(flashes/min) vs 1/T, ‘we get a straight line. Sce Polymath program P3-4-fireflies.pol. For Crickets: Plotting lo{chisps/min) Vi IT, we get a straight line ‘PBoth, Fireflies and Crickets data follow the Arthenius Model. Iny = A+ BIT, and have the same activation energy. Sce Polymath program P3-4-crickets pol. 4S ba “ aa] a aa Sard DRED Doan, SES LED es ” . a“ OED Shand Dom SEED ED La) Digitaizado com CamScannerP3-4 (b) Fou A Tak) | Veemvay | ivy x10" 208 3386 [07 0.357 4 Es EE aw sa7]s TT “ Pioting WV) Ve 1/7 alma straight line lo(V) © 44 6~ 133EAT ” AIT = 40°C(313K) V=64cms ALT = -S°C(268K) V=000Scm/s(Buibee 04 ‘would not be alive at this temperature) See Polymath program P3-4-becs.pol. as SasES MES AVE 3H a “ om . [ar faa _ [es _ [rar Plotting In(V) Vs IT, hd almost straight line ‘Sce Polymath program P3-4-ants.pal. “4 So activity of bees at eishets and fines allow 18 Tae Hae THEN TEED HC Atthenius model. So activity increases with an Increase in temperature Activation energies for fireflies and crickets are almost the same. Tnsect___| Activation Energy | Cricket| $2150 Fuefly | $4800 ‘Ant 95570. [toneytee [141800 P3-4 (d) ‘There is limit wo temperatuse for which data for any one of he insect can be extrapolaie Data which would be helpful isthe maximum and the minimum temperature that these insects can endure before death ‘Therefore, even if extrapolation gives us a value that looks reasonable, at certain temperature it could be ascless P3-5 ‘There are two competing effects that bring about the maximum in the corrosion rate: Temperature and HCN-115S0, concentiation The corrosion rate incieases with increasing temperature and increasing ‘concentration of HCN-H,SO, complex "The temperanwe creases 42 we go fom top to botiom of te ‘column and consequently the rate of corrosion should increase. However, the HCN concentrations (and the 36 Digitaizado com CamScannerHICN-H2S04 complex) dectease as we go from top to bottom of the column. There is virtually no HCN in the boom of the column. These two opposing factors results in the maximum of the corrosion rate somewhere around the middle of the column 3-6 Amidote did not dissolve ftom glass at low temperatures. P3-7 (a) Ma reaction rate doubles for an increase in 10°C, at T = Ty let k= ky and at T= T; = T,+10, let k= ky = ‘2ky. Then with k= Ae in general, k, = Ae!" and k, = Ae!" , or ned ee) Hl) k eT) Gk wa) om ‘Therefore: eon EJ) way 7) 10E T(%+10)- 2S hich can eprint by 7 = WOE P3-7 (b) ' Equation 3-18 is k = Ae From the data, at Ty = 0°C, &, = Ae™®’™ and at Ty = 100°C, ky = Ae™E™ Dividing gives he a oe i co Digitaizado com CamScanner=2100min™ 3-7 (c) Individualized solution P3-8 ‘When the components inside ait bag are ignited, following reactions ake pace, 2NaNy -* 2Na 4 3Ny . WO 1ONs + 2KNO, — K20 + $N3,0 + Ny Q) K,0 + NayO + SiO; —+ alkaline silicate glass... 6.0...) 5x ran(I)+ ran(2)+ ran(3) = ran(4) 01Si0; 9 O4Na:0 + LON; + complewIO. .....(4) NaN + 02KNO, Stoichiometric table: [ Species [Symbol [Tnitial [Change [Final] a a SP SS SC [BNO |B [rng | O2X% [nc o,-020 | [5 [proce | | wacae-o10 | Given weight of NaN;= 1503 My of NaN = 65 Therefore. no of moles of NaN; = 23 1 moles of NaN requites 02 mole of KNO, => Moles of B, KNO; =02(23)=046 miles Myof KNO}= 101.1 ‘Therefore, grams of KNO} requited = 046 x 101.1 = 465 g 1 moles of NaN requites 0 1 mole of SiO Moles of C, SiO; = 0.1(2 3) = 023 moles M,. of SiO; = 60.08 jams of SiO?2 required = 023 x 60.08 = 13 8 g Following proposals are given to handle al the un-dctonated air bags in cars piling up in the junkyards: ‘© Stote cas in cool, dry, ventilated areas ‘© Avoid Physical damage ofthe bag in cat. © Itis stable under ordinary conditions of storage Decomposes explosively upon beating (over 221° For 105°C), shock. concussion, or friction Mu Digitaizado com CamScanner‘* Conditions to avoid: heat, lames, ignition sources and incompatibles. P3-9 (a) Fomite web module we row hat Em KC~2) and that k is a function of temperature, but not a linear function. Therefore doubling the temperature will not necessarily double the reaction rate, and therefore halve the cooking time. P3-9 (b) ‘When you boil the potato in water, the beat transfer coefTicient is much larger, but the temperature can only tbe 100°C. ‘When you bake the potato, the heat transfer coefficient is smaller, but the temperature can be more than double that of boiling water, P3-9 (€) No solution will be given P3-10 (a) 1) CH = Call 6 Hy Rate law: -t4 # Coy, 2) CHL + 120; - CHO Rate lave ty © ACen, Co," 3) (CH)COOCICH)) — CH, + 2CH,COCH, rN -B+ 2x Rate law: -t, = KICa-CuCcMKe} 4) Calle EC Rate law: ote = MCoesig ~Crcyng Red 5) CH;COOGH, + CAH,OM ++ CH;COOCAIy + C101 A + Bowe Cc + D Rate law: ty = KC\Ca-CeCoKel P3-10 (b) 2A+B=—C a ta = ECAC? @ ay 2 Cy eo ae o ot, = RCAC P3-10 (c) ) City = Gitte + Hy Rate aw: ty = kCon, 3 Digitaizado com CamScanner@) Hy + By — 2b Rate law: yyy = 8) Hy ¢ ty 2 P3-11 (a) Liquid phase reaction, ° ci-on cN | City Cih, + 1,0 + CHO A +B= ¢ Cao = 1 Hbmol/t? Cpo = 3.47 Ibmol/h Stoichiometric Table: Species Ethylene oxide ‘Water =(347-X) bmov ttt Giyeot € Cee CX = X Ibmobifi? Ratelaw. 14 = KCC Therefore, tye Chg (1X) Oy -X) = MU-XW3AT-XD A1300K B= 12500caVmol, X09, 35.315 fi" /bmol.s = 0.0035 ft’ /Ibmol.s Team = £0X , —_(00.9) am,” (00035KD(1-0.9)3a7-09) ‘At 350K, sky = k exp((EURMI/T-1/T3))= 0.003Sexp((12S00/1 987 L/T-1/T;))= 0.071 den'/mol s Theretore, C, oX 7 yo.9) 2 a! (.071)()*1-0.93.47-0.9) Tes = mt P3-11 (b) Isothermal, isobaric gas-phase pyrolysis, Ci CH, + Wy A> Bee ‘Stoichiometric able: C; = Bal Digitaizado com CamScannerEER sserbdeompony — (Pesauisar Resolucdo fogler 4ed. OD BQ Jéssica Kulhavy 07 de Jun de 2015 - 40 gostaram + 17.768 visualizacdes Gi_[-a To Tr, th [ eo —| ae Feta FF a 1(ielty=T veudisen) Sy evdlex Coos noCw=yo0 oe a (1)(6aim} 0.067 tmim= 0057 moti? 082 (110%) Full=%),¢ (IHX) Fin) : votl# x)! (Ix) Fo) 2 X vette OT] FX) eX = ue rattan Te] cr o fie fee cookie Rate le fe wteult=X) 1- x! ct steat=§) gant] sam hon nas ie reaction Cx=Cull Xml? P3.11 (0) thermal, haha ety gs pase odo, f can + 40, 9c Hh + 50, > CLO Tene Fast TXT Fath O-¥) Fst Digitaizado com CamScanner(6am) at Cyo = aol =o eed = 0.0920 (oom os2 md mn’ 533K) Fy, Fal!=X) _ Cuo(I-X pomt-x) yyp(leeX) ”(1-033K) ~ (1-033x) oui Foo| O~ 4) _0.046(1-X) . v vo(l+eX) — (1-0.33X) Fe FyoX - 0.092(X v yp(l+eX) (1-033X) I the reaction follow elementary rte law G Rate law:=r, = kC,C9? 4 {0.092(1- x) x *\qr03mx) er (1-0.33x) P3-11 (d) Isothermal, isobaric, catalytic gas phase reaction in a PBR Calle + 2H, > Callie A +B>C ‘Stoichiometric table: F, sas 2 400 Fanta 3 £2 yyS=4(1-2-1)=-2 3 3 Pl Cro * Crore = Ze(4)= ofa ~ Ful!=X) _ Cuo(I-X) _ 0055(1-x eat Ee)” (ikt) 312 Digitaizado com CamScannerZserbdcompany — \ Pesauisey Resolucao fogler 4ed. Oo &-: Jéssica Kulhavy 07 de Jun de 2015 - 40 gostaram + 17.768 visualizagoes wf = Fanl= 2X) _ 01N(1- ee (eR) 2x 3 cote Snk nt YT pllse z | 12x) [1-2 tyr) eon hey foci =n '=IC,C} mr,'= 0.0007 oe + (+34) Feta dad CST: Digitaizado com CamScannerP3120 cay $9 > onto G72) _oor0-x) “1-0.15X — 1=0.15x CyoX _ _ _O.041X =0.1SX 1 0.15 TT P3-13 (a) le Aw ONCH Ce Nitvonatine Denil, = Ammonium Corie A+2B—Sc4D or 2hC Cy a4 Digitaizado com CamScannerP3-13 (b) ‘Species Entering | Cha Leaving A F, -F Fpl | 2 B Fro = OF 2X Pe S668 Pig Fyf@y ~ 2X) Cc 0 F, Fis FagX D 0 E FF, CasNV sty RNAV? P3-13 (d) ot, =kC,Cy Na _ Ng _ WN, Fo MaMa Mai x )ecg(t-x), C,2fbeFbacg(tex Byte Manx) Clt-X), C2 En Bb acu (t-X) F, oe Me Mae (0,-2x) = C(O, -2X). 6, = 4 = C45(0,-2) , a vow Wt = RC jo (I~ X)(0, -2X) Cro _ 6.6 0, = Git =e = 367 Cy =1.8 |-r, = (1.8) (1-X)(3.67-2x) P3-13 (e) 1) AUX =Oand T= 188°C = 461 K 2 a Jmol knoll ~My = BCID, = KyCasCyp = 0.0017 ma satel) aoteet) =r = 0.0202. 2)ALX 2 OandT = 25C = 298K ss Digitaizado com CamScanner2serbdcompary — (_ Pesquis 7 Resolucdo fogler 4ed. DO gw Jéssica Kulhavy 07 de Jun de 2015 « 40 gostaram - 17.768 visualizagées keoo1s2 Trot ACC P3130 FAI 20) a +(oon Justa -09}3 67-2(09)) et 21x somna «250~ 298k & < 83desss > Solucionario Fogler I Owoew: Digitaizado com CamScannera “th {21200 (1-0.9¥3.67 - 2(0.9)) Amol = 1.28x10 ee min » ‘MX =090 and T = 288C = S61K m -n= (001s ra -0.9¥3.67 -2(0.9)) = 0,00333—Amal_ im? min P3-13 (g) eu 2nfin = 0.0020" /nin =1.28x10" va teLuolt-X) “Taxos knoll DFor CSTR at 25C ty + m min = 0.002mn? J minx 8konol /m™x0.1 128x1g- Anal min Amol = 281.25m" 2)At288C, «1, = 0.00333- va 2eCaall- x) Taxes . , ¥ = 2.002? mint Bkmol dm 0.1 _ 6 1g) P3-14 CaHliO6 + 20, + BN + e(Caatty sNowO12) + IO + eCO; Eorraiculae the yields of biomass, you mus first balance the reaction equation by finding the coefficients a, bicvd, and. This can be done with mass balances on each clement involved in the eaction Once al the P3-14 (a) 3s Digitaizado com CamScanner2 Scribd company Pessl Resolugao fogler 4ed. QD Bw Jéssica Kulhavy 07 de Jun de 2015 + 40 gostaram + 17.768 visualizagées ‘Apply ens tlance fac Gadicve FO Gs 2ae L220 do2e FAN boos Fall Bytbet3ee2d ‘Also, 62/9) =44e which pres = 0909 Next we solve for tsng he thr carton balance Gadd O46 ena We eansole for b sing he sogen tance be O86 086" (0909) 78 [Next we we he hyhopen balance to salve fd Soe 736020 +3078) «71090 24 ar ally we sole fora wig the expen balance Geen ldesd rae 65 2a 1210908) + 385 20 ¥] P3-14 (b) ‘Assume rs lose (180) sects: Year mas of ells /massf laose = mas of cls 180g as of els = (molar weight) = 0 909 (91 4pm) smamsof colt 83 12g Yaa mas of els mas of we assume | mule of gcse reacted, hea 147 moles of Oy ae need and 89.12 fells ate rodent rmassof Oy = 147 mat *(32 pw) mass of 0) 4704 Yous BLI2g HTO4g Vous 8 Digitaizado com CamScanner3-15 (a) [uothrmal as phase reaction 13 ty +3n, 9M SNy+ 5H, Nl, Mating Hy athe basis of clelation: 1y 92 H,+4.N, 92M, a3) 3 Vp? ttn AegBoge Stichiomewic tbe [Sol | taal [iy [a1 Bs [8 [Fro dpFoo | mile To P3-15 (b) “wo (1-X) _ 02(1-X) . weg aoa ma 3 Ceol =X). 2,021) 29 mots dn! 0, {eex) 3 (-E P3-15 (c) PIS, seat L < s6desss > ia Ww Solucionario Fogler ot Digitaizado com CamScanner= WD ascrivdcompany TAM Resolucao fogler 4ed. DO S - Jéssica Kulhavy 07 de Jun de 2015 - 40 gostaram - 17.768 visualizagées 1-X) v8 3, (2) Fox bate sytem, conta volume win etal [6a] (eur [(-2)ft0-F 21 fi-% xy 3-16 (a) Liga pe eon ase coasn voteme Rae Ln everblereacton? & onetles for Stachinneey: C,=CulI-X). Cy =Cu(I-X). C= CygX “Totind th eqiitiom comer, t=O, combine schon nthe rae. and sere for X CC, Ke = Ce Cholt-X,) Ke = CX, 4 l xt (2+, x, +120 . ( wat} . x, =0.80 ‘Torin the equlinium coecenations, subsite he ealiviom conversion into the sic hometc selon 320 Digitaizado com CamScanner= WG aseriba company Soee—COR Resolugao fogler 4ed. DO km Jéssica Kulhavy 07 de Jun de 2015 + 40 gostaram - 17.768 visualizagées & =Cy(1-) = 2224 (1 080) 04-5, Cr= Cu (I~ x) 2 080) 045% a= Ck = 20080-1625 3.16 (b) Swicki: = yy5™ (I)(3-1) 2 and Q =0 Cyn Mee Malle X) gtx), Vv W(leex) ~*(1e2x) Gowen aX ax V “Wlieex) [ls2x) (Combine and solve for X kK x,) ax, } Reowttaayy [cog] Ke(I-X,)(142K,) =270,x? (2) 43K, 41-0 x,=058 quite concertos: 10am Cy athe. Fh (400 x) 008: (1-058) et exo +2(0:58)) cin _24038(0305)_ oe Tre (038)) =o P3-16 (c) ‘Same reaction. re law, and ntl concentration asp (0) ga phase, batch reaction 31 Digitaizado com CamScanner2seribécompary —(_ Pesquisar ) Resolucdo fogler 4ed. DO @ ws Jéssica Kulhavy 07 de Jun de 2015 + 40 gostaram - 17.768 visualizagées Conic nt eX, KCallX,) "(000%)" 39 teen 6,=(0305)1-039) 049% = (03902-0304 P3.16 () (inpatient pach ea Ee are mites) "Tey ple cena & < 89deses > fo Solucionario Fogler Digitalizado com CamScannera Scribd company \ nesqulser J Resolugao fogler 4ed. QD @ ov Jéssica Kulhavy 07 de Jun de 2015 « 40 gostaram « 17.768 visualizagdes (0.305) (0.58) 142(058) cad P3-17 ‘Gives: Gas phase reaction A+ B-> SC in batch ect ited with piston sh dl Si Grp na btch resco fed with piston ch that ty =ACICy soy Trace VME (itex) oe vEaUg(Ieek) Me= Nall X] Me=NualQ-X] 0,2 Nit ot am oe capa AMEN, NGfL]? antec, = WN. Naalt= x] Wa ( 2a v We(l+ex) ar te Trereone a Digitaizado com CamScannerResolucao fogler 4ed. DO Siw Jéssica Kulhavy 07 de Jun de 2015 + 40 gostaram « 17.768 visualizagdes oreesoseio LAAT, Wiel (ax 3-17 (b) veewg(ivex) 02" «015'(t4ex) 9 P3-1B nossa corsa, ay < 91desss > ra La Solucionario Fogler a Xi P< Digitaizado com CamScannerWELS*C)=192om/ CDP3-B Polanyi equation: E = C~ a(-AHa) ‘We have to calculate E forthe reaction From the given data table, we 68=C~a(l75) and 6.0 C-0(20) => C= 124 Ki/mol anda = 032 Using these values, and Ala =. 6 kcal/mol, we get E'= 10.48 KJ/mot —_—.?> CDP3-C (a) ADB Rate law at low temperature: — 14 = kCy ‘The rte law higher temperature mast: 1D Satisfy 32s Digitaizado com CamScannerResolucdo fogler 4ed. DO @ Jéssica Kulhavy 07 de Jun de 2015 - 40 gostaram « 17.768 visualizagées cors.c@) Ractwstbnenpeaae =m £1C,"Cy ‘Serene mt fe cDP3-C(e) PP, PR, Weta, Ky = oho pp, — Pho Kyo ip nt, Meo Me sna ea P+ aly # Koh + Koh a6 < 93desss > ae Solucionario Fogler Digitaizado com CamScannerCDP3-D >) e » ANIL, + 50, -- 4Ko + 61,0 - 0.8) PeB2 ate | T= 2278 = 500K *T3.0 Assuaing 14: yg 2 FE = Ge eh at = 0.2 gaol/t to Rr, lata o gota (500K) Gran, | 7 Tea, , Cre * (0+152(0.2 gmol/1) = 0.03 gnot/t 3.0 3.0 3 2 Mis + 70, —> No +> 0 Compound Symbol = Tnitial Final 1, 4 e.as 0.35% 0.15¢1-2) = - (0.182) °, B 0.38 Sco.1sx) o.28- 3 0 © ° s0,35x 0.18z 2 3 #0 D ° + Ho.1sx) + do.sszy N, o 0.67 T ar 15E) «a + 87 400.155) Tnitiol N, = 0.79(1-0.15) = 0.75¢0.85) = 0.67 Taitial 0, P path — AEP RDP 02 ate ae? c- = = 0,2 anh «4 1 TOOTS oH eeacon) 1 yea 327 Digitaizado com CamScanner1 P, (ated a 0.15(1-2) 133 st TeT0.25741k 9:03 T0457 and MLEaS/4L0,151), One =F Connsy 2D (0 036 — ML aya ME Dy x O15. © ousK arma oorx fry Ex 4 2 wow on dream wa s.otsePald xy on pat on a0 para sand 1 4 a oheck Proy I(0.15/4)E ~ LEU Lg, {0.15/05 o.1s rev, adn 2) Constant volune Cpe 02 a Py = CRF = (0,082)(300)(0.2)n, = 8.2 vy 4 1 oy ™ a 0.15¢1-2) 0.03 (1-2) a oS to.ssx 0.036 - 932 5 ¢ oa x 0.03 x D 2 to.asx 0.045 x I 0.67 0.1233 5.49 0.199 + 0.008r 3.2 - 0,313 5 ou -O.2 (le + x 3B Digitaizado com CamScannerResolucdo fogler 4ed. Oo aScribd company = esquisar Jéssica Kulhavy 07 de Jun de 2015 + 40 gostaram - 17.768 visualizagées Pag ¢ 82 = 0,313 Fame 3) Sane ne OD ¢) 4A45B24C+6D Mole balance for a PFR Ts oF 4 av Ss=-r, a5 aFe =-r 8 aF y av =-" Rate Lax(assume elementary): ar 2kC,'C,* Cratos wi epson 340 ud 348 .04(42)(_& _)(_4 an) Rvne |e Heo 5i(Fo.)(__* __)(__4 aR) Eth Fe) (Fak, he He, 4{ta)(__& _)(_&_Y wlan) (Rane) (Rahoe oy, a eellastvnllaston q Digitaizado com CamScannerMix) Naty Rik Nal aco Ba Net6eD Natdenory Mok Wel) Nagnren, PO Stole Waivie alate Nag-¥, ®B~ Cao/Cag = 6/23 X = Nag-Na Pe = ayo 0.25 i Final cone. of snes oF 6 pt26-200.25 5072 o ‘ *Hisal cone. of bensytuaide « Af ae D309 0.28) «0.8 gaeild ©) Stoicbiesetsic tate ter a tow 17cm osiog anneal as the basis £.p pre E.2 ra 885 > ts V <€ 97de eo Solucionario Fogler Lr ODVeow: Digitaizado com CamScannerSpecies Symbol Entering Change Exit Concenration Ammonia B Foo -FeoX = Fro(I-X) Fol l-XWvo Benzo chloride A 8,Fuo -FoX/2 Fao(®,-X/2) Fao(@p-¥2vo Benzylamide ~«C — OcFno — FaoX/2- Fro(8c+X/2) Fuol8ct#evo Ammonium Chloride D = @pFs0 FaoX/2 Fao(@p+X/2) Faol®p vo Table for the flow system asing ammonia ax the basis is different from the original in the folloviss ways. 2) Molar flow rates considered rather than aumber of moles. 2) 0) = Fy /Fyge as opposed to Mi /K,, found by dividing the exiting molar Clow se vy the CDP3-F Given : A+B -) C taking place in a square duct. P, = 1 ata. = constant x + 105 £23/(1d.mole) (see.) T = Ty = 540°F = 1000en P= 0.25 ata. = 165 1b wote Fo G) eB tae Alibelem in the gas phase throughout the reactor Cyn GE 7 constant. Since Busiatains its equilidrine vapor pressere throughout the resetor, as soon a 1 molecule of B is consumed by the ceuction, At Us replaced by a solecole of Bin the Liquid. Hones, $= 2-1-0, 8 > Toh 31 Digitaizado com CamScanner“21; ide the reactor, wr, EC, Cy = E Cag Cygla-X]: Just inside the Yrofo _ -Fp0'?o ~ RT Cxo * — BT Fo O32 -) ote mE ECASR OE Ypol2-Yno! Gy (1-K) (be) Ac le 0.5 fr _3 meq Timetcbeesey (EE ssl t8 ated) 9,5) = cara Abele CRO EE x 20008)? te cpP3-G Bs 3 SLHC)s + 3H; 251 (S) + THC + SiH: Ch Take S; HCI; as basis SLHGy + Hp 2Si() +2 HO +d SHC SHHCh@) A Fro Fox Fa =Fro(l-X) Ha) Bios O3Fao © Fao Fa = Fiala -x) HRHClig) CC ° +ZFioX Fo = LF, X Si HyCh () D 0 eheox Fo =p FaoX Si(s) s 0 ZF pox: 7 332 Digitaizado com CamScannerAssume isothermal and conscant pressure. Neglect the vapor pressure of Si(s) @p = 1 Stoichiomeric feed 6 only involves the changes in gas phase © enysod=L(L+1-1-1) e=}8)-4 Cao = Yao geo = 2, Liomaitaml Cao = 0.0088 mold aan (= 9.0088 (1X) med Coots 7g T+x5 Ce = Bt» c,{0n-¥) . ooots t-29) 1+XB » Feo 2__FacX_ Cos $= Figateg 7 SC Meg + 000 aay 1 Fk x $0001 a7 ‘Une solution to parts (b) and (c) » 2S) HO) + 2H ~9 5; (S)+ SHC + SSHOs, 8 2S) HO — $,+ 2H + SHC ‘are similar to Past (a). CDP3-H 4 Cl, + CH, —-) CCL, + 4HCL Tes 159C = 348 5 P= 950 ¥Pa = 9.39 ata Cl, vapor pressure = 95 kPa = 0.94 ate = Digitaizado com CamScannerSo we can ase the stoichionetric table, substitoting C's for F's 1 F ¢ A Fygta=x) Colt) Bo AFAg(1-Z) Ag t-3D c Fg Myo X D F, 0 x ¢ 0 x 5 Fro 5 oho where Cig = 0.0658 gaol/t and Fag - 0.02631 enol /s After cosdensacion 1 & = wee ey CA se ° Fie os Fro (0.90) oe 4.5 FF, Mote: at X= 0.5 (bepinsing of cee ara condeasation) Cy = Ct jo GT A ‘SF ar-F aX. Caaf 1-XMAS5-X) B FroS-X) AC ro 1X4. SS-X) c 4Fa0X ACeX4.SUS-X) D OF AS-XYO9 ___ Caol5-X)(4.5(5-XY9=0.5Cx0 Total FaatS-X)+Fact5-XV9 Cao -XV 40.5 whore Fi = 0.02631 gnol/S and C,, = 0.0658 gzol/L 34 Digitaizado com CamScannerBe ote Stolen Tedte Cy © ACL, > auch + CCL, Asvune ateledionctric feed Fy Species Syedot Ta cy Rag Ragt Fy FygKte®D Taott cya “Argh Rye AP yglteDD gt) Hohhot it cet, ety Fgh o.itiy wu 8 = - tro * an Ti he FoF gh ary 1 . fem .., 5 Fg * Fag SGM --) 2, = 0.80 Before Condensation Ea rpd S80 rene AT = 4P = 0 --> Total cone: Cy = 3 egy = S22 nets = 0.0658 gett Fro Cag My ~ (0.0658) geot/t (0.4) 1/2 = 0.02631 gnats Digitaizado com CamScannerCDP3-1 C84) © 28246) —) CR Sey (G1) & 28BeL ed Te 200% = 412 EP» 2500 EPA = 24,7 ate p = 506.5 ea VCE ae, P wt, ES. Ye" F* as0g * 9203 Steich table Cogls) + 2 Bry(e) --> 2 MBe(g) + C)H{Br(e.1) assume stoichiometric feed Species Symbol In._=— Change “F,before After condensation Pp = condensation Py Py remaining ‘ 7 VGA “C v, (3-2) e Note that at X = 0.609 (beginning of condensation) C, = Ci “ a 7 Clgpaum + can " ca ean or [ty +r Ft (geal) 02} 7 |r ro a eas CDP3-J Digitaizado com CamScanneroS company. Resoluc3o fogler 4ed Oo Jéssica Kuthavy Yu 503 #8 a8 O501412-3-)u P, Ca0 = YaoCzy = 0. Fo YaoCre off ¢, G= net = 6.18"10% alee 73K 2.06=10+x fe + 143xX 2.47*107 x oe “on 1ess10-(1 C= vax 2.08104 x < » 13K Rarmio'x fee= 13x Digitaizado com CamScanneCDP3-K HC) + 2 cryCe > caergte.a) + amend (0) Sososseat © Sembol Initial soles Chane oo c12 a 2.0 x ar cu B 0.5 ~O.sr 0.5(1-2) CE2C12 c 20.5 0.st EL > = z Total T 1s Ls O) eers2-a- "Oy 2.0 atl ate. Digitaizado com CamScannerResolucio fogler ded, Jéssica Kulhavy 07 de Junde 2015.49 8ostaram. 17.768 visualizacées (eo a, = Sno" UF + oahae the Oveanae tanh “A Sho GEN » 0.02024 (300.6) « O.010s0 ABet (mye 2k es ae a" 3 CO.2ho.027203 (.9,6)3 hae7 5 107 got a a Bee sott et 0.2 wae aod : ‘atm ae ase w Digitaizado com CamScan