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GIB 31604.1-2015
GB 31604.1--2015
GB 31604.1--2015
GB 31604.1--2015
GB 31604.1--2015
t ≤0.5h 0.5h
0.5h<t ≤1h 1h
1h<t ≤2h 2h
2h<t ≤6h 6h
6h<t ≤24h 24h
1d<t ≤3d 3d
3d<t ≤30d 10d
Over 30d Can be carried out in accordance with the
provisions of 5.1.1.4
Table 4 Specific migration test conditions (temperature)
Predictably most extreme contact migration test temperature
temperature
T ≤ 5℃ 5℃
5<T ≤ 20℃ 20℃
20<T ≤ 40℃ 40℃
40<T ≤ 70℃ 70℃
70<T ≤ 100℃ 100℃or reflux temperature
100<T ≤ 121℃ 121℃(*)
121<T ≤ 130℃ 130℃(*)
130<T ≤ 150℃ 150℃(*)
150<T < 175℃ 175℃(*)
T > 175℃ Adjusting the temperature to the actual
temperature in place of contact with foods. (*)
(*)The temperature is only applicable to the simulant of fatty foods. For migration test
under conditions of pressure, it may be implemented via heating under pressure to
achieve the corresponding temperature. For the simulant of water soluble foods, and
GB 31604.1--2015
GB 31604.1--2015
5.1.2.3 For the food contact substances that are not allowed appearance as a specific
migration limit in detection, the compliance judgment is performed based on the results of
the first migration test.
5.2 Overall migration test conditions
5.2.1 Overall migration test conditions should be consistent with the provisions of table 6.
Table 6 Overall migration test conditions
Respected use condition Migration test condition
Frozen and cool storage 20℃, 10d
heating treatment without in container 100℃, 2h
Heating in containers before eating
Filling into a tin at room temperature for 40℃, 10d
long-term storage (including hot filling and
pasteurization under conditions: T≤ 70,℃ t≤ 2 h
or T ≤100.℃,t ≤15min)
After hot filling into a tin and pasteurization at 70℃, 2h
room temperature or below room temperature
without long-term storage under conditions: T≤
70,℃ t≤ 2 h or T ≤100.℃,t ≤15min
Use at T≤100,℃ t>15 m i n conditions (such as 100℃, 1h
cooking or boiling disinfection)
Use at T≤121℃ (high temperature sterilization 100℃,or Reflux temperature, 2h or
or distillation) 121℃, 1h
contact with waterborne food, acidic food, 100℃,or Reflux temperature,4h
alcoholic beverages and content of
alcohol≤20%(v%) food at T>40℃ temperature
Use at T>121℃(e.g., high temperature baking) 175℃,2h(only for vegetable oil)
But the test results at higher temperatures can replace the test results at a lower
temperature. Under same storage and use conditions, the test results in a short time can
replace the result in a long time.
5.2.2 For the materials and articles that unsuitable for the use of 5.2.1 provisions in the
overall migration test, the most stringent test conditions supported by a scientific evidence
should be chosen and it may be performed according to the specific provisions of the
national food safety standard ,
5.2.3 For repeatedly using food contact materials and articles, it should be performed in
accordance with the implementation of the 5.1. 2.2.
6 Screening test and alternative test of chemical solvent
6.1 Screening test of overall migration test
GB 31604.1--2015
For the specific migration of non volatile substance, it can be estimated by using the
overall migration amount measured under the same or more stringent test conditions test.
When the overall migration amount is less than the specific migration amount, the specific
migration amount may no longer be measured.
6.2 Screening test of amount of residue
For some of the most used processing aids or additives as well as unstable substances in
the or food simulants or the substances without analysis method, their specific migration
amount may be estimated via determination of the residual amount of the substance to
replace the specific migration amount. When the conversed migration amount with the
residual amount according to the relevant conversion mode is less than the specific
migration limit, the specific migration amount may no longer be measured.
6.3 Alternative test of chemical solvent
6.3.1 For grease foods, 95% (v%) alcohol, n-hexane, n-heptane or other chemical
solvents with stronger extraction ability may alternate the fats and oils food simulant to
measure extraction volume of materials and articles. When the extraction volume of
solvent meets the regulations of the oerall migration limit or the specific migration limit, the
migration test of grease food simulants may no longer be performed. When the extraction
volume of solvent does meet the regulations of the oerall migration limit or the specific
migration limit, the migration test of grease food simulants should be performed and the
compliance judgment is performed based on the migration amount in grease food
simulants
6.3.2 The test conditions for the chemical solvent alternative test shall be the most
stringent and supported by scientific evidence and can reflect the migration situation of the
actual grease food or the corresponding food simulants.
7 Correction of results
The results of the determination shall be corrected by the following correction factors
referring to the requirements in the appendix A
a) The ratio of the contacted surface area to the volume for food contact materials and
articles with simulant
b) The correction factor for grease- containing food simulant,
c) Correction factor of fat.
GB 31604.1--2015
Appendix A
Selection of food category and its corresponding food simulant
A.1 Selection of the food contact materials and articles being expected to contact with the food
category and its corresponding food simulant should accord with the regulations in table A.1.
Table A.1 Selection of food category and its corresponding food stimulant
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
01 Beverages
01.01 Non alcoholic
beverages or
alcoholic
beverages
(alcohol content
≤10%)
Clarified beverage:
including water,
apple juice, fruit
and vegetable
juice, fruit juice,
01.01.01 lemonade, syrup, X X(*)
coffee, tea, beer,
soft drinks, energy
drinks and
analogues, flavor
beverage etc.
Turbid beverage:
including fruit and
vegetable juice
containing pulp,
01.01.02 X(*) X
fruit juice and
other soft drinks,
chocolate, liquid
etc.
01.02 Alcoholic
beverages
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
Alcoholic
beverages (10%<
01.02.01 X(*) X
alcohol content
≤20%)
Alcoholic
beverages,
including various
01.02.02 X(*) X
milk wine
(20<alcohol
content ≤ 50% )
Alcoholic
actual
beverages with
concentratio
more than 50%
01.02.03 X(*) n
alcohol content
alcohol
(v/v) or edible
substitution
alcohol
02 Cereals, beans
and their
products
02.01 starch
02.02 Cereals, including
unprocessed,
expanding (such
as popcorn), sheet
(such as corn
flakes, oatmeal,
etc.)
02.03 Cereal flour and
coarse powder
02.04 Wet and dry rice
products
02.04.01 Wet rice products
X
(such as wet
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
noodle, rice noodle
02.04.02 Dry rice products
(such as hanging
noodles, instant
noodles etc.)
02.04.02.01 Surface containing
X/3
grease
02.04.02.02 Surface no
containing grease
02.05 Pastry, bread,
dessert, crisp
cake, biscuits,
fried and baked
foods
02.05.01 Surface containing
X/3
grease
02.05.02 Surface free of
X
grease
02.06 Steamed bread,
roll steamed
bread, bun,
sponge cake,
dumpling, new
year cake, and
other cooking
foods, etc.
02.06.01 Surface containing
X(*) X/3
grease
02.06.02 Surface free of
X
grease
02.07 Soy product
02.07.01 Beancurd, dried
X
bean curd,stinky
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
bean curd, etc.
02.07.02 Fried beancurd,
dried bean
X X/3
curd,stinky bean
curd, etc.
02.07.03 Soy milk X
02.07.04 Fermented soy
X(*) X
milk drink
03 Chocolate,
confectionery
and sugar
03.01 Chocolate and
coating foods,
cocoa butter X/3
chocolate and its
coated food
03.02 Candy
03.02.01 Solid candy
03.02.01.01 Surface containing
X X/3
grease
03.02.01.02 Surface free of
X
grease
03.02.02 Liquid or
semi-solid candies
03.02.02.01 Surface containing
X X/2
grease
03.02.02.02 Surface free of
X
grease
03.03 Sugar and sugar
products
03.03.01 Solid sugar (such
as sugar, sugar,
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
cotton sugar, etc.)
03.03.02 Liquid sugar (such
as syrup, honey X
and the like, etc.)
04 Fruits,
vegetables and
their products
04.01 Unpeeled fruit
(fresh or frozen)
04.02 Processed fruits
04.02.01 Dried fruit
(including whole,
flake or powder)
04.02.02 Unpeeled fruit
X/3
(fresh or frozen)
04.02.03 Purees, preserves,
jams (may contain
fruit juice or X(*) X
syrup), candied
fruits, etc.
04.02.04 Canned fruit
04.02.04.01 In grease
-containing X
medium
04.02.04.02 In alcoholic
X
medium
04.02.04.03 In aqueous
X X(*)
medium
Nuts (such as
peanuts,
04.03
chestnuts,
almonds,
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
hazelnuts,
walnuts, pine
cones, etc.)
Surface containing
grease (such as
04.03.01 fried peanuts, X/3
sesame powder
etc.)
Surface free of
grease (such as
04.03.02 raw shelled or skin
roasted peanuts or
peanut)
04.03.03 Nut butters, pastes
X X
or cream
04.04 Unpeeled whole
grain and
vegetables (fresh
or frozen)
04.05 Processed
vegetables
Dried dehydrated
vegetables
04.05.01 (including whole,
sliced or powder
-like)
04.05.02 Fresh vegetables
X
(peeled or cut)
Vegetable puree,
candied
04.05.03 vegetables, X(*) X
vegetable sauce,
pickles and spiced
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
corned foods
04.05.04 Canned
vegetables
04.05.04.01 In the grease
-containing X X
medium
04.05.04.02 In the alcohol
-containing X
medium
04.05.04.03 In aqueous
X
medium
05 Edible oils and
fats
05.01 Animal and
vegetable fats,
including natural
and processed
(Such as X
vegetable oil,
cocoa butter, lard,
and solid butter,
etc.)
05.02 Margarine, butter
and other
X/2
oil-in-water type oil
foods
06 Foods of animal
origin and eggs
06.01 Fish
06.01.01 Fresh, frozen,
processed, salted
X X/3(**)
or smoked fish
and roe
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
06.01.02 Canned fish
06.01.02.01 In the oily medium X X
06.01.02.02 In an aqueous
X(*) X
medium,
06.02 Crustaceans and
molluscs
(including oysters,
shellfish class,
octopus, etc.)
06.02.01 Fresh shelled X
06.02.02 Peeled or shelled
processing
06.02.02.01 In grease
-containing X X
medium
06.02.02.02 In alcohol
-containing X
medium
06.02.02.03 In aqueous
X(*) X
medium
06.03 Poultry meat
06.03.01 Fresh, frozen,
X X/4(**)
salted, smoked
06.03.02 Processed meats
(including ham,
sausage, bacon,
X X/4(**)
sausage, etc.) or
in a paste or
paste-like meat
06.03.03 Meat marinated in
X X
oily medium
06.04 Canned meat
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
06.04.01 In the grease
-containing X X/3
medium
06.04.02 In aqueous
X(*) X
medium
06.05 Whole egg, egg
yolk and egg white
06.05.01 Powdered
products (dried or
freeze-dried)
06.05.02 Liquid and cooked X
07 Milk and dairy
products
07.01 Milk
07.01.01 Milk and milk
drinks (including
whole milk, skim or
X
part skim milk and
concentrated milk,
etc.)
07.01.02 Milk and
milk-based infant
formula powder
07.02 Fermented milk
(eg yoghurt,
X(*) X
skimmed yogurt,
etc.)
07.03 Butter and sour
X(*) X
cream
07.04 Cheese
07.04.01 Complete
cheese (cheese
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
containing inedible
skin)
07.04.02 No peel or
containing edible
peel natural X/3(**)
cheese and melt of
cheese
07.04.03 Processed cheese
(including soft
cheese, nonfat X(*) X
cottage cheese
etc.)
07.04.04 Canned cheese
07.04.04.01 In the oily medium X X
07.04.04.02 In an aqueous
X(*) X
medium
08 Others
08.01 Vinegar X
08.02 Fried, baked foods
08.02.01 Fried potatoes,
X X/5
fried pies, etc.
08.02.02 Animal original
X X/4
fried, baked foods
08.03 Liquid, solid or
powder form,
soup, gravy,
sauces, yeast or
baking powder,
prefabricated
dishes, etc.
08.03.01 Powder or dry
form
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
08.03.01.01 With fat
X/5
characteristics
08.03.01.02 Others
08.03.02 Other types except
the powder and
stem-like
08.03.02.01 With fat
X X(*) X/3
characteristics
08.03.02.02 Others X(*) X
08.04 Sauce juice, sauce
08.04.01 Water-soluble X(*) X
08.04.02 Oil lipids (such as
peanut butter,
sesame, egg yolk
sauce, salad
X X(*) X
dressing, cocoa
butter and other
oils, water mixed
compound)
08.05 Mustard (except
mustard powder in X X(*) X/3(**)
08.14 )
08.06 Sandwiches, pizza
and other foods
with stuffing
08.06.01 Surface containing
X X/5
fats and oils
08.06.02 Surface free of fats
X
and oils
08.07 Ice cream X
08.08 Dried foods
08.08.01 Surface containing X/5
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
fats and oils
08.08.02 Surface free of fats
and oils
08.09 Frozen or deep
frozen foods
08.10 Concentrated
extract substance
with content of X(*) X
alcohol not less
than 6% (v / v)
08.11 Cocoa
08.11.01 Cocoa powder,
degreasing and
high
degreasing-type
08.11.02 Cocoa butter X/3
08.12 Coffee (roasted
and non-roasted,
decaffeinated or
speed
dissolved) and
coffee substitutes
(granulated or
powdered)
08.13 Vanilla and other
(such as
chamomile,
mallow, mint,
tea, flowers, etc.)
08.14 Seasoning (such
as cinnamon,
cloves, mustard
powder, pepper
GB 31604.1--2015
food simulant
Food 10%( 4%(v/ 20%(v/v 50%(v/v)
classificatio Food category v/v) v) ) Alcohol Vegetabl
n number Alcoh Aceti Alcohol e oil
ol c acid
powder, vanilla,
saffron, salt, etc.)
08.15 Seasonings
immersed in an
oily medium (such X
as garlic oil, curry
sauce)
08.16 Edible
essence(solid,
semi-solid, liquid)
a
X means the food simulant supposed to be selected in this kind of food.
b
relavant figure in this table means the correction factor of greasy-containing food
simulant
c
only select acidic food of PH<5
d
only select greasy-containing food
A.2 Correction of migration amount
A.2.1 Correction factor of grease-containing food simulants;
A.2.1.1 The determination results of migration amount for vegetable oil and other
grease-containing food simulants in Table A.1 should be divided by the corresponding
number of the table (Correction factor of grease-containing food stimulant) and the
compliance judgement after correction.
A.2.1.2 The Correction factor of grease-containing food simulants; does not apply to
specific migration limits as the "not be allowed appearance in detection" substances.
A.2.2 Fat correction factor (FRF)
A.2.2.1 For the food with more than 20% fat content, the specific migration amount should
be corrected using FRF for lipophilic substances. For the calculation method of fat
correction factors, please see formula (A.1)
Where:
5 一一 conversion factor,
f 一一 fat content in food, units as grams per hundred grams (g/100 g);
100-- conversion coefficient.
GB 31604.1--2015