30/03/2023, 02:03 Cosmetic Chemistry – The Compounds in Red Lipstick – Compound Interest

Cosmetic Chemistry – The Compounds in Red

Lipstick
By Compound Interest <
https://www.compoundchem.com/author/compound-interest/>

August 18, 2014 <

https://www.compoundchem.com/2014/08/18/lipstick/>

Click to enlarge

www.compoundchem.com/2014/08/18/lipstick/ 1/5
30/03/2023, 02:03 Cosmetic Chemistry – The Compounds in Red Lipstick – Compound Interest

< https://i0.wp.com/www.compoundchem.com/wp-
content/uploads/2014/08/The-Chemistry-of-Lipstick.png?ssl=1>

Click to enlarge

Lipstick is one of the most commonly used cosmetic products – and a range of
chemicals are required for its production. The choice of these ingredients is carefully
considered to provide the desired colour, glossiness, and indelibility. A single stick of
lipstick will contain several hundred different chemical compounds, but there are a
few substances and compounds whose inclusion is essential.

An average composition of lipsticks is given in the graphic, but, in truth, this can be
widely varied from lipstick to lipstick. Generally, however, waxes and oils make up the
bulk of lipstick’s composition. Waxes are perhaps the most important, as they are
crucial for the structure and shape of the lipstick. A range of different naturally
occurring waxes can be utilised, with beeswax commonly a major constituent.
Beeswax is composed of around 300 different chemical compounds; the
principal compounds are esters, which make up around 70% of the composition. The
remaining 30% of compounds includes organic acids and hydrocarbons.

www.compoundchem.com/2014/08/18/lipstick/ 2/5
30/03/2023, 02:03 Cosmetic Chemistry – The Compounds in Red Lipstick – Compound Interest

Another type of wax used is Carnauba wax, obtained from the Brazilian Carnauba
Palm, which at approximately 87˚C has the highest known melting point of any wax.
Its inclusion can give the lipstick the rather useful characteristic of not melting in the
sun as a result of the lower melting points of some of the other waxes used. As well as
beeswax, these other waxes can include Candelilla wax, obtained from the Mexican
Candelilla shrub, and lanolin, a wax secreted by the glands of woollen animals. Though
they primarily provide the structure of the lipstick, these waxes can also impart other
useful properties – they can act as emulsifying agents to help bind together the other
ingredients, and can also impart glossiness on application of the lipstick.

As well as the waxes, another important component of lipsticks is oils. The most
commonly used is castor oil, which can often comprise the largest percentage of the
lipstick, but others, such as olive oil and mineral can also be utilised. The oils give the
lipstick emollient, or skin-softening properties; they also make application of the
lipstick easier, and contribute glossiness to its appearance. Additionally, they act as
solvents for soluble dyes used in the lipstick, or dispersing agents for any insoluble
pigments.

The pigments and dyes, though they make up only a minor percentage of the lipstick’s
composition, are certainly the most important, as they impart the colour of the
lipstick. Pigments are coloured compounds that are insoluble, whilst dyes are more
commonly either liquids themselves, or soluble. The manner in which they provide
colour can also vary. Carmine red, also known as carminic acid, is a common red
pigment, which is derived from cochineal bugs, a variety of scale insects that live on
cacti. It is prepared by boiling the insect bodies in ammonia or sodium carbonate
solution, filtering, and then adding hydrated potassium aluminium sulfate (more
commonly known as alum). 

Another common colour imparting component is a compound called eosin. This is a

dye that actually subtly changes its colour when applied. In the lipstick, it is red, with a
slightly blue tinge; when it is applied, however, it reacts with the amine groups found
in proteins in the skin, and this reaction causes its colour to intensify to become a
deeper red. Another benefit of this reaction is that it makes the dye indelible, or long-
lasting.

Of course, red is not the only lipstick colour, and in order to achieve the wide range of
colours available today, other pigments and dyes are needed, of which there are a
variety. Additionally, other compounds can be added in order to alter the intensity of
the red coloured pigments and dyes. Titanium dioxide, a white compound in isolation,

www.compoundchem.com/2014/08/18/lipstick/ 3/5
30/03/2023, 02:03 Cosmetic Chemistry – The Compounds in Red Lipstick – Compound Interest

is a common addition, which can be added to red dyes in varying amounts to produce
a range of pink coloured lipsticks.

Several other compounds can be added in small quantities to provide moisturising

qualities, or to provide a pleasant fragrance that also masks the smells of the other
compounds that make up the lipstick. Interestingly, capsaicin, the major capsaicinoid
compound in chillis which is largely responsible for spiciness, can also sometimes be
found in lipsticks. Its presence is down to its ability to act as a minor skin irritant,
which means it can cause lips to appear plumper.

On a final note, in recent years there has been concern over the very small amounts of
heavy metals that can be found in some lipsticks. A recent study of 32 popular
lipsticks < http://ehp.niehs.nih.gov/1205518/> found trace contaminant
amounts of lead, cadmium, aluminium, chromium and manganese in many of them.
However, this study has come in for criticism in some quarters <
http://ehp.niehs.nih.gov/wp-content/uploads/121/6/ehp.121-a196.pdf> , as
it based its human ingestion estimates on a range of different data for each metal, and
also assessed the amounts ingested with the assumption that all of the applied lipstick
was ingested – an unlikely scenario. Additionally, the highest levels of the metals in the
study were still below the recommended daily intake. The presence of heavy metals in
lipsticks is still a legitimate concern, however, particularly with no safe level of
exposure to lead being recognised, and as such there is a push for a limit of specific
levels of the metals in lipstick to be set. In the meantime, many companies now
produce lead-free lipsticks to assuage consumer fears.

DOWNLOAD

< https://www.compoundchem.com/wp-content/uploads/2014/08/The-
Chemistry-of-Lipstick.pdf>

< https://www.compoundchem.com/subscribe/>

The graphic in this article is licensed under a  Creative Commons Attribution-

NonCommercial-NoDerivatives 4.0 International License <

www.compoundchem.com/2014/08/18/lipstick/ 4/5
30/03/2023, 02:03 Cosmetic Chemistry – The Compounds in Red Lipstick – Compound Interest

http://creativecommons.org/licenses/by-nc-nd/4.0/> . See the site’s content

usage guidelines < http://wp.me/P4aPLT-ir> .

References & Further Reading

Waxes used in cosmetics < http://www.makingcosmetics.com/articles/28-

waxes-used-in-cosmetics.pdf> – Making Cosmetics
What’s in Lipstick? <
http://pubs.acs.org/cen/whatstuff/stuff/7728scit2.html> – C&EN
Indelible Lipsticks <
http://www.cosmeticsandskin.com/cdc/indelible.php> – Cosmetics & Skin
The cosmetic chemistry behind lipsticks <
http://www.beautybythegeeks.com/luscious-lippy-the-cosmetic-chemistry-
behind-lipstick/> – Beauty & the Geeks
Vanity, Vitality & Virility – The Science Behind the Products You Love to
Buy < http://books.google.co.uk/books?
id=F06i5gEJqSUC&source=gbs_navlinks_s> – John Emsley
Analysis of Lipsticks by Surface Enhanced Raman Scattering <
http://pubs.rsc.org/en/Content/ArticleLanding/1998/AN/a805275a#!div
Abstract> – C Rodger & others

© 2023 Compound Interest < https://www.compoundchem.com/> Up ↑

www.compoundchem.com/2014/08/18/lipstick/ 5/5