DELHI) (2020) TRAPUR CLASSES __PURIFIGATION—N1__GURJIT S. KAPUR (PG. 1. Glycerol is separated in soap industries by {a) fractional distil (b) differential extraction (c) steam distillati (4) distillation under reduced pressure. 2. A chromatography column, packed with silica gol as stationary phase, was used to separate a mixture of compounds consisting of (A) benzanilide, (B) aniline and (C) acetophenone. When the column is eluted with a solvents, hexane : ethyl acetate (20 : 80), the sequence of obtained compounds is (a) (8), (A) and (C}—_(b) (A), (B) and (C) (c) (B), (C) and (A) (4) (C), (A) and (B) (2020) 3. A flask contains a mixture of ischexane and 3-methylpentane. Ono of the iquids boils at 63°C while the other boils at 60°C. What is the best way to separate the two liquids and which one will be distilled out first ? ixture of (b) Simple distillation, 3-methylpentane {c) Fractional distillation, 3-methylpentane (d) Simple distillation, isohexane (2020) 4, The principle of column chromatography is (a) differential adsorption of the substances on the solid phase. (b) capillary action. {c) differential absorption of the substances on the solid phase. (2019) (d) gravitational forc 5. In chromatography, which of the following statements is incorrect for Ri? {a) The value of Ry cannot be more than one. (b) Higher R; value means higher adsorption. (c) Rrvalue is dependent on the mobile phase. (d) Rr value depends on the type of chromatography. (2019) 6. The correct match between item-I and item-ll is ttem-1 Item-ll P., Benzaldehyde (i) Mobile phase Q. Alumina (ii) Adsorbent (lil) Adsorbate R. Acetonitrile (a) P —> (i, Q—> (), R-—> (ill) (b) P—> (ll), Q—> (i), R—> (I) (6) P —> (i), Q—> (ii), R—> (il) (d) P—> (i), Q—> (i > (i) (2019) 7. If dichloromethane (DCM) and water (H20) are used for differential extraction, which one of the following statements is correct ? (a) DCM and H-0 will be miscible clearly. (b) OCM and H20 would stay as lower and upper layer respectively in the separating funnel. (c) DCM and H0 would stay as upper and lower layer respectively in the separating funnel. ill make turbid/colloidal mixture. (2019) (d) DCM and H20 8. The correct match between items and Il is Item-1 tem-II (Mixture (Separation method) (A) H20 : Sugar (P) Sublimation (8) H20 : Aniline (Q) Recrystall (C) H.0 : Toluene (R) Steam di (S) Differential extraction PURIFICATION—N2__ GURJIT S. KAPUR (PG.1IT-DELHN) (B) > (R); (C) > (8) (b) (A) —> (R) ;(B) > (P); (©) —> (8) >) (a) (A) ~> (8); 1B) > (R); (C) —> (P) KAPUR CLASSES. (a) (A) -> (Q) (e) (A) ~> (Q); (B) —> (R}; (C) > (P) ). The correct match between items of List— 1 and List-ll is List -1 A. Coloured impurity B. Mixture of o-nitrophenol and p-nitrophenol ©. Crude Naphtha R. Charcoal treatment S. Distillation under reduced pressure D. Mixture of glycerol and sugars (A)(R), (B){S), (C){P),(D)Q)_—_(b) (A)-AR), (B)4P), (C)-(Q), (0)-{S) Statler terish fesse: Orta) a) aya) (8)4P), (4S), (O)A0) (2018) 10.Two compounds i and Ware eluted by column chromatography (adsorption of | wing Is a correct statement Seance Atl Which one of the fol {a) li moves faster and has higher R; value than (b) | moves faster and has higher Rivalue than {c) II moves slower and has higher Ry value than (2018) 41.Which of the following statements is not true about partition chromatography? (a) Mobile phase can be a gas. (b) Separation depends upon equilibration of solute between mobile and a Stationary phase. (c) Paper chromatography is an example of partition chromatography. (a) Stationary phase is a finely divided solid adsorbent. (2017) 12.The distillation technique most suited for separating glycerol from spent-lye in the soap industry is (a) simple distillation (b) fractional distillation (c) steam distillation (d) distillation under reduced pressure. (2016) 1 13. Given beow are two statements. One is labelled as Assertion (A) and the other is labelled as Reason (R) Assertion (A) : A simple distillation can be used to separate a mixture of propanol and propanone. Reason (R) : Two liquids with a difference of more than 20°C in their boiling points can be separated by simple distillation. In the light of the above statements, choose the most appropriate answer from the options give below. (a) Both assertion and reason are correct but reason is not the correct explanation of assertion. (b) Both assertion and reason are correct and reason is the correct explanation of assertion. (c) Assertion is true but reason is false. (d) Assertion is false but reason is true. (2021) 414.Which purification technique is used for high boiling organic liquid compound (decomposes near its boiling point) ? (a) Simple distillation (b) Fractional distillation (c) Reduced pressure distil (a) Steam dis (2021)—_PURIFICATION—N2__GURJITS. KAPUR DELI) KAPURCLASSES _PURIFICATION—N4_ GURUIT S. KAPUR (PG.IIT-DELHI he purification of compound is independent of System, vit 20. Which technique among the following. is most appropriate in separation of a ire of 100 mg of p-nitrophenal and picric acid 7 (b) 2-5 ft long column of silica get Preparative TLC (Thin Layer Chromatography) (2022) icentimeter. 21,Match List—1 with List—tl _ ui List ] {Purification Process) | Chloroform and Anil Benzoic acid and (2021) 1m volatile due to intramolecular hydrogen igh melting due to hydrogen bonding. ts, choose the most appropriate answer from (2021) A thin layer of silica gol is spread over a glass plate of chromatography which acts as an adsorbent. In san be separated by si joth A and R are true and Ris the correct explanation of A. joth A and R are true but R is not the correct explanation of A. ge scale separation ? {¢) Statement | 1s tatse but statement (2021) (a) Chromatographic separation (b) Fractional crystallization 18.Using the proviced information in the following paper chromatogram: (c) Steam distillation {¢) Sublimation 24.Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R. (2022) mixture contains benzoic acid and napththalene. The pure 11 be separated out by the use of benzene. jenzoic acid is soluble in hot water. In the light of the above wus an wn cre epi otannemresarmats Fig: Pi he fe inds A and B is true and R is false. / Reciensrewanegatr mete con GAEIIRR SS wv(PG.NT-DELH)) pURIFICATION—NS__GURJITS. KAPUR sted HNO: “sodium fusion extract is boited with concentra .st, sodium fusion ext uy Me cLASSES _ PUREICATION NS _GURJIT S. KAPUR (PG.IT-DELHI) KAPUR CLASSES. (2022) Me gines of me feowing ss Stucture of 2 Separating funnel? 31.During halogen te: to * _ cted sodium . u te id of sodium npor yeni gai compound wit th nitrogen and sulphur are present 8 $ 3 2 Q i 3 nen bo! 1s whies one he fotowing techniques isnot used to spot components of a aesaign fT Sieees spec on tin lyer chromatographic pat (e022) F vapour yanate is formed. ae (b) UV. Light rp uitrogen and sulphur are present in an SS irascn agent as 2 component of mobile phase ot ives of sodium used in sodium fusion ne ex formed to give NaCN and Na:S. ‘choose the most appropriate answer from ‘Spraying of an appropriate reagent je Tithe separation of two coloured substances was done by paper (2022) oCdnneda TESS yaaty. The cotance travelled by solvent front, substance A and : 3 an: the options given below: spsanee Bien te base ine a8 3.25 cm, 2.08 em and 1.05 cm, respectively. eh statement_—t and Statement—l are correct. a is___- (2022) and Statement—Il rect. sas os ef te folowing eto laments canbe detected using sium rect but Stateme! correct. = - (d) Statement incorrect but Stater correct. Paospherces, Oxygen, Nitrogen, Halogens 2 ate etnod of estimation of halogen, 0.172 g of an organic compound 9 Cr a ogee Showed presence rae got bromine Wich of esse correct structure Phosphorous, Helogens of the compound ? Halogens, Narogen, Oxygen, Sulphur (2021) je composm eh Scipnar, nzrogen, phosphorus and halogens can be detected by sodium jw me cme as) oS «a cee 20) 24.The Kjeldahl method of nitrogen estimation fails i ee cosets? rogen estimation fails for which of the following \ qeecn <> ao Fa rere 3) and (4) {b) (1) and (4) ind (4) (4) (2) and (3) (2020) scat cannot be used to estimate nitrogen for which of the (b) FecfFe(Cny] (@) CoHt2NO2 (2) FedFe{CNh]s (©) CH,CcH,—C=N (2019)PURIFICATION—NS Gi 5. Which of the following is structure of a Separating leita? Ser “Sr > eS «a> (2022) (b) ULV, Light ent) Visualisation agent as a component of mobile phase {d) Spraying of an appropriate reagent 27.The separation of two coloured substane: chromatography. The distance travelled Substance 5 from the base line are 3.25, ‘The ratio of R: values of A to 28.Which one of the followin fusion extract ? (a) Phosphorous, Oxygen, Nitrogen, Halogens (b) Nitrogen, Phosphorous, Carbon, Sulphur (c) Sulphur, Nitrogen, Phosphorous, Halogens (d) Halogens, Nitrogen, Oxygen, Sulphur (2021) A. (c) Sulphur, nitrogen, phosphorus and halogens can be detected by sodium fusion extract. 29:Match List-1 with List — "es was done by paper by solvent front, substance A and ‘6m, 2.08 em and 1.05 cm, respectively. ots (2022) 1g set of elements can be detected using sodium [ List=1 List— | Test Reagents / Species detected Observation(s) [ay T Lassaigne’s test [Carbon ‘Sulphur N, S, P and halogen Halogen specifically (D) | The sodium fusion | extract gives black precipitate with acetic acid and lead | acetate ‘The correct match is (2) (A) ~ (ii), (8) ~ @), (C) ~ Gv), (0) ~ (1 () (A) (i, (B) ~ (iv), (C) ~ (i), (D) ~ (i) (c) (A) ~ Gi), (B) ~ (i), (C) ~ Gi), (0) ~ (iv) (a) (A) ~ (i), (B) ~ (ii), (C) = (iv), (D) — (ii) (2024) 30.Fe* cation gives a Prussian blue precipitate on addition of potassium ferrocyanide solution due to the formation of (2022) (2) [Fe(H:O)le [Fe(CN)e} (b) FealFe(CN)e] (c) Fes[Fe(OH)2(CN)4]2 (d) Fea{Fe(CN)e]s (iv) URIFICATION-—-NB__ GURJIT S. KAPUR (Pt alogen test, sodium fusion extract is boiled with concentrated HNOs 24.During halogen test, seam f IN {a) remove unreacted sodium {b) decompose cyanide or sulphide of sodium {c) extract halogon from organic compound (4) maintain the pH of extract. 32.Given below are two statements: ‘Statement! : In Lassaigne’s test, when both nitrogen and sulphur are present in an organic compound, sodium thiocyanate is formed. - Statement-l : If both nitrogen and sulphur are present in an organic ‘compound, then the excess of sodium used in sodium fusion will decompose the sodium thiocyanate formed to give NaCN and Na3S. In the light of the above statements, choose the most appropriate answer from f (2022) ‘and Statement—Il are correct. (b) Both Statement—t and Statement—il are incorrect. (c) Statement—t is correct but Statement— is incorrect. (d) Statement— is incorrect but Statement—l is correct. 33.In Carius method of estimation of halogen, 0.172 g of an organic compound ‘showed presence of 0.08 g of bromine. Which of these is the correct structure of the compound ? === | |= as ; (2020) 34.The Kjeldahl method of nitrogen estimation fails for which of the following reaction products ? RO. oo Sete ou.cn <= ca Somes | Ne sao. oe Se {a) (3) and (4) (©) (1) and (4) (6) (1), (3) and (4) —_(@) (2) and (3) (2020) 35.Kjeldahi's method cannot be used to estimate nitrogen for which of the following compounds ? (@) CoHsNOz (©) CH,CH, -—C=N (a) CHE, (2019)PURIFICATION—N@___GURJIT S. KAPUR (PG IT-DELHI) PURIFICATIONN7_ GURUJIT S, KAPUR (PG.IT-DELHI) pound evolve 6 moles of CO;, is estimated thro 4 moles of H.0 a1 ‘ugh Dumas method and was found to nd 1 mole of nitrogen gas. The formula re (cia, — (ors owing compounds wil be suitable ff Kicieents melon for halogens 250 mg of an organic compound No, or 32.In Carius method of estimation of gave 141 mg of AgBr. The percentage of bromine in the compound is (et, mass | Ag = 108; Br= 20) (2016) method /10 HzO. solution. The 20 mL of M/10 NaOH solution for neutralization. The percentage of nitrogen in the compound is (a) (b) 5 ic) 10 (4) 24 (2016) ation of nitrogen, 1.4 g of an organic compound was digested by volved arnmonia was absorbed in 60 mL of M/10 id required 20 mL of M/10 sodium hydroxide jen in the compound is (c) 10% (a3 jic compound containing nitrogen was disgested fahl’s method and ved ammonia was absorbed in 20 acid required 15 mL of 0.1 M NaOH (2014) ) 47.4 (a) 23.7, (2010) reatment of 0.30 g of an organic compound rogen was passed in 100 mL of 0.1 Ms quired 20 mL of 0.5 M sodium hydroxide ion. The organic compound {a) acetamide (b) benzamide (c) urea (d) thiourea. (2004) 43.In a compound C,H and N atoms are present in 9: 4 : 3.5 by weight. Molecular ight of compound is 108. Molecular formula of compound is (d) CoHsaNs (2002) a) CoH (b) CHAN CHiN: 44.In an estimation of bromine by Carius method, 1.6 g of an organic compound ‘gave 1.88 g of AgBr. The mass percentage of bromine in the compound is (Atomic mass, Ag = 108, Br = 80 g mol—1) (2020) 45.In Carius method, halogen containing organic compound is heated with fuming nitric acid in the presence of ) CuSO, —(b) HNOs (c) BaSOx (d) AgNOS (2021) KAPUR CLASSES 46.Nitrogen can be estimated by Kjeldahl’s method for which of the following os Nex Nci CH, — NH, (2021) 47.Complete combustion of 1.20 g of an oxygen containing compound (C,H,0,) ‘gave 2.64 g of CO; and 1.02 g of H;0. The percentage of oxygen in the organic compound is (a) 5033 {b) 53.33, (c) 51.63, (6) 63.53 (2021) 48.Vihich of the following is a false statement 2 - .) Kjeldaht's method is used for the estimation of nitrogen in an organic mpound. )) Phosphoric acid produced on oxidation of phosphorus present in an ganic compound is precipitated as MgzP:0; by adding magnesia mixture. Carius tube is used in the estimation of sulphur in an organic compound. ‘arius method is used for the estimation of nitrogen in an organic mpound. (2021) .In the sulphur estimation, 0.471 g of an organic compound gave 1.44 g of barium sulfate. The percentage je compound is__%. (Nearest integ (2021) 50.n Carius meth imation of halogens, 0.2 g of an organic compound ga Percentage of bromine in the compound is 108, Br = 20) 021) 51.The number of moles of CuO, that will be utilized in Dumas method for estimating nitrogen in a sample of 57.5 g of N, N-dimethylaminopentan (2021) exist ecanig Dune shod grsteto CGH N+ (2++2)ou0 30, + 2H.0 t: Pet leZ)ou value of yis_ (nteger answer) > 53.When 0.15 g of an organic compound was analyzed using C: estimation of bromine, 0.2397 g of AgBr was obtained. Th bromine in the organic compound is [Atomic mass: Silver = 108, Bromine = €0) vueura KAPUR CLASSES PURIFICATION Ne (Roune off to the Nearest integer) (Given atomic mass C 12.0 4, H: 1.0 u, N $8.1n Canus methos of estimation of halogen, gave 0.36 ¢ of AgBt Find out the percentage of bromine in the compound. (Motu masses AgBr = 188 g mot, Br = 80 g mol) (a) 34.06% (b) 40.04% " (c) 36.03% (a) 38.04% 80.120 g of an organic compound that contains only carbon and hydrogen gives 380 g of CO, ana 270 g of water on complete combustion. The percentage of carbon and hydrogen, respectively are (2022) (a) 25 ang 75 (b) 40 and 60 (0) 75 and 25 1 While estimating the nitrogen present in an organic compound by Kjeldah's method, the ammonia evolved trom 0.25 g of the compound neutralized 2.5 mL of 7M HSO, Te personage of ateagen present in Stpenis compound s___ ) €2.4 sample of 0.126 g of an organic compound when analyzed by Duma’s metho yields 22.78 mL of nitrogen gas collected over KOH solution at 260 K and 758 mm Hg, The percentage of nitrogen in the given organic compound 5 (Nearest integer) ‘The vapour pressure of water at 280 K is 14.2 mm Hg. (b) R= 0.082 L atm K—' mor (2022) KAPUR CLASSES _PURIFICATION—Nto 62.40.166 g sample of an organic compound was digested wit! then distilled with NaOH The ammonia gas evolved was pas: mi of 0. MSO. The used acid required 30.0 mL of 0.25 N complete neutralization The mass percentage of nitrogen in th compound is 64.0 2g of an organic compound w Dumas method in which volume mL. The percentage of nitrogen in (2022) 65.0n complete combustion 0.30 g of an organic compound gave 0.26 g of carbon dioxide and 0.10 g of water. The percentage of carbon in the given ‘organic compound is rest integer) (2022) sociation reaction, yields 7.5 g of hydrogen, 60 g irbon. Given that the atomic masses of H, O and C. sctivoly. The data agrees with how many form (b) HCHO (c) CHOOCH, the compound is (2022)