First Class achineryY Service! SAFETY DATA SHEET (SDS) 1. CHEMICALS AND VENDOR INFORMATION (CHEMICAL NAME-F10 OTHER/GENERIC NAMES: RECOMMENDED USE AND RESTRICT THE USE OF: MANUFACTURERS, INPUT OR SUPPLIER NAME: 3P Machinery Co., Ltd. 1 Lane 8, Hebei E. St, Taichung 40669 TAIWAN Tel: +886-4-22473218 Fax: +886-4-22473180 e-mail:padpak@ms29,hinet.net Emergency Telephone Number: +886-4-22473218 Fax Number : +886-4-22473180 2. HAZARDS IDENTIFICATION Chemical Hazard Classification: Flammable liquid Class 2, Class 4 acute toxic substance (ewallowing), corrosion / irritation Category 2 substances, severe damage / eye irritation Category 2A, a hazard level 1 Marked: Waming Symbol: ©.O. Signal word: Danger Hazard: Highly flammable liquid and vapor. Causes skin irritation Cause severe irritation of the eyes Harmful when swallowed Long-term or repeated exposure may cause damage to organs If possible fatal if swallowed and enters airways Phrases: Place container in a well-ventilated place Product away from ignition - No smoking If contact with eyes, wash immediately with plenty of water after medical consultation Prevent electrostatic Avoid release home environment Other hazards: - FIO. Page 1 of 10SAFETY DATA SHEET (SDS) 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixture Hazardous substances Common Name CAS No @ercentage composition) ‘Isopropyl alcohol 67-63-.0 30=10% (Toluene 108-88-3 15=10% “sobutyl alcohol 78-83-1 15=10% Polyamide resin 68139-79-7 30410% Pigment = 105% 4.FIRST AID MEASURES Different exposure routes first aid: Inhalation: 1 If the patient is unconscious or reactive, rescue before the first good physical protection measures to ensure their own safety. 2. Removal of the source of pollution or the patient is moved to fresh air. 3.1f breathing stops, artificial resuscitation immediately by a trained person: cardiac arrest Resuscitate. 4. Immediately taken to hospital Skin contact 1. Immediately ease the brush off or siphoning off excess chemicals 2. Ease of cleaning of water or non-frosted thoroughly with soap for at least 20 minutes, or until the contaminant removal 3, Take off contaminated clothing, shoes and leather accessories Flush. (such as strap belt) 4.As rinse irritation persists, seek medical care immediately. 5. Contaminated clothing, shoes and leather accessories will need to remove the dirt completely before reuse or discard, Eye contact: immediately eyelids, with running warm water to wash contaminated eye 20 minutes. 2. Rinse to be careful not to let the eyes rinse water is not polluted with pollutants 3. after flushing throw with irritation, wash repeatedly. 4, Immediate medical attention. Ingestion: F10 Page 2 of 10SAFETY DATA SHEET (SDS) 1 lf the patient is about to lose consciousness, lose consciousness or spasm not anything after taste 2. patients with clear minds, their mouth thoroughly with water. 3. Do not induce vomiting. 4.Let the patient drink 240 to 300 ml. 5. patients with spontaneous vomiting their body to lean forward to reduce inhalation hazard, and let the mouthwash and water repeatedly. 6 If breathing stops, give artificial respiration immediately by a trained person, if cardiac arrest cardiopulmonary resuscitation. 7. Immediately hospital. 5.FIRE FIGHTING MEASURES Suitable Extinguishing Media: Dry chemical, alcohol foam, polymer foam, carbon dioxide Special hazards that may be encountered when extinguishing a fire: before extinguishing the fire managed to stanch or spills vapor form explosive mixtures in the air and ignited. Special fire fighting procedures: (1) water extinguishing is invalid, but can be spray the cooling water inside of the container, to prevent the expansion of an explosion. (2) fire fighting personnel should wear protective equipment and respirators in the wind at the fire-fighting 3) stop solvent leakage and flow together with a fire extinguishing agent. if possible, try to remove the storage vessel, or water cooling container near the disaster area, pay attention to water and do not get too close to the isolated the leakage area all sources of ignition. @) the solvent liquid floating on the water, may spread to distant fire spread. (6) easy-oxidants react violently. (6) the vapor Mars ignite easily and are heavier than air and the solid may spread to distant, when in contact with an ignition source will spread back. (7) to make use of automatic or fixed fire extinguishing equipment fire. (8) If the leakage area yet to fire to disperse the vapors, mist, and protection to prevent the leakage of the safety of personnel, but aot to the escape of the oil mist sprayed directly. Special protective equipment for firefighters: Fire protection with a full set of clothing and air-supplied or self-contained breathing with. FIO Page 3 of 10SAFETY DATA SHEET (SDS) 6.ACCIDENTAL RELEASE MEASURES Personal precautions: (1) the contaminated area has not been fully cleaned up before the area close to limit non-essential personnel. Q determine stanch and clean-up work is responsible for by trained persoanel ) notify the government health and safety, environmental protection, fire units. G) to avoid the escape of material into the sewer or confined spaces. 7. HANDLING AND STORAGE, Methods for cleaning up: (1). Remove all sources of ignition, not touch Transudate. (2) The closure of the contaminated area, near the evacuation. (3) Use water spray to the scene to reduce the concentration in air. (4) leakage relief workers must wear positive pressure respirator comprehensive type since portability. (5) the disaster area near the absclute prohibition of fireworks. (© Leakage drive the implementation of effective ventilation, blocking solvent source concentration Note detonated (1) such as for small-scale leak, available sand or other sorbent after absorption line processing and then placed in a clean sealed container (8) If the need for large-scale leak built dike containment (with soil, sand bags. concrete ot Polyurethane), to avoid allowed to diffuse out, and then collected to be processed together (9) can not be transudate into drains, to avoid burning explosion. Disposal: (1) of this type of flammable liquid substances and toxic liquid disposal engineering controls should be running and unauthorized use of personal protective equipment staff shall be subject to the safe use of appropriate substances risk method of training, (2) Remove all ignition sources and incompatible materials away from heat. (3) The work area should be prohibited fireworks, and "No Smoking" signs G) the liquid accumulated charge. consider additional design to increase the electrical conductivity. All tanks, transfer containers and pipelines have grounded, grounding must come into contact with bare metal transport operation should reduce the flow rate, increased operating time, increase the time of liquid left in F10 Page 4 of 10SAFETY DATA SHEET (SDS) the pipeline or low temperature operation. (© When the deployment of the operation is not carried out in a closed system, to censure that the deployment of the delivery of the container and receiving equipment and containers have to wait for potential connections. (© Empty tanks, containers and pipelines may still contain hazardous residues, the cleaning up of the former shall not engage in any welding. cutting. drilling or other hot work. (1) Operating avoid mist or vapor, operate in a well-ventilated designated area and to adopt minimum so that the amount of use, the operating area is separated from the storage area Storage: (1)Process of the use of compatible materials storage containers, dispensing careful not to spray out. Do not allocate storage area, (2) Do not be material to use (such as strong oxidant) so as not to increase the risk of fire and explosion. @) Do not be affected by the contamination of the liquid back into the original container, (4) The containers should be labeled, Paul tightly when not in use and avoid damage. (5) The storage area should be marked at the channel without obstacles, now specify or trained personnel to enter. (6 Check all new containers are properly labeled and no damage. (1) stored in a cool, dry, well-ventilated, and direct sunlight, away from heat, light source and incompatible materials. (8) mounted in the storage containers made of compatible materials spills. (9) the area of the storage area and a large number of operations, consider installing spills and fire detection systems and automatic fire control system or sufficient available emergency treatment equipment. (10) the door slope or threshold, or digging a trench so that the spill can be ischarged to a safe place. (11) tank for ground tank, at the bottom of the entire area should be sealed to prevent leakage around the entire capacity of anti-overflow embankment must have energy containment. F10 Page 5 of 10SAFETY DATA SHEET (SDS) 8.EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Provide general or local exhaust ventilation systems to maintain airborne concentrations below exposure levels. Regularly inspect all electrical and mechanical equipment used with or toluene. Ground and bond metal containers to minimize static sparks PERSONAL PROTECTIVE EQUIPMENT SKIN PROTECTION: Protective gloves and clothing are recommended. Vintoa or nitride rubber offers acceptable chemical resistance. Clothing should be static free. EYE PROTECTION: Wear safety glasses with non-perforated side shields for normal handling. Goggles or a fall face shield may be necessary depending on quantity of material and conditions of use. RESPIRATORY PROTECTION: ADDITIONAL RECOMMENDATIONS: Emergency eyewash fountains and safety showers should be available in the vicinity of any potential exposure. EXPOSURE GUIDELINES [OTHER [LIMIT 400ppm 500ppm = =- INGREDIENT NAME, TWA STEL GEILING Personal protective equipment: respiratory protection: a comprehensive anti-organic vapor and droplets of respiratory protective equipment Hand Protection: Impervious gloves. Eye Protection: Chemical safety goggles and face shields. Skin and body protection: coveralls, safety shoes or other protective clothing. Health measures: (1) should use the qualified protective gear, and daily to check whether the damage be updated. @) Do not wear contact lenses work, attention to personal 549 pyee Gof 10SAFETY DATA SHEET (SDS) hygiene, working to complete the necessary cleaning and off overalls, before eating should face with soap and water to wash. @ work spaces non-smoking or dict. (@) Keep the work area clean. ©) for regular health checks 9.PHYSOCAL AND CHEMICAL PROPERTIES [Appearance: [Olfactory thresholds Liquid 3.3 ~ 610ppm (detection), IColor: Odor: |depending on the ink color [Rubber alcohol taste PH: — Boiling point / melting range: 182.3 °C /-88.5 C [Flammability (solid, gas): — [Decomposition temperature: — [Flash Point Test Method: Closed Cap leg Henition temperature: [Explosion limits 399 2.0% to 12% |(Ray’s) vapor pressure: Vapor Density (Air = 1); [33 mm Hg @ 20 °C 2.07 [Density (water = 1) Solubility: lo.785 [Completely soluble in water |Octanol / water partition [Evaporation rate: coefficient (log Kow) 1.5 (butyl acetate = 1) 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Special Conditions of Hazardous Reaction: a strong oxidizing agents (such as peroxides nitrate or perchlorate) increased the risk of fire and explosion Chromium trioxide: ignited due to severe oxidation. Perchlorate, barium chloride, ethylene glycol, isocyanates, hydrogen peroxide, sulfuric acid, hypochlorous acid, nitrogen tetroxide: Mixed explosion. Conditions to avoid: heat, sparks, static electricity, ignition sources, light Substances to be avoided: oxidants, chromium chloride, perchlorate, barium chloride, ethylene glycol, isocyanates, hydrogen peroxide, sulfuric acid, hypochlorous acid and nitrogen tetroxide Hazardous decomposition products: - F10. Page 7 of 10SAFETY DATA SHEET (SDS) 11. TOXICOLOGICAL INFORMATION Acute toxicity: Skin: 1.Caused mild irritation. Tahalation: 1 Vapor can irritate the nose and throat. High concentration will seriously irritate the aose, throat and respiratory tract, causing coughing and difficulty breathing and suppress the central nervous system, causing nausea, vomiting. headache. dizziness, and may even lose consciousness. Ingestion: 1.will suppress the central nervous system, causing nausea, vomiting, stomach pain, chest pain, headache, weakness and dizziness. 2.The excessive ingestion lead to coma and even death. 3.May damage the liver and kidney Eyes: High concentrations of vapor may cause irritation, LCS50/LD50 (test animal, the route of exposure): [INGREDIENT NAME LD50 L30 [4710mg/kg,( Rat, ingestion) [16000ppm/8H Chronic toxicity or long term toxicity: Long-term excessive exposure can damage the nervous system, causing nausea, dizziness, vomiting, and other symptoms [INGREDIENT NAME LD50 LC50 [4710mg/ke,( Rat, ingestion) |16000ppm/SH Chronic toxicity or long term toxicity: Long-term excessive exposure can damage the nervous system, causing nausea, dizziness, ‘vomiting, and other symptoms. Long-term skin contact may cause skin redness, drying and cracking, causing dermatitis. 12.ECOLOGICAL INFOROMATION Ecotoxicity: ECSO bioconcentration factor LC50 (fish) coe) | qq) (BCF) Persistence and degradability When released into water, is expected to be volatile and biodegradable. 2with a high degree of anti-biodegradable FIO Page ott0SAFETY DATA SHEET (SDS) When released into the atmosphere, is expected to be photolysis role phase halflife of afew hours from the urban air pollution half-life (water half-life ee eo 6.2~7.2hr 24~168hr 48-336 24~168 Bioaccumulation: quickly broken down in the body, and excreted in the urine, and therefore do not accumulate The fluidity of the soil: the release of home soil is expected to quickly evaporate and into the underground. Other adverse effects: — 13.DISPOSAL CONSIDERATIONS OTHER DISPOSAL CONSIDEERATIONS: Dispose of material in accordance with all applicable local, state and federal regulations ‘The information offered here is for the product as shipped. Use and/or alterations to the product such as mixing with other materials may significantly change the characteristics of the material and alter the RCRA classification and the proper disposal method. 14. TRANSPORT INFORMATION: US DOT HAZARD CLASS 3,Flammable Liquid US DOT ID NUMBER: UN No. 1866 Transport hazard class Class 3 Flammable liquids Packing group 0 Environmental hazard: No ‘Transport/Additional information FIO Page9 of 10SAFETY DATA SHEET (SDS) 15.REGULATORY INFORMATION: Applicable Regulations: Occupational Safety and sanitation rules Labeling of hazardous chemicals and Liberal rule Permissible Exposure workplace labor standards Road safety rules Industrial waste treatment and storage facilities Clear Standards Public hazardous materials and can then set the standard high pressure gas and Security Measures 16.OTHER INFORMATION: 1The Center For Safety & Health Technology & Industrial Technology Research MSDS CD data 2. HSDL Database, TOMES PLUS CD,VOL.65,2005 3. cheminfo Database, ccinfo CD,2005-3 4, RTECS Database, TOMES PLUS CD,VOL.65.2005 5. HAZARDTEXT Database, TOMES PLUS CD.VOL.65.2005 6. Chinese Hazardous chemical substances database. EPD 7. Chem Watch Database,2005-1 Watchmaking sectorRD 3P Machinery Co., Ltd. 1 Lane 8, Hebei E. St., Taichung 40669 TAIWAN Tel: +886-4-22473218 Fax: +886-4-22473180 e-mail:padpak@ms29.hinet.net DATA:2017.07.24 REMARK: —No reference