Sec: XI-IIT CPT – 12 Ex.

Date : 26-09-2022

KEY SHEET
PHYSICS

1 2 3 4 5 6 7 8 9 10
D C C C D C C D D C
11 12 13 14 15 16 17 18 19 20
B B C B B C C B A B
21 22 23 24 25 26 27 28 29 30
10 4 8 1 120 4 0 240 4 2

CHEMISTRY
31 32 33 34 35 36 37 38 39 40
C B B D D D B A D C
41 42 43 44 45 46 47 48 49 50
C A A D C B C C B C
51 52 53 54 55 56 57 58 59 60
98 3 128 40 24 50 4 434 1 1

MATHEMATICS
61 62 63 64 65 66 67 68 69 70
B C D C A A D A A C
71 72 73 74 75 76 77 78 79 80
B C D B D B C A C A
81 82 83 84 85 86 87 88 89 90
8 2 7 6 8 0 2 28 1 363
 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022

Hints & Solution

PHYSICS
1. (D)
2. (C)
3. (C)
 = v2/2gS
4. (C)
5. (D)
2l 2l
tp  ; ts  , tp = 2ts
g  sin    cos  g sin 

6. (C)
For upper half,
 L/
2
v=
0
a  g sin  , v2 = 0 + 2g sin  … (i) R
2
For lower half, 2
a  g(sin    cos ) , L/
  
0  v 2  2g(sin    cos ) …(ii) in mg cos
m gs 
2
= 0 mg
Solving (i) and (ii), we get v
 = 2 tan 
7. (C)
First of all consider the forces on the blocks
a
2 3
T1 T 2 T3
m m

a T1 mg mg

m 1

mg
For the 1st block,
mg  T1 = m × a … (i)
nd rd
Let us consider 2 and 3 block as a system
T1 – 2mg = 2m × a … (ii)
Solving equations (i) and (ii), we get
 mg – T1 = m × a
 T1 – 2mg = 2m × a
Adding equations (i), we get
g
mg(1  2 ) = 3m × a  a = (1  2)
3
8. (D)
Maximum value of fiction between B and ground,
= N = (mA  mB )g
= (0.5)(2 + 8)(10) = 50 N

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022
Since applied force F = 25 N is less than 50 N.
Therefore system will not move and force of friction between A and B is zero.
9. (D)
Maximum friction available to m2 is
(fmax) =  m 2g
Therefore maximum acceleration which can be provided to m2 by friction, (without the help of
normal reaction from m1) is
f max
amax = = g
m2
If a >  g , normal reaction from m1(on m2) is non-zero.
10. (C)
4g  3g g
a 
 4  3 7
6g
g  T  1 a  T
7
11. (B)
v B cos30  3
vB  2 m / s
12. (B)

dl
l   xB  xF   2  xB  xA  0
dt
 3xB  xF  2 x A 3 V0  2 V A
VA  1.5 V0
VAB  0.5 V0 (towards right)
13. (C)
w.r.t. an observer in chamber
Fs = ma Fs  Pseudo force
ma sin N

ma cos
mg sin
mg
 mg cos

Fnet (along inclined plane)

= mg sin  + ma cos  = m(g sin  + a cos )
 geff = g sin  + a cos 
Time (T) required to cover L distance along inclined would be
2L 2L
T 
g eff  g sin   a cos  
1 2
( disp. = L = ut + at ; u = 0 and a = geff)
2
14. (B)
At end P and Q

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022
T T x
P Q A h B
u u l    l
T. v  Tu T. v  Tu M
  P Q
 T.v  0
T T
 Tu  Tu  2Tv cos   0
 2u = 2v cos 
u M v
 v=
cos T. v  2Tv cos 
15. (B)
v 'cos  90     v
v
v' 
sin 
16. (C)

ma

30°
mg
mgsin30 ma cos30
a  g tan30
F   M  m  a   M  m  g tan30
17. (C)
18. (B)
TAB  m1g
2 m2m3
m1g  2  g
m2  m3
19. (A)
11g
effective g ' 
10
20. (B)
F
For pulley A, T '  ;
2
F
For pulley B, 2T = T '  ;
2
F
T
4
The block of mass 5 kg will be lifted off if,
F
  5g  F  200N (5 kg is lifted off)
4
The block of mass 10 kg will be lifted off if,
F
 10g  F  400N
4
When F = 300 N, a 2  0 ;
F F
 50  100
F
 50  5a1  a1  5m / sec2 When F = 500N, a1  4  15m / sec 2 : ; a 2  4  2.5 / sec 2
4 ; 5 10

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022
21. (10)
N
N

  60
mg sin  mg cos    tan 
  tan 30
Along incline plane
mg sin   N = ma
Perpendicular to plane
N = mg cos 
 mg sin 60  tan 30.mg cos 60 = ma
Solving, we get
g
a=  3 a  10 Ans.
3
22. (4)
Force of friction, f = mg
f mg
a=  = g = 0.5  10 = 5 m/s2
m m
Using, v2 – u2 = 2aS
02 – 22 = 2(5)  S  S = 0.4 m
23. (8)
mg = 100 N  m = 10 kg
a1 = 1 m/s2, a2 = 10 m/s2
F – f = ma1, 2F – f = ma2
24. (1)
Net force acting on the body = (s  k)mg
Acceleration = (s – k)g = 0.1  10 = 1 m/s2
25. (120)
The free body diagram of two blocks is as shown below.
f1 f2

F A R R B R

wA = 20 N f1 wB = 100 N
Reaction force R = applied force F
For vertical equilibrium of A;
f1 = friction between two blocks = wA = 20 N
For vertical equilibrium of B;
f2 = friction between block B and wall
= wB + f1 = 100 + 20 = 120 N
26. (4)
(f2 kg)max =  2 m 2g = 0.6 × 2 × 10 = 12 N
(f4 kg)max =  4 m 2g = 0.3 × 4 × 10 = 12 N
Net pulling force F= 16 N, and

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022
Net resistive force F ' = (f2kg)max + (f4kg)max
= 24 N
Since, F < F ' , system will not move and free body diagrams of two blocks are as shown below.
T T F = 16N
2 kg 4 kg
f2 f4 = 12N
4 kg, T + 12 = 16  T = 4 N
2 kg, f2 = T = 4 N
27. (0)
Maximum force of friction between c and ground is
(fc)max = (0.5)(60)(10) = 300 N
Since, it is pulling the blocks by the maximum force (without moving). Therefore the applied force is
F = 300 N
A
F = 300 N
m

(fAB)max = 0.4 × 60 × 120 × 10 = 240 N

(fBG)max = 0.3 × 120 × 10 = 360 N
Since (fBG)max is greater than 300 N, blocks will not move. Free body diagrams of block are as shown
below.
A T=0
f=0
f=0
F = 300N m T=0
fBG = 300 N
28. (240)
N1 N2
2
2 m/s 2 m/s2

N1 – mg = ma mg – N2 = ma
N1 – N2 = 2ma
= 2 × 60 × 2
= 240 N
w = 2ma
29. (4)
0.5 g  N  0.5  2
30. (2)
2T  p, a  T / m

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022

CHEMISTRY
31. If x = 4
H3PO4 + 3KOH  Na3PO4 + 3H2O
0.1 mole  0.3 mole
If x = 3
H3PO3 + 2KOH  Na2PO3 + 2H2O
0.1 mole  0.2 mole
If x = 2
H3PO2 + KOH  NaPO2 + H2O
0.1 mole  0.1 mole
So, if x = 2, 5.6 g KOH will be required.
32. In acidic medium MnO4–  Mn2+
M
n f  5, E 
5
33. n = |1 + 5  2| 11
34. 14 mole HCl loses 6 mole e –
6
 1 mole HCl loses mole e –
14
M
 eq. mass of HCl =
6
 
 14 
36.5  14
  85.1
6
n1  n2 4  2 8 4
35. n-factor =   
n1  n2 4  2 6 3
mol mass M  3
Eq. mass = 
n  factor 4
36. n-factor = |2  2 + 8  3|  28
37. In SCl2
71 g chlorine combines with 32 g S
So, 35.5 g chlorine will combine with = 16 g
So, Eq. mass of S = 16
As the mass which combines with 35.5 g chlorine is equivalent mass.
38. K2Cr2O7 + Xn+  X5+O3– + Cr3+
6  10–3  6 = (5 – n)  9  10–3 ;  n = 1

39. +3 +3 +4
KHC2O4 . H2C2O4 . 4H2  CO2

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022
M
nf = 1  4 = 4;  E 
4
40. E chloride = E element + E chlorine
E chloride = w + 35.5
 Metal is divalent, nf for chloride = 2
M
E  M = 2(w + 35.5) = 2w + 71
2
3RT U H2 50 32
41. U ms  ;    1
Mw U O2 2 800
42.
2 RT 8 RT 2 RT
43. U rms  ; U avg  ; U mp 
M  M M
U rms : U avg : U mp
1.224 : 1.128 : 1
U rms  U avg  U mp

8
44.  :v:u  2 : : 3

45. For ideal gas PV = nRT
Volume of 1 mol gas at 1 atm pressure and 273 K is 22.4 L and
at 300 K and 1 atm pressure volume = 24.63 L.
46. Real gas behaves like an ideal gas at low pressure and high temperature at this condition Z = 1.
47. Liquefaction  I. M. A. F.  a
 a 
48. At low pressure,  P  2 (V )  RT
 V 
2
i.e., PV – RTV + a = 0
RT  R 2T 2  4 Pa RT
V 
2P 2P
( 4a.P  R T )
2 2

49. van der Waal’s equation for one mole of a real gas is
 a 
 P  2 (V  b)  RT
 V 
ab a
or PV  RT  Pb  
V2 V
At high pressures, then van der Waals’ gas equation reduces to PV = RT + Pb
PV Pb
or 1
RT RT
PV Pb
 Compressibility factor Z  1
RT RT
50. Z > 1 real gas shows positive deviation from ideal behaviour when repulse forces dominate.
51. H3PO4 + 3NaOH  Na3PO4 + 3H2O
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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022
52. 0.05 moles An+ is oxidized by 0.02 moles MnO4–
5 moles An+ is oxidized by 2 moles MnO4– balance redox equation is
5 An+ + MnO4–  5A5+ + 2 Mn2+
In a redox reaction, increase in O. N. of one atom = decrease in O.N. of another atom
5(5 – n) = 10, 5 – n = 2, n = 3
53. Ratio of molecules is equal to inverse ratio of their mol. wts. If the wts. are equal.
54.
V 1 N 1 = V2 N 2
N of H3PO3 = 2  0.1 = 0.2 N
55. 6Fe2+ + Cr2O72– + 14H+  2Cr3+ + 6Fe3+ + 7H2O
n=1 n=6
By law of equivalence,
Meq of Fe2+ = Meq of Cr2O72–
1  M  15 = 0.03  6  20
M = 0.24 = 24  10–2
56. M. eq. of K2Cr2O7 = M. eq. of FeC2O4
FeC2O4 + Cr2O72–  Fe3+ + CO2 + Cr3+
0.288
V  0.02  6 =  3  1000  50 mL
144
3RTx 2 RTy
57. Vrms of X  ; Vmp of Y 
Mx My

3RTx 2 RTy
Given Vrms  Vmp  
Mx My

2 RTy M x 2  60  40
 My   4
3RTx 3  400

3RT 8RT
58. Crms  ; Cav 
M M

Crms 3RT M 3
    1.085
Cav M 8 RT 8
Crms  1.085  Cav  1.085  400  434 ms –1
59. P(Vm – b) = RT
 PVm – Pb = RT
PVm Pb
 1
RT RT
Pb  Z  b 1
 Z 1 ;    ;x=1
RT  P T RT
pVm
60. The compressibility factor of a as is defined as Z 
RT
For an ideal gas, pVm  RT , Hence Z = 1.

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022

MATHEMATICS
61. (B)
Sum of A.P. = (no. of terms) (middle term)
62. (C)
an  Sn  Sn 1  5n 2  2n  5  n  1  2  n  1
2

 5  n 2  n 2  2n  1  2
= 10n – 3
63. (D)
In A.P. sum of n terms is quadratic in n.
64. (C)
General term of the series is given by
2 n 1  1 1
an  n
2 n
2 2
Taking summation both sides, we have
S n  2n  1  2  n
65. (A)
2ce 2 2ce c c  e
c 2  bd , d  , c  b.  b
ce ce 2e
c c  e
So, 2 a  c
2e
 c 2  ce  ae  ce  c 2  ae
66. (A)
1 1 1 
an    
n  n  1  n n  1 
 1 1 1 1 1 1 1 
a1  a2  a3  ...  an   1       ...   
 2 2 3 3 4 n n 1
 1  n
 1  
 n 1 n 1
67. (D)
n
A=   nr  r 
r 0
2

 n  n  1  n  n  1 2n  1
 A n  
 2  6
68. log 5 x  log51/3 x  log51/4 x  .... upto 7 terms
log x log x log x log x
  1/3
 1/4
 ... upto 7 terms  [2  3  4  ...  8]
log 5 log 5 log 5 log 5
log x  7  log x log x
  (2  8)   (35)  35 (given)   1  log x  log 5  x  5
log 5  2  log 5 log 5
69. (A)
Sum of n rational terms cannot be irrational, cannot be infinite.

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022
70. (C)
71. We have, b3  4b2  3b1  b1r 2  4b1r  3b1  r 2  4r  3 ( b1  0)
 r  4r  3  0  (r  3)(r 1)  0  r  3 or r  1
2

72. (C)
1  1 3  1 7  1 15  1
a1   1   ; a2   1   ; a3   1   ; a4   1  
2  2 4  4 8  8 16  16 
1 1 1 1 
i.e., a1  a2  .......  an  n      .....  n 
2 4 8 2 
  1 n 
   1
12 
 n 
2 1  
   1 
 2  
 
n
1
 n    1
2
2ab
73. Harmonic mean of a, b, is H 
ab
Geometric mean G  ab
H 4 2 ab 4
Given:  , so 
G 5 ab 5
ab 5
or, 
2 ab 4
By componendo and dividend
( a  b )2 9 a b 3
 or 
( a  b) 2
1 a b 1
2 a 3 1
Again, by componendo and dividend 
2 b 3 1
a a 4
 2 or 
b b 1
74. (B)
2ab
H 4 ………………(1)
ab
ab
A ………………….(2)
2
G  ab …………………..(3)
G 2  AH we know
Or G 2  4 A  H  4
Also given, 2 A  G 2  27
 2 A  A  4   27
9
 A
2

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022
2ab
a b9   4  ab  18
9
 a  6, b  3 or a = 3, b = 6
75. (D)
A.P. 1, 3,5,7,...
G.P. 1, x, x 2 , x 3 ,...  r x
Let S = 1  3x  5 x 2  7 x 3  ...
xS  x + 3x2 + 5x3 +…
– – –

S  Sx  1  2 x  2 x 2  2 x 3  ...
2x
S 1  x   1 
1 x
76. (B)
1 1 1
Let , , ,... be an HP
a a  d a  2d
1 3 1
 4th term =  
a  3d 5 a  3d
5
  a  3d …………….(1)
3
Similarly, 3 = a + 7d ……………..(2)
From equations (1) and (2), we get
1 2
d  ,a 
3 3
1 1 3
Thus, 6th term =  
a  5d 2  5 7
3 3
77. (C)
1
x  1  a  a 2  ... 
1 a
1
y  1  b  b2  ... 
1 b
1
z  1  c  c 2  ... 
1 c
Now a, b, c are in AP
1 1 1
 1  a,1  b,1  c are in AP  , , are in HP. Therefore x, y, z are in HP.
1 a 1 b 1 c
78. (A)
1, 2, 4, 7, 11, 16,…. Here difference between consecutive 1, 2, 3, 4, 5,… are in A.P. So
an  An 2  Bn  C
1  A  B  C (Ist terms) ……………..(1)
2  4 A  2 B  C (IInd term)……………..(2)
4  9 A  3B  C (IIIrd term)…………………(3)

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022
On solving these equations, we get
3 A  B  1, 5 A  B  2
1 1
 2 A  1  A  , B   and C  1
2 2
1
So, an   n 2  n  2 
2
79. (C)
3, 7, 11, 15,…. Are in AP
1 1 1 1
Sn     ... 
3  7 7  11 11  15  4n  1 4n  3
1  7  3 11  7 15  11
Sn      ...
 4n  3   4n  1 
4  3  7 7  11 11  15  4n  1 4n  3 
1  1 1   1 1   1 1   1 1 
Sn              ...   
4  3 7   7 11   11 15   4n  1 4n  3  
1 1 1 
Sn   
4  3 4n  3 
80. (A)
Sum of Ist n odd natural numbers is n2.
1 + 3 + 5 +…+ 23 + 25 +…+ n = (n + 12)2
And 1 + 3 + 5 +…+ 23 = 122
25 + 27+…+ n terms =  n  12   12 2
2

81. (8)
1  x 1  x 1  x  ... 1  x 
1 2 4 128


= 1  x 2
0

1  x 1  x  ... 1  x 

21 2 2 2 7

Clearly the number of terms is 28.

82. (2)
Let the number be a and b
ab
A1  , G1G2  ab
2
2
b b
G1  a . , G2  a 3  
3
a a
2
b b
G13  G23  a 3  a 3   …………..(1)
a a
ab  a  b 
G1G2 A1  ……………(2)
2
On dividing equation (1) by equation (2)
G13  G23 2ab  a  b 
  2
G1G2 A1 ab  a  b 
83. (7)

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022

1 n  n  1 1 n  n  1 2n  1
n  5 n 2

2

5 6
  2n  1 15  n7
84. (6)
n i j n i

1   j
i 1 j 1 k 1 i 1 j 1

1 n n

  
2  i 1
i 2
  i
i 1 

1  n  n  1 2n  1 n  n  1 
 
2  6 2 
n  n  1
  2n  1  3
12
n  n  1 n  2 

6
85. (8)
1 1 1 1
   .......... 
10  9 11  10 12  11 121  120
After rationalizing,  10  9    11  10    
12  11  .........   121  120 
= 9  121  3  11  8
86. (0)
1 1
Tm  a  (m  1)d  , Tn  a  (n  1)d 
n m
1
a=d=
mn
87. (2)
1 1 1 1  a 1  a n a1  a n a a 
We have,   .....  =    .....  n 1 
a1a n a 2 a n 1 a n a1 a1  a n  a1a n a 2a n 1 a n a1 
1  a1  a n a 2  a n 1 a a  1  a1  a n a 2  a n 1 a a 
=    .....  n 1      .....  n 1 
a1  a n  a1a n a 2a n 1 a n a1  a1  a n  a1a n a 2 a n 1 a n a1 
 a1  a n   a1  d    a n  d   a 2  a n 1 

1  1 1   1 1   1 1  2 1 1 1
         .....          .......  
a1  a n  a n a 1   a n 1 a 2  a
 1 a n  a 1  an  a1 a 2 an 
88. (28)
a
 a  r  512
r
a
a  8   4, a  4, ar
4
a 
2(a  4)    4   ar
r 

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 NARAYANA IIT Academy XI-IIT- CPT-12 : EX. DT. 26-09-2022
1
r  2; r 
2
So terms will be 4, 8, 16
89. (1)
3
 1 2
Product of 3 G.M.’s is  4.   1 .
 4
21
21
90. j1
a j  693  (a1  a 21 )
2
 a1  a 21  66
693
Now, a 11  A.M.   33
21
Also, a 2  a 20  a 3  a19  a 9  a13  a10  a12
10
 ai0
2i 1  5  (a1  a 21 )  a11

 5  66  33  363

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