Tg rote Set of wrtter directions belltng hon to — [Ke =" a i — \ POY crriccctcton +0 Chremicye Jnmiyses tte cs [S r 20. focen, o_obtarming si ic i F cal altdad : , | — —eaateticad Metrocoloss: —~j 4 =p Understnading anc) defining the prablean es Focctliatze witth bockgraurd of problem a hisby of sample + 7 amelrag. = freparcitoo G pretreatrrnt of s. mt \ =p Litecgture “Seorch ao Analyse PPO renuiteed stattstcas techn | =r Nectfy Cesutls fort Regattas Classrfreation of yee Techomus al Closstca9 Metnool» . “etn pie metieds 'S Classic Lwetchomnrcad [equiva “Nig staua_&nstumen’ | nethads of analyss telied ore _Uued fo study Praperdien of aralyes wa change & color & scanned with OKEN ScannerW2Gomplpeatt?on GF ONO nn ones pots ext @ oldstll”. J anoyle Jrom malse using ppt, Detaled classtPrearteas 9 $$$ Se @rowmete methods delamina the cnass of analye hromecally elated fe ft: e — _ a Nlolumetrte methods neanure tha volumes of a u PPeofert \_ react completely mitts “tho analyte. 3H Cleckoanalytcal ethads Priaive the Mearurerent o& electfal prpertien such a» Naligge, CUrrent , reststang and Quanity, of electteal charge | Ua] _Specbascapte_methads are bases) On- the measur ientnt of the folernottan between electromag neti. peidtatim _ rc af such radfattos by analyles. Si Meccellanecun Methads induce tho Meaputement | of such quanttires G» Mass -to-charge (OHO, t ‘ Irale_o& OdfanctNe decay, heat and rale of remote, Yareat It He teal acersf Ry and 4 | x cefra fe —tndey , % * x SL x 7 ype 2 | & > enpapect mensuced ieee wa” UY pis Malad Number Nalume 1 M fro Forrnatthy, Num ber Volume € eng L_Noarenabety Number Nalume Ni arena Lo TL motatiity Nvuce Ber ~ 4 wWerght m anol _by— & scanned with OKEN Scanneri0 2 (Pte Of Soluttan at -equelebaisen | = Parts per meliton (ppm) = Mass of sdule Mass of sample sis ong [L = pem | | Pacts per, beitan (eeBy= Mass of eal 10 2 1 ™Mass of sample , [Or wg Le pre : —— farts per +rellton (pet) = Mass ofA salule jos Mass af sample Or Ag! t= ppt Jo ULLAL el LI / & scanned with OKEN Scanner| Preparattan of SalutidO ——— 7 usuad slep:_Wetgh_cestam aty.of reagent —G AtSSolve - eee ef? ~ ql 6 a_solventto wolumette— flank > fs: re en solvent volum fh Accuraey ts\ emporiant Ad x x x x i [ How to prepare Lf. VIN thane Po water 2 “Take _£ ml_ethane|. 2 f£00.m) ernpty Pladk tor Pg | _Standarcl Ovemtons Traceclure (SOP) = | re. fl ena peers natty are cleserfthed, by a SOP — Ths Sof fodtmies how we pocese tae ) Shdes hoyl_wie Separate ‘tho analyie Prom patentral - Pnker Pereaig et a Pp Sh ons_hon!_We Staodardtze tho method 6" - : & scanned with OKEN Scannerl | eee WY ay & scanned with OKEN Scannerale _pINo forgone Set | Colicuflale _pNo_. ttre 809: On c ste pene a nck deel NY =~ L0G 19 (5:28) +? 4 2-23 | | Good LaborsinyPractrees _(Gitts) —___— uM “Tha broad) degentttao: encampasses $Ssuts sioh — as_meéthoc! 02 the laboratacy Manag efor 7 Personnel factltien aqurement, operations Methoc! veailidaten —equalfty assuarance and tecars) keepPog. Ls des rato oH that we must follow fn any analysts These off reco i! rds hain ~of - to, Orr's: Pox _Sarmplen. speorhying aod purPytng charne col. - 2 21. ni — Organic pemsrelt . ruyderoperoxiclen :- Organre camp und — & scanned with OKEN Scannera eA Pe classmate Ca—=O = a =a | budeageo pensxtte —lbere ena or_mort 0 the hydhaany FB cecctsattbte Ino = Any liq that hap a Plot pitt at or ahov, cate — | and below 9a0°F | 9a°c Ct r a —— oS f ¥|| Clommable Gao: Placmab: ic icnth ia | pressure €XCepleng HOpSi (275 ka) absolute at Jane (as A £ || Flammable leq = Any (raul hautng a flash pt_belan 105F/a8¢. #1 Coostve Calectat PB lquicl or soled thal Causes vfs?ble Aertructtan “ar Prreverseble” allercatrons #n bumnan. shen, tfssus at the fle o2 contact. o, lig that hay a Seuene OREM s 41 Etfolag tc agent - a fe © Pls to) “nibtch Cause OF Chay couse human fee = : hich: oe -— Lm fantzalon Od tahon' ee subl. Mag. tO) reqitre - ( a p git, +o cause aur ea “ S a. or detonate °r arr. & scanned with OKEN ScannerMafor al teal g fnfury. Do net & Bho < expose any bady surface fo this maserral oy Expose may be hazarclous to heath. Protcceite 2 Measures are endicater i ese Moy coum PrrPlaton / minoe fnpury _ b= Expo! fers No sf Gh ek tn heath _—s- arr Fe) pies & scanned with OKEN ScannerE FP below m f= FP above Lr (Reo tutte tozerd) a = Sub: aby abate fo} Bret Ay capable of defanaten —~\— Ssure . = Substances oA A ree nifty Waker. 2 Mo. ce. te a 8 JEMP@ PSSUH ATI a PB a? expdater & scanned with OKEN ScannerFre TP. OX? on fs = —~ :, Ff Sbaibie selé hegh rq ne sro Pt ie ob oe P bron. & scanned with OKEN Scannerfe a, fopulation i Set o@ ol = oP Creasey elie ? Sample = Set of data catiecs . eleetety. shigatiny | in a Ms ann ea delined di. “aa = “Casras -SMauld pass be ia Malerta. hose esmpasition rears pea | of the Materrae being sampled. Thrs ts fa “Same os oa Pinile Curnber of Perry a lahon, The _compostifen 0% Section cunt ae 03 closals ak possrile “| ee ct ean Stotfsticos to dis Meo a | Tyres of sam) Ple_analy: Tago ersten RN a pA t Spee spem ate ler Loh Parmpe—ste-e 6G} Prayle Tevet for sein Ae ice Ud bbe lean G pnert 40 _axiot) conkrmenes + Preserve befo gross _(inttfat [prema fo a moe analyeatle / - & scanned with OKEN Scannersh mi 1 Methods Por reducing Stree oe 8 le particles -- — Blender p25. —_ Crane — > Bindin, — Hom name Mae, eee NTU Cea ae Mince ——_ Prersen. = Puier: — Greve Leelee Rardomt collect sted 2 2 guss sample se parte a and homogenize [ES fro sarmpe labo & scanned with OKEN Scanneri Qy \ aie Bal re ben :- LF coird-tequed extraction. Soxhlet exrtocten, Parced- flor (coches. homogearzation, Sanication anc) dtsscuWoo ee | Modern techniqua Accelerates! ‘Solvent er tractron Supercerter cal. | dlued edttrocttan | mrcrowiave -asstsstec) extraction thamak = _extracl-tan Mextog Sated Sameles:- = Common method of mtxing Ponder Relitng-sempleon_sheer of glazed paper 0 we Pre O2 Substance: plcicec Repeated) many times TH ON cenee G_entxed ty [tPling ade Corners oP tte tte sheer | 4 comer of paper (PPrec alknately j y x x *<. SS ef Al Dillerent Methocls for Lignizl= Sampling WK et re S See 7 J passed) througin a solid) phos whith Sele level i tha analyte Thetiafler, +re ANayle can be th oO. Strong Solvent : i = o rel a . : 2 ; j ; : a — - : Z LE | bh 2 Pmmmscible phase. nat ef Psatubility oe a oe fe reliable ruth cannes by ob Ly a a & scanned with OKEN Scanner_S— fae, fs tha eluant of ithe separatian eys (€g!* LC) to Gvord > Prasue ith Plonfng aie or pnett Gas or va. 22m Shoutdr't be pesRumec! foo auiichly G bumping —> samp hy, exoporate: f Quito. Sys (eg» TurboVep> “Drstellattoo = + Sornpte e PE oe solv . Gndtylen oes en) Othe lle Used for samples eanrly VOlatnlrzed —Semples_can_clecarnpose jf temp. toa bfgh > pS. Noccum dfsirvat? i> for EB Steam. Ats tay? + — (Mg; teme 'g0T a | Mecro dghyas Some perneable membrana 5 Ow Moa! Q Aca va rd) GMPle vol. Gn be hordleo & scanned with OKEN ScannerEx is of Sel To. M ert +h _Speed, igh Sensrtrurty, low lim of d a sample W/o loss / enka rane? ry and ticemetry (onSse) paren among claia bt. fo_sace or enterrmediale error LOO 4 & scanned with OKEN Scannerreer Cee =~ ps ablety, Dcscremenate Pit S Mate —— | Meas ure a? diflerences eo _analyfe con ° —| Seas ptevety Ps ecurmaten fo —p 2 a eonsinar Ke 19 , = Keene ori Speke Ca =P_BSy ps the alten iP/ that we cao Meovuss 8 Piss sentimental 2 ; to establish that dpphrerce bln sample Cio SAgnittees. —— | bh 2 Stonals phon, the smalbst delectable il? in absalak amt’ / relate crab of) Qnatjle C= eI Ce ae Cree i See egse a 4 Gh Greceercry Qs Serecervary (Kae) ——t|_ An _analytfeas method *s Speerfec *f Signak clepenos on_ths_anatyle SpestPicry is reco, Githar 0% (PB fee 0. Seams Se + =a Same= Sat Sr= BaCat Bocr & scanned with OKEN Scanner| AnowkesSensrnts fy = mjpsj 1 a ~ there M= Sapa o Coltbrafon qué al Ss = Standigns clerraran A (reaselr———$$—_ Seta qr, bots = + OF LOG = ie foie ee LOR = Liner, Dycamk Range. : Cm = Delectton gem _= Cond? dldesled woth Con fading Pll LOM, you uit get Lfnear stgna! a 7 “Resut shoud be sq LOM 6 LOL 90 ae [Sion Lecance : ea | mia” G mas” cone” which gray |! i —— ae irae & scanned with OKEN ScannerSS C=O = fo 2 20 strmwot 1) ee OR er 2™ conc*/mams a2 Gnalyle that Con be fenomo —confrdence Lovel Hoof Magnttucdia 512 analyte ow ze fO__Si2e 08 Slatistrcal fluctuatons iO he blanked. Srgnes fom Suitable plank Nust_hyeo! Attanak MPO + + Zea Fay. aS ‘Signal Po Consumin, TP COD, PF eReMCey 5 v2 sare ty Pee OS & scanned with OKEN Scannerae cy oy a C Scale Dis SS Gample_si2e_and Ve_€0nc?_contetn') & scanned with OKEN Scanner& scanned with OKEN Scannerall Lectoup Soo ee (alae = ae | ae = —— = __7& | Eaaors : Meantlys ee | Ff Atty, th a | second. denote tha estén ncerkarrs A * Ac YRACH. i — tad a ac _Accepless value OQ fs expensed bj error. —t Exprssec! pn tems _of absolik ar_elativ< erro ene *f €, = Oblotned) redult — expected reals ! a -ompected resudt ee * || Pbsoluk Eero " ss i tee absowwk error Ce) fs tha! meat of | IE fas ops =lo/ a Measures | clos chy Sacra soy, a el of acho & scanned with OKEN Scannerset to dip~Rr Exot ____— aia ge ee 3 ag . . . & scanned with OKEN ScannerL Dus ta human errors, oCCur oCCadionally Gross _€cror i 7 a — May cou a rdutt to be efttur high OF low i ce Oni a mMeosuurens that duller sqm Picante from tre rest SH £ yr TBuching o bette pith boges sah _Meavry fom a slo gtnimnertes CPs Example > @) Pipette, turetia hold noe (ler Volume © DBtortten tn _orfgtnat calpbrab'os al Q@) Cleotra nic in frunmns hosing Pp Msiumentas gys- errors @ Nottage ce battery operalee by Porer suppl J by we ©) Temp effect, catebraten changing Wh fergp ethod 6 | a aa = of Most re re, possible _ || accorence 0? stile reactfan tha Prkréow wiih —MeOrunementr POC plore: fersonat Errors Zs || Examoes = ©) Colour ce sal ab ond ptt f¥trabion — |) Esteroattry past? 2 stale dviv'a s tea foduettion a bia» a _—— tre es true & scanned with OKEN Scanner| b Se F Feo = Henly ‘ E Ge)\G less than batioy of 400 g .500 pe: uu2 < uso hence rounds OF ty (2-4 Pee o i. ee ee bE is 9 Bo 2-8 : | Reas02:+ Ce USO. Hence 12-S— 2? Example- TP exact hatlway treo, found oft _te neorel ever Dumber Pann G2-5£0) | v & scanned with OKEN ScannerS] Sal f ‘le Ge Srvloo = Ee (00. _ Nactanee Nod fon ce = pi _Prerage squad devtatfon 0? mndnrdua® cout from tho Mean : isfc tye £ “ee & scanned with OKEN ScannerMedian Per od) 9 —+ Centred vadue RS TC! Ga Pa tagat > Xsmaltost ; Sta dew = Be, Soyre > SMS 25 n0 oe eee 2 S yeah Nastance = 33— eee vole tty BS Ras at SS Bee Sic ain ws ECFSIO9 = Meare of SPAS of lata cibout ACen ira onditions (Include ag4 3 aT Be gysem fb Dati to onody & scanned with OKEN ScannerZ. on idence emer.) — For stage sample, o:s e390 Xp = ch 2 ep =e) OS: 26 €or Whar sever. | B6.64 for arnt of asprin = 1 -S+Aigle tabter— 196 95.60 whe win 259 4 2-00 Os 4uy Gos cag 2:50 98:76 7 a ORE ia = Of 2-5 3.00 99:73 a BS0 99:9S— = eras coos Dinas Une nailenwaolchwrie coh Wecaupieaen pel few p icl_cey_@ vralus of single drawn the = i et : eal. r Ot aspirin Par-a_baten, Random aber fakin nim is mg oaprin. Whar Ssh Cr 2 pieona= PUT t 27 = Lust uiny. probabeltty that pap!? Mean [res b/s 2.31- 269 ad error of Mean tobs with rneca B96 x7 & scanned with OKEN ScannerZe Standara Score wate cualt) Pa Ze xX-H Gee ae yuidh = ae reales of vavfonces ins callie! clegstte OF v aoe | P | E — E i | E — be = fr cae fe fat \o - Do-f= t cae - es ToT oe 2 Usa = i Ag ee Poros 3 gig = 2-51 & 2-Us~ NUE bypotheat, Cue): DiPPerence bli 2 vale can ; t z i : a soi le fb t Lar. Alternative Hy pothes (ua): DrPPerance bi 2 valu — too. great_to be é€aplarred by PNdekyninak Error. — & scanned with OKEN Scanneraaa Ecrors tn stg mftcabce Teateng t err se ie ee aan —~T *Tjpe 1 Brroc Type 2 Leror oo Rik oe Jalsely rgfecting Rak of fabely | the guste hypothesis (x) f acceping the oe | probability P type 1 error 1s in to prob: A yee 2 error = e Gompams 0 w= xt teapS S| el oe a GmMpaimy s* to oe a) ‘ ; aE (nhe sizs) = anes : wrth Mean A Mean is 10 Cr op 9571 fe sampla dare som pp ae gives idea Abowt precksic _____—— + Precrsion Oe preene j & scanned with OKEN ScannerMt oe Lal en ou pnivioys «5 known for many bundhede anal have a sli dey of O-2 ppm of CO of dot. 12. “12 ppro +30 = eps. Si- Olspem (Mont Sa- O12 ppm _(_Mod-2 & scanned with OKEN Scanner_Amalysis oF @ calcclo Sampe ‘ylelel toh ae 55°95, 56:00, 56:0u Show) t+ be retained or repecles) at Ot ce yihere O Crtitend = 0-1 ! Oe Seep ee _ o Is: O53 56-23 S595 02 . oe «© <@ + le: |_Gjcubb's Tek es i ‘oop + [o-orse+ (0119 & scanned with OKEN Scanner= Y Gignat) ay ae Se fF 2.96 2.96 ( 27 7 5-06 (ote 4 2-6 a os 705° 2S 3 43-70 ——— 4 92. 3x66 16 19-56] ona (od BaT 2 (13:65 aa p SZ y= BU.83 Zar idan F9%~ sv PA <= | Forroulae & scanned with OKEN ScannerSy >— he Co b Seid fst Pee 2) Ssare _[osnlt Beats (emery & scanned with OKEN Scanner= 6 i Single Point vs e " 2D cd A Single standard containing i OAs ee age ; i i él (n ’ aun a | Ne. U = ’ Shi), 4 is used io pnany laboratories WAleothe_* \ ant. ee ' [TD _coutttple = _Slandordizaten ab [east stander sud & scanned with OKEN Scanner6 _ classmate 2) oA RN) Covel wf + GC Ve/yr) sa = (Sb. GraNod Ne/ Ssprte~ Sp ) z O'1Sd Ne = tmu ——~ Ip = SL aol + futl 1560 ppb St pbt?— = OuUlS Seog bors SRS gn? ge PEI in Pinel nek 2. 0-199 = jal es — Cae — oz] “) O-ul = eS lian: ee | Dossy Issowio™ o-uls = a'(s3) & scanned with OKEN Scannerclassmate Date set } =(ave Css eee ve Ne E “| M= Bow i _ -iolen cept = _baCare FOr_A-Fotereps Y =9 - ae ie btloe bp Gus =CeVa Ve ve & scanned with OKEN Scanner(S€o ppb Ve = Sm Bie mh ~ ~Is E | S. Ss 5S For a-iokneA, yo Bli27x\y= — 9-266 ~ 2. SSE — es one 0.266 ee Biz Cok O-266 iSGOe (3S ppb dl & scanned with OKEN Scanner2wt cla (600 ppb Pb" 5 Smy , on spt O:$00. Pemmina dre conc | ot Pv 3m originad Sample of _bloach 2 f TP Seyre ss 4 g S samp -— OO 4 § (609 eve Olu cA Ca xf E ‘ US So= 14+ 16oo ye? t Gus = @S356 ppb = Amount of Pet in Orginal sample js 0-35 ¢ Q G_Semi-valaffle Compow do_oat tale same sarcompeuod Qs sta Standard Shousenor _oveilop— Forew sd 9, — 4 & scanned with OKEN Scanneresignment : Gees © Shs, ce @ Saus.c a . me 2 TOME OSS NMBNT. a & scanned with OKEN Scanner