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Chemistry Paper 1 TZ2 HL
Chemistry Paper 1 TZ2 HL
Chemistry
Higher level
Paper 1
1 hour
Instructions to candidates
• Do not open this examination paper until instructed to do so.
• Answer all the questions.
• For each question, choose the answer you consider to be the best and indicate your choice on
the answer sheet provided.
• The periodic table is provided for reference on page 2 of this examination paper.
• The maximum mark for this examination paper is [40 marks].
2218 – 6113
19 pages © International Baccalaureate Organization 2018
The Periodic Table
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
1 Atomic number
2
1 H He
1.01 4.00
Element
3 4 5 6 7 8 9 10
2 Li Be B C N O F Ne
6.94 9.01 Relative atomic mass 10.81 12.01 14.01 16.00 19.00 20.18
11 12 13 14 15 16 17 18
3 Na Mg Al Si P S Cl Ar
22.99 24.31 26.98 28.09 30.97 32.07 35.45 39.95
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38 69.72 72.63 74.92 78.96 79.90 83.90
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
–2–
85.47 87.62 88.91 91.22 92.91 95.96 (98) 101.07 102.91 106.42 107.87 112.41 114.82 118.71 121.76 127.60 126.90 131.29
55 56 57 † 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.91 137.33 138.91 178.49 180.95 183.84 186.21 190.23 192.22 195.08 196.97 200.59 204.38 207.2 208.98 (209) (210) (222)
87 88 89 ‡ 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
7 Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Cn Unt Uug Uup Uuh Uus Uuo
(223) (226) (227) (267) (268) (269) (270) (269) (278) (281) (281) (285) (286) (289) (288) (293) (294) (294)
† 58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.12 140.91 144.24 (145) 150.36 151.96 157.25 158.93 162.50 164.93 167.26 168.93 173.05 174.97
‡
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.04 231.04 238.03 (237) (244) (243) (247) (247) (251) (252) (257) (258) (259) (262)
M18/4/CHEMI/HPM/ENG/TZ2/XX
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1. What is the number of atoms of oxygen in 2.0 mol of hydrated sodium carbonate, Na2CO3•10H2O?
Avogadro’s constant, L or NA : 6.02 × 1023 mol-1
A. 6
B. 26
C. 3.6 × 1024
D. 1.6 × 1025
2. What is the volume, in cm3, of the final solution if 100 cm3 of a solution containing 1.42 g of
sodium sulfate, Na2SO4, is diluted to the concentration of 0.020 mol dm-3?
Mr (Na2SO4) = 142
A. 50
B. 400
C. 500
D. 600
3. What is the percentage yield when 2.0 g of ethene, C2H4, is formed from 5.0 g of ethanol, C2H5OH?
Mr (ethene) = 28; Mr (ethanol) = 46
2.0 5.0
A. × × 100
28 46
2.0
B. 28 × 100
5.0
46
28 5.0
C. × × 100
2.0 46
28
D. 2.0 × 100
5.0
46
Turn over
–4– M18/4/CHEMI/HPM/ENG/TZ2/XX
n=5
B
n=4
A
n=3
C
n=2
D
n=1
5. The graph shows the first ionization energies of some consecutive elements.
X
1st ionization energy
Atomic number
A. Y is in group 3
B. Y is in group 10
C. X is in group 5
D. X is in group 18
–5– M18/4/CHEMI/HPM/ENG/TZ2/XX
A. Pb
B. Pm
C. Pt
D. Pu
C. A complex with Cl− is more likely to be blue than that with NH3.
A. MgN
B. Mg2N3
C. Mg3N
D. Mg3N2
Turn over
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10. Which species has the longest carbon to oxygen bond length?
A. CO
B. CH3OH
C. CH3CO2−
D. H2CO
11. What are the predicted electron domain geometries around the carbon and both nitrogen atoms in
urea, (NH2)2CO, applying VSEPR theory?
C. tetrahedral tetrahedral
A. CO
B. CO2
C. SF2
D. SF4
–7– M18/4/CHEMI/HPM/ENG/TZ2/XX
13. Which overlap of atomic orbitals leads to the formation of only a sigma (σ) bond?
I. s − p
II. p − p
III. s − s
A. I and II only
D. I, II and III
14. Which describes the reaction shown in the potential energy profile?
products
Enthalpy
reactants
Reaction coordinate
A. The reaction is endothermic and the products have greater enthalpy than the reactants.
B. The reaction is endothermic and the reactants have greater enthalpy than the products.
C. The reaction is exothermic and the products have greater enthalpy than the reactants.
D. The reaction is exothermic and the reactants have greater enthalpy than the products.
Turn over
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15. Two 100 cm3 aqueous solutions, one containing 0.010 mol NaOH and the other 0.010 mol HCl,
are at the same temperature.
When the two solutions are mixed the temperature rises by y C.
Assume the density of the final solution is 1.00 g cm−3.
Specific heat capacity of water = 4.18 J g−1 K−1
200 × 4.18 × y
A.
1000 × 0.020
200 × 4.18 × y
B.
1000 × 0.010
100 × 4.18 × y
C.
1000 × 0.010
16. Which value represents the lattice enthalpy, in kJ mol−1, of strontium chloride, SrCl2?
+550
Enthalpy
−829
Sr Cl2 (s)
All values in kJ
A. - (-829) + 164 + 243 + 550 + 1064 - (-698)
Turn over
– 10 – M18/4/CHEMI/HPM/ENG/TZ2/XX
17. Which system has the most negative entropy change, ∆S, for the forward reaction?
18. The potential energy profile for the reversible reaction, X + Y Z is shown.
Enthalpy
X+Y A
D
C
B
Z
Reaction coordinate
Which arrow represents the activation energy for the reverse reaction, Z → X + Y, with a catalyst?
A. I and II only
D. I, II and III
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20. When X reacts with Y to give Z, the following graph is plotted. What can be deduced from the
graph?
[X]
Time
A. The value of the rate constant, k, is independent of temperature and is deduced from the
equilibrium constant, Kc.
B. The value of the rate constant, k, is independent of temperature and the overall reaction
order determines its units.
C. The value of the rate constant, k, is temperature dependent and is deduced from the
equilibrium constant, Kc.
D. The value of the rate constant, k, is temperature dependent and the overall reaction order
determines its units.
22. Which factor does not affect the position of equilibrium in this reaction?
B. Change in temperature
C. Addition of a catalyst
D. Change in pressure
Turn over
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23. What occurs when the pressure on the given equilibrium is increased at constant temperature?
C. Kc stays the same and the position of equilibrium moves to the left.
I. Cu
II. CuO
III. CuCO3
A. I and II only
D. I, II and III
A. A strong acid is a good proton donor and has a strong conjugate base.
B. A weak acid is a poor proton acceptor and has a strong conjugate base.
C. A strong acid is a good proton donor and has a weak conjugate base.
D. A strong base is a good proton donor and has a weak conjugate acid.
– 13 – M18/4/CHEMI/HPM/ENG/TZ2/XX
A. an electrophile
B. BF3
C. CH4
D. a nucleophile
A. Loss of hydrogen
C. Gain of electrons
D. Loss of oxygen
29. What are the products of the electrolysis of molten zinc bromide?
A. zinc bromine
B. hydrogen bromine
C. bromine zinc
D. bromine hydrogen
Turn over
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Cell 1 Cell 2
If x g of silver are deposited in cell 1, what volume of oxygen, in dm3 at STP, is given off in cell 2?
x 1
A. × × 22.7
108 4
x
B. × 4 × 22.7
108
x 1
C. × × 22.7
108 2
x
D. × 2 × 22.7
108
31. What are the major products of electrolysing concentrated aqueous potassium iodide, KI (aq)?
A. potassium iodine
B. hydrogen iodine
C. hydrogen oxygen
D. potassium oxygen
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A. CHCCH2CH3, CHCCH2CH2CH3
B. CH3CH2CH2CH2OH, CH3CH2OCH2CH3
C. CH2CHCH3, CH3CH2CH2CH3
D. CH3COCH3, CH3CH2OCH3
CH3 H O
H C C C
CH3 H OH
A. 1,1-dimethylpropanoic acid
B. 3,3-dimethylpropanoic acid
C. 2-methylbutanoic acid
D. 3-methylbutanoic acid
A. I and II only
D. I, II and III
Turn over
– 16 – M18/4/CHEMI/HPM/ENG/TZ2/XX
Cl CH 3 CH2Cl
B. nucleophilic nucleophilic
36. Propene is reacted first with hydrogen chloride to produce X which is then reacted with aqueous
sodium hydroxide to give Y. Finally, Y is reacted with excess acidified potassium dichromate
solution.
A. CH3CH(OH)CH3
B. CH3COCH3
C. CH3CH2CHO
D. CH3(CH2)2COOH
A. cis-trans isomers
B. diastereomers
C. enantiomers
D. structural isomers
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38. How are the uncertainties of two quantities combined when the quantities are multiplied together?
A. rate dependent
B. rate independent
C. temperature independent
D. temperature dependent
Turn over
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40. The IR spectra of low density polyethene (LDPE), high density polyethene (HDPE), polypropene
(PP) and polytetrafluoroethylene (PTFE) are shown (not necessarily in that order).
H H H H H CH3 F F
C C C C C C C C
H H n H H n H H F F n
n
A.
B.
(Question 40 continued)
C.
D.