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Article history: Increased temperature and decreased hardness values of the tube metal and development of oxide scale
Received 8 April 2009 on the inner surface of boiler tubes over prolonged period of time are typical problems in power plants.
Received in revised form Appropriate life assessments or condition monitoring of boiler tube should be carried out from time
8 June 2009
to time. Computer simulations may economically support the post-failure assessment method, i.e. visual
Accepted 9 June 2009
inspections, metallurgical examinations and mechanical strength measurements. However, estimations
obtained from the simulations may provide an advanced warning to take preventive actions prior to
Keywords:
failure. In this work two failure cases of the reheater and superheater tubes made of a typical material of
SA213-T22 steel
Creep rupture SA213-T22 steel are evaluated. As the oxide scales are increasingly developed on the inner surface, the
Remnant life assessment increasing of temperature and decreasing of hardness value in tube metal for both cases are determined.
Elevated temperature The remnant life estimations are then made in the form of creep cumulative damages.
Boiler tube Ó 2009 Elsevier Ltd. All rights reserved.
Finite element modeling
1. Introduction the insulating effect of the oxide scales raising tube temperatures.
In addition, scale spallation could also increase tube temperatures,
The strength of low-alloy steel may change for prolonged period as spallation debris may collect in the bottom of tubes, blocking
of service. Estimations of change in temperature, hardness and oxide steam flow. Attention is drawn to a potential problem in which the
scale thickness during service may be used to estimate the remnant tube temperature and rate of oxidation increase with time as the
life of the component. In particular, estimations of the average oxide builds up.
temperature in tube metal are important in heat recovery steam Chaudhuri (2006) described some aspects of metallurgical
generator (HRSG). It may provide an advanced warning of failure by assessment of boiler tubes. He discusses some failure problems in
estimating temperature increase in water-tube boiler. carbon steel, reheater and superheater tubes. Ray et al. (2007)
Port and Herro (1991) reported that almost 90% of failures reported remaining life assessment and creep analysis of superheater
caused by long-term overheating occur in superheaters, reheaters and reheater tubes made of 2.25Cr–1Mo steel of a thermal power
and wall tubes. Tubes that are especially subjected to overheating plant. The tubes had operated for 17 years with average operating
often contain significant deposits. The deposits reduce coolant flow temperature of 540 C and having design pressure of 40 MPa. The
and the tubes will experience excessive fire-side heat input. Scales remnant life is predicted through dimensional, hardness and tensile
and other materials on external surfaces will slightly reduce metals measurements. Viswanathan, Foulds, and Roberts (1988) performed
temperatures. The thermal resistance of the tube wall may cause estimation on the temperature of reheater and superheater tubes in
a very slight drop in temperature across the wall. When heat fossils boilers. They made correlation between hardness and Larsen–
transfer through the steam-side surface is considered, the effect of Miller parameter for 1Cr–½Mo, 2¼Cr–1Mo and 9Cr–1Mo steels.
deposits is reversed. Steam layers and scales insulate the metal Finite element simulations have been used to investigate failures
from the cooling effects of the steam. It results in reducing of heat in superheater tube (Othman, Purbolaksono, & Ahmad, 2009) and
transfer into the steam and increasing of metal temperatures. reheater tubes (Purbolaksono, Hong, Nor, Othman, & Ahmad, 2009).
Starr, Castle, and Walker (2004) also described that oxidation on Othman et al. (2009) simulated the deformed superheater tube
the steam side of the tubing can induce premature failures due to using the finite element method. The simulation results have a good
conformity with the finding from the visual site inspection. Pur-
* Corresponding author. Tel.: þ60 3 89212213; fax: þ60 3 89212116. bolaksono et al. (2009) reported evaluation on reheater tube failure.
E-mail address: judha@uniten.edu.my (J. Purbolaksono). The geometry and the scale thickness of the as-received failed tube
0950-4230/$ – see front matter Ó 2009 Elsevier Ltd. All rights reserved.
doi:10.1016/j.jlp.2009.06.005
Please cite this article in press as: Purbolaksono, J., et al., Failure case studies of SA213-T22 steel tubes of boiler through computer simulations,
Journal of Loss Prevention in the Process Industries (2009), doi:10.1016/j.jlp.2009.06.005
ARTICLE IN PRESS
720 J. Purbolaksono et al. / Journal of Loss Prevention in the Process Industries 22 (2009) 719–726
were measured and used to generate the finite element models. The due to cross flow of the hot flue gas over bare tubes, are carried out in
scale thickness inside tube over service time is considered as order to determine temperature distribution in the tube. An iterative
a linear scale growth. Results obtained from the simulations have procedure is performed to determine the average temperature and
shown agreement with the result from the microscopic examina- hardness of the tube steel over period of time as oxide scale thickness
tion. Both results showed that the failed reheater tube had over- on the inner surface increases. Two failure cases in reheater (Case 1)
heating for prolonged period of time. and superheater (Case 2) tubes are evaluated through the finite
Nowadays, a large percentage of power and chemical plants element simulations and iterative procedures. The reheater and
worldwide have been in operation for long durations. There are strong superheater tubes are made of a typical material of SA213-T22 steel.
economic reasons and technical justifications for continued operation As the oxide scales are increasingly developed on the inner surface,
of the power plants. In order to realize the continuing operations in the increasing of temperature and decreasing of hardness in
practice, however, appropriate techniques and methodologies are tube metal for both cases are determined. The remnant life estima-
needed to evaluate the current condition of the plant components and tions are then made in the form of creep cumulative damages. Besides
to estimate their remaining useful lives. The techniques should also be computer simulations utilizing parameters of the operational
valuable with respect to relatively younger power plants in the condition may economically support the post-failure assessment
context of safety, availability and reliability, operation, maintenance method, i.e. visual inspections, metallurgical examinations and
and inspection practices. An important ingredient in the continuing mechanical strength measurements, the estimations obtained from
operation of power plants is the remaining life assessment technology the simulations may provide an advanced warning to take preventive
(Viswanathan, 1989). The remaining life estimations could help in actions prior to failure.
setting up proper inspection schedules and operating procedures in
2. Heat transfer parameters
order to avoid premature retirement of the plants.
An accurate prediction of the temperature distribution in tube
Model of the tube section used is 25 mm in length. In modeling
metal of the superheater and reheater will aid the power plant
of the steady state heat transfer for the problem using ANSYS
inspectors or engineers in evaluating the remaining life of the boiler
(ANSYS, 2008), the area of the model is divided into two regions, i.e.
tubes. A continually increasing scale thickness may occur on the inner
scale region and tube region (see Fig. 1). The steam region is taken
surface of superheater and reheater tubes during the service.
into account in determining the convection coefficient of steam
Presence of oxide scales on the inner surface of boiler tubes may
film for fully developed turbulent flow in a circular tube.
significantly contribute to the increased tube metal temperature.
The chemical composition of SA213-T22 steel is listed in Table 1.
Consequently, in the prolonged exposure this phenomenon will
Steam properties and the thermal conductivities for SA213-T22 and
worsen situation that leads to potential tube rupture problems. When
oxide scale (magnetite) are shown in Table 2. The steam-side scale
a power plant is forced to shut down because of the single component
is usually reported to be duplex (inner spinel (Fe–Cr–Mo)3O4 layer
failure, the cost of the lost electric-power generation can run to
and outer magnetite (Fe3O4) layer) or triplex (inner spinel layer,
several hundred thousand dollars a day. It is essential to perform life
middle magnetite layer and outer hematite (Fe2O3) layer). In this
assessments through the operational condition-based monitoring of
study material of the scale is treated to be all magnetite.
the power plant regularly than allowing the equipments to fail. In this
Phenomenon of heat transfer inside the boiler tube is considered
work the life assessments are performed by using finite element
as forced convection with turbulent flow. Correlation for fully devel-
simulations and utilizing the empirical formulae through iterative
oped turbulent flow in tube is expressed as (Incropera & DeWitt, 1996)
procedures. The first empirical formula is correlating scale thickness
with Larsen–Miller parameter (Rehn, Apblett, and Stringer,1981). The
Nus ¼ 0:023ðRes Þ0:8 ðPrs Þ0:4 (1)
second empirical formula is correlating the experimental hardness
data for 2¼Cr–1Mo steel with Larsen–Miller parameter (Viswana- where Res is Reynolds number that may be expressed as
than et al., 1988). The finite element analysis is carried out using
software package of ANSYS (ANSYS, 2008). Finite element models for o
Res ¼ 4ms :
heat transfer analyses, that involve forced convections on the inner (2)
surface due to the turbulent flow of steam and on the outer surface
pDi ms
Please cite this article in press as: Purbolaksono, J., et al., Failure case studies of SA213-T22 steel tubes of boiler through computer simulations,
Journal of Loss Prevention in the Process Industries (2009), doi:10.1016/j.jlp.2009.06.005
ARTICLE IN PRESS
J. Purbolaksono et al. / Journal of Loss Prevention in the Process Industries 22 (2009) 719–726 721
Table 2
Properties of fluid and solid materials.
GD0
steam
Reg ¼ (7)
remaining tube 12mg
metal thickness
hollow
radius initial tube metal thickness
where G is gas mass velocity and may be defined as
Wg
G ¼ 12 (8)
Fig. 1. Model of the superheater and reheater tubes with scale on the inner surface. Nw LðSt D0 Þ
in which Wg is gas flow; Nw is number of tube wide; St is transverse
pitch (see Fig. 2), and L is the tube length.
o
in which ms is mass flow rate of the steam; Di is the inner diameter However, the evaluation will be more accurate if the non-
of the tube; ms is steam viscosity, and Prs is its Prandtl number that luminous coefficients for water vapour and carbon dioxide are
is defined as taken into account in determining the gas side convective heat
transfer coefficient. Hence, there will be an additional increase
ms Cps on the overall heat transfer coefficient at flue gas temperature of
Prs ¼ (3)
ks 800–900 C by 5–6%, assuming that the external or direct radiation
from the furnace is absent.
in which Cps and ks are specific heat and thermal conductivity of the
steam, respectively.
3. Estimations of temperatures, scale thickness and hardness
Convection coefficient of steam film for fully developed turbu-
lent flow in circular tube is expressed as (Incropera & DeWitt,
The increasing scale thickness may occur in superheater and
1996):
reheater tubes during the service. Therefore, estimation must be
ks made of the average temperature in the oxide scale as a function of
hs ¼ 0:023 ðRes Þ0:8 ðPrs Þ0:4 (4) time and scale thickness. In this work in order to perform a scale
Di
growth prediction, steam-side scale formation for ferritic steel of
where ks is steam conductivity. 1–3% chromium correlated with the Larson–Miller parameter as
Heat transfer outside the boiler tube is considered as forced reported by Rehn et al. (1981) is utilized (see Fig. 3). The data of
convection due to cross flow of the hot flue gas over bare tubes. Fig. 3 may be approximated as
A conservative estimated convection coefficient of flue gas hg on
X
outer surface of bare tube in inline and staggered arrangements
log ¼ 0:00022P 7:25 (9)
(see Fig. 2) is given by (Ganapathy, 2003) 0:0254
Please cite this article in press as: Purbolaksono, J., et al., Failure case studies of SA213-T22 steel tubes of boiler through computer simulations,
Journal of Loss Prevention in the Process Industries (2009), doi:10.1016/j.jlp.2009.06.005
ARTICLE IN PRESS
722 J. Purbolaksono et al. / Journal of Loss Prevention in the Process Industries 22 (2009) 719–726
The increasing of scale thickness DX in the reheater or super- tube, the average temperature of Taveh_i is determined from average
heater tubes (SA213-T22) may be obtained from Eq. (9) corre- of the temperatures on the inner and outer surfaces of the tube. Eqs.
sponding to the given running hours and average temperature in (9) and (10) are used to calculate the scale thickness of Xia for the
the oxide scale. The steps of time as shown in Table 3 are used in the service hours of 1 h and the scale thickness of Xib for the service
iterative procedures. The iterative procedures used to determine hours of 250 h (see Table 3) using Taves1. Next, by subtracting one
scale thickness and hardness of the tube as a function of time and from the other, the scale increase of DXi (¼Xib Xia) is determined
temperature are as follows: and a new scale thickness of Xi (¼X0 þ DXi) is obtained. Eqs. (10) and
(11) with Taveh_i are used to determine the hardness of Hia for the
3.1. Procedure 1 service hours of 1 h and the hardness of Hib for the service hours of
250 h. Hardness Hi is equal to Hia.
For initial step i ¼ 1, the design temperature for the steam is set
to Ts at the inlet of reheater or superheater tube. From the
numerical simulation in the absence of scale (X0), the average
temperature of Taves_i is the temperature on the inner surface of the
Fig. 3. Steam-side scale formation for ferritic steels of 1–3% chromium correlated with Fig. 4. Correlation between hardness and the Larsen–Miller parameter for 1Cr–½Mo,
the Larsen–Miller parameter (Rehn et al., 1981). 2¼Cr–Mo and 9Cr–1Mo steels (Viswanathan et al., 1988).
Please cite this article in press as: Purbolaksono, J., et al., Failure case studies of SA213-T22 steel tubes of boiler through computer simulations,
Journal of Loss Prevention in the Process Industries (2009), doi:10.1016/j.jlp.2009.06.005
ARTICLE IN PRESS
J. Purbolaksono et al. / Journal of Loss Prevention in the Process Industries 22 (2009) 719–726 723
Table 3 Table 5
Steps of time used in the iterative procedure. Parameters used to determine gas mass velocity G for validation of actual data.
Table 4 Table 6
Geometry of the as-received tubes, service time and the inner scale thickness. The estimated convection coefficients hs and hg for internal and external surfaces
respectively.
Case Inner Tube Service Scale Date of
radius, m thickness, mm time, h thickness, mm failure Case hs, W/m2 C hg, W/m2 C
1 0.0219 3.5 117,522 0.58 10/10/2003 1 2053.65 126.01
2 0.0163 4.0 115,494 0.2 04/08/2003 2 6084.32 129.99
Please cite this article in press as: Purbolaksono, J., et al., Failure case studies of SA213-T22 steel tubes of boiler through computer simulations,
Journal of Loss Prevention in the Process Industries (2009), doi:10.1016/j.jlp.2009.06.005
ARTICLE IN PRESS
724 J. Purbolaksono et al. / Journal of Loss Prevention in the Process Industries 22 (2009) 719–726
Please cite this article in press as: Purbolaksono, J., et al., Failure case studies of SA213-T22 steel tubes of boiler through computer simulations,
Journal of Loss Prevention in the Process Industries (2009), doi:10.1016/j.jlp.2009.06.005
ARTICLE IN PRESS
J. Purbolaksono et al. / Journal of Loss Prevention in the Process Industries 22 (2009) 719–726 725
305
1.2 610
285
Cumulative creep damage
Temperature, °C
Hardness, HV
0.8 Temperature-Case 1 590
Case 2 - superheater tube 245
225 580
0.6
205
570
0.4
185
560
0.2 165
550
0 145
0 20000 40000 60000 80000 100000 120000
125 540
Service hours
0 20000 40000 60000 80000 100000 120000
Fig. 7. The estimated cumulative creep damages. Service hours
Fig. 8. The estimated hardness and the average metal tube temperatures over period
coefficient and temperature of flue gas would lead to increasing tube of time.
metal temperature and oxide scale thickness. Tube metal temperature
may increase slowly over many years or rapidly over a few hours. in reduced cost. Then, life estimations of the boiler tubes through the
Internal oxide scales usually result in long-term overheating that computer simulations may be employed from time to time.
gradually increase the tube metal temperature. The increasing tube Failure analysis on the water-tube boiler can also be performed
metal temperature and oxide scale growth have a reciprocal casual. As by referring to Section 2, Part D of The ASME Boiler and Pressure
the tube metal temperature increase, so does the rate of internal scale Vessel Code (ASME, 1998) for the maximum allowable stress values
formation. As the oxide scale thickness increases, so does the tube and data from United States Steel Corporation (1972) as shown in
metal temperature. The cycle continues progressively over period of Table 8. The maximum allowable stresses and the operational hoop
time. Loss of boiler feedwater or impaired steam flow usually results in stresses of the tubes (Case 1 and Case 2) over the service hours are
rapid overheating and often rapid failure. Localized high temperature then plotted in Fig. 9. It can be illustrated that the critical conditions
flue gas flow definitely causes localized overheating of the boiler tube. may be predicted when the stresses in the tube exceeding the
These features potentially lead to rupture of the boiler tubes that maximum allowable stress. It can also be seen from Fig. 9 that the
consequently leads to unscheduled and costly outages. tube can be estimated when the overheating condition occurs.
It is an essential element of condition-based maintenance in Since the operating hoop stresses are higher than the allowable
which the equipment is maintained on the basis of its condition, or it stresses, tubes in Case 1 and Case 2 are estimated to be critical at
allows actions to be taken to avoid the consequences of failure, before the beginning of service. Even though the operating hoop stresses
the failure occurs. It is typically much more cost-effective than remain much lower than the ultimate strength shown in Table 8,
allowing the components to fail. By selecting a physical measurement a careful consideration needs to be taken. Monitoring on the
which indicates that deterioration is occurring, the readings on the temperature increase over period of time is particularly important
parameter need to be taken at regular interval. Since failure occurs to when overheating in the tube is concerned. Thus, combination of
individual components, the monitoring measurements need to focus estimating the life expectancy using the cumulative creep damage,
on the particular failure modes of the critical component. If a power considering the maximum allowable stresses and monitoring the
plant has been operating with breakdown maintenance or regular increasing of temperature in tube metal may provide better
planned maintenance, a change over to condition-based mainte- monitoring of the boiler tubes. Appropriate preventive actions may
nance can result in significant improvements in plant availability and be taken during the scheduled outage for close inspections and
necessary examinations in order to avoid forced outage due to
Table 7
a single failure of a component.
Estimations for scale thickness for Case 1and Case 2. It is reported that the microscopic examination for Case 1 and
Case 2 were also carried out to support the life assessment. The
Case 1 (reheater tube) Case 2 (superheater tube)
finding of Case 1 indicated that the tube metal microstructure had
Service hours Scale thickness, mm Service hours Scale thickness, mm a complete stage of spheroidization where the carbide particles
0 0.0000 0 0.0000
250 0.0556 250 0.0229
500 0.0736 500 0.0301 Table 8
1000 0.0965 1000 0.0392 The maximum allowable stresses and tensile strengths for seamless tube SA213-T22.
2500 0.1371 2500 0.0550
5000 0.1783 5000 0.0707 Temperature, C Max. allow. stress, Tensile strength, MPa (United
10,000 0.2315 10,000 0.0907 MPa (ASME, 1998) States Steel Corporation, 1972)
20,000 0.3008 20,000 0.1163 537.78 55.16 377.16
40,000 0.3916 40,000 0.1491 565.56 39.30 –
60,000 0.4584 60,000 0.1728 593.33 26.20 282.69
80,000 0.5133 80,000 0.1920 621.11 16.55 –
100,000 0.5610 100,000 0.2085 648.89 9.65 –
117,522 0.5982 115,494 0.2200 784.00 – 151.69
Please cite this article in press as: Purbolaksono, J., et al., Failure case studies of SA213-T22 steel tubes of boiler through computer simulations,
Journal of Loss Prevention in the Process Industries (2009), doi:10.1016/j.jlp.2009.06.005
ARTICLE IN PRESS
726 J. Purbolaksono et al. / Journal of Loss Prevention in the Process Industries 22 (2009) 719–726
50 6. Conclusions
620
Finite element simulations incorporated with the iterative proce-
610 40 dures may be used to estimate the increased temperature and
Average temperature, °C
Fig. 9. Operational hoop and maximum allowable stresses of the failed tubes for Case 1 Acknowledgements
and Case 2 at the corresponding average tube temperatures and service hours.
Please cite this article in press as: Purbolaksono, J., et al., Failure case studies of SA213-T22 steel tubes of boiler through computer simulations,
Journal of Loss Prevention in the Process Industries (2009), doi:10.1016/j.jlp.2009.06.005