= =| ‘Subsidiary of Greatbalch, In ° = G70 Perameurt bre ; Electrochem Solutions, inc Greatbatch CREATING TOMORROW Raynham, MAO2767 USA Tel: 781,830,680 Fax: 781.575.1545, MATERIAL SAFETY DATA SHEET Issued: 8/30/2011 ‘Section — IDENTIFICATION. Product Name: LITHIUM THIONYL CHLORIDE CELLS AND BATTERIES Hermetically-Sealed Lithium Thionyl Chloride Cells & Batteries 1m 100, 150, 150/165MR, 180/180MR, 200/200MR series, QTC, MWD, VHT Cellsand Barter All Electro ‘Section 2 COMPOSITION/INFORMATION ON INGREDIENTS, Thionyl Chloride ‘OSHA: 10pm (S.0mg/m3) eeling 7719.00.7, ACGIH: LOppm (5.0mg/m3) ceiling Lithium . Sa ‘TLV/PELNA Corben. ACGIE: 35 mg/m3 TLVITWA, 1333-864 = Section 3~ HAZARDS IDENTIFICATION “*DANGER* INTERNAL CONTENTS ARE EXTREMELY HAZARDOUS, LEAKING FLUID IS CORROSIVE AND. DANGEROUS UPON INHALATION, BATTERY MAY BE EXPLOSIVE AT HIGHER TEMPERATURES. Do not expose to temperatures above the maximum rated temperature as specified by the manufturer due to Teak hazard If cell or battery leaks or vents Primary Routes of Entry: Inhalation Carcinogenicity: Not lsiod by NTP, IARC, or regulated by OSHA. Health Hazards: Acute ~ Vapors are very iritating to skin, eyes, and mucous membranes, Inhalt ‘or sulfur chloride vapors may result in pulmonary edema, ‘Chronic — Overexposure ean eause symptoms of non-fbratie lung injury. ‘Signs and Symptoms of Exposure: Eve and mucous membrane initaton, Medical Conditions Generally Aggravated by Exposure: sthia, othe respiratory disorders, shin allergies, and eczema ion of thiony| chloride ‘Section 4— FIRST AID MEASURES Eye Contact: Flush with running water fort least 15 minutes. Hold eyelids apart. Seek immediate medical attention, Contact sults in acidic burns, Skin Contact: Rinse with large amounts of running water. Avoid hot water and rubbing skin. If bums develop, seek medical tention, Contact results in acidic burns. Inhalation: Remove to fresh air. If breathing is difficult, administer oxygen, Ifnot breathing st in poimonany edema, Ingestion: Drink copious amounts of water (or milk if available). Do not induce vomiting, NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON, Immediately seek modi anificial respiration. May Page 1 of 4Section 5— FIRE FIGHTING MEASURES: Flash Point: N/A Auto-Ignition Temp: N/A Flammable Limits: N/A Extinguisher Media: Copious amounts of water. Lith-X powder. Class D fire extinguisher. Dry Lithium Chloride, Graphite Powder, Pytene Gel may not be effective on resulting secondary fies. Special Fire Fighting Procedures: Cover with Lith-X powder, Class D fire estinguisher, dry lithium chloride, of graphite Powder. DONOT USE CO:, Class ABC. or soda ash extinguisher. Wear protective breathing apparatus; a positive pressure Self Contained Breathing Apparatus (SCBA). or Air Purifying Respirator (APR), Be aware of secondary Tires, Unusual Fire and Explosion Hazards: Do not shor circuit recharge, over discharge (discharge below 6.0 Vols), puncture «rush or expose to temperatures above the maximum rated temperature as specified by the manufacturer. Cell may’ leak, vent, oF explode. Ifa bright white flame is present, lithium content is exposed and on fie. Section 6~ ACCIDENTAL RELEASE MEASURES, aa arene ane Accidental Releases: Do not breathe vapors or touch Tiguid with bare hands (see seetion 4), Waste Disposal Methods: Evacuate area. If possible, a trained person should atempt to stop or contain the lak by neutralizing spill wth soda Time or baking soda. A NIOSH Approved Acid Gas Filter Mask or Self-Contained Breaths Apparstus should he ‘Wor. Seal leaking battery and soda ime or baking soda ina plastic bag and dispose of a hazardous waste Other: Follow Nozth American Emergeney Response Guide (NAERG) #138 for cells involved in am accident, cells that have vented, or have exploded. Section 7 HANDLING & STORAGE, ells should be stored at room temperature, approx. 21°C (70°F), Do aot store bateres in high humidity environments ils, High Temperature storage Will degrade performance Do not short cireuit or expose to temperatures above the maximum rated temperature as specified by the manufacturer. Do not recharge, over discharge, puncture or crush Other Conditions: Do not store ces in close proximity of other combustible / flammable material Seetion 8 EXPOSURE CONTROLS / PERSONAL PROTECTION | ‘When handling internal components: Respiratory Protection: NIOSH Approved Acid Gas Fier Mask, or SeiContained Breathing Apparatus Protective Gloves: Nitile or PVC, Gloves should be 15 ml (0,015 in). o thicker. Eye Protection: Chemical Worker Safety Glasses or face sie, Ventilation To Be Used: Negative pressure chemical fume hood. Other Protective Clothing & Equipment: Chemical Laboratory Safety Gi Clothing, and face shield Hygienie Work Practices: Use good chemical hygiene prac ary contact. Protective Apron, Acid Resistant Protective ce. Do not eat o drink when handling contents. Avoid Section 9 PHYSICAL/CHEMICAL CHARACTERISTICS aay ae aint Boiling Poi Thiony] Chloride: 770 Vapor Pressure: Thiony! Chloride: 92mm @ 20 °C Vapor Density: Thiony| Chloride: 4.1 (air = 1) Solubility in Water: Thions! Chloride: Decomposes violently on evntat with wa Specific Gravity Thion$! Chloride: 1.63 gems Melting Point: Thionl Chloride: -108 °C Evaporation Rate: No Data Water Renetive: Thiony! Chloride hydrolyzes to form SO2 and HCI gasses and sirogly acidie wastewater. Appearance & Odor: Thion! Chloride - Colorless to pale yellow sharp. pungent odor Other: Iniemal contents contain Bromine and Chlorine ey Section 10 - STABILITY & REACTIVITY LL s Incompatibility: VA Hazardous Polymerization: Will not occur by the manufacturer due to leak hazard emperatures above the maaimumn rated temperature High humidity for extended periods Hazardous Decomposition Products: Sulfur Diowide\y, Hydrogen Chloride i. Hydrogen NE spec Page 2 of 4Section 11 — TOXICOLOGICAL INFORMATION ‘Acute Toxicity (as applicable): ‘Thiony! Chloride Sulfury! Chloride UCen (inhalation): $00 ppm (rat -hr) LCuy (Inhalation): — 130-250 ppm (rat Li) LDy: NA LDa: N/A Eye Effects: Corrosive Bye Effects: | Costosive Skin Effects: Corrosive Skin Effects: Corosive ‘Section 12 - ECOLOGICAL INFORMATION, ‘Aquatie Toxicity: Do not let internal components enter marine environments, Avoid releases into waterways, ‘wastewater or groundwater Section 13 ~ DISPOSAL CONSIDERATIONS. Proper Shipping Name: Waste Lithium Batteries UN Number: 3090 Hazard Classification: Class 9 (Mise) Packing Group: I Labels Required: MISCELLANEOUS, HAZARDOUS WASTE Waste Disposal Code: DOOS Other: ll lithium thionyl chloride batteries should be disposed of by « certified hazardous waste disposal facility ‘Section 14— TRANSPORT INFORMATION US DOT (per 49 CFR 172.101) and IATAICAO, Proper Shipping Name: Lithium Metal Batteries UN Number: UN 3090 (UN 3091 for Lihium Metal Baeries Contained in Equipment or Lithium Metal Batteries Packed Wil Equipmen) Hazard Classification: Class 9 (Mise) Packing Group: Il Labels Required: MISCELLANEOUS HAZARD CLASS 9, LITHIUM BATTERY LABEL IATA 7.4.8) Other: CARGO AIRCRAFT ONLY (Forbidden as cargo aboard passenger aircraft) Shipping Requirements DOT: Lithium batteries and ces are subject to shipping requirements exceptions under 49 CFR 173.185, hipping of lithium batteries in aircrafts are regulated by the International Civil Aviation Organization (ICAO) and the International Air Transport Association (IATA) requirements in Special Provisions A48, A88, A99, A1S4, and A164 and Packing Instruction 968, 969, or 970 Section 15 - REGULATORY INFORMATION OSHA Status: his product is considered an “Article” and the intemal component (thions! chloride / sulfur chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 19201200, Section 16 - OTHER INFORMATION Lithium Battery Safety With proper use and handling. ithium batteries have demonstrated an excellent safety record. The suovess and wide use of lithium batteries is partially de tothe feet that they contain more energy per unit weight than conventional batteries. However. the same properties that result in a high energy density also contribute i potential hazard ith od at a fast uncontrolled rate. In recognition of the higheenergy content of lithium systems, safety has cen incorporated into the design and ‘manufacture ofall Electrochem batteries, However, abuse or mishandling of lium batteries ean still result in hazardous ‘conditions, The information provided here is intended to give users some guidelines wo safe handling and use of Electrochem Tihium batteries Cell Abuse In general. the conditions that eaus 3s include: + Short Circuit # Chargi + Fotwed Over discharae 4 Exeessive heating or incineration 1 damage to cells and jeopardize safety are summarized on the label of cach eell, These ‘Crush, puneture or disassembly ‘Very rough handling or high shock and vibration could also result in cell damage. Page 3 of 4Cell Handling and Inspection Guidelines ‘The most frequent forms of cell abuse can easily be identified and controlled in the workplace. It sour experience that inadvertent short circuits are the largest single cause of field failures Problems associated with shorting as well as other hazardous conditions can be greatly reduced by observing the following guidelines: ‘© Coverall metal work surfaces with an insulating materia ‘+ The work area should be clean and free of sharp objects that could puncture the insulating sleeve on each eel ‘© Never remove the shrink-srap from a cell or battery pack. ‘+ All persons handling cells should remove jewelry items such as rings, wristwatches, pendants, etc. that could come in contact with the battery terminals, {eels are removed from ther original packages for inspection, they shouldbe neatly arranged to prelude shorting. * Cells shouldbe transported in plastic rays set on pushcars, This will reduce the chances of ells being dropped on the ‘oor, causing physical damage, + Allinspection tools (calipers, rulers, et.) should be made from non-conductive mate feonductive tape ‘+ Cells shouldbe inspected for physical damage. Cells with dented cases or terminal caps should be inspected for electrolyte leakage. If any is noted, the cell should he disposed of in the proper manner als, or covered with a non Call Storage Cells should be stored in ther original container, Store cells n a well ventilated, cool, dry atea. Store ells in an isolated a ‘away from combustible materials. Never stack heavy objects on top of boxes containing lithium bateres to preclude crushing or Duneturing the cell case, Handling During Product Assembly All personnel handling batteries should wear appropriate protective equipment such as safety glasses, + Do not solder wites or tabs directly to the battery. Only solder wo the leads welded tothe eell by the manufacturer * Never touch acll case directly with a hot soldering iron, Heatsinks should be used when soldering othe tabs, and ntact withthe solder tabs shouldbe limited 10 a few seconds. ‘+ Cells should not be forced ino (or out of battery holders or housings. This could deform the cell causing an internal short circuit, or fracturing the glass to metal hermetie seal ‘+ Allovens or envitonmental chambers used for testing cells or batteries should he equipped with an over controler to protect against excessive heat perature ‘+ Only precision convection ovens should be used for cell esting, Lesser ovens may exhibit uneven heating and hot spots ‘hat ean exceed the rated temperature of the battery. # Do not connect cells or bateries of different chemistries together. ‘+ Dont connect cells or hattercs of differen sizes together. ‘+ Donot connect old and new batteries together. ‘Consult Electrochem before encapsulating batteries during discharge Cells may execed their maximum rated temperature if insulated, + Although we hove provided a general overview of lithium battery safety and handling. we urge you to eal us with any questions. Our technical services stafT will be pleased to assist you with your questions, NEPA RATING For cells or battery packs involved in an accident, cells that have vented, or exploded, Flammability, follow the North American Emergency Response Guide (NAERG) #138, > 24-HOUR EMERGENCY RESPONSE. PHONE NUMBER: (800) 255-3924 Rev. 20104 Date: 05/05/2010 Page 4 of 4