JEE (MAIN + ADVANCED) 2024

CLASS TEST # 07 NURTURE COURSE

MM : 43 TIME : 30 MIN

PHYSICAL CHEMISTRY
SECTION–I : (i) Only One option correct Type
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct. 3(–1)
1. If mole fraction of NaCl(aq) is same as that of water then molality of NaCl is
(A) 5.55 (B) 55.55 (C) 0.18 (D) 58.5
1. NaCl dk eksy izHkkt H2O ds leku gS] rks NaCl dh eksyyrk gksxhA
(A) 5.55 (B) 55.55 (C) 0.18 (D) 58.5
Ans. (B)
2. Aspartame an artificial sweetner contains 10 % by weight of nitrogen. There are two nitrogen atoms
per molecule, then the moleculer weight of aspartame is -
(A) 560 (B) 70 (C) 140 (D) 280
2. ,d d`f=e e/kqjd (Sweetner) ,LikVsZe esa, Hkkj }kjk 10 % ukbVªkt
s u mifLFkr gAS ;fn nks ukbVªkt
s u ijek.kq izfr v.kq
mifLFkr gksa rks ,LikVsZe dk v.kq Hkkj gS -
(A) 560 (B) 70 (C) 140 (D) 280
2. Ans (D)
3. A mixture containing 3 moles each of C4H8 and C6H6 undergoes complete combustion with O2 to
form CO2 and H2O. Calculate total mass of CO2 produced
(A) 1320 gm (B) 610 gm (C) 528 gm (D) 792 gm
3. C4H8 rFkk C6H6 dk ,d feJ.k] ftlesa izR;sd ds 3 eksy mifLFkr gSa ] ds O2 ds lkFk iw.kZ ngu ls CO2 rFkk H2O
fufeZr gksrk gSA mRikfnr CO2 dk dqy æO;eku gS&
(A) 1320 gm (B) 610 gm (C) 528 gm (D) 792 gm
3. Ans. (A)
4. 300 gm, 30% (w/w) NaOH solution is mixed with 500 gm 40% (w/w) NaOH solution. What is
% (w/v) NaOH if density of final solution is 2 gm /mL :
(A) 72.5 (B) 65 (C) 62.5 (D) 36.25
4. 300 gm, 30% (w/w) NaOH foy;u dks 500 gm 40% (w/w) NaOH foy;u ds lkFk fefJr fØ;k x;k gS ;fn
vfUre foy;u dk ?kuRo 2 gm/mL gks rks % (w/v) NaOH D;k gksxh\
(A) 72.5 (B) 65 (C) 62.5 (D) 36.25
Ans. (A)
5. If a solution of stearic acid (C18H36O2 ; M = 284) in benzene contains 1.42 gm acid per L. When
this solution (100 L) is dropped on surface, C6H6 gets evaporated and acid forms a unimolecular layer
on the surface. If it covers an area 6020 cm2 with unimolecular film. Find the area covered by one
molecule of acid. [NA = 6.02 × 1023]
(A) 2 × 10–20 cm2 (B) 4 × 10–20 cm2 (C) 2 × 1020 cm2 (D) 4 × 1020 cm2
5. ;fn csUthu esa LVsfjd vEy (C18H36O2 ; M = 284) ds ,d foy;u esa 1.42 gm vEy izfr yhVj mifLFkr gAS
tc bl foy;u (100 L) dks lrg ij fxjk;k tkrk gSa] rks C6H6 ok"ihd`r gks tkrk gS rFkk vEy lrg ij ,dy vkf.od
ijr dk fuekZ.k djrk gS ;fn ;g 6020 cm2 dk {ks=Qy ,dy ijekf.o; ijr ds lkFk ?ksjrk gS rks vEy ds ,d
v.kq }kjk ?ksjk x;k {ks=Qy Kkr dhft;s &[NA = 6.02 × 1023]
(A) 2 × 10–20 cm2 (B) 4 × 10–20 cm2 (C) 2 × 1020 cm2 (D) 4 × 1020 cm2
5. Ans. (A)
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 JEE (MAIN + ADVANCED) 2024
CLASS TEST # 07 NURTURE COURSE

6. 100 ml aqueous solution containing equimolar mixture of Ca(OH)2 and Al(OH)3 requires 0.5 litre of
4M HCl for complete neutralisation. Molarity of Ca(OH)2 in the original solution is :
(Assume Ca(ox)2 and Al(OH)3) are completely soluble in water ?
(A) 2 M (B) 4 M (C) 8 M (D) 10 M
6. Ca(OH)2 rFkk Al(OH)3 ds leeksyj feJ.k okys ,d 100 ml tyh; foy;u ds iw.kZ mnklhuhdj.k ds fy,
0.5 yhVj 4M HCl dh vko';drk gksrh gAS okLrfod foy;u esa Ca(OH)2 dh eksyjrk gSA
(A) 2 M (B) 4 M (C) 8 M (D) 10 M
6. Ans. (B)
7. Molarity and Molality of an aq. solution of a liquid (M.W. = 50) in water is 9 and 18
respectively. What is density of solution–
(A) 1g/cc (B) 0.95 g/cc (C) 1.05 g/cc (D) 0.662 g/cc
7. ,d nzo (v.kq Hkkj = 50) dh tyh; foy;u esa eksyjrk rFkk eksyyrk Øe'k% 9 rFkk 18 gAS foy;u dk ?kuRo g&S
(A) 1g/cc (B) 0.95 g/cc (C) 1.05 g/cc (D) 0.662 g/cc
7 Ans (B)
(ii) One or more options correct Type
This section contains 2 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–1)
8. 50 ml of CO is mixed with 20 ml of oxygen and sparked. After reaction, the mixture is treated with
an aqueous KOH solution. Choose the correct option -
(A) The volume of the CO that reacts is 40 ml
(B) The volume of the CO2 formed is 40 ml
(C) The volume of the CO that remains after treatment with KOH is 20ml.
(D) The volume of mixture obtained after reaction when treated with KOH solvent remains 10 ml
8. 50 ml CO dks 20 ml vkWDlhtu ds lkFk fefJr fd;k x;k vkjS fpaxkfjr (sparked.) fd;k x;kA vfHkfØ;k ds
i'pkr~ feJ.k dks tyh; KOH foy;u ds lkFk mipkfjr fd;k x;kA lgh fodYi dk p;u dhft;s &
(A) CO dk vk;ru] tks vfHkfØ;k djrk gS] 40 ml gS
(B) fufeZr CO2 dk vk;ru 40 ml gSA
(C) CO dk vk;ru tks KOH ds lkFk vfHkfØ;k djkus ds i'pkr~ 'ks"k jgrk gS] 20ml gSA
(D) vfHkfØ;k ds i'pkr~ izkIr feJ.k dk vk;ru tc KOH foyk;d ds lkFk mipkfjr djrs gS ] 10 ml 'ks"k
jgrk gSA
8. Ans. (A, B, D)
9. For reaction
MnO2 + 4HCl ¾¾
® MnCl2 + 2H2O + Cl2(g)
261 gm MnO2 mixed with 448 litre of HCl gas at 273°C & 1 atm pressure to produce product.
[NA = 6 × 1023; Atomic mass of Mn = 55, Cl = 35.5]
Select correct statement(s).
(A) MnO2 is limiting reagent
(B) Chlorine gas produced contains 15 × 1023 molecules.

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CLASS TEST # 07 NURTURE COURSE

(C) Moles of excess reactant left is 0.5 moles

(D) If % yield of reaction is 50%, then mass of MnCl2 obtained will be 315.
9. fuEu vfHkfØ;k
MnO2 + 4HCl ¾¾ ® MnCl2 + 2H2O + Cl2(g)
273º C rFkk 1 atm nkc ij 261 gm MnO2 dks 448 yhVj HCl ds lkFk mRikn fufeZr djus fy;s fefJr fd;k
tkrk gAS
[NA = 6 × 1023; Mn dk ijek.kq nz O ;eku = 55, Cl = 35.5]
lgh dFkuksa dk p;u dhft;s&
(A) MnO2 ] lhekdkjh vfHkdeZd gS
(B) fufeZr Dyksfju xl
S esa 15 × 1023 v.kq mifLFkr gS
(C) vkf/kD; fØ;kdkjd ds 'ks"k eksy 0.5 eksy gS
(D) ;fn vfHkfØ;k dh % yfC/k 50% gks rks izkIr MnCl2 dk nzO;eku 315 gksxkA
9. Ans (B,C)

SECTION-III : (Integer Value Correct Type)

This section contains 2 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive) 3(0)
1. Calculate the density (in gm/ml) of aqueous NaOH solution of which molarity & (w/w%) are equal
1. tyh; NaOH foy;u] ftldh eksyjrk rFkk (w/w%) leku g]S ds ?kuRo (gm/ml esa) dh x.kuk dhft;sA
1. Ans. (4)
2. If 40 gm of NaOH is added in 2 litre solution of 4M NaOH. Find the molality of final solutions if its
density is 0.68gm/ml.
2. ;fn 40 gm NaOH dks 4M NaOH ds 2 yhVj foy;u esa feykrs gS rks vfUre foy;u dh eksyyrk Kkr dhft;s
;fn bldk ?kuRo 0.68gm/ml gSA

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CLASS TEST # 07 NURTURE COURSE

2. Ans. (9)

SECTION–IV : Matrix-Match Type

This Section contains 1 question. Question has four statements (A, B, C and D) given in Column
I and five statements (P, Q, R, S and T) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in Q and R, then for the particular question, against
statement B, darken the bubbles corresponding to Q and R in the ORS. 8(0)
1. Match the column-
Column-I Column-II
(Concentration of aqueous solution) (Density of given solutions is 1.2 g/ml)
(A) 2M NaOH solution (P) 16gm solute in 240gm solution

æwö
(B) 8% ç ÷ KOH solution (Q) 60gm solute in 240 gm solution
èVø

æwö
(C) 25% ç ÷ CaCO solution (R) 8gm solute in 100 ml solution
èWø 3

1
(D) X C3H7OH = (S) 30 gm solute in 100 ml solution
11
(T) 1 mole solute in 400 gm solution
1. Ans (A) - P,R ; (B) - P,R ; (C) - Q,S,T ; (D) - S, Q

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