Ciba Specialty Chemicals Corporation USA ‘540 White Plains Road P.O, won 2008 Sarytown NY 1050-8005 Ciba tam to Spm Phone: 800) 41-2960 i 2i-Hour Emergency Phone: (800) 873-1138 ‘Value beyond chemistry a Effective Date: 9/16/03 "Material Safety Data Sheet MSDS No. 7590 1, PRODUCT IDENTIFICATION [ Team | 2 Trade Name: Irganox 1726 > “» Flammability: | 1 ceaciiiigs | 0 Intended Use: Antioxidant ae NFPA RATING Important Use Information: ‘This material is not intended for use in products for which prolonged contact with mucous membranes or abraded skin, body fluids, or implantation within the human body, is specifically intended, unless the finished product has been tested in accordance with national and international applicable safety regulations. Because of the wide range of such potential uses, Ciba Specialty Chemicals Corporation is not able to recommend this material as safe and effective for such uses and assumes no liability for such uses. OMPOSITION / INFORMATION ON INGREDIENTS O] CASNo. (CHEMICAL IDENTITY EXPOSURE LIMITS Ss H ACG ‘OSHA MFR. A TWA PEL Confidentiat | Antioxidant for polymen Nor [Not | _ No Wot [Not] Nor | Nor Esib- | Esab- | Esub- | Esab- | Esab- | Rev | Rev | Rev lished | lished } lished | lished | lished | iewed | iewed | iewed Concentration | 1-100 % by wt 4, HAZARDS IDENTIFICATION Emergency Overview Appearance: Low melting solid Printed: 10/6/2003 Page 1 of 8Trganox 1726 Effective Date: 9/16/03 “Tse proper grounding techniques when emptying this product ffom containers weighing more than 1 pound. A build-up of hazardous electrostatic charges could cause a flash fire or explosion when contents are emptied into a flammable atmosphere. See Section 7. Environmental “The aquatic toxicity ofthis product has not been fully assessed. Avoid spillage or leakage t0 a body of water. Health: “This product has not been assessed for hazards to people and animal; avoid contact if spilled. Disposal ‘Sweep or shovel spilled material and place into a sealable container. Dispose in accordance with local, state and federal regulations. Incineration is recommended, This product is not a hazardous waste under RCRA. Primary Route of Entry: Dermal, inhalation, ingestion Eye: ‘This product has not been tested for eye irritation potential; avoid eye contact, Ski ‘This product has not been tested for skin irritation or sensitization potential. Avoid skin contact. Swallowi This product has not been tested for oral toxicity; avoid swallowing, Inhalatio This product has not been tested for inhslation toxicity; avoid inhalation. Note: Refer to Seetion 11, Toxicological Information for details 4. FIRST AID MEASURES First Aid for Swallowing: Trswallowed, give at east 3-4 glasses of water, but DO NOT induce vomiting. Do not give anything by mouth to an unconscious or convulsing person, First Aid for Skin: ‘Following skin contact, wipe away excess material with a dry towel. Then wash affected areas with plenty of water and soap, if available, for several minutes. Get medical attention if irritation occurs. First Aid for Inhalation: If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops, or if breathing becomes difficult. First Aid for Eye: Following eye contact, flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs ‘Note to Physician: ‘Specific identity ofthis product or component(s) ofthis product is withheld asa trade secret. A more complete description will be provided to a doctor or nurse in the event of a medical emergency, Aggravated Medical Conditions: None known, Printed: 10/6/2003 Page 2 of 8Trganox 1726 Extinguishing Media: Carbon dioxide, dry chemical, foam, water mist Unusual Hazards: ‘Decomposition and combustion products may be toxic. Fire Fighting Instructions: Use self-contained breathing apparatus. ACCIDENTAL RELEASE M Spill or Release Procedures: ‘Sweep or vacuum and place into sealable container for disposal. Wear protective equipment as specified below. HANDLING AND STORAGE Handling: Health and environmental effect test data are limited or do not yet exist for this chemical. As with all industrial chemicals of unknown toxicity, use prudent practices when handling, Avoid eye, skin and clothing contact. Do not inhale. Do not taste or swallow, Use only with adequate ventilation, Storage: Keep container tightly closed when not in use and during transport. Explosion Hazards: © Fordll Packages. DANGER! EXPLOSION RISK - Risk of explosion if an air-dust mixture forms Avoid creating dusty conditions - Empty only into grounded containers - If container is larger than 550 US gallons (21m) in volume, or when flammable solvents are present, the container must be inerted or the system otherwise designed to prevent or contain an explosion - seek expert advise. ‘© Inaddition, for products packaged in fused-lined (coated) fiber drums, fiber drums with conductive liners, steel drums, steel pails, and Ciba supplied bulk bags, the following instructions also apply: Always ground this package before emptying For products which have external protective packaging, discharge product only from the primary product packaging, not from the external container or its liner ‘The user is responsible for designing a system that safely handles solid additives and to ensure proper training of employees in the system's use. Printed: 10/6/2003, Page 3 of 8LEE EEE EEE Trganox 1726 Effective Date: 9/16/03 8. EXPOSURE CONTROLS / PERSONAL PROTECTIO? Engineering Controls: ‘Work in well-ventilated areas. Do not breathe dust. General Protection: ‘Wear coveralls Eye/Face Protectio Tn cases where there is likelihood of eye contact, wear chemical goggles. Skin Protection: ‘Wear impervious gloves as a standard handling procedure, Respiratory Protection: ‘Wear dust mask or respirator in conditions where dust arises from use, 9, PHYSICAL AND CHEMICAL PROPERTIES Appearan Low melting solid Bolling Point Confidential Antioxidant for polymers > 400°C (> 152 °F) Freezing/Melting Point: 28°C (82 °F) Ignition: Confidential Antioxidant for polymers > 400°C (> 752 °F) 10. STABILITY AND REACTIVITY Chemical Stability: Stable. Incompatibility with other Materials: Strong oxidizing agents, strong acids, strong bases Hazardous Decomposition Products: ‘Thermal decomposition and burning may produce carbon monoxide, carbon dioxide, nitrogen oxides and other toxic organic compounds. ‘Hazardous Polymerization: Will not occur. Conditions to Avoi ‘None known. Printed: 1016/2003, Page 4 of 8Trganox 1726 Effective Date: 9/16/03 XI OGICAL, FOR! IN Acute Oral Toxicity: NITS# 2994330001-6227 (antioxident for polymers) from similar products LDS0 (Rats) >5000 mg/kg, ‘Acute Dermal Toxicity: NJTS# 29943300001-6227 (antioxident for polymers) from similar products, LDS0 (Rats) >2000 mgike Skin Irritation: [NJTS# 29943300001-6227 (antioxident for polymers) form similar products (Rabbit) Not an irritant Eye Irritation: ‘NITS# 29943300001-6227 (antioxident for polymers) from similar products (Rabbit) Not an iritant [NJTS# 29943300001-6227 (antioxident for polymers) from similar products (Guinea Pigs) Skin sensitization in Maximization Test (7/20 at first challenge, 1/20 at second challenge) Mutagenicit Confidential Antioxidant for polymers ‘Ames Test: Non-mutagenic NITS# 29943300001-6227 (antioxident for polymers) from similar products A teratology study was perfomred with rats which received oral doses of 0, 50, 150 or 300 mg/kg/day during days 6-15 of gestation. While 300 mg/kg was slightly toxic to the mothers, there were no significant effects on pregnancy or embryo/fetal development Subchronie Toxicity NJTS# 29943300001-6227 (antioxident for polymers) from similar produets Daring a 28-day oral administration study with ras, an apparent functional adaptation ofthe liver occurred in animals receiving 250 and 1000 mg/kg body weight per day, The effects included a limited increase in liver weight (approximately 15%) and serum alkaline phosphate (approximately 30%) without any signs of liver lesions. The no-observable-effect-level (NOEL) for these effects was 50 mglkg A 90-day oral Gavage study was conducted n the rat using doses of 0, 10, 100 and 1000 mg/kg/day. Effects included bypersalivation and increased liver weight without histopathologic changes. The NOAEL is considered to be 1000 mg/kg/day with the NOEL equal to mg/kg/day. ‘A L4-day range finding study was conducted using the beagle dog. The NOEL is 2000 my/kg/day; higher doses were not use, (Oral administration to dogs at dose levels of 10, 100 or 1000 mg/kg/day for thirteen weeks was found to cause biliary cell, proliferation at the 1000 mg/kg dose level that was not reveres by 4-weeks, post-dose. A slight to moderate increase in aminotrasferases and/or alkaline phosphatase activites were recorded at the 100 and 1000 mg/kg dose levels. The no-observable- effect-level (NOEL) was determinded to be 10 mg/kg. Printed: 10/6/2003 Page 5 of 8Trganox 1726 Effective Date: 9/16/03 paki EEE 12, ECOLOGICAL INFORMATION Acute Toxicity to Fish \NJTS# 29943300001-6227 (antioxident for polymers) from similar products Zebra Fish, acute, 96-hour, LCS0:>100 ppm (estimated, based on components) Acute Toxicity to Invertebrates: [NITS# 29943300001-6227 (antioxident for polymers) from similar products (Daphnia magna) EC%), 24-hour: Could not be calculated; ECO is <0.5 ppm and EC100 is >5.5 ppm Acute Toxicity to Algae: [NITS# 29943300001-6227 (antioxident for polymers) from similar products (Scenedesmus subspicatus) ELS0, 72-hour: > 100 mg/t Toxicity to Sewage Bacteria: [NITS# 29943300001-6227 (anitoxident for polymers) from similar products Inhibitory Concentration on Respriation of Aerobic Waste Water Bacteria: IC20, 1C50, IC80>100 ppm Biodegradability: [NITS# 29943300001-6227 (antioxident for polymers) from similar products ‘Not biodegradabel in Modified Sturm Test. Chemical Oxygen Demand: NITS# 29943300001-6227 (antioxident for polymers) from similar products 2.66 g Oxydgen/g Other Toxicity Da No ecological data are available 13. DISPt Ns NS Disposal Considerations: Dispose in accordance with federal, state and local regulations 14 TRANSPORT INFORMATION, This product is not regulated by any means of transport. EGULATORY INI ON Federal Regulations: (Clean Air Act -Hazardous Air Pollutants (HAP): This product contains no hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act, ‘Clean Air Act - Ozone Depleting Substances (ODS): This product neither contains, nor was manufactured with, a Class I or Class Il ozone depleting substance (ODS). We have relied con our suppliers labeling ther products. None have done so, (Clean Water Act- Priority Pollutants (PP): ‘This product contains no chemicals listed under the U.S. Clean Water Act Priority Pollutant List Printed: 10/6/2003 Page 6 of 8Trganox 1726 ‘Occupational Safety and Health Act (OSHA): “This product is considered to be a hazardous chemical under the OSHA Hazard Communication Standard (29 CFR 1910.1200). Its hazards are: Not known, Resource Conservation and Recovery Act (RCRA): ‘This product is not considered to be a hazardous waste under RCRA (40 CFR 261). SARA Title III: Section 302 - Extremely Hazardous Substances (EHS): This product contains no chemicals regulated under Section 302 as extremely hazardous substances. SARA Title III: Section 304 - CERCLA: ‘This product contains no chemicals regulated under Section 304 as extremely hazardous chemicals for emergency release notification ("CERCLA” Lis) SARA Title III: Section 311/312 - Hazard Communcation Standard (HCS): ‘This product is regulated under Section 311-312 (40 CFR 370). SARA Title II: Section 313 Toxic Chemical List (TCL): “This produet does not contain a toxic chemical for routine annual 'Toxic Chemical Release Reporting’ under Sec. 313 (40 CFR 372) TSCA Section 5(e) - Consent Order / SNUR: This product is not subject to a Section $(c) Consent Order or Significant New Use Rule (SNUR). ‘TSCA Section 8(b) - Inventory Status All chemical(s) comprising this product are either exempt or listed on the TSCA inventory. TSCA Section 12(b) - Export Notification: ‘This product does not contain any chemicals subject to Section 12(b) export notification, Additional Federal Information: This product is not subject to a Section 5(0/6(a) rule. International Regulations: Canadian Inventory Status: ‘Not all components listed on the Domestic Substance List (DSL) European Inventory Status (EINECS): This product contains one or more chemicals currently not on the European Inventory of Existing Commercial Chemical Substances (EINECS) or Pre-market notified. ‘Chemical Name: antioxidant for polymers CASRN: Confidential Percent in Composition: 1 - 100 % by wt te Regulation: California Proposition 65: ‘This produet does not contain any chemicals currently on the California list of Known Carcinogens and Reproductive Tox ‘Massachusetts Right-to-Know: Printed: 10/6/2003 Page 7 of 8TS t jrganox 1726 Effective Date: 9/16/03 This product does not contain any chemicals which are sul New Jersey Right-to-Know: “The following is required composition information: (Chemical Name: Antioxidant for polymers ‘NI Registry #: 29943300001-6227 Pennsylvania Right-to-Know: The following is required composition information: Chemical Name: Antioxidant for polymers CASRN: Confidential (Comment; Not on Pennsylvania Hazardous Substance List 16, OTHER INFORMATION ‘MSDS No: 7590 Disclaimer: Jbject to Massachusets Right-to-Know disclosure requirement. "The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or ‘warranty of any kind expressed or implied is made with respect to the information contained herein. Information Contact: For technical information contact your technical sales representative. For additional health / safety / regulatory information, contact the Product Safety Customer Coordinator at (914) Printed: 10/6/2003 785-4288, Page 8 of 8