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Sayantan Dutta
Air Pollution
Pollution is one of the major environmental
problems these days. The term pollution can
be defined in various ways.
According to E. P. Odum “Pollution is an
undesirable change in physical, chemical or
biological characteristics of air,
water and soil that may harmfully affect the
life or create a potential health hazard for
living organisms”.
According to Edward (1972) “Pollution is the
release of substance or energy into
environment by man which damages either his
health or resources.”
Pollution can be divided as follows:
a) On the basis of site of occurrence :
i) Air Pollution
ii) Water Pollution
iii) Soil Pollution
b) On the basis of origin :
i) Natural e.g. Volcanic eruptions, release of CH4 by paddy
fields and cattle, release of CO2 by plants and animals,
emission of natural gas, O3, nitrogen oxides, cosmic rays, UV-
Rays etc.
ii)Anthropogenic (man-made) : Burning of fossil fuels,
deforestation, mining, sewage, industrial effluent, pesticides,
fertilizers etc.
Pollutant : A pollutant is anything including a chemical,
geochemical substance or a biological product that deteriorates
our natural environment. The United States Environment
Protection Agency (EPA) defines a pollutant as any substance
introduced into the environment that adversely affects the
usefulness of a resource.
Question 6
Option A
Option B
Option C
Option D
What is air?
Air is a precious resource that most of us take for granted.
Air supplies us with oxygen, which is essential for our bodies
to live.Without it,we would die within minutes.
Question 7
Option A
Option B
Option C
Option D
Air pollution
According to ‘WHO’ Air pollution is mixing of some
substances in the ambient air in such concentrations that a
situation arise in which man and his environment is badly
affected
On the basis of the sources air pollution may be classified
under the following categories :
Question 9
Option A
Option B
Option C
Option D
A. Anthropogenic (man-made) sources:
1. Stationary sources include smoke stacks of power plants,
manufacturing facilities (factories) and waste incinerators, as well as
furnaces and other type of fuel burning heating devices.
2. Mobile sources include motor vehicles, marine vessels and aircraft.
3. Chemicals, dust and controlled burn practices in agriculture and forest
management.
4. Waste deposition in land fills generates methane. Methane is highly
flammable and may form explosive mixtures with air. Methane is also an
asphyxiant and can displace oxygen in an enclosed space. Asphyxia or
suffocation may result if the oxygen concentration is reduced to below
19.5% by displacement.
5. Military resources, such as nuclear weapons, toxic gases, germ warfare
and rocketry.
6. Fumes from paints, hair spray, varnish, aerosol sprays and other
solvents.
Summary of Today’s Class
B. Natural sources :
1. Dust from natural sources, usually large areas of land with few or no
vegetation. Methane, emitted by the excreta by animals for example cattle.
2. Radon gas from radioactive decay within the Earth’s crust. Radon is a
colourless, odourless, naturally occurring radioactive noble gas that is
formed from the decay of radium. It is considered to be a health hazard.
Radon gas from natural sources can accumulate in buildings, especially
confined areas such as the basement and it is the second most frequent
caused of lung cancer after cigarette smoking.
3. Smoke and carbon monoxide from wild fires.
4. Vegetation, in some regions, emits environmentally significant amounts
of VOCs on warmer days. These VOCs
react with primary anthropogenic pollutants specifically NOx, SO2 and
anthropogenic organic carbon compounds to produce a seasonal source of
secondary pollutants.
5. Volcanic activity, which produces sulphur, chlorine and ash particulates.
Primary pollutants
There are mainly five primary pollutants which together
contribute more than 90% of global air pollution. These
are :
A. Carbon Monoxide
B. Nitrogen Oxides
C. Sulphur Dioxide
D. Hydrocarbon or VOC
E. Particulates
Carbon monoxide(CO)
It is a colourless, odourless and tasteless gas (b.p. liquid
CO) –192°C ( –314°F). It is 96.5% as heavy as air and is
not soluble in water. The basic chemical reactions
yielding CO are:
1. Incomplete combustion of fuel or carbon containing
compounds
2C + O2 → 2CO ..... (1)
2. Reaction between CO2 and carbon containing materials
at elevated temperatures in industrial processes e.g. in
blast furnaces.
CO2 + C → 2CO
3. Dissociation of CO2 at high temperatures
CO2 — CO + O
It reduces oxygen
carrying capacity
by forming
carboxy
haemoglobin in
blood cell caused
headache,
breathing trouble,
drowsiness and
chest pain.
Nitrogen Oxides :
1. Nox represents composite atmospheric gases, nitric oxide (NO),
and nitrogen dioxide (NO2) which are primarily
involved in air pollution.
2. NO is a colourless, odourless gas, but NO2 has a reddish-brown
colour and pungent suffocating odour.
3. The formation of NO is favoured at high temperature, normally
attained during many combustion processes involving air (1210-
1763°C).
4. Nitrogen oxides, particularly nitrogen dioxide are expelled from
high temperature combustion, wood burning and are also produced
during thunder storm by electric discharge.
5. Nitrogen dioxide is a chemical compound with the formula NO2. It
is one of several nitrogen oxides. One of the most prominent air
pollutants, this reddish-brown toxic gas has a characteristic sharp,
biting odour.
6. Oxides of nitrogen create blue baby syndrome, cause
irritation in the fibers of the lungs and in mucus membrane, and
can create different disease such as bronchitis, pneumonia etc.
7. In plant it suppressed growth, chlorosis and marginal
bleaching
Sulphur Dioxide(SO2)
1. It is a colourless gas with a pungent odour. It is
produced from the combustion of any sulphur bearing
material .
2. SO2 comes from fuel combustion (especially high
sulphur coal), electric utilities and industrial processess
as well as natural occurrence like volcanoes.
3. Coal and petroleum often contain sulphur compounds,
and their combustion generates sulphur dioxide. This is
one of the causes for concern over the environmental
impact of the use of these fuels as power sources.
4. It creates irritation of eyes, burning sensation within the
respiratory tract, disease related to ear and nose and throat.
5. In plant it may create necrosis on leaf, bleaching of leaf
pigments due to conversion of chlorophyll-a to phaeophytin-a
resulting decrease in productivity, affects stomatal pores,
stomatal frequency, trichomes and chloroplast structure.
6. Lichens experience bleaching in the presence of SO2 in air.
Because of this lichen is called as Bioindicator of air pollution.
Hydrocarbons :
1. Natural sources, particularly trees, emit large quantities of
hydrocarbons in the atmosphere.
2. CH4 is the major naturally occurring hydrocarbon emitted
into the atmosphere. It is produced in considerable quantities
by bacteria in the anaerobic decomposition of organic matter
in water, sediments and soil.
3. Domesticated animals contribute about 85 million tonnes
of CH4 to the atmosphere each year. CH4 has a mean
residence time of about 3 to 7 years in the atmosphere.
4. It has been estimated the anthropogenic source (human
activities) contribute about 15% of the hydrocarbons emitted
to the atmosphere each year. Automobiles are the major
source in this respect.
Volatile Organic Compounds :
1. VOCs are a well-known outdoor air pollutant. They are categorized as either
methane (CH4) or nonmethane
(NMVOCs).
2. Methane is an extremely efficient green house gas which contributes to global
warming. Other hydrocarbon VOCs are also significant green house gases because
of their role in creating ozone and prolonging the life of methane in the
atmosphere. This effect varies depending on local air quality.
3. Hydrocarbons from human activities are generally found in areas of high
population density where the maximum
damage to human beings and plants can occur.
4. About 20 different hydrocarbon were identified and analyzed. Among them,
mention may be made of: ethane and ethylene, acctylene and propane, n-butane,
isopentane, toluene, m-xylene, n-pentane, and isobutane. The concentrations of
these hydrocarbons varied with traffic density at different hours of the day.
5. The aromatic NMVOCs benzene, toluene and xylene are suspected carcinogens
and may lead to leukemia with prolonged exposure.
Particulates
A particulate pollutant is a microscopic or microscopic liquid and
solid particles present in the form of the suspension in the air.
Particulate matter can be released from different types of human
activities such as vehicle emissions, smoke particles, dust particles,
and ash from industries.
Particulate matter pollution :
1. The short-term effects include irritation to the
eyes, nose and throat and lower respiratory
infections such as bronchitisand pneumonia. Others
include headaches, nausea and allergic reactions.
2. Long-term air pollution can aggravate the medical
conditions of individuals with asthma and
emphysema. Long term health effect can include
chronic respiratory disease lung cancer, heart
disease and even damage of the brain, nerves, liver or
kidneys.
3. In plant it may cause chlorosis followed by
reddening and yellowing, necrosis, bleaching of leaf
margin.
Chlorofluorocarbons(CFCs) :
Secondary Pollutants :
Secondary pollutants are those which are formed in the atmosphere by
chemical interactions among primary pollutants and normal atmospheric
constituents. The examples are : sulphur trioxide, nitrogen dioxide, PAN
and SMOG etc.
A. Photo chemical smog:
1. Particulates created from gaseous primary pollutants and other compounds make
photochemical SMOG. Smog (Smoke + Fog) is a kind of air pollutant.
2. Classic smog results from large amounts of coal burning in area caused by a
mixture of smoke and sulphur dioxide.
3. Modern smog does not usually come form coal but from vehicular and industrial
emissions, that are acted on in the atmosphere by ultraviolet light from the Sun to
form secondary pollutants that also combine with the primary emissions to form
photochemical smog.
■In the great “SMOG Disaster” in London in 1952, four thousand peoples died in a
few days due to the high concentrations of pollution.
■Smog ozone may damage plant as well as animal life.
Several species of plants are very susceptible to PAN is
smog. PAN damages chloroplasts, which results in
reduction of Photosynthetic efficiency by inhibiting the
Hill reactionsand growth of plants.
Ground level Ozone(O3) :
Ground-level ozone is a colorless and highly irritating gas
that forms just above the earth's surface. It is called
a "secondary" pollutant because it is produced when two
primary pollutants react in sunlight and stagnant air. These
two primary pollutants are nitrogen oxides (NOx) and
volatile organic compounds (VOCs).
It decreases lung function and causes respiratory
symptoms, such as coughing and shortness of breath, and
also makes asthma and other lung diseases get worse.
Effect of Air Pollution:
• Acidification :
• Excessive amount of pollutants sulphur and nitrogen
oxides released by car and industrial processes are the
main cause of acidification of rain.
• Normal rain water is slightly acidic and has a pH range
of 5.6 – 6.5. When pH range of rain water is less than
5.6,it is called acid rain.
• Global warming : Another direct effect of air pollution is
the immediate alternations, that the world is suffering
due to global warming. With increased temperatures
worldwide, increase in sea levels by melting of ice from
cooler regions and icebergs, displacement and loss of
habitat have already signalled an impending disaster, if
action for prevention and normalization are not
undertaken soon.
Water Pollution
Water pollution is the contamination of water sources by
substances which make the water unusable for drinking, cooking,
cleaning, swimming, and other activities. Pollutants include
chemicals, trash, bacteria, and parasites. All forms of pollution
eventually make their way to water.
Radioactive waste :-
Nuclear power plants,
Nuclear testing and
explosion add variable
amount of Radioactive
materials to soil.
Effects of soil Control measures :-
pollution:-
■ Biodegradable wastes used
●Disposal of industries and non biodegradable wastes
wastes on fertile land may be recycled.
degrades the quality of
■ Planting of trees must be
soil.
encouraged.
● Urban waste slowly ■ Solid waste can also be
poison the soil,damaging used for electricity
its fertility. generation.
● Radioactive elements ■ Use of chemical fertilisers
that present in polluted and pesticides should be
soil enter food chain minimize.
through plants.
Light Pollution:-
Light pollution refers to artificial light flow which is inappropriate
in intensity, direction and duration, which creates disharmony in
the surrounding.
It is a fall out of unplanned urbanization and rapid
industrialization. Nightglow and city lights severely impact the
visibility of stars at night.
■Impacts of Light Pollution :-
1. Increased exposure to light interferes with sleep, increase
stress response and lower job productivity.
2. Excessive light interferes with the natural rhythm of nocturnal
wildlife. Habitat of nocturnal is destroyed by bright light. It
increases predation of prey and thereby impacts their population
structure. Many species stop reproduction in the presence of
bright light. Bats are essential for seed dispersal but their vision
is blinded by bright light. They are unable to perform their
ecological function.
3. Olive Ridley turtles which track moonlight
reflection in ocean gets confused with city lights
and start moving towards cities. They meet with
accident when they enter urban areas.
4. Astronomers and stargazers find it difficult to
observe the shimmering stars and other heavenly
bodies.
Control measures of light pollution:-
Control measures of light pollution:-
1. Downlighting of street lights directed
downwards to create a pool of light on the road
as sending light emission
upwards leads to considerable wastage of light
energy.
2. Intelligent lighting system which can adjust
themselves to the available light from vehicular
source.
3. Promote lighting options that are low-impact,
energy-efficient and visually pleasing.
Radioactive Pollution:-
The radioactive pollution is defined as the physical
pollution of living organisms and their
environment as a result of release of radioactive
substances into the environment during nuclear
explosions and testing of nuclear weapons.
The release of spent fuel(Radioactive waste)is
increasing with the establishment of nuclear
reactors, nuclear weapons. The major issue with
radioactive material is that ionizing radiation from
these substances is long lasting and takes millions
of years for degradation.
What is the effect of radioactive pollution?
Exposure to large amounts
of radioactivity can cause
nausea, vomiting, hair loss,
diarrhea, hemorrhage,
destruction of the intestinal
lining, central nervous
system damage, and death.
It also causes DNA damage
and raises the risk of
cancer, particularly in young
children and fetuses.
Thank You
See you next day